JPH0860510A - 線状低密度ポリエチレンバインダー繊維を含む繊維構造体 - Google Patents

線状低密度ポリエチレンバインダー繊維を含む繊維構造体

Info

Publication number
JPH0860510A
JPH0860510A JP7202582A JP20258295A JPH0860510A JP H0860510 A JPH0860510 A JP H0860510A JP 7202582 A JP7202582 A JP 7202582A JP 20258295 A JP20258295 A JP 20258295A JP H0860510 A JPH0860510 A JP H0860510A
Authority
JP
Japan
Prior art keywords
fiber
melting point
density polyethylene
fibers
linear low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7202582A
Other languages
English (en)
Inventor
James Dulaney Geiman
デュラネイ ガイマン ジェームズ
Rakesh K Gupta
クマー グプタ ラケシュ
Randall Earl Kozulla
アール コズラ ランダル
Richard Jean Legare
ジーン レゲーア リチャード
Robert Gray Maclellan
グレイ マックレーラン ロバート
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hercules LLC
Original Assignee
Hercules LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hercules LLC filed Critical Hercules LLC
Publication of JPH0860510A publication Critical patent/JPH0860510A/ja
Pending legal-status Critical Current

Links

Classifications

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    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
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    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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Abstract

(57)【要約】 【課題】 寸法的に安定な繊維構造体の提供。 【解決手段】 融点が109℃未満の線状低密度ポリエ
チレンを少なくとも約80重量%含むバインダー繊維を
使用する。

