JPH0853737A - High strength and high toughness hot-dip plated steel wire and its production - Google Patents

High strength and high toughness hot-dip plated steel wire and its production

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Publication number
JPH0853737A
JPH0853737A JP18964494A JP18964494A JPH0853737A JP H0853737 A JPH0853737 A JP H0853737A JP 18964494 A JP18964494 A JP 18964494A JP 18964494 A JP18964494 A JP 18964494A JP H0853737 A JPH0853737 A JP H0853737A
Authority
JP
Japan
Prior art keywords
steel wire
hot
strength
plating
subjected
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP18964494A
Other languages
Japanese (ja)
Other versions
JP3246210B2 (en
Inventor
Masato Shikaiso
正人 鹿礒
Nobuhiko Ibaraki
信彦 茨木
Kenji Ochiai
憲二 落合
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
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Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP18964494A priority Critical patent/JP3246210B2/en
Publication of JPH0853737A publication Critical patent/JPH0853737A/en
Application granted granted Critical
Publication of JP3246210B2 publication Critical patent/JP3246210B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Coating With Molten Metal (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)

Abstract

PURPOSE:To develop a high strength and high toughness hot-dip plated steel wire excellent in corrosion resistance by subjecting the hot rolled material of high carbon steel to patenting treatment, thereafter subjecting it to cold wire drawing to form into a steel wire, subjecting only the surface to tempering treatment and subsequently applying plating of Zn or the like thereto. CONSTITUTION:A high carbon steel contg., by weight, 0.7 to 1.2% C, 0.5 to 2.0% Si, 0.2 to 1.0% Mn, 0.02 to 0.07% Al and 0.003 to 0.015% N, furthermore contg. specified small amounts of one or more kinds among Cu, Cr, Ni, Co and W and moreover contg. one or more kinds among V, Nb, Ti and B is subjected to hot rolling to form into a wire rod. After that, it is subjected to patenting treatment or is subjected to patenting treatment after reaustenitization to form into a steel wire rod having a main structure of fine pearlite, which is thereafter subjected to cold wire drawing to form into a steel wire having a required diameter. Next, only the surface of the steel wire is subjected to heating and tempering treatment by the induction hardening method, etc., and is thereafter applied with galvanizing or Zn-Al allay plating. HV/TS, i.e., the average Vickers thickness of the steel wire stock to 50mum toward the center of the steel wire from the boundary of the plating layer and the steel wire stock to the tensile strength TS (kgf/mm<2>) of the plated steel wire is regulated to <2.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、PC鋼線、亜鉛めっき
鋼撚線、バネ用鋼線、吊り橋用ケーブル等に有用な耐食
性に優れた高強度高靭性溶融めっき鋼線の製造方法に関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a high-strength, high-toughness hot-dip galvanized steel wire having excellent corrosion resistance, which is useful for PC steel wire, galvanized steel stranded wire, spring steel wire, suspension bridge cable and the like. Is.

【0002】[0002]

【従来の技術】耐食性が要求されるPC鋼線や吊橋用ケ
ーブル等の高強度線材を製造する場合、ある程度の線径
を有する高炭素鋼線材にパテンティング処理を行い、さ
らに所定の線径まで伸線加工して、その後耐食性を付与
するための溶融Znめっきが施されるのが一般的であ
る。しかしながらこの方法では、伸線加工後に400℃
以上の高温での溶融めっき処理を行うため、せっかく伸
線加工によって向上した線材の強度が、再び低下してし
まうという問題があった。また伸線の度合いを増大させ
て強度を高めれば高めるほど、めっき処理による強度低
下が大きくなるため、結局この方法ではめっき鋼線の高
強度化が困難であった。
2. Description of the Related Art When manufacturing high-strength wires such as PC steel wires and cables for suspension bridges, which are required to have corrosion resistance, high carbon steel wires having a certain diameter are subjected to patenting treatment to a predetermined wire diameter. In general, wire drawing is performed, and then hot dip Zn plating for imparting corrosion resistance is performed. However, with this method, 400 ° C after wire drawing
Since the hot-dip galvanizing process is performed at the above-mentioned high temperature, there is a problem that the strength of the wire material improved by the wire drawing is reduced again. Further, the higher the degree of wire drawing and the higher the strength, the greater the decrease in strength due to the plating treatment. Therefore, it was difficult to increase the strength of the plated steel wire by this method.

【0003】そこで、高炭素鋼線材のC含有量を増加さ
せて強度向上を図ることが、安価で効果も大きいことか
ら、工業的に望ましい方法として検討されている。しか
し、C含有量が0.9%以上の過共析領域では、パテン
ティング時にオーステナイト粒界に沿って脆い初析セメ
ンタイトがネットワーク状に生成するため、伸線加工時
に初析セメンタイトの割れを起点とする断線が発生し、
伸線加工性が劣化するという問題が新たに生じた。
Therefore, increasing the C content of the high carbon steel wire rod to improve the strength has been studied as an industrially desirable method because it is inexpensive and has a great effect. However, in the hyper-eutectoid region where the C content is 0.9% or more, brittle pro-eutectoid cementite forms along the austenite grain boundaries during patenting in the form of a network. Disconnection occurs,
A new problem has arisen that wire drawability deteriorates.

【0004】一方、Siは、パテンティング処理後の鋼
線強度を高め伸線後の鋼線強度も向上させる効果と、鋼
線の焼入性を向上させて初析セメンタイトの析出を押さ
える効果を持つ元素である。また、これらの効果だけで
なく、めっき処理による強度低下を抑制する効果も有し
ており溶融めっき鋼線の高強度化には非常に有効な元素
であるが、過剰な添加が鋼線の靭延性を低下させること
も知られている。
On the other hand, Si has the effect of increasing the strength of the steel wire after patenting and improving the strength of the steel wire after drawing, and the effect of improving the hardenability of the steel wire and suppressing the precipitation of pro-eutectoid cementite. It is an element that has. In addition to these effects, it also has the effect of suppressing the strength reduction due to plating treatment, and it is a very effective element for increasing the strength of hot dip plated steel wire, but excessive addition causes toughness of the steel wire. It is also known to reduce ductility.

