JPH09164189A - Deodorants - Google Patents

Deodorants

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Publication number
JPH09164189A
JPH09164189A JP7347085A JP34708595A JPH09164189A JP H09164189 A JPH09164189 A JP H09164189A JP 7347085 A JP7347085 A JP 7347085A JP 34708595 A JP34708595 A JP 34708595A JP H09164189 A JPH09164189 A JP H09164189A
Authority
JP
Japan
Prior art keywords
extract
deodorant
plants
leaf
blending
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7347085A
Other languages
Japanese (ja)
Inventor
Masao Hashimoto
雅男 橋本
Yoshiaki Nakajima
嘉章 中島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zeria Pharmaceutical Co Ltd
Original Assignee
Zeria Pharmaceutical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zeria Pharmaceutical Co Ltd filed Critical Zeria Pharmaceutical Co Ltd
Priority to JP7347085A priority Critical patent/JPH09164189A/en
Publication of JPH09164189A publication Critical patent/JPH09164189A/en
Pending legal-status Critical Current

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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a deodorant safe for human bodies which can remove halito sis, fecal smell and body odor by blending an extract of one or more plants selected from guava leaf, Macrocarpium Napai, Mallotus japonicus, cinnamon and. SOLUTION: A deodorant which is safe for human bodies to remove halitosis, fecal smell and body odor of human beings and animals is prepared by blending an extract of one or more plants selected from among leaf of Pridium guajava L., bark of Myrica rubra Sieb. et Zucc., seed of Jermiralia chebuta Retz., leaf of Viola monorhurica BecKer, Ge chome hederacea L. var grandis (A. Gray) Kudo, Puhalu tea (a sort of fungally fermented Chinese tea with a specific smell of the fungi and produced in sauth China), Curnees afficinalis Sieb. et Zucc., Mallotus japonicus (Thumb.) Muell Arg., Cinamomum siebaldii Meisn., and Aralia elate Seem. The extract of these plants includes extracted liquids obtained by extracting the plants with a polar or non-polar solvent, their dilutions, their concentrates, extracts or dried products thereof. The blending ratio of the extract is set at 0.0001-80wt.%, especially in a range of 0.001-50wt.% depending on the type of the deodorant.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は消臭剤に関し、詳し
くはグアバ葉、ヨウバイヒ、訶子、シバイカ葉、レンセ
ンソウ、プーアル茶、サンシュユ、アカメガシワ、ケイ
ヒ、タラより選ばれる1種以上の植物の抽出物を配合す
る消臭剤に関する。
FIELD OF THE INVENTION The present invention relates to a deodorant, and more particularly to the extraction of at least one plant selected from guava leaf, eucalypt, rye, sycamore leaf, lensou, puerh tea, sanshuyu, akamegashiwa, keihi and cod. The present invention relates to a deodorant for compounding substances.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】従来、
アンモニア、アミン、メルカプタン、スルフィドに代表
される悪臭、異臭の消臭法としては、シリカゲル、活
性炭等に臭気を吸着させたり、シクロデキストリンのよ
うな包接化合物に臭気物質を包接する方法、香料等の
芳香性物質によって悪臭、異臭をマスキングする方法、
悪臭、異臭を化学反応により無臭化する方法等が知ら
れている。の方法は、主に消臭装置として広く用いら
れているものであるが、人体や動物の体に適用すること
はできず、またシリカゲルや活性炭の吸着力は持続性が
低い。の方法は、消臭剤自身の香気により、悪臭や異
臭をマスキングするものであるが、マスキングに必要な
香気量のコントロールが難しく、また、香気に対する人
の嗜好は多種多様であり、香気に対して嫌悪感を催す人
も考えられ、一般的ではない。の方法は、使用薬剤の
取扱いに注意を要するものが多く、また人体や動物の体
に適用することは困難である。これより、家庭や工場等
で発生する悪臭、異臭の除去には、これらの方法を、そ
れぞれの目的に合わせて使用することができるが、特に
人や動物の口臭、便臭、体臭を除去する方法としては、
これらの方法は適当ではない。
2. Description of the Related Art
As a deodorizing method for odors and off-flavors represented by ammonia, amine, mercaptan, and sulfide, silica gel, activated carbon, etc. can be used to adsorb odors, or inclusion compounds such as cyclodextrin can be included in odorants, fragrances, etc. How to mask offensive odors and offensive odors with
A method of deodorizing a bad odor or a bad odor by a chemical reaction is known. This method is widely used mainly as a deodorizing device, but it cannot be applied to the human body or animal body, and the adsorption power of silica gel or activated carbon is low. The method described in (1) masks offensive odors and off-flavors with the odor of the deodorant itself, but it is difficult to control the amount of fragrance required for masking, and there are a wide variety of human tastes for fragrance. It is uncommon for some people to feel disgust. The method of (1) requires careful handling of the drug used, and is difficult to apply to the human body or animal body. Therefore, these methods can be used to remove the offensive odors and offensive odors generated in homes and factories according to their respective purposes. As a method,
These methods are not suitable.