Description

【発明の詳細な説明】
【0001】
【発明の属する技術分野】本発明は、ポリエチレン繊維
並びに高融点繊維及び低融点バインダー繊維を含む繊維
構造体に関する。
【0002】
【従来の技術】繊維構造体は、種々の天然繊維材料又は
人造繊維材料から製造される。これらの構造体の製造に
は、種々の方法、例えば、紡糸、製織、編成、タフティ
ング、カーディング及びニードルパンチングが用いられ
る。このようにして製造された構造体は、寸法的に不安
定である。これらの構造体を安定化するために、いくつ
かの手法、例えば、ラテックス処理又はラミネーション
が用いられる。これらの処理には、環境に好ましくない
影響を与える溶剤や薬品を必要とするものがある。他の
手法は、非接着繊維と接着の可能性のあるバインダー繊
維とをブレンドして糸又は他の繊維構造体を形成し、次
いで接着の可能性のある繊維を活性化して他方の繊維に
結合するものである。米国特許第 2,277,049号及び同第
2,464,301号には、不織材料を安定化するに当たってバ
インダー繊維の使用が記載されている。欧州特許第 32
4,773号には、融点が110〜170℃のバインダー繊
維を用いて製造された撚糸が記載されている。米国特許
第 4,668,552号には、融点が149℃未満のコポリアミ
ド及びコポリエステル系低融点バインダーラップストラ
ンドを含むラップステープルヤーンが記載されている。
米国特許第 4,634,739号には、融点が約107℃の分枝
低密度ポリエチレンと結晶性ポリプロピレンのブレンド
から製造されたバインダー繊維が開示されている。米国
特許第 5,077,874号及び同第 5,199,141号には、ニード
ルパンチされた不織ウェブにおいて融点が110℃より
高いポリエチレン繊維及びポリプロピレン繊維の使用が
記載されている。不織構造体におけるこの繊維の組合わ
せには、その2つの繊維の融点の差が小さいことから、
その構造体の主繊維、即ち、ポリプロピレン繊維への逆
効果を防止するために熱処理温度の正確な制御が必要で
ある。
【0003】
【発明が解決しようとする課題】従って、繊維構造体の
主繊維の融点とバインダー繊維の融点間に顕著な差を与
えて、寸法的に安定な繊維構造体の製造における寛容な
熱処理方法を提供することが望ましい。この差は、十分
に低い融点温度を有するバインダー繊維を供給すること
により達成される。しかしながら、本発明の以前には、
融点が109℃未満の線状低密度ポリエチレン繊維を含
むバインダー繊維を製造することができなかった。
【0004】
【課題を解決するための手段】本発明は、融点が109
℃未満の線状低密度ポリエチレン(LLDPE)を少な
くとも約80重量%含む繊維に関する。これらの繊維
は、これらのLLDPE以外の繊維を任意に含有する様
々な種類の繊維構造体に用いることができる。
【0005】
【発明の実施の形態】好適実施態様においては、LLD
PE繊維は、寸法的に安定な熱固化繊維構造体であっ
て、(1)線状低密度ポリエチレンを少なくとも約80
重量%含む低融点繊維を該構造体の全重量に対して少な
くとも約3重量%及び(2)非溶融繊維又は該線状低密
度ポリエチレン繊維より融点の高い繊維を該構造体の全
重量に対して約97重量%以下含む前記構造体を調製す
るために用いられる。その繊維構造体は、高融点繊維を
溶融せずに線状低密度ポリエチレンバインダー繊維を加
熱溶融することにより固化される。本発明の繊維構造体
は、糸、織布又は不織布、カーペット及び少なくとも1
層が本発明の繊維構造体を含むラミネートの形とするこ
とができる。その熱固化繊維構造体は、改良された寸法
安定性、耐摩耗(abrasion)性及び摩耗(wear)特性を有す
る。その線状低密度ポリエチレンバインダー繊維は、良
好なドレープを有する軟質の可撓性布状構造体を与える
ことができる。
【0006】線状低密度ポリエチレンを少なくとも約8
0重量%含む繊維は、エチレンと炭素原子3〜12個の
α−オレフィン、例えば、プロピレン、ブテン、オクテ
ン及びヘキサン20重量%までとのコポリマーである。
炭素原子4〜8個を有するα−オレフィンが好ましい。
α−オレフィンコモノマーの混合物、例えば、ブテン/
オクテン又はヘキサン/オクテンも用いることができ
る。コポリマーは、エチレンを少なくとも80%含むこ
とが好ましい。線状低密度ポリエチレン(LLDPE)
は、『線状』であるが、低密度ポリエチレンの場合のよ
うに重合したエチレン単位の短鎖が主ポリマーの側鎖と
なっているよりはむしろα−オレフィンコモノマーのア
ルキル基がポリマー鎖の側鎖となっている。LLDPE
の密度は、典型的には約0.88〜0.94g/ccである。
LLDPE繊維の融点は、エチレンモノマーとコモノマ
ーの比率及びポリマー構造によって変動させることがで
きる。適切な線状低密度ポリエチレンとしては、融点が
