JPH0922872A - Semiconductor laminated structure, manufacturing method thereof, and semiconductor device using the same - Google Patents

Semiconductor laminated structure, manufacturing method thereof, and semiconductor device using the same

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Publication number
JPH0922872A
JPH0922872A JP7169524A JP16952495A JPH0922872A JP H0922872 A JPH0922872 A JP H0922872A JP 7169524 A JP7169524 A JP 7169524A JP 16952495 A JP16952495 A JP 16952495A JP H0922872 A JPH0922872 A JP H0922872A
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JP
Japan
Prior art keywords
semiconductor
layer
type
substrate
laminated structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7169524A
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Japanese (ja)
Inventor
Yoko Uchida
陽子 内田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
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Publication date
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Priority to JP7169524A priority Critical patent/JPH0922872A/en
Publication of JPH0922872A publication Critical patent/JPH0922872A/en
Pending legal-status Critical Current

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Abstract

(57)【要約】 【構成】Si基板とGaAs層からなる半導体積層構造
により構成され、Si基板表面を清浄化ししかも不活性
にするために水素で終端化し、その上に転位の発生を抑
制するためのGa層,GaAs層が形成されている。ま
た、その上のGaAs層中に、光電変換部となるpn構
造が形成されている半導体装置。 【効果】低温で清浄表面が得られ、拡散層からの不純物
の拡散、あるいは加工マスクによる汚染,不純物の拡散
を抑制できる。また、転位の発生を抑制でき、GaAs
層をエピタキシャル成長できる。
(57) [Summary] [Structure] A semiconductor laminated structure consisting of a Si substrate and a GaAs layer is formed, and the surface of the Si substrate is cleaned and terminated with hydrogen to make it inactive, and the generation of dislocations on it is suppressed. Ga layer and GaAs layer are formed for this purpose. Also, a semiconductor device in which a pn structure serving as a photoelectric conversion portion is formed in a GaAs layer thereon. [Effect] A clean surface can be obtained at a low temperature, and the diffusion of impurities from the diffusion layer, the contamination by the processing mask, and the diffusion of impurities can be suppressed. In addition, the generation of dislocations can be suppressed, and GaAs
The layer can be grown epitaxially.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は格子定数の異なる複数の
半導体からなる半導体積層構造とその製造方法、および
それを用いて作製した半導体装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a semiconductor laminated structure composed of a plurality of semiconductors having different lattice constants, a method for manufacturing the same, and a semiconductor device manufactured using the same.

【0002】[0002]

【従来の技術】従来、半導体積層構造を形成するため
に、基板となる半導体表面の汚染物除去を目的とし、前
処理として、基板の洗浄,表面層のエッチングを行い、
その後、通常、酸化膜等の保護膜を形成し、積層構造形
成前にこれらの保護膜を除去する手法を採っている。酸
化膜を保護膜として用いた場合、加熱処理により酸化膜
が分解するため、真空中で加熱処理を行うことにより、
半導体清浄表面が得られ、結晶性のよい半導体積層構造
が形成されることが知られている。Si基板上にGaA
s等化合物半導体層が形成されている積層構造の製造方
法ではSi基板における酸化シリコンの分解温度が12
00℃程度であるため、通常は1100℃、良く制御さ
れた数10Å程度の薄い酸化膜を用いた場合でも800
℃15分程度の高温熱処理が必要となる(例えば、ジャ
ーナル・オブ・エレクトロケミカル・ソサエティー,1
33(1986)第666頁〜第671頁(J.Electroc
hem.Soc.133(1986)pp666〜671)で周
知である)。このため、高温熱処理の採用しにくい加工
マスク等で覆われたパターン基板,拡散しやすい不純物
を添加した基板では酸化膜で保護した簡便な基板清浄化
処理が使えない。
2. Description of the Related Art Conventionally, in order to form a semiconductor laminated structure, the purpose is to remove contaminants on the semiconductor surface to be a substrate. As a pretreatment, the substrate is washed and the surface layer is etched.
After that, usually, a protective film such as an oxide film is formed, and these protective films are removed before the laminated structure is formed. When an oxide film is used as a protective film, the oxide film is decomposed by heat treatment, so by performing heat treatment in vacuum,
It is known that a semiconductor clean surface is obtained and a semiconductor laminated structure having good crystallinity is formed. GaA on Si substrate
In the method of manufacturing a laminated structure in which a compound semiconductor layer such as s is formed, the decomposition temperature of silicon oxide on the Si substrate is 12
Since it is around 00 ° C, it is usually 1100 ° C, and even if a well-controlled thin oxide film of several tens of liters is used,
High temperature heat treatment of about 15 minutes at ℃ is required (for example, Journal of Electrochemical Society, 1
33 (1986) 666 to 671 (J. Electroc
hem.Soc. 133 (1986) pp 666-671)). For this reason, a simple substrate cleaning process protected by an oxide film cannot be used on a patterned substrate covered with a processing mask or the like that is difficult to employ high-temperature heat treatment, or a substrate to which impurities that easily diffuse are added.