【0003】一方、近年の清潔志向者の増加に伴い、
人、動物などの口臭、便臭、体臭の除去を行うための消
臭剤の開発が望まれている。口臭を除去する有効成分と
しては、銅クロロフィリンNaが知られており、種々の
口腔用組成物に多用されている。しかし、銅クロロフィ
リンNaは、歯磨等の口腔用組成物にメルカプタン等に
対して有効な消臭効果を発揮し得る量を配合すると口腔
用組成物の色が非常に濃くなるという問題がある。ま
た、消臭有効成分として、レッドビートエキス、カカオ
エキス、コーヒーパセリエキス(特開昭60−2076
64号公報)、緑茶エキス(特開昭60−185558
号公報)、シソエキス(特開昭60−214726号公
報)、柿エキス(特開昭61−87562号公報)、フ
キエキス(特開昭61−206448号公報)や、海の
り(特開昭62−152463号公報)、マンネンタケ
細砕物(特開昭62−181048号公報)、マッシュ
ルーム抽出物(特開平2−277456号公報)を使用
することが提案されているが、さらに悪臭、異臭に対す
る消臭効果が高く、かつ人体や動物の体に適用しても安
全性の高い消臭有効成分が望まれている。
On the other hand, with the recent increase in cleanliness,
Development of deodorants for removing halitosis, fecal odors and body odors of humans and animals is desired. Copper chlorophyllin Na is known as an active ingredient for removing bad breath and is often used in various oral compositions. However, when copper chlorophyllin Na is added to an oral composition such as toothpaste in an amount capable of exerting an effective deodorizing effect on mercaptan and the like, the color of the oral composition becomes very dark. Further, as deodorant active ingredients, red beet extract, cacao extract, coffee parsley extract (JP-A-60-2076).
64), green tea extract (JP-A-60-185558).
Japanese patent publication No. 60-214726), persimmon extract (Japanese patent publication No. 61-87562), Japanese butterbur extract (Japanese patent publication No. 61-206448), and seaweed (Japanese patent publication No. 62-62). Japanese Patent No. 152463), crushed Ganoderma lucidum (Japanese Unexamined Patent Publication No. 62-181048) and mushroom extract (Japanese Unexamined Patent Publication No. 2-277456) have been proposed. There is a demand for a deodorant active ingredient that is highly safe and highly safe even when applied to the human body or animal body.

【0004】[0004]

【課題を解決するための手段】本発明者らは、上記の実
情に鑑み、家庭や工場等で発生する悪臭、異臭のほか、
人や動物の口臭、便臭、体臭をも除去する消臭有効成分
として、植物中の有効成分を用いることを案出し、様々
な植物についてその消臭効果を調べた結果、グアバ葉、
ヨウバイヒ、訶子、シバイカ葉、レンセンソウ、プーア
ル茶、サンシュユ、アカメガシワ、ケイヒ、タラより選
ばれる1種以上の植物の抽出物に強い消臭活性のあるこ
とを見い出し、本発明を完成するに至った。
SUMMARY OF THE INVENTION In view of the above situation, the inventors of the present invention have taken into consideration the bad odors and offensive odors generated at home, factories, etc.
As a deodorant active ingredient that also removes halitosis, fecal odor, and body odor of humans and animals, we devised to use the active ingredient in plants, and as a result of examining the deodorant effect on various plants, guava leaf,
The inventors have found that an extract of one or more kinds of plants selected from euphorbiasis, rye, sycamore leaves, lotus root, puerh tea, sanshuyu, akamegashiwa, keihi, and cod has a strong deodorizing activity, and completed the present invention. .