約90〜130℃である、ダウケミカル社、米国、ミシ
ガン州、ミッドランドから入手できる例えば、INSI
TE(登録商標)、ENGAGE(登録商標)及びAS
PUN(登録商標)ポリエチレンが挙げられる。好まし
い繊維の融点は、109℃未満である。融点が109℃
未満の線状低密度ポリエチレンから紡糸された繊維は、
以前には得られなかった。
【0007】線状低密度ポリエチレン繊維は、けん縮又
は非けん縮連続フィラメント;長さが約3〜150ミリ
メートル(mm)、好ましくは約5〜150mm、最も好まし
くは約25〜50mmのけん縮又は非けん縮切断繊維、即
ち、ステープルファイバー又は不連続ミクロファイバ
ー、即ち、メルトブローンファイバーとすることができ
る。線状低密度ポリエチレン繊維は、好ましくは約1〜
30デニール、より好ましくは約2〜15デニール、最
も好ましくは約2〜6デニールを有する。本明細書にお
いて『繊維』なる語は、上記繊維及びフィラメントの全
ての種類を含むことを意味する。その繊維は、他の材
料、例えば、安定剤、顔料、添加剤及び線状低密度ポリ
エチレン以外のポリマー(例えば、ポリプロピレン、ポ
リスチレン、プロピレン、エチレン及びブチレン等のオ
レフィンのコポリマー、ポリエステル及びポリアミド)
を約20重量%まで含むことができる。その繊維は、親
水性あるいは疎水性とすることができる表面仕上げ剤を
適量、例えば、約2重量%まで含有することができる。
適切な仕上げ剤としては、例えば、リン酸エステル帯電
防止仕上げ剤、エトキシル化脂肪酸エステル及びポリジ
メチルシロキサンが挙げられる。かかる仕上げ剤は、例
えば、米国特許第 4,938,832号及び公開欧州特許出願第
486158号、同第557024号及び同第516412号に記載されて
おり、該明細書の内容は本願明細書に含まれるものとす
る。
【0008】融点が109℃未満の線状低密度ポリエチ
レンを少なくとも約80重量%含む線状低密度ポリエチ
レン(LLDPE)繊維は、特定された線状低密度ポリ
エチレン繊維以外の繊維を任意に含む様々な種類の繊維
構造体に用いることができる。本発明の繊維構造体とし
ては、糸、例えば、連続フィラメント糸、ステープル
糸、ラップ糸又はノベルティ糸;織布又は編成織布;ベ
ルベットのようなタフテッド織布;ループパイル又はカ
ットパイルカーペット;不織布又は不織構造体、例え
ば、ニードルパンチ又はヒドロエンタングル不織物;及
び本発明の繊維構造体を数層含む積層物又は本発明の織
物構造体を少なくとも1層と他の繊維構造体を少なくと
も1層含む積層物が挙げられる。好適実施態様において
は、LLDPE繊維は、熱固化繊維構造体であって、
(1)線状低密度ポリエチレンを少なくとも約80重量
%含む低融点繊維を該構造体の全重量に対して少なくと
も約3重量%及び(2)非溶融繊維又は該線状低密度ポ
リエチレン繊維より融点の高い繊維を該構造体の全重量
に対して約97重量%以下含む前記構造体に用いられ
る。典型的には、その構造体はLLDPE繊維を50重
量%未満含む。LLDPE繊維の好適範囲は、約5〜約
20重量%である。
【0009】本発明の熱固化構造体における第2の高融
点繊維は、線状低密度ポリエチレン繊維より少なくとも
10℃、好ましくは少なくとも20℃、最も好ましくは
少なくとも30℃高く溶融する繊維とすることができ
る。融点が109℃未満の線状低密度ポリエチレン繊維
をポリプロピレン繊維と用いる場合、その2つの繊維の
融点の差は50℃より高くすることができる。これらの
繊維は、けん縮又は非けん縮連続フィラメント;けん縮
又は非けん縮切断繊維又は不連続ミクロファイバーとす
ることができる。かかる繊維としては、例えば、ポリプ
ロピレン繊維、ポリアミド繊維及びポリエステル繊維が
挙げられる。ポリプロピレン繊維が好ましい。非溶融繊
維を用いることもできる。かかる繊維としては、例え
ば、綿繊維、羊毛繊維、アクリル繊維及びレーヨン繊維
が挙げられる。これらの繊維は、好ましくは約80〜約
95重量%の範囲で用いられる。線状低密度バインダー
繊維と高融点繊維を合わせた後、そのバインダー繊維は
その高融点繊維を相互に加熱結合することにより溶融さ
れる。冷却後、ポリエチレンが固化し、高融点繊維を所
定の場所に固着して、寸法的に安定な構造体を生じる。
【0010】下記実施例で用いられる融点が約107℃
の線状低密度ポリエチレンマルチフィラメント糸及びス
テープルファイバーは、ダウケミカル社、米国、ミシガ
ン州、ミッドランド(ダウ)から入手できる58200.
03と称するENGAGE(登録商標)樹脂を用いて調
製した。実施例における融点が約128℃の線状低密度
ポリエチレンマルチフィラメント糸及びステープルファ
イバーは、ダウから入手できる6835と称するASP
UN(登録商標)樹脂を用いて調製した。これらの樹脂