【0005】そこで、Siを有する高炭素鋼線材に、溶
融めっきした後、加工や熱を加えることによって、高強
度高靭性を有する鋼線を得ようとする提案がいくつかな
されている。例えば、特開平4−246125号では溶
融Zn−Alめっきを施した後に矯正加工およびブルー
イング処理を施す方法が開示されている。また、特開平
4−236756号、特開平4−236742号には、
溶融Zn−Alめっきを施した後に伸線加工および加熱
処理を施す方法が開示されている。しかし、吊橋用めっ
き鋼線のようにめっき後の鋼線の加工ができない品種の
場合は、これらの従来技術を応用することはできない。
Therefore, several proposals have been made to obtain a steel wire having high strength and high toughness by subjecting a high carbon steel wire material containing Si to hot-dip plating, and then applying working and heat. For example, Japanese Patent Application Laid-Open No. 4-246125 discloses a method of performing a straightening process and a bluing process after performing a hot dip Zn-Al plating. In addition, Japanese Patent Laid-Open Nos. 4-236756 and 4-236742 disclose that
A method of performing wire drawing and heat treatment after performing hot dip Zn-Al plating is disclosed. However, in the case of a type such as a plated bridge steel wire for suspension bridges in which the steel wire after plating cannot be processed, these conventional techniques cannot be applied.

【0006】他方、鋼線表面の残留応力を圧縮応力とす
ることによって、捻回時の縦割れが抑制できることが知
られており、例えば、特公平3−66386号には表面
の圧縮残留応力を特定範囲に制御した鋼線が開示されて
いる。しかし、この様に残留応力を制御しても、溶融め
っき工程を通過する鋼線の場合、線温が上昇してしまう
ため残留応力の効果はほとんど得られない。
[0006] On the other hand, it is known that by using the compressive stress as the residual stress on the surface of the steel wire, vertical cracking at the time of twisting can be suppressed. For example, Japanese Patent Publication No. 3-66386 discloses the compressive residual stress on the surface. A steel wire controlled within a specific range is disclosed. However, even if the residual stress is controlled in this way, in the case of a steel wire that passes through the hot dip plating process, the effect of residual stress is hardly obtained because the wire temperature rises.

【0007】[0007]

【発明が解決しようとする課題】本発明では、めっき工
程を通過しても、良好な捻回時の縦割れ特性と回転曲げ
疲労特性を有する高強度高靭性溶融めっき鋼線とその製
造方法を提供することを目的とする。
DISCLOSURE OF THE INVENTION In the present invention, a high strength and high toughness hot dip galvanized steel wire having good longitudinal cracking characteristics during twisting and rotary bending fatigue characteristics even after passing through a plating step and a method for producing the same are provided. The purpose is to provide.

【0008】[0008]

【課題を解決するための手段】上記課題を解決した本発
明の高強度高靭性溶融めっき鋼線は、 C:0.7〜1.2% Si:0.5〜2.0% Mn:0.2〜1.0% Al:0.02〜0.07% N:0.0030〜0.0150%を含有し、残部Fe
および不可避不純物からなる高炭素鋼線に溶融めっきを
施しためっき鋼線であって、めっき層と基材の界面から
中心へ向かって50μmまでの基材表層部の平均ビッカ
ース硬さHvと、めっき鋼線の引張強度TS(kgf/mm2)
の比:Hv/TSが2以下であるところに要旨を有す
る。
The high-strength and high-toughness hot-dip galvanized steel wire according to the present invention, which has solved the above-mentioned problems, is C: 0.7-1.2% Si: 0.5-2.0% Mn: 0. 2 to 1.0% Al: 0.02 to 0.07% N: 0.0030 to 0.0150%, balance Fe
And a high-carbon steel wire consisting of unavoidable impurities, which is hot-dipped galvanized steel wire having an average Vickers hardness Hv of the surface layer of the base material of up to 50 μm from the interface between the plating layer and the base material toward the center, and plating Steel wire tensile strength TS (kgf / mm 2 )
Ratio: Hv / TS is 2 or less.

【0009】また上記高炭素鋼線は、さらに、Cu:
0.05〜0.5%、Cr:0.05〜1.0%、N
i:0.05〜1.0%、Co:0.05〜1.0%、
W:0.05〜1.0%の1種以上や、V:0.05〜
0.5%、Nb:0.01〜0.2%、Ti:0.01
〜0.2%、B:0.0005〜0.0050%の1種
以上を含有していてもよい。
The high carbon steel wire further comprises Cu:
0.05-0.5%, Cr: 0.05-1.0%, N
i: 0.05 to 1.0%, Co: 0.05 to 1.0%,
W: 0.05 to 1.0% or more, V: 0.05 to
0.5%, Nb: 0.01 to 0.2%, Ti: 0.01
.About.0.2% and B: 0.0005 to 0.0050% may be contained.

【0010】本発明のめっき鋼線において、めっき層と
基材の界面から中心へ向かって50μmまでの基材表層
部の平均ビッカース硬さHvと、めっき鋼線の引張強度
TS(kgf/mm2)の比:Hv/TSを2以下にするため
に、上記高炭素鋼線に、熱間圧延後直接パテンティング
処理を行うかもしくは再オーステナイト化後にパテンテ
ィング処理を行って微細パーライトを主要組織とする鋼
線とした後に冷間伸線を行い、この冷間伸線後の鋼線の
表面のみに焼戻し処理を施し、次いで溶融ZnまたはZ
n−Alめっきを施す方法が推奨される。このときの、
焼戻し処理手段が、高周波加熱法またはレーザー加熱法
であることは本発明法の好ましい実施態様である。
In the coated steel wire of the present invention, the average Vickers hardness Hv of the surface layer of the base material up to 50 μm from the interface between the plated layer and the base material and the tensile strength TS (kgf / mm 2) of the plated steel wire. Ratio: Hv / TS of 2 or less, the high carbon steel wire is directly subjected to patenting treatment after hot rolling, or patenting treatment after re-austenization to make fine pearlite a main structure. Cold drawing is performed after the steel wire has been formed, and only the surface of the steel wire after the cold drawing is subjected to tempering treatment, and then molten Zn or Z
A method of applying n-Al plating is recommended. At this time,
It is a preferred embodiment of the method of the present invention that the tempering means is a high frequency heating method or a laser heating method.

【0011】また、めっき層と基材の界面から中心へ向
かって50μmまでの基材表層部の平均ビッカース硬さ
Hvと、めっき鋼線の引張強度TS(kgf/mm2)の比:H
v/TSを2以下にするために、焼戻しではなく、冷間
伸線前の鋼線に脱炭処理を行う方法を採用することも本
発明法の好ましい実施態様である。
Further, the ratio of the average Vickers hardness Hv of the surface layer of the base material up to 50 μm from the interface between the plating layer and the base material and the tensile strength TS (kgf / mm 2 ) of the plated steel wire: H
In order to reduce v / TS to 2 or less, it is also a preferred embodiment of the method of the present invention to employ a method of decarburizing the steel wire before cold drawing instead of tempering.

