JPH09227486A5 - - Google Patents
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- Publication number
- JPH09227486A5 JPH09227486A5 JP1997011812A JP1181297A JPH09227486A5 JP H09227486 A5 JPH09227486 A5 JP H09227486A5 JP 1997011812 A JP1997011812 A JP 1997011812A JP 1181297 A JP1181297 A JP 1181297A JP H09227486 A5 JPH09227486 A5 JP H09227486A5
- Authority
- JP
- Japan
- Prior art keywords
- carbon atoms
- group
- formula
- nitrogen atom
- represent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Description
【００２４】
本発明は又次式Ｉ：
【化１】
（式中、Ｘは反応に対して不活性である基を表し；ｍは０乃至４を表し；Ｒ３ は水素原子，ＣＨ３ ，ＣＨ２ Ｆ又はＣＨＦ２ を表し；Ｙは基ＯＲ４ ，Ｎ（Ｒ５ ）２ 又はＮ（ＣＨ３ ）ＯＣＨ３ を表し；Ｒ４ 乃至Ｒ５ は各々他と独立して、水素原子又は炭素原子１乃至８のアルキル基を表し；又は（Ｒ５ ）２ はそれらが結合する窒素原子と一緒になつて５又は６員の未置換又は置換された環を表す。）で表わされる化合物を製造する方法であつて、次式Ｖ：
【化２】
（式中、Ｘ，ｍ及びＹは前記式Ｉの定義と同一の基を表し，Ｒ１ 及びＲ２ は各々他と独立して、炭素原子数１乃至６のアルキル基，炭素原子数１乃至６のアルケニル基，炭素原子数１乃至６のアルコキシアルキル基又は炭素原子数３乃至６のシクロアルキル基を表し，又はＲ１ 及びＲ２ は窒素原子と一緒になつて、該窒素原子に加えて更に窒素原子を含有してもよい６又は７員の未置換又は置換された環を表す。）で表される化合物を、いずれかの順序で、ｃ１）ｏ−メチルヒドロキシルアミンによりオキシム化する；又はヒドロキシルアミンによりオキシム化し、次いでメチル化又はフルオロメチル化又はジフルオロメチル化する；
ｃ２）クロロ蟻酸エステルと反応させる；ことを特徴とする式Ｉで表される化合物を製造する方法に関する。
本発明は又次式Ｉ：
【化１】
（式中、Ｘは反応に対して不活性である基を表し；ｍは０乃至４を表し；Ｒ３ は水素原子，ＣＨ３ ，ＣＨ２ Ｆ又はＣＨＦ２ を表し；Ｙは基ＯＲ４ ，Ｎ（Ｒ５ ）２ 又はＮ（ＣＨ３ ）ＯＣＨ３ を表し；Ｒ４ 乃至Ｒ５ は各々他と独立して、水素原子又は炭素原子１乃至８のアルキル基を表し；又は（Ｒ５ ）２ はそれらが結合する窒素原子と一緒になつて５又は６員の未置換又は置換された環を表す。）で表わされる化合物を製造する方法であつて、次式Ｖ：
【化２】
（式中、Ｘ，ｍ及びＹは前記式Ｉの定義と同一の基を表し，Ｒ１ 及びＲ２ は各々他と独立して、炭素原子数１乃至６のアルキル基，炭素原子数１乃至６のアルケニル基，炭素原子数１乃至６のアルコキシアルキル基又は炭素原子数３乃至６のシクロアルキル基を表し，又はＲ１ 及びＲ２ は窒素原子と一緒になつて、該窒素原子に加えて更に窒素原子を含有してもよい６又は７員の未置換又は置換された環を表す。）で表される化合物を、いずれかの順序で、ｃ１）ｏ−メチルヒドロキシルアミンによりオキシム化する；又はヒドロキシルアミンによりオキシム化し、次いでメチル化又はフルオロメチル化又はジフルオロメチル化する；
ｃ２）クロロ蟻酸エステルと反応させる；ことを特徴とする式Ｉで表される化合物を製造する方法に関する。
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1/96 | 1996-01-03 | ||
| CH196 | 1996-01-03 | ||
| CH111296 | 1996-05-02 | ||
| CH1112/96 | 1996-05-02 | ||
| CH1874/96 | 1996-07-26 | ||
| CH187496 | 1996-07-26 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH09227486A JPH09227486A (ja) | 1997-09-02 |
| JPH09227486A5 true JPH09227486A5 (ja) | 2004-11-11 |
| JP4621308B2 JP4621308B2 (ja) | 2011-01-26 |
Family
ID=27171705
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP01181297A Expired - Lifetime JP4621308B2 (ja) | 1996-01-03 | 1997-01-06 | ｏ−クロロメチル−フェニルグリオキシル酸誘導体の製造方法 |
Country Status (23)
| Country | Link |
|---|---|
| US (2) | US5756811A (ja) |
| EP (1) | EP0782982B1 (ja) |
| JP (1) | JP4621308B2 (ja) |
| KR (2) | KR100540153B1 (ja) |