を、約200〜230℃の温度で(通常の紡糸は170
〜250℃で実施される)多孔紡糸口金を用いて溶融押
出し、その押出された繊維をパッケージに取り上げた。
更に、これらの繊維を約2〜4回引き伸ばしてフィラメ
ント当たりの最終デニールを得た。ステープル繊維にけ
ん縮を与え、切断した。下記実施例で用いられるポリエ
チレン300デニール/52フィラメント連続フィラメ
ント糸は、ヘンケル社、米国、ペンシルヴェニア、アン
バーから入手できる表面仕上げ剤TRYLUBE764
0Aを2%未満含有した。ポリエチレンステープルファ
イバーは、ジョージA.ゴールストン社、米国、ノースカ
ロライナ、モンローから入手できる表面仕上げ剤LUR
OL PP912を2%未満含有した。本明細書におい
て、%は特にことわらない限り全て重量による。
【0011】
【実施例】実施例1 ポリプロピレン(PP)かさ高連続マルチフィラメント
糸と線状低密度ポリエチレン(LLDPE)連続マルチ
フィラメント糸とを共に混合して表1に示されるポリプ
ロピレン/ポリエチレン複合糸を製造した。次いで、こ
の複合糸を表1に示された温度で5分間熱処理した。こ
の熱処理した糸の物理的特徴をその表に示す。ポリプロ
ピレンフィラメント間の結合が良好な寸法的に安定な糸
が得られた。
【0012】
【表1】 表1 試料 ポリプロピレン ポリエチレン PE/LLDPE比 熱処理温度 熱処理複合糸 No. 糸(PP) 糸(LLDPE) (%/%) (℃) の特徴 ──────────────────────────────────── A 500 デニール/ 300 デニール/ 62/38 120 ℃ 軟質、繊維間 144 フィラメン 52フィラメント の結合良好 トの1エンド の1エンド 融点約 162℃ 融点約 107℃ B 500 デニール/ 300 デニール/ 77/23 120 ℃ 軟質、繊維間 144 フィラメン 52フィラメント の結合良好 トの2エンド の1エンド 融点約 162℃ 融点約 107℃ C 500 デニール/ 300 デニール/ 62/38 135 ℃ 硬質、繊維間 144 フィラメン 52フィラメント の結合良好 トの1エンド の1エンド 融点約 162℃ 融点約 128℃ ────────────────────────────────────
【0013】実施例2 ポリエステル(PET)かさ高連続マルチフィラメント
糸と線状低密度ポリエチレン(LLDPE)連続マルチ
フィラメント糸とを加撚して表2に示されるポリエステ
ル/ポリエチレン複合糸を製造した。次いで、これらの
撚糸を表2に示された温度で5分間熱処理した。この熱
処理した糸の物理的特徴をその表に示す。ポリエステル
フィラメント間の結合が良好な寸法的に撚りの安定な糸
が得られた。
【0014】
【表2】 表2 試料 ポリエステル糸 ポリエチレン PET/LLDPE 熱処理温度 熱処理複合糸 No. (PET) 糸(LLDPE) 比(%/%) (℃) の特徴 ──────────────────────────────────── D 400 デニール/ 300 デニール/ 73/27 135 ℃ 軟質、繊維間 94フィラメント 52フィラメント の結合良好 の2エンド の1エンド 融点約 260℃ 融点約 128℃ E 400 デニール/ 300 デニール/ 84/16 135 ℃ 軟質、繊維間 94フィラメント 52フィラメント の結合良好 の4エンド の1エンド 融点約 260℃ 融点約 128℃ F 400 デニール/ 300 デニール/ 57/43 135 ℃ 軟質、繊維間 94フィラメント 52フィラメント の結合良好 の1エンド の1エンド 融点約 260℃ 融点約 128℃ ────────────────────────────────────
【0015】実施例3 表3に示された種々の経糸と緯糸を用いて織布を調製し
た。LLDPEは、線状低密度ポリエチレンである。次
いで、これらの織布を表3に示された温度で5分間熱処
理した。この熱処理した布の物理的特徴をその表に示
す。繊維間の結合が良好な寸法的に安定な布が得られ
た。表中、den.はデニール;fil.はフィラメン
トである。
【0016】
【表3】 表3 試料 LLDPEの LLDPE 熱処理温 熱処理布の No. 経糸 緯糸 融点(℃)(%) 度 (℃) 特徴 ──────────────────────────────────── G ポリエステル; 300den./52フ 128 21 135 軟質、繊維 500 デニール ィラメントLL 間の結合良 ステープルスパ DPE;400den./ 好 ンヤーン 92fil.ポリエ 融点約 260℃ ステルの交互 エンド H ポリエステル; 300den./52フ 107 21 120 軟質、繊維 500 デニール ィラメントLL 間の結合良 ステープルスパ DPE;400den./ 好 ンヤーン 92fil.ポリエ 融点約 260℃ ステルの交互 エンド I ポリエステル; 300den./52フ 107 21 120 軟質、繊維 500 デニール ィラメントLL 間の結合良 ステープルスパ DPE;500den./144 好 ンヤーン fil.ポリエステ 融点約 260℃ ルの交互エンド 融点約 162℃ ────────────────────────────────────