【0005】すなわち、本発明はグアバ葉、ヨウバイ
ヒ、訶子、シバイカ葉、レンセンソウ、プーアル茶、サ
ンシュユ、アカメガシワ、ケイヒ、タラより選ばれる1
種以上の植物の抽出物を配合する消臭剤に関する。
That is, the present invention is selected from guava leaf, eucalypt, rye, sycamore leaf, lotus root, puerh tea, sanshuyu, akamegashiwa, keihi, cod 1
The present invention relates to a deodorant containing an extract of one or more plants.

【0006】本発明に用いられるグアバ葉は、フトモモ
科バンジロウの葉であり、茶の代用として、また、民間
薬として糖尿病や下痢止めに用いられている。
The guava leaf used in the present invention is a bunzi wax leaf of the Myrtaceae family, and is used as a substitute for tea and as a folk medicine to prevent diabetes and diarrhea.

【0007】本発明に用いられるヨウバイヒは、ヤマモ
モ科ヤマモモの樹皮であり、利尿作用があり、また収れ
ん薬として下痢に用いられている。
The lobster bark used in the present invention is the bark of the bayberry family bayberry, has a diuretic action, and is used as an astringent drug for diarrhea.

【0008】本発明に用いられる訶子(カシ)は、シク
ンシ科ミロバランの果実であり、インドのアユルベーダ
医学の要薬として用いられるほか、皮なめしの材料とし
ても用いられている。
[0008] The licorice (oak) used in the present invention is the fruit of Myrobalan, which belongs to the family Asteraceae, and is used not only as an essential drug in Ayurvedic medicine in India but also as a material for skin tanning.

【0009】本発明に用いられるシバイカ葉は、バラ科
ヤマハマナスの葉であり、漢方では消化不良、胃痛等に
用いられている。
The mosquito leaf used in the present invention is a leaf of Yamahanas, which is a member of the family Rosaceae, and is used in Chinese medicine for indigestion, stomach pain and the like.

【0010】本発明に用いられるレンセンソウは、シソ
科カキドオシの全草であり、小児のかんの治療に用いら
れる。また、利胆作用があることが知られている。
The lentilum used in the present invention is a whole plant of the perilla family Kakidooshi and is used for the treatment of kan in children. It is also known to have a bile action.

【0011】本発明に用いられるプーアル茶は、緑茶を
黒麹菌を用いて発酵させたものであり、中国では古くか
ら飲料として利用されている。
The puer tea used in the present invention is a green tea fermented with Aspergillus niger and has been used as a beverage in China since ancient times.

【0012】本発明に用いられるサンシュユは、ミズキ
科サンシュユの果実であり、滋養、強壮、収れん薬とし
て使用される。
Sanshuyu used in the present invention is a fruit of Sanshuyu, a family of the dogwood family, and is used as a nourishing, tonic and astringent drug.

【0013】本発明に用いられるアカメガシワは、トウ
ダイグサ科アカメガシワの樹皮であり、潰瘍や胆石症に
用いられている。
The red-spotted wrinkles used in the present invention are the bark of the red-spotted red-spotted spurge, which is used for ulcers and cholelithiasis.

【0014】本発明に用いられるケイヒは、クスノキ科
ケイの樹皮であり、発汗解熱健胃剤として用いられるほ
か、矯味の目的で食品にも用いられている。
The cinnamon bark used in the present invention is a bark of the Lauraceae family, and is used not only as a stomachic agent for antiperspirant and antipyretic, but also for food for the purpose of taste masking.

【0015】本発明に用いられるタラは、ウコギ科タラ
ノキの樹皮であり、民間薬として糖尿病に用いられてい
る。
The cod used in the present invention is the bark of the Araliaceae cod, which is used as a folk medicine for diabetes.