| CN (3) | CN1073554C (ja) |
| AR (1) | AR005362A1 (ja) |
| AT (1) | ATE193010T1 (ja) |
| AU (1) | AU714429B2 (ja) |
| BR (1) | BR9700009A (ja) |
| CA (1) | CA2194203C (ja) |
| CZ (1) | CZ290146B6 (ja) |
| DE (1) | DE59605241D1 (ja) |
| DK (1) | DK0782982T3 (ja) |
| ES (1) | ES2147357T3 (ja) |
| GR (1) | GR3033714T3 (ja) |
| HK (2) | HK1048982A1 (ja) |
| HU (1) | HUP9603547A1 (ja) |
| IL (1) | IL119922A (ja) |
| MX (1) | MX9700003A (ja) |
| PL (1) | PL184464B1 (ja) |
| PT (1) | PT782982E (ja) |
| SK (1) | SK168996A3 (ja) |
| TW (1) | TW477785B (ja) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990036612A (ko) * | 1997-10-08 | 1999-05-25 | 고사이 아끼오 | 벤질 브로마이드 유도체의 제조 방법 |
| GB9908530D0 (en) * | 1999-04-14 | 1999-06-09 | Novartis Ag | Organic compounds |
| WO2008125592A1 (en) * | 2007-04-12 | 2008-10-23 | Dsm Fine Chemicals Austria Nfg Gmbh & Co Kg | Improved process for preparing o-chloromethylphenylglyoxylic esters, improved process for preparing (e)-2-(2-chloromethylphenyl)-2-alkoximinoacetic esters, and novel intermediates for their preparation |
| WO2009037230A2 (en) * | 2007-09-17 | 2009-03-26 | Dsm Fine Chemicals Austria Nfg Gmbh & Co Kg | Improved process for preparing (e)-2-(2-chloromethylphenyl)-2-alkoximinoacetic esters |
| CN108358797A (zh) * | 2018-04-20 | 2018-08-03 | 南京农业大学 | 一种烷基甘氨酸的合成方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ213630A (en) * | 1984-10-19 | 1990-02-26 | Ici Plc | Acrylic acid derivatives and fungicidal compositions |
| GB8617648D0 (en) | 1986-07-18 | 1986-08-28 | Ici Plc | Fungicides |
| DE3835028A1 (de) * | 1988-10-14 | 1990-04-19 | Basf Ag | Oximether-derivate, verfahren zu ihrer herstellung und diese enthaltende fungizide |
| DE3843439A1 (de) * | 1988-12-23 | 1990-06-28 | Basf Ag | Schwefelhaltige oximether und diese enthaltende fungizide |
| DE3932542A1 (de) * | 1989-09-29 | 1991-04-11 | Basf Ag | Neue anilinderivate und diese enthaltende fungizide |
| ATE144494T1 (de) * | 1992-08-29 | 1996-11-15 | Basf Ag | N-methylamide, verfahren und zwischenprodukte zu ihrer herstellung sowie verfahren zur bekämpfung von schädlingen |
| DE4305502A1 (de) * | 1993-02-23 | 1994-08-25 | Basf Ag | Ortho-substituierte 2-Methoxyiminophenylessigsäuremethylamide |
| CA2179418C (en) | 1994-01-05 | 2004-06-22 | Hugo Ziegler | Pesticides |
| KR100371884B1 (ko) | 1994-02-04 | 2003-12-01 | 바스프 악티엔게젤샤프트 | 페닐아세트산유도체,이의제조방법및이에대한중간체 |