【0012】[0012]

【作用】まず本発明のめっき鋼線の最適化学成分限定理
由を説明する。 C:0.7〜1.2% Cは、鋼線の強度を上げるために有効な元素であり、経
済的でもある。C含有量が0.7%より少ないと、鋼線
の強度向上効果を発揮するには不充分である。しかし、
C量が1.2%を超えると鋼線の延性の低下が顕著とな
る。
First, the reason for limiting the optimum chemical composition of the plated steel wire of the present invention will be explained. C: 0.7 to 1.2% C is an element effective for increasing the strength of the steel wire and is economical. If the C content is less than 0.7%, it is insufficient to exert the effect of improving the strength of the steel wire. But,
If the C content exceeds 1.2%, the ductility of the steel wire will be significantly reduced.

【0013】Si:0.5〜2.0% Siは脱酸剤として働く上、フェライトに固溶して、固
溶体の強度を顕著に高める効果がある。さらに、フェラ
イト中のSiは、伸線後に行われる溶融めっき時の強度
低下を低減させる効果がある。これらの効果は鋼線中に
Siが含まれていれば認められるが、より顕著に発現す
るのはSiが0.5%以上のときである。しかし、Si
を過剰に添加すると、伸線後の鋼線の延性が低下するの
で、Si量の上限は2.0%とした。
Si: 0.5 to 2.0% Si acts as a deoxidizing agent and also has the effect of forming a solid solution with ferrite to remarkably increase the strength of the solid solution. Further, Si in the ferrite has an effect of reducing the strength reduction during hot dipping performed after wire drawing. These effects are recognized when the steel wire contains Si, but the more remarkable effect is when Si is 0.5% or more. But Si
However, since the ductility of the steel wire after wire drawing is deteriorated, the upper limit of the amount of Si was set to 2.0%.

【0014】Mn:0.2〜1.0% Mnは脱酸剤としての効果と、鋼線の焼入性を向上させ
て鋼線の断面内の組織の均一性を高める効果を有する。
しかし、Mnを過剰に添加するとMnの偏析部にマルテ
ンサイト、ベイナイト等の過冷組織が生成して伸線加工
性が低下するため、含有量の上限は1.0%とした。
Mn: 0.2 to 1.0% Mn has an effect as a deoxidizing agent and an effect of improving the hardenability of the steel wire and enhancing the uniformity of the structure in the cross section of the steel wire.
However, if Mn is excessively added, a supercooled structure such as martensite or bainite is generated in the segregated portion of Mn to deteriorate the wire drawing workability. Therefore, the upper limit of the content is set to 1.0%.

【0015】Al:0.02〜0.07% Alは脱酸剤として、またNとの複合添加によりオース
テナイト粒度の粗大化防止に有効である。しかし、添加
量が0.02%より少ないとこの効果の発現が不充分で
あり、過剰に添加すると窒化物量が増加し過ぎて伸線性
を悪化させるため0.07%を超えて添加してはならな
い。
Al: 0.02 to 0.07% Al is effective as a deoxidizing agent, and is effective in preventing coarsening of the austenite grain size by adding N together. However, if the added amount is less than 0.02%, this effect is insufficiently expressed, and if added excessively, the amount of nitride increases excessively and the wire drawability deteriorates. I won't.

【0016】N:0.0030〜0.0150% Nは鋼線中でAlの窒化物となり、加熱時のオーステナ
イト粒度の粗大化防止に有効である。添加量が0.00
30%より少ないとこの効果が充分発現されない。また
0.0150%を超えて添加すると、Alの窒化物が増
加し過ぎて伸線性に悪影響を及ぼすだけでなく、固溶N
が伸線中の時効を促進することがあるため上限を0.0
150%とした。
N: 0.0030 to 0.0150% N becomes a nitride of Al in the steel wire and is effective in preventing coarsening of the austenite grain size during heating. 0.00 0.00
If it is less than 30%, this effect is not sufficiently exhibited. Also, if added in excess of 0.0150%, not only does Al nitride increase too much, which adversely affects the wire drawability, but also solid solution N
May accelerate aging during wire drawing, so the upper limit is 0.0
It was set to 150%.

【0017】本発明のめっき鋼線は、上記必須成分を有
し、残部Feおよび不可避不純物からなるものである
が、次に挙げる化学成分、すなわち、Cu、Cr、N
i、CoおよびWよりなる群から選択される1種以上、
あるいはさらに、V、NbおよびTiよりなる群から選
択される1種以上の化学成分を積極的に添加した鋼種に
おいても本発明法を好適に用いることができる。
The galvanized steel wire of the present invention has the above-mentioned essential components and is composed of the balance Fe and unavoidable impurities. However, the following chemical components, that is, Cu, Cr and N.
one or more selected from the group consisting of i, Co and W,
Alternatively, the method of the present invention can be preferably used for steel grades to which one or more chemical components selected from the group consisting of V, Nb and Ti are positively added.

【0018】Cu:0.05〜0.5% Cuは析出硬化作用によって鋼線の強度を向上させる
が、0.05%より少ない添加量では効果が小さ過ぎ
る。しかし過剰に添加すると、強度向上効果が飽和する
だけでなく、粒界脆化を招くため、熱間圧延時に鋳塊表
面がひび割れてしまうことがあるので上限を0.5%と
した。
Cu: 0.05 to 0.5% Cu improves the strength of the steel wire by the precipitation hardening action, but if the addition amount is less than 0.05%, the effect is too small. However, if it is added excessively, not only the strength improving effect is saturated, but also grain boundary embrittlement is caused, and the ingot surface may be cracked during hot rolling, so the upper limit was made 0.5%.

【0019】Cr:0.05〜1.0% Crは、鋼線の強度と伸線加工性を向上させる。これ
は、Crによってパーライトにおけるラメラ間隔が微細
化することによる。この効果が認められるのは0.05
%以上の添加量のときであるが、1.0%を超えて添加
すると変態終了時間が長くなり過ぎるため、生産性の点
から好ましくない。
Cr: 0.05 to 1.0% Cr improves the strength and drawability of the steel wire. This is because Cr reduces the lamellar spacing in pearlite. This effect is observed at 0.05
%, But when added in excess of 1.0%, the transformation end time becomes too long, which is not preferable from the viewpoint of productivity.