【0016】本発明の抽出物としては、植物を極性又は
非極性溶媒で抽出して得られる抽出液、その希釈液、濃
縮液、エキス又は乾燥物を意味する。溶媒としては、例
えばメタノール、エタノール、1−プロパノール、2−
プロパノール、1−ブタノール、2−ブタノール等のア
ルコール類、エーテル、テトラヒドロフラン等のエーテ
ル類、酢酸エチル等のエステル類、アセトン等のケトン
類、アセトニトリル等のニトリル類、ベンゼン、トルエ
ン等の芳香族炭化水素類、塩化メチレン、クロロホルム
等のハロゲン化脂肪族炭化水素類、水等を適宜選択して
使用することができるが、抽出後の使用における安全性
及び便宜の観点からはメタノール、エタノール、1−プ
ロパノール、2−プロパノール、1−ブタノール、2−
ブタノール等のアルコール類、水が好ましい。
The extract of the present invention means an extract obtained by extracting plants with a polar or non-polar solvent, a diluted solution thereof, a concentrated solution, an extract or a dried product. As the solvent, for example, methanol, ethanol, 1-propanol, 2-
Alcohols such as propanol, 1-butanol, 2-butanol, ethers such as ether and tetrahydrofuran, esters such as ethyl acetate, ketones such as acetone, nitriles such as acetonitrile, aromatic hydrocarbons such as benzene and toluene. , Halogenated aliphatic hydrocarbons such as methylene chloride and chloroform, and water can be appropriately selected and used, but from the viewpoint of safety and convenience in use after extraction, methanol, ethanol, 1-propanol , 2-propanol, 1-butanol, 2-
Alcohols such as butanol and water are preferred.

【0017】本発明の消臭剤において、植物の抽出物の
配合量は、消臭剤の種類によっても異なるが、0.00
01〜80重量%、特に0.001〜50%が好まし
い。
In the deodorant of the present invention, the compounding amount of the plant extract varies depending on the type of deodorant, but is 0.00
01 to 80% by weight, particularly 0.001 to 50% is preferable.

【0018】[0018]

【発明の実施の形態】本発明の抽出物は、例えば、植物
又はその乾燥物を破砕、裁断し、これに約5倍〜200
倍量の水若しくは有機溶媒、又は水分含量約10重量%
以上の含水有機溶媒を加え、0℃〜還流温度の範囲で約
5分〜48時間攪拌又は静置して抽出を行う。抽出後、
濾過、遠心分離等により不溶物を除き、必要に応じて希
釈、濾過、濃縮操作を行うことにより目的とする抽出物
を得ることができる。また、必要ならば不溶物を前記と
同様の操作により抽出し、その抽出液を合わせて使用す
ることもできる。
BEST MODE FOR CARRYING OUT THE INVENTION The extract of the present invention is obtained by, for example, crushing and cutting a plant or a dried product thereof, and adding about 5 to 200 times to this.
Double amount of water or organic solvent, or water content about 10% by weight
The above-mentioned water-containing organic solvent is added, and the mixture is stirred or left standing at 0 ° C to the reflux temperature for about 5 minutes to 48 hours for extraction. After extraction,
The insoluble matter is removed by filtration, centrifugation, and the like, and the desired extract can be obtained by performing dilution, filtration, and concentration operations as necessary. Further, if necessary, the insoluble matter can be extracted by the same operation as described above, and the extracts can be used together.

【0019】本発明の抽出物は、そのままでも使用する
ことができるが、適当な溶媒で希釈又は濃縮することも
でき、単独あるいは適当な担体とともに噴霧乾燥、凍結
乾燥、減圧乾燥、流動乾燥等の公知の方法により粉末状
とするか、慣用の添加剤を用いることにより液剤、錠
剤、顆粒剤等にするか、又はゲル状、ペースト状、ブロ
ック状、エアゾール等、任意の形態で使用することがで
きる。
The extract of the present invention can be used as it is, but it can also be diluted or concentrated with a suitable solvent, and can be spray-dried, freeze-dried, vacuum-dried, fluidized-dried or the like alone or together with a suitable carrier. It may be powdered by a known method, or may be made into a liquid, tablet, granule or the like by using a conventional additive, or may be used in any form such as gel, paste, block or aerosol. it can.

【0020】本発明で製造される消臭剤には、さらに公
知の甘味剤、殺菌剤、防腐剤、矯味剤、安定化剤、その
他の生薬成分、水溶性薬品等を適宜配合することができ
る。
The deodorant produced in the present invention may further contain known sweeteners, bactericides, preservatives, corrigents, stabilizers, other herbal ingredients, water-soluble chemicals and the like. .