【0003】また、Siと化合物半導体の格子定数が異
なるために転位が発生し、半導体積層構造上に形成され
た半導体装置の特性劣化が生じる。これまで、転位低減
のため、種々の方法が提案されている。ジャーナル・オ
ブ・クリスタル・グロウス,115(1991)第122
頁〜第127頁(J. Crys. Growth115(1991)p
p.122〜127),ジャーナル・オブ・クリスタル
・グロウス,128(1993)第527頁〜第532
頁(J. Crys. Growth128(1993)pp.527〜5
32)に報告されているように、Si基板上GaAs結
晶層構造で、両者の間にGaAsアモルファス層を挿入
し、転位を低減するという手法が知られている。
Further, since the lattice constants of Si and the compound semiconductor are different, dislocations occur and the characteristics of the semiconductor device formed on the semiconductor laminated structure deteriorate. Various methods have been proposed so far for reducing dislocations. Journal of Crystal Grouse, 115 (1991) 122
Pp.-127 (J. Crys. Growth 115 (1991) p.
p. 122-127), Journal of Crystal Grouse, 128 (1993) pages 527-532.
Page (J. Crys. Growth 128 (1993) pp. 527-5
32), it is known that a GaAs crystal layer structure on a Si substrate has a GaAs amorphous layer inserted between them to reduce dislocations.

【0004】また、ジャパニーズ・ジャーナル・オブ・
アプライド・フィジクス,30(1991)第L668
頁〜第L671頁(Jpn. J. Appl.Phys.30(199
1)pp.L668〜L671)に報告されているよう
に、熱サイクルアニール法と、InGaAs/GaAs
歪格子挿入の手法を取り入れ、更に低温で結晶層を1層
ずつ、時間間隔をおきながら成膜するマイグレションエ
ンハンストエピタキシー法によって、105/cm3程度の
転位密度が実現されている。GaAs基板上と同程度の
特性を持つ半導体装置を実現するためには104/cm3
が必要と言われている。
[0004] Also, Japanese Journal of Japan
Applied Physics, 30 (1991) L668
Page-L671 (Jpn. J. Appl. Phys. 30 (199
1) pp. L668-L671), thermal cycle annealing method and InGaAs / GaAs
A dislocation density of about 10 5 / cm 3 has been realized by adopting a method of inserting a strained lattice and forming a single crystal layer at a lower temperature at time intervals with a migration enhancement epitaxy method. It is said that 10 4 / cm 3 units are required to realize a semiconductor device having characteristics similar to those on a GaAs substrate.

【0005】[0005]

【発明が解決しようとする課題】従来の基板清浄化処理
では800℃以上の高温熱処理が必要であり、また、転
位低減のための熱サイクルアニールでは900℃での処
理が必要である。このため、pn接合部,異種半導体接
合部を持つ半導体装置ではドーパント原子あるいは半導
体構成原子が拡散し、接合部の急峻性が保てないという
問題があった。また、アモルファス層を挿入する手法は
低温でアモルファス層を形成,高温で結晶層を形