【0020】Ni:0.05〜1.0% Niは鋼線の強度向上にはあまり寄与しないが、伸線材
の靭性を高める効果を有する。この効果が認められるの
は0.05%以上の添加量のときであるが、1.0%を
超えて添加すると変態終了時間が長くなり過ぎるため、
生産性の点から好ましくない。
Ni: 0.05 to 1.0% Ni does not contribute much to the improvement of the strength of the steel wire, but has the effect of increasing the toughness of the drawn wire. This effect is recognized when the addition amount is 0.05% or more, but if the addition amount exceeds 1.0%, the transformation end time becomes too long,
It is not preferable in terms of productivity.

【0021】Co:0.05〜1.0% Coは0.05%以上の添加で、初析セメンタイトの析
出を抑制する。しかし1.0%を超えて添加してもその
効果は飽和し、不経済であるため上限を1.0%とし
た。
Co: 0.05 to 1.0% Addition of 0.05% or more of Co suppresses the precipitation of pro-eutectoid cementite. However, even if added over 1.0%, the effect is saturated and it is uneconomical, so the upper limit was made 1.0%.

【0022】W:0.05〜1.0% Wは0.05%以上の添加で、鋼線強度を向上させる作
用を有する。しかし1.0%を超えて添加しても、その
効果は飽和し、逆に延靭性の低下を引き起こすため上限
を1.0%とした。
W: 0.05 to 1.0% W is added in an amount of 0.05% or more and has the effect of improving the strength of the steel wire. However, even if added over 1.0%, the effect is saturated and conversely causes a decrease in ductility, so the upper limit was made 1.0%.

【0023】V:0.05〜0.5%、Nb:0.01
〜0.2%、Ti:0.01〜0.2%、B:0.00
05〜0.0050% これらの元素は、鋼線中で微細な炭窒化物を形成し、析
出硬化によって鋼線の強度を向上させると共に、加熱時
のオーステナイト粒度の粗大化防止に役立つ。上記下限
値より少ない添加量ではこの効果は認められない。一
方、上限値を超えて添加すると、炭窒化物量が増大し過
ぎ、炭窒化物自体の粒子径も大きくなり過ぎるため延性
が悪くなる。
V: 0.05 to 0.5%, Nb: 0.01
-0.2%, Ti: 0.01-0.2%, B: 0.00
05 to 0.0050% These elements form fine carbonitrides in the steel wire, improve the strength of the steel wire by precipitation hardening, and serve to prevent coarsening of the austenite grain size during heating. This effect is not observed when the amount added is less than the above lower limit. On the other hand, if the amount exceeds the upper limit, the amount of carbonitrides increases too much and the particle size of the carbonitride itself becomes too large, resulting in poor ductility.

【0024】本発明のめっき鋼線は上記化学成分を含有
するものであるが、本発明において最もポイントとなる
必須構成要件は、溶融めっき鋼線のめっき層と基材の界
面から中心へ向かって50μmまでの基材表層部の平均
ビッカース硬さHvと、めっき鋼線の引張強度TS(kg
f/mm2)の比:Hv/TSが2以下であるという点であ
る。本発明者等が一般的な鋼線の上記比Hv/TSを検
討したところ、2.8〜2.9であった。従って、強度
TSが大きくなるとHvも大きくなっていることがわか
る。しかし、鋼線の強度が高くなると延性が悪化するた
め、捻回時の縦割れ性も劣ったものとなってしまう。こ
の点について本発明者等が検討した結果、鋼線の表面層
のみを軟化すれば高強度でしかも捻回時の縦割れの発生
がない鋼線が得られることを見出したものである。
The galvanized steel wire of the present invention contains the above-mentioned chemical components, and the essential constituent requirement which is the most important point in the present invention is from the interface between the plating layer of the hot dip galvanized steel wire and the substrate toward the center. Average Vickers hardness Hv of the surface layer of the base material up to 50 μm and tensile strength TS (kg
Ratio of f / mm 2 ): Hv / TS is 2 or less. When the present inventors examined the above-mentioned ratio Hv / TS of a general steel wire, it was 2.8 to 2.9. Therefore, it can be seen that Hv increases as the strength TS increases. However, as the strength of the steel wire increases, the ductility deteriorates, and the vertical cracking property during twisting also deteriorates. As a result of the present inventors' study on this point, it was found that by softening only the surface layer of the steel wire, it is possible to obtain a steel wire having high strength and free from vertical cracks during twisting.

【0025】本発明では、軟化させるべき鋼線の表面層
は、めっき層と金属基材の界面から中心へ向かって50
μmまでの部分である。すなわち、めっき前の鋼線にお
いては鋼線表面から深さ50μmまでの部分である。こ
の表面層のみを後述の焼入れまたは脱炭によって軟化さ
せる(軟化後の表面層を表面軟化層ということがある)
ことによって、捻回時の縦割れを可及的に抑制すること
ができる。図1には、表面軟化層の深さ(めっき層と金
属基材の界面から中心へ向かって測定される層の深さ)
を変化させた時のめっき鋼線の回転曲げ疲労試験で測定
された疲労限(繰り返し回数1000万回で破断しない
応力)を示した。図1から明らかな様に表面軟化層が5
0μmを超えると疲労限が低下していくので、本発明で
は軟化させるべき表面層を鋼線表面から50μmまでと
規定した。
In the present invention, the surface layer of the steel wire to be softened is 50 from the interface between the plating layer and the metal substrate toward the center.
The part up to μm. That is, in the steel wire before plating, it is a portion from the surface of the steel wire to a depth of 50 μm. Only this surface layer is softened by quenching or decarburization described later (the surface layer after softening may be referred to as surface softening layer)
As a result, vertical cracking during twisting can be suppressed as much as possible. FIG. 1 shows the depth of the surface softening layer (the depth of the layer measured from the interface between the plating layer and the metal substrate toward the center).
The fatigue limit (stress that does not break after 10 million cycles) was measured in the rotating bending fatigue test of the plated steel wire when the value was changed. As is clear from FIG. 1, the surface softening layer is 5
If it exceeds 0 μm, the fatigue limit will decrease, so in the present invention, the surface layer to be softened is defined as 50 μm from the steel wire surface.