【0021】こうして製剤化された本発明の消臭剤は、
家庭や工場等で発生する悪臭、異臭の除去剤として利用
できるほか、人、動物の口臭、便臭、体臭の除去剤とし
て使用することができる。
The deodorant of the present invention thus formulated is
It can be used as a remover for offensive odors and offensive odors generated at home, in factories, etc., and can also be used as a remover for bad breath, stool odor, and body odor of humans and animals.

【0022】[0022]

【実施例】以下に実施例を挙げて本発明をさらに説明す
るが、本発明はこれに限定されるものではない。
EXAMPLES The present invention will be further described below with reference to examples, but the present invention is not limited to these examples.

【0023】<検体の調製>グアバ葉、シバイカ葉、レ
ンセンソウ、プーアル茶についてはそれぞれ裁断して、
ヨウバイヒ、訶子、サンシュユ、アカメガシワ、ケイ
ヒ、タラについてはそれぞれ破砕して細分し、この細分
した各々の植物8gに50%エタノール200mlを加
え、1時間加熱還流した後セライト濾過し、得られた抽
出液を減圧濃縮してエタノールを除き、精製水を加えて
全量を200mlとしたものを濾紙で濾過して試料とし
た。この試料75ml(植物3gに相当)に1N水酸化ナ
トリウム溶液を加えpHを7.2に調整した後、リン酸
緩衝液(pH7.2)を加え全量を100mlとした。対
照としては、銅クロロフィリンNa(タマ生化学社製)
1gを精製水75mlに溶解した液に、10%リン酸でp
H7.2に調整した後、リン酸緩衝液(pH7.2)を
加え全量を100mlとした。ブランクとしては、精製水
75mlにリン酸緩衝液(pH7.2)を加え全量を10
0mlとしたものを用いた。
<Preparation of Specimen> Guava leaves, sycamore leaves, lotus roots, and puerh tea are cut into pieces,
Extracts obtained by crushing and slicing each of the following plants: 200 g of 50% ethanol was added, and the mixture was heated under reflux for 1 hour and filtered through Celite. The liquid was concentrated under reduced pressure to remove ethanol, purified water was added to make the total amount 200 ml, and the sample was filtered with filter paper to obtain a sample. After adjusting the pH to 7.2 by adding 1N sodium hydroxide solution to 75 ml of this sample (corresponding to 3 g of plant), a phosphate buffer (pH 7.2) was added to bring the total volume to 100 ml. As a control, copper chlorophyllin Na (manufactured by Tama Seikagaku)
To a solution of 1 g dissolved in 75 ml of purified water, p with 10% phosphoric acid.
After adjusting to H7.2, phosphate buffer (pH 7.2) was added to make the total volume 100 ml. As a blank, phosphate buffer (pH 7.2) was added to 75 ml of purified water to bring the total volume to 10 ml.
What was made 0 ml was used.

【0024】<消臭力試験>3500mlガラス製試薬ビ
ンにメチルメルカプタン標準液(1μg/μlベンゼン溶
液:和光純薬工業社製)を6〜7ppmとなるように注入
し、密栓して10分間室温(25℃)放置後、ガス検知
管(全メルカプタン70L:ガステック社製)を用いて
容器内のメチルメルカプタンガスの濃度(0分間)を測
定した。これに試料溶液100mlをすばやく加えて振り
混ぜ、5分及び60分放置後の容器内のメチルメルカプ
タンガスの濃度を測定した。なお、ガス検知管へのサン
プリング量は4ppm以上で50ml(1.4%)、4ppm未
満で100ml(2.8%)であり、採取後同量の空気を
容器内に導入した。結果を表1に示す。
<Deodorization test> A methyl mercaptan standard solution (1 μg / μl benzene solution: manufactured by Wako Pure Chemical Industries, Ltd.) was poured into a 3500 ml glass reagent bottle so as to have a concentration of 6 to 7 ppm, and the bottle was tightly sealed and kept at room temperature for 10 minutes. After standing at (25 ° C.), the concentration of methyl mercaptan gas (0 minutes) in the container was measured using a gas detector tube (all mercaptan 70L: manufactured by Gastec). To this, 100 ml of the sample solution was quickly added, shaken and mixed, and the concentration of methyl mercaptan gas in the container after standing for 5 minutes and 60 minutes was measured. The sampling amount to the gas detector tube was 50 ml (1.4%) above 4 ppm and 100 ml (2.8%) below 4 ppm, and the same amount of air was introduced into the container after sampling. Table 1 shows the results.