【0017】実施例4 融点が約107℃の線状低密度ポリエチレン3デニール
/フィラメントステープルファイバーと融点が約162
℃のポリプロピレン2.2デニール/フィラメントステー
プルファイバーの50重量%/50重量%ブレンドを用
いて、基礎重量約74g/m2 (62g/yd2 )を有す
る不織ウェッブを調製した。この不織ウェッブを融点が
約260℃のポリエステル織布約114g/m2 (95
g/yd2)にニードルパンチした。この布構造体の2試
料を各々118℃、次に123℃で5分間熱処理した。
これらの熱処理した布構造体は、良好な寸法安定性と柔
軟な手触りを示した。
【0018】実施例5 融点が約107℃の線状低密度ポリエチレン3デニール
/フィラメントステープルファイバーと融点が約162
℃のポリプロピレン2.2デニール/フィラメントステー
プルファイバーの25重量%/75重量%ブレンドを用
いて、基礎重量約63g/m2 (53g/yd2 )を有す
る不織ウェッブを調製した。この不織ウェッブの2層、
4層及び6層を含む積層物を調製し、各々120℃で5
分間熱処理した。これらの熱処理した不織構造体は、良
好な寸法安定性と柔軟な手触りを示した。
【0019】実施例6 融点が約107℃の線状低密度ポリエチレン3デニール
/フィラメントステープルファイバーと融点が約162
℃のポリプロピレン2.2デニール/フィラメントステー
プルファイバーの50重量%/50重量%ブレンドを用
いて、基礎重量約74g/m2 (62g/yd2 )を有す
る不織ウェッブを調製した。この不織ウェッブを基礎重
量約114g/m2 (95g/yd2 )を有する平織りポ
リエステル織布と合わせ、この2つの構造体を一緒にニ
ードルパンチした。次いで、この複合繊維構造体を12
0℃で5分間熱処理して線状低密度ポリエチレン繊維を
実質的に溶融した。得られた繊維構造体は、良好な寸法
安定性と柔軟な手触りを示した。
【0020】実施例7 融点が約107℃の線状低密度ポリエチレン5デニール
/フィラメントステープルファイバーを用いて、基礎重
量約32g/m2 (27g/yd2 )を有する不織ウェッ
ブを調製した。この不織ウェッブを基礎重量約114g
/m2 (95g/yd2 )を有する平織りのポリエステル
織布と合わせ、この2つの構造体を一緒にニードルパン
チした。次いで、この複合繊維構造体を120℃で5分
間熱処理して線状低密度ポリエチレン繊維を実質的に溶
融した。得られた繊維構造体は、良好な寸法安定性と柔
軟な手触りを示した。
【0021】実施例8 融点が約107℃の線状低密度ポリエチレン5デニール
/フィラメントステープルファイバーを用いて、基礎重
量約57g/m2 (48g/yd2 )を有する不織ウェッ
ブを調製した。この不織ウェッブを基礎重量約114g
/m2 (95g/yd2 )を有する平織りのポリエステル
織布と合わせ、この2つの構造体を一緒にニードルパン
チした。次いで、この複合繊維構造体を120℃で5分
間熱処理して線状低密度ポリエチレン繊維を実質的に溶
融した。得られた繊維構造体は、良好な寸法安定性と柔
軟な手触りを示した。LLDPEを使用すると、特にポ
リプロピレン、ポリアミド又はポリエステルのような他
のポリマー又は天然繊維の高融点繊維を用いて繊維構造
体を製造するのに十分に適する繊維が得られる。融点が
109℃未満のLLDPEを含む本発明の繊維は、高融
点LLDPEで製造されたものより柔軟な構造体を生じ
る。更に、当業者が低温で構造体を製造することを可能
にし、もって、主繊維に対して起こりうる損傷が低減さ
れる。
───────────────────────────────────────────────────── フロントページの続き (72)発明者 ラケシュ クマー グプタ アメリカ合衆国 ジョージア州 30208 コーニアーズ サンデュー ドライヴ 962 (72)発明者 ランダル アール コズラ アメリカ合衆国 ジョージア州 30279 ソシアル サークル サーマン バーカス ロード 5240 (72)発明者 リチャード ジーン レゲーア アメリカ合衆国 ジョージア州 30208 コーニアーズ カントリー クラブ ドラ イヴ 2619 (72)発明者 ロバート グレイ マックレーラン アメリカ合衆国 ジョージア州 30208 コーニアーズ フィールドストーン ドラ イヴ 2356