【0026】上記表面層を軟化させる度合いは、表面層
の平均ビッカース硬さで規定する。表面層の平均ビッカ
ース硬さHvは、コード法で測定される値を採用した。
コード法とは、R.H.Gassner, Metal Progress, March,
59(1978)に示された方法である。具体的には、図2に示
す様に、鋼線を表層から中心へ向かって斜めに研磨し、
研磨面端部からΔの点でビッカース硬さを測定する。研
磨面長さをC、鋼線の半径をrとすれば測定点の深さd
はd=r−{r2 −Δ・(C−Δ)}1/2 で与えられ
る。本発明では表面層のHvを、めっき層と金属基材の
界面から鋼線中心方向へ向かって深さ10、20、3
0、40、50μmのそれぞれの部分について測定した
Hvの平均値と定めた。コード法は、鋼線表面近傍の硬
さを比較的大きな荷重で測定できるため、誤差は従来法
に比べ非常に小さくなる。
The degree of softening the surface layer is defined by the average Vickers hardness of the surface layer. As the average Vickers hardness Hv of the surface layer, a value measured by the code method was adopted.
The code method is RHGassner, Metal Progress, March,
59 (1978). Specifically, as shown in FIG. 2, a steel wire is polished obliquely from the surface layer toward the center,
Vickers hardness is measured at the point Δ from the end of the polished surface. If the polished surface length is C and the radius of the steel wire is r, the depth d of the measurement point is
Is given by d = r− {r 2 −Δ · (C−Δ)} 1/2 . In the present invention, the Hv of the surface layer is set to a depth of 10, 20, 3 from the interface between the plating layer and the metal substrate toward the center of the steel wire.
It was defined as the average value of Hv measured for each part of 0, 40 and 50 μm. The code method can measure the hardness near the surface of the steel wire with a relatively large load, so the error is much smaller than in the conventional method.

【0027】図3には、後述する実施例で得られためっ
き鋼線の引張強度TSと表面軟化層の平均ビッカース硬
さHvの関係を示した。捻回試験の破面状態で正常なも
のを白丸、異常破面を黒丸としてプロットしている。点
線はHv/TS=2の直線である。図3からも明らかな
様に、同じTSを示すめっき鋼線であっても、Hv/T
Sが2を超えるめっき鋼線はすべて異常破面である。表
面軟化層のHvが捻回時の破面状態に大きな影響を及ぼ
すことがわかる。従って本発明では、Hv/TSが2以
下であることを必須要件とした。
FIG. 3 shows the relationship between the tensile strength TS of the plated steel wire obtained in the examples described later and the average Vickers hardness Hv of the surface softening layer. The normal fracture surface of the twist test is plotted as a white circle, and the abnormal fracture surface is plotted as a black circle. The dotted line is a straight line of Hv / TS = 2. As is clear from FIG. 3, even in the case of plated steel wire showing the same TS, Hv / T
All the plated steel wires with S exceeding 2 are abnormal fracture surfaces. It can be seen that Hv of the surface softening layer has a great influence on the fracture surface state during twisting. Therefore, in the present invention, it is an essential requirement that Hv / TS is 2 or less.

【0028】次に、Hv/TSを2以下にするための方
法を説明する。本発明のめっき鋼線は、前記化学成分の
高炭素鋼線を、熱間圧延→直接もしくは再オーステナイ
ト化後にパテンティング→冷間伸線→溶融ZnまたはZ
n−Alめっきという工程を通して高強度高靭性溶融め
っき鋼線とするものである。本発明では上述の様に鋼線
の表面層を軟化させる必要があるので、上記工程中、冷
間伸線前または後に鋼線表面層のみを焼戻す方法、また
は冷間伸線前の鋼線表面層の脱炭を行う方法を採用する
ことが推奨される。鋼線の表面層を焼き戻すための好ま
しい方法としては、高周波加熱またはレーザー加熱が挙
げられる。
Next, a method for reducing Hv / TS to 2 or less will be described. The galvanized steel wire of the present invention is obtained by subjecting the high carbon steel wire having the above chemical composition to hot rolling → direct or after reaustenizing, patenting → cold drawing → molten Zn or Z.
High-strength and high-toughness hot-dip galvanized steel wire is obtained through a process called n-Al plating. In the present invention, since it is necessary to soften the surface layer of the steel wire as described above, during the above step, a method of tempering only the steel wire surface layer before or after cold drawing, or the steel wire before cold drawing It is recommended to adopt the method of decarburizing the surface layer. Preferred methods for tempering the surface layer of the steel wire include high frequency heating or laser heating.

【0029】また脱炭処理は冷間伸線前、特にパテンテ
ィング処理時に同時に行うことが製造効率的に好まし
い。パテンティングのときの加熱時間を長めに設定する
ことによって脱炭が可能である。なお、焼戻しと脱炭の
両方を行って表面層の軟化を行ってもよい。
Further, it is preferable from the viewpoint of production efficiency that the decarburizing treatment is carried out before cold drawing, especially at the same time as the patenting treatment. Decarburization is possible by setting a long heating time during patenting. The surface layer may be softened by performing both tempering and decarburization.

【0030】[0030]

【実施例】以下実施例によって本発明をさらに詳述する
が、下記実施例は本発明を制限するものではなく、前・
後記の趣旨を逸脱しない範囲で変更実施することは全て
本発明の技術範囲に包含される。
The present invention will be described in more detail with reference to the following examples, but the following examples do not limit the present invention.
All modifications and implementations that do not depart from the spirit of the description below are included in the technical scope of the present invention.

【0031】表1には、実施例で使用した鋼の化学成分
をそれぞれ重量%で示した。表1に示した鋼を、まず溶
融めっき後の最終線径3mmのものは7.5mmに、最
終線径5mmのものは12mmに、最終線径7mmにす
る場合は14mmに熱間圧延し、その線径のまま鉛パテ
ンティング処理(再加熱:950℃×5分、恒温変態:
540℃×4分)を行った。パテンティング時に脱炭を
行う場合(表4)は、再加熱の時間を10分とした。
In Table 1, the chemical composition of the steel used in the examples is shown in% by weight. The steels shown in Table 1 were first hot-rolled to 7.5 mm for a final wire diameter of 3 mm after hot dipping, 12 mm for a final wire diameter of 5 mm, and 14 mm for a final wire diameter of 7 mm. Lead patenting treatment (reheating: 950 ° C x 5 minutes, constant temperature transformation:
540 ° C. × 4 minutes). When decarburizing was performed during patenting (Table 4), the reheating time was 10 minutes.