【0025】[0025]

【表1】 [Table 1]

【0026】[0026]

【発明の効果】本発明の消臭剤は、既存の消臭剤に比べ
て消臭活性が高く、家庭や工場等で発生する悪臭、異臭
の除去剤として有用である。また、人、動物の口臭、便
臭、体臭のもととなるメチルメルカプタンの除去に優
れ、かつ安全性も高いので、人、動物の口臭、便臭、体
臭の除去剤としても利用できる。
INDUSTRIAL APPLICABILITY The deodorant of the present invention has a higher deodorant activity than existing deodorants, and is useful as a remover for offensive odors and offensive odors generated at home, factories and the like. Further, since it is excellent in removing methyl mercaptan, which is a source of bad breath, fecal odor, and body odor of humans and animals, and has high safety, it can be used as a remover of bad breath, fecal odor, and body odor of humans and animals.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】グアバ葉、ヨウバイヒ、訶子、シバイカ
葉、レンセンソウ、プーアル茶、サンシュユ、アカメガ
シワ、ケイヒ、タラより選ばれる1種以上の植物の抽出
物を配合することを特徴とする消臭剤。
1. A deodorant characterized by containing an extract of one or more kinds of plants selected from guava leaves, eucalyptus serrata, callus, sycamore leaves, lensou, puerh tea, sanshuyu, akamegashiwa, keihi and cod. .
JP7347085A 1995-12-15 1995-12-15 Deodorants Pending JPH09164189A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7347085A JPH09164189A (en) 1995-12-15 1995-12-15 Deodorants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7347085A JPH09164189A (en) 1995-12-15 1995-12-15 Deodorants

Publications (1)

Publication Number Publication Date
JPH09164189A true JPH09164189A (en) 1997-06-24

Family

ID=18387819

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7347085A Pending JPH09164189A (en) 1995-12-15 1995-12-15 Deodorants

Country Status (1)

Country Link
JP (1) JPH09164189A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11269007A (en) * 1998-03-22 1999-10-05 Nippon Doubutsu Yakuhin Kk Insect repellent and deodorizer
JP2007055995A (en) * 2005-07-27 2007-03-08 Hidefumi Kojima Medicinal liquid for eliminating body smell and curing disease
KR101305689B1 (en) * 2013-02-25 2013-09-09 송기원 The method to remove the smell of tobacco plant fruit extract
JP2013203700A (en) * 2012-03-28 2013-10-07 Mandom Corp Body odor inhibitor
CN103721288A (en) * 2013-12-10 2014-04-16 宿州军创佳美环保科技有限公司 Traditional Chinese medicine aldehyde-removing air purifying agent and preparation method thereof
CN110545671A (en) * 2017-03-07 2019-12-06 利利斯科学工业株式会社 Deodorizing and antibacterial agent

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11269007A (en) * 1998-03-22 1999-10-05 Nippon Doubutsu Yakuhin Kk Insect repellent and deodorizer
JP2007055995A (en) * 2005-07-27 2007-03-08 Hidefumi Kojima Medicinal liquid for eliminating body smell and curing disease
JP2013203700A (en) * 2012-03-28 2013-10-07 Mandom Corp Body odor inhibitor
KR101305689B1 (en) * 2013-02-25 2013-09-09 송기원 The method to remove the smell of tobacco plant fruit extract
CN103721288A (en) * 2013-12-10 2014-04-16 宿州军创佳美环保科技有限公司 Traditional Chinese medicine aldehyde-removing air purifying agent and preparation method thereof
CN110545671A (en) * 2017-03-07 2019-12-06 利利斯科学工业株式会社 Deodorizing and antibacterial agent
GB2574546B (en) * 2017-03-07 2021-11-17 Rilis Co Ltd Method for producing a deodorizing and antimicrobial agent

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