| GEP20012438B (en) * | 1994-06-10 | 2001-05-25 | Basf Ag | Process of Preparing α-Methoxyimino-carboxylic Acid Methylamides and Intermediates Used in the Method |
| US5583249A (en) * | 1994-08-19 | 1996-12-10 | Ciba-Geigy Corporation | Pesticides |
-
1996
- 1996-12-17 ES ES96810878T patent/ES2147357T3/es not_active Expired - Lifetime
- 1996-12-17 EP EP96810878A patent/EP0782982B1/de not_active Expired - Lifetime
- 1996-12-17 AT AT96810878T patent/ATE193010T1/de active
- 1996-12-17 DE DE59605241T patent/DE59605241D1/de not_active Expired - Lifetime
- 1996-12-17 PT PT96810878T patent/PT782982E/pt unknown
- 1996-12-17 DK DK96810878T patent/DK0782982T3/da not_active Application Discontinuation
- 1996-12-19 HU HU9603547A patent/HUP9603547A1/hu not_active Application Discontinuation
- 1996-12-26 IL IL11992296A patent/IL119922A/en not_active IP Right Cessation
- 1996-12-30 KR KR1019960082484A patent/KR100540153B1/ko not_active Expired - Lifetime
- 1996-12-30 SK SK1689-96A patent/SK168996A3/sk unknown
- 1996-12-30 PL PL96317751A patent/PL184464B1/pl not_active IP Right Cessation
- 1996-12-30 US US08/774,470 patent/US5756811A/en not_active Expired - Lifetime
- 1996-12-30 CN CN96123428A patent/CN1073554C/zh not_active Expired - Lifetime
- 1996-12-31 CA CA002194203A patent/CA2194203C/en not_active Expired - Fee Related
- 1996-12-31 TW TW085116323A patent/TW477785B/zh not_active IP Right Cessation
-
1997
- 1997-01-02 CZ CZ19973A patent/CZ290146B6/cs not_active IP Right Cessation
- 1997-01-02 AU AU10003/97A patent/AU714429B2/en not_active Ceased
- 1997-01-03 BR BR9700009A patent/BR9700009A/pt not_active IP Right Cessation
- 1997-01-03 AR ARP970100032A patent/AR005362A1/es unknown
- 1997-01-06 JP JP01181297A patent/JP4621308B2/ja not_active Expired - Lifetime
- 1997-01-07 MX MX9700003A patent/MX9700003A/es active IP Right Grant
-
1998
- 1998-10-19 US US09/174,966 patent/US6124493A/en not_active Expired - Lifetime
-
2000
- 2000-06-16 GR GR20000401404T patent/GR3033714T3/el not_active IP Right Cessation
-
2001
- 2001-04-29 CN CNB011174889A patent/CN1185209C/zh not_active Expired - Lifetime
- 2001-04-29 CN CNB011174870A patent/CN1185208C/zh not_active Expired - Lifetime
-
2003
- 2003-02-18 HK HK03101145.9A patent/HK1048982A1/zh unknown
- 2003-02-18 HK HK03101146.8A patent/HK1048983A1/zh unknown
-
2005
- 2005-08-26 KR KR1020050079026A patent/KR100540148B1/ko not_active Expired - Lifetime
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