【0032】その後ダイスの出口で線材を冷却し170
℃以下に保持したままで目標線径に伸線した。続く直線
加工の後に、表2に示した実験では、出力一定の高周波
加熱炉内に鋼線を通した。このとき、線速を変えながら
表面軟化層の深さ(厚み)と硬さを変化させている。焼
戻しの後は、溶融Znめっきを施した。表3には、出力
一定のCO2 レーザーで線速を変えながら表面層軟化処
理を行い、溶融Znめっきを施した鋼線についての結果
を示した。表4には、パテンティング時に脱炭を行った
溶融Znめっき鋼線の特性結果を示した。
After that, the wire rod is cooled at the exit of the die and 170
The wire was drawn to the target wire diameter while maintaining the temperature below ℃. After the subsequent linear processing, in the experiment shown in Table 2, the steel wire was passed through a high-frequency heating furnace with a constant output. At this time, the depth (thickness) and hardness of the surface softening layer are changed while changing the linear velocity. After tempering, hot dip Zn plating was performed. Table 3 shows the results for the steel wire which was subjected to the hot-dip Zn plating by performing the surface layer softening treatment while changing the linear velocity with a CO 2 laser having a constant output. Table 4 shows the characteristic results of the hot-dip galvanized steel wire that was decarburized during patenting.

【0033】なお、表2〜4に示した各特性の測定方法
は以下の通りである。 〔表面層の平均ビッカース硬さHv:平均硬さHvと省
略する〕コード法で測定される値を採用し、めっき層と
金属基材の界面から鋼線中心方向へ向かって10、2
0、30、40、50μmのそれぞれの部分について測
定したビッカース硬さHvの平均値。 〔捻回時の異常破面率〕10本のサンプルを捻回試験に
供し、異常破面が発生する比率をパーセントで示した。 〔回転曲げ疲労特性〕繰り返し回数1000万回で破断
しない応力(疲労限)が40kgf/mm2以上のもの
を「良好」とした。 〔判定〕めっき鋼線の引張強度が200kgf/mm2以上で、異
常破面率が0%、かつ回転曲げ疲労特性が良好なものを
○として、いずれかひとつでも満足しないものを×とし
た。
The methods for measuring the characteristics shown in Tables 2 to 4 are as follows. [Average Vickers hardness Hv of surface layer: abbreviated as average hardness Hv] A value measured by the code method is adopted, and 10 or 2 is measured from the interface between the plating layer and the metal substrate toward the center of the steel wire.
Average value of Vickers hardness Hv measured for each part of 0, 30, 40, and 50 μm. [Abnormal Fracture Surface Ratio During Twisting] Ten samples were subjected to a twisting test, and the ratio of occurrence of abnormal fracture surface was shown in percent. [Rotary Bending Fatigue Properties] The stress (fatigue limit) that does not break after the number of repetitions of 10 million times is 40 kgf / mm 2 or more is defined as “good”. [Judgment] When the tensile strength of the plated steel wire was 200 kgf / mm 2 or more, the abnormal fracture surface ratio was 0%, and the rotary bending fatigue property was good, it was evaluated as ◯, and when any one was not satisfied, it was evaluated as x.

【0034】[0034]

【表1】 [Table 1]

【0035】[0035]

【表2】 [Table 2]

【0036】[0036]

【表3】 [Table 3]

【0037】[0037]

【表4】 [Table 4]

【0038】以上の実験例から次のことがわかった。実
験No. 1〜28は、高周波加熱で表面層を軟化させた実
験例である。No. 1はCの少ない鋼種Aを用いているた
め、引張強度が低かった。No. 2、3および7、8は本
発明例であり、強度、捻回時の特性、回転疲労特性のい
ずれにも優れていた。No. 4は、表面軟化層は25μm
と本発明規定範囲内であるが、軟化が不充分でHv/T
Sが2を超えたため、捻回時の縦割れ発生率が100%
と非常に劣っている。No. 5は表面軟化処理を施してい
ないため、やはり異常破面率が高い。No. 6、10は、
軟化させた表面層が50μmをこえているので回転曲げ
特性が劣ったものとなった。No. 7、8はBを用いてい
るが、めっき後の伸線工程での減面率が低いため強度が
低く、No. 9は軟化が不充分でHv/TSが2を超えた
ため捻回試験時の異常破面率が多い。
From the above experimental example, the following was found. Experiment Nos. 1-28 are experimental examples in which the surface layer was softened by high frequency heating. Since No. 1 uses steel type A with less C, the tensile strength was low. Nos. 2, 3 and 7, 8 were examples of the present invention, and were excellent in all of strength, twisting characteristics, and rotational fatigue characteristics. No. 4 has a surface softening layer of 25 μm
And within the specified range of the present invention, the softening is insufficient and Hv / T
Since S exceeds 2, the vertical crack occurrence rate during twisting is 100%
And very inferior. Since No. 5 is not surface softened, it has a high abnormal fracture rate. No. 6, 10 are
Since the softened surface layer exceeded 50 μm, the rotary bending property was inferior. No. 7 and 8 use B, but the strength is low due to the low surface reduction rate in the wire drawing process after plating, and No. 9 is twisted because Hv / TS exceeds 2 because of insufficient softening. There are many abnormal fracture rates during the test.

【0039】鋼種DはCが上限値を超えているため、こ
れを用いたNo. 11では初析セメンタイトが多く析出し
て伸線性が低下し、冷間伸線時に断線した。No. 12は
Siが多過ぎる鋼種Eを用いているので延性が低下し、
やはり断線が多発した。また、No. 13はMnの少ない
鋼種Fを用いたため伸線可能であったが、鋼線の強度が
不充分である。鋼種GはMnが多いので過冷組織の存在
のために伸線性が悪く(No. 14)、鋼種IはAlが多
いため窒化物が多く生成し伸線不能であった(No. 1
6)。また、Alの少ない鋼種Hを用いたNo. 15は、
結晶粒径が粗大化したため、伸線性に劣るものとなっ
た。
Since C of steel type D exceeds the upper limit value, in No. 11 using this steel, a large amount of pro-eutectoid cementite was precipitated and the wire drawability was deteriorated, and wire breakage occurred during cold wire drawing. No. 12 uses the steel type E with too much Si, so the ductility decreases,
After all, there were many disconnections. Further, No. 13 was able to be drawn because it used the steel type F with a small amount of Mn, but the strength of the steel wire is insufficient. Since steel type G has a large amount of Mn, the wire drawability is poor due to the presence of a supercooled structure (No. 14), and steel type I has a large amount of Al and therefore a large amount of nitride is formed and wire drawing is impossible (No. 1)
6). In addition, No. 15 using the steel type H with less Al,
Since the crystal grain size became coarse, the wire drawability was inferior.