Claims (16)

    【特許請求の範囲】
  1. 【請求項1】 融点が109℃未満の線状低密度ポリエ
    チレンを少なくとも約80重量%含む繊維。
  2. 【請求項2】 請求項1記載の繊維を含む繊維構造体。
  3. 【請求項3】 (1)請求項1記載の繊維及び(2)該
    線状低密度ポリエチレン繊維(1)以外の繊維を含む繊
    維構造体。
  4. 【請求項4】 マルチフィラメント糸、織布、編成織
    布、タフテッド織布、不織布又はカーペットの形として
    の請求項2又は3記載の構造体。
  5. 【請求項5】 該構造体が不織布である請求項4記載の
    構造体を少なくとも1層含むラミネート。
  6. 【請求項6】 熱固化繊維構造体であって、(1)線状
    低密度ポリエチレンを少なくとも約80重量%含む低融
    点繊維を該構造体の全重量に対して少なくとも約3重量
    %及び(2)非溶融繊維又は該線状低密度ポリエチレン
    繊維より融点の高い繊維を該構造体の全重量に対して約
    97重量%以下含む前記構造体。
  7. 【請求項7】 該線状低密度ポリエチレンの融点が10
    9℃未満である請求項6記載の熱固化構造体。
  8. 【請求項8】 繊維(1)と繊維(2)の融点の差が少
    なくとも10℃である請求項6又は7記載の構造体。
  9. 【請求項9】 繊維(1)と繊維(2)の融点の差が少
    なくとも30℃である請求項8記載の構造体。
  10. 【請求項10】 繊維(1)と繊維(2)の融点の差が
    少なくとも50℃である請求項9記載の構造体。
  11. 【請求項11】 該線状低密度ポリエチレンが、エチレ
    ンと炭素原子3〜12個のα−オレフィンの少なくとも
    1種とのコポリマーであり、約0.88〜0.94g/ccの
    密度を有する請求項1〜10のいずれか1項に記載の発
    明。
  12. 【請求項12】 該α−オレフィンがプロピレン、ブテ
    ン、オクテン、ヘキセン及びその混合物からなる群より
    選ばれる請求項11記載の発明。
  13. 【請求項13】 該コポリマーがエチレンを少なくとも
    80%含む請求項11又は12記載の発明。
  14. 【請求項14】 繊維(2)がプロピレン繊維、レーヨ
    ン繊維、綿繊維、アクリル繊維及び羊毛繊維からなる群
    より選ばれる請求項6〜13のいずれか1項に記載の構
    造体。
  15. 【請求項15】 繊維(2)がポリプロピレン繊維、ポ
    リエステル繊維又はポリアミド繊維である請求項6〜1
    3のいずれか1項に記載の構造体。
  16. 【請求項16】 該線状低密度ポリエチレン繊維が、3
    〜150mmの長さを有する1〜30デニールのステープ
    ルファイバーである請求項1〜15のいずれか1項に記
    載の発明。
JP7202582A 1994-08-09 1995-08-08 線状低密度ポリエチレンバインダー繊維を含む繊維構造体 Pending JPH0860510A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/287973 1994-08-09
US08/287,973 US5698480A (en) 1994-08-09 1994-08-09 Textile structures containing linear low density polyethylene binder fibers

Publications (1)

Publication Number Publication Date
JPH0860510A true JPH0860510A (ja) 1996-03-05

Family

ID=23105192

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Country Status (6)

Country Link
US (3) US5698480A (ja)
EP (1) EP0696654A1 (ja)
JP (1) JPH0860510A (ja)
KR (1) KR960007850A (ja)
CN (1) CN1123854A (ja)
CA (1) CA2155404A1 (ja)

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CN1123854A (zh) 1996-06-05
US5712209A (en) 1998-01-27
KR960007850A (ko) 1996-03-22
US5698480A (en) 1997-12-16
EP0696654A1 (en) 1996-02-14
US5824613A (en) 1998-10-20
CA2155404A1 (en) 1996-02-10

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