【0040】No. 17、18、21〜27はいずれも本
発明鋼を用いて、本発明の規定範囲の表面軟化層を有し
Hv/TSを満足するものであるため、引張強度、捻回
時の特性、回転曲げ疲労特性のいずれにも優れためっき
鋼線が得られている。No. 19は表面層の軟化度合いが
不充分であるため、Hv/TSが2を超えてしまった。
No. 18はCrが上限値を超える鋼種Lを用いているの
で、変態時間が長時間となり、今回のパテンティング条
件では時間内に変態が終了しなかったことによって、過
冷組織が存在し断線が多発したものである。No. 28
は、Nが上限値を超える鋼種Tを用いたため、伸線中の
時効硬化作用が強過ぎて断線してしまった。
Nos. 17, 18, 21 to 27 all use the steel of the present invention and have a surface softening layer within the specified range of the present invention to satisfy Hv / TS. The plated steel wire has been obtained that is excellent in both time characteristics and rotary bending fatigue characteristics. In No. 19, Hv / TS exceeded 2 because the degree of softening of the surface layer was insufficient.
Since No. 18 uses the steel type L in which Cr exceeds the upper limit value, the transformation time becomes long, and under the patenting conditions of this time, the transformation did not end within the time, so there was a supercooled structure and there was a wire breakage. Is a frequent occurrence. No. 28
Since the steel type T in which N exceeds the upper limit value was used, the age hardening action during wire drawing was too strong and the wire was broken.

【0041】表3に示した実験No. 31〜36は、レー
ザー加熱によってめっき前の鋼線の表面層を焼戻しした
実験例である。表3においても表2の高周波加熱の場合
と同様に、本発明の規定範囲の表面軟化層を有しHv/
TSを満足する実験例のもの(本発明例)は、引張強
度、捻回時の特性、回転曲げ疲労特性のいずれにも優れ
ためっき鋼線が得られている。また表4には、パテンテ
ィング時に脱炭させて鋼線表面層の軟化を行った実験例
を示した。この例においても、本発明の効果が明らか
で、表面軟化層が大き過ぎる実験No. 43では回転曲げ
疲労特性が悪く、また表面軟化層の軟化が不充分でHv
/TSが2を超えている実験No. 42、45、47は捻
回時の異常破面率が高いものであった。
Experiment Nos. 31 to 36 shown in Table 3 are experimental examples in which the surface layer of the steel wire before plating was tempered by laser heating. In Table 3, as in the case of high frequency heating in Table 2, Hv / having a surface softening layer within the specified range of the present invention was used.
In the experimental example satisfying TS (inventive example), a plated steel wire having excellent tensile strength, twisting characteristics, and rotational bending fatigue characteristics was obtained. Further, Table 4 shows an experimental example in which decarburization was performed during patenting to soften the surface layer of the steel wire. Also in this example, the effect of the present invention is clear, and in Experiment No. 43 in which the surface softening layer is too large, the rotational bending fatigue property is poor, and the softening of the surface softening layer is insufficient, so that Hv
In Experiment Nos. 42, 45, and 47 in which / TS exceeds 2, the abnormal fracture surface rate at the time of twisting was high.

【0042】[0042]

【発明の効果】本発明では最適化学成分の高炭素鋼線の
捻回時の縦割れを抑制するためには、めっき前の鋼線の
表面層50μmを焼戻しまたは脱炭によって軟化させる
ことが効果的であることを知見したので、高強度高靭性
であり、かつ捻回時の縦割れの発生がなく、しかも回転
曲げ疲労特性にも優れた溶融めっき鋼線とその製造方法
を提供することができた。本発明の方法はPC鋼線、亜
鉛メッキ鋼線、バネ用鋼線、吊り橋用ケーブル、ACS
R(送電線ケーブルの補強用素線)用めっき鋼線等の高
強度化が必要な鋼線用途にも非常に有用である。
According to the present invention, in order to suppress vertical cracking during twisting of a high carbon steel wire having an optimum chemical composition, it is effective to soften the surface layer 50 μm of the steel wire before plating by tempering or decarburizing. Therefore, it is possible to provide a hot-dip galvanized steel wire that has high strength and high toughness, does not cause vertical cracks during twisting, and has excellent rotary bending fatigue properties, and a manufacturing method thereof. did it. The method of the present invention is applicable to PC steel wire, galvanized steel wire, spring steel wire, suspension bridge cable, ACS.
It is also very useful for steel wire applications such as plated steel wire for R (strengthening wire of a transmission line cable) requiring high strength.

【図面の簡単な説明】[Brief description of drawings]

【図1】表面軟化層の深さが回転曲げ疲労試験に及ぼす
影響を示すグラフである。
FIG. 1 is a graph showing the influence of the depth of a surface softening layer on a rotary bending fatigue test.

【図2】コード法によるビッカース硬さ測定方法を説明
する鋼線側面図および断面図である。
FIG. 2 is a side view and a sectional view of a steel wire for explaining a Vickers hardness measurement method by a cord method.

【図3】めっき鋼線の引張強度TSと表面軟化層の平均
ビッカース硬さHvの関係を示すグラフである。
FIG. 3 is a graph showing the relationship between the tensile strength TS of the plated steel wire and the average Vickers hardness Hv of the surface softening layer.

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】C:0.7〜1.2%(重量%、以下同
じ) Si:0.5〜2.0% Mn:0.2〜1.0% Al:0.02〜0.07% N:0.003〜0.015%を含有し、残部Feおよ
び不可避不純物からなる高炭素鋼線に溶融めっきを施し
ためっき鋼線であって、めっき層と基材の界面から中心
へ向かって50μmまでの基材表層部の平均ビッカース
硬さHvと、めっき鋼線の引張強度TS(kgf/mm2) の
比:Hv/TSが2以下であることを特徴とする高強度
高靭性溶融めっき鋼線。
1. C: 0.7 to 1.2% (weight%, the same applies hereinafter) Si: 0.5 to 2.0% Mn: 0.2 to 1.0% Al: 0.02 to 0. A high-carbon steel wire containing 07% N: 0.003 to 0.015%, the balance of which is Fe and unavoidable impurities, obtained by hot-dip plating. Ratio of the average Vickers hardness Hv of the surface layer of the base material up to 50 μm and the tensile strength TS (kgf / mm 2 ) of the plated steel wire: Hv / TS is 2 or less, high strength and high toughness Hot dip steel wire.
【請求項2】C:0.7〜1.2% Si:0.5〜2.0% Mn:0.2〜1.0% Al:0.02〜0.07% N:0.003〜0.015%を含有し、さらに、 Cu:0.05〜0.5% Cr:0.05〜1.0% Ni:0.05〜1.0% Co:0.05〜1.0% W:0.05〜1.0%の1種以上を含有し、残部Fe
および不可避不純物からなる高炭素鋼線に溶融めっきを
施しためっき鋼線であって、めっき層と基材の界面から
中心へ向かって50μmまでの基材表層部の平均ビッカ
ース硬さHvと、めっき鋼線の引張強度TS(kgf/mm2)
の比:Hv/TSが2以下であることを特徴とする高強
度高靭性溶融めっき鋼線。
2. C: 0.7 to 1.2% Si: 0.5 to 2.0% Mn: 0.2 to 1.0% Al: 0.02 to 0.07% N: 0.003 .About.0.015%, and further, Cu: 0.05-0.5% Cr: 0.05-1.0% Ni: 0.05-1.0% Co: 0.05-1.0 % W: Containing one or more of 0.05 to 1.0%, balance Fe
And a high-carbon steel wire consisting of unavoidable impurities, which is hot-dipped galvanized steel wire having an average Vickers hardness Hv of the surface layer of the base material of up to 50 μm from the interface between the plating layer and the base material toward the center, and plating Steel wire tensile strength TS (kgf / mm 2 )
Ratio: Hv / TS is 2 or less, a high-strength, high-toughness hot-dip galvanized steel wire.
【請求項3】C:0.7〜1.2% Si:0.5〜2.0% Mn:0.2〜1.0% Al:0.02〜0.07% N:0.0030〜0.0150%を含有し、さらに、 Cu:0.05〜0.5% Cr:0.05〜1.0% Ni:0.05〜1.0% Co:0.05〜1.0% W:0.05〜1.0%の1種以上と、 V:0.05〜0.5% Nb:0.01〜0.2% Ti:0.01〜0.2% B:0.0005〜0.0050%の1種以上を含有
し、残部Feおよび不可避不純物からなる高炭素鋼線に
溶融めっきを施しためっき鋼線であって、めっき層と基
材の界面から中心へ向かって50μmまでの基材表層部
の平均ビッカース硬さHvと、めっき鋼線の引張強度T
S(kgf/mm2)の比:Hv/TSが2以下であることを特
徴とする高強度高靭性溶融めっき鋼線。
3. C: 0.7 to 1.2% Si: 0.5 to 2.0% Mn: 0.2 to 1.0% Al: 0.02 to 0.07% N: 0.0030 .About.0.0150%, and further, Cu: 0.05-0.5% Cr: 0.05-1.0% Ni: 0.05-1.0% Co: 0.05-1.0 % W: One or more of 0.05 to 1.0%, V: 0.05 to 0.5% Nb: 0.01 to 0.2% Ti: 0.01 to 0.2% B: 0 A high-carbon steel wire containing at least one of 0.0005 to 0.0050% and the balance being Fe and unavoidable impurities, and a hot-dip plated steel wire, which is directed from the interface between the plating layer and the base material to the center. Average Vickers hardness Hv of the substrate surface layer up to 50 μm and tensile strength T of the plated steel wire
Ratio of S (kgf / mm 2 ): Hv / TS is 2 or less, high strength and high toughness hot-dip galvanized steel wire.
【請求項4】 請求項1〜3のいずれかに記載の高炭素
鋼線に、熱間圧延後直接パテンティング処理を行うかも
しくは再オーステナイト化後にパテンティング処理を行
って微細パーライトを主要組織とする鋼線とした後に冷
間伸線を行い、この冷間伸線後の鋼線の表面のみに焼戻
し処理を施し、次いで溶融ZnまたはZn−Alめっき
を施すことによって、該めっき層と基材金属の界面から
中心へ向かって50μm以下の鋼線表層部の平均ビッカ
ース硬さHvと、めっき鋼線の引張強度TS(kgf/mm2)
の比:Hv/TSを2以下にすることを特徴とする高強
度高靭性溶融めっき鋼線の製造方法。
4. The high carbon steel wire according to any one of claims 1 to 3 is directly subjected to patenting treatment after hot rolling or is subjected to patenting treatment after re-austenization to form fine pearlite as a main structure. Cold drawing is performed after the steel wire to be formed is subjected to a tempering treatment only on the surface of the steel wire after the cold drawing, and then a hot dip Zn or Zn-Al plating is applied to the plated layer and the base material. The average Vickers hardness Hv of the steel wire surface layer portion of 50 μm or less from the metal interface toward the center and the tensile strength TS (kgf / mm 2 ) of the plated steel wire
Ratio: Hv / TS is set to 2 or less, a method for producing a high-strength and high-toughness hot-dip galvanized steel wire.
【請求項5】 高周波加熱法によって前記鋼線の表面の
みに焼戻し処理を施すものである請求項4に記載の製造
方法。
5. The manufacturing method according to claim 4, wherein only the surface of the steel wire is tempered by a high frequency heating method.
【請求項6】 レーザー加熱法によって前記鋼線の表面
のみに焼戻し処理を施すものである請求項4に記載の製
造方法。
6. The method according to claim 4, wherein only the surface of the steel wire is tempered by a laser heating method.
【請求項7】 請求項1〜3のいずれかに記載の高炭素
鋼線に、熱間圧延後直接パテンティング処理を行うかも
しくは再オーステナイト化後にパテンティング処理を行
って微細パーライトを主要組織とする鋼線とし、この鋼
線の表面のみに脱炭処理を施してから冷間伸線を行い、
次いで溶融ZnまたはZn−Alめっきを施すことによ
って、該めっき層と基材金属の界面から中心へ向かって
50μm以下の鋼線表層部の平均ビッカース硬さHv
と、めっき鋼線の引張強度TS(kgf/mm2)の比:Hv/
TSを2以下にすることを特徴とする高強度高靭性溶融
めっき鋼線の製造方法。
7. The high carbon steel wire according to any one of claims 1 to 3 is directly subjected to patenting treatment after hot rolling or is subjected to patenting treatment after re-austenization to make fine pearlite as a main structure. Steel wire to be used, decarburizing only the surface of this steel wire, then cold drawing,
Then, by performing hot dip Zn or Zn-Al plating, the average Vickers hardness Hv of the steel wire surface layer portion of 50 μm or less from the interface between the plated layer and the base metal toward the center.
And the tensile strength TS (kgf / mm 2 ) of the plated steel wire: Hv /
A method for producing a high-strength, high-toughness hot-dip galvanized steel wire, characterized in that TS is 2 or less.
JP18964494A 1994-08-11 1994-08-11 High strength and high toughness hot-dip coated steel wire and method for producing the same Expired - Lifetime JP3246210B2 (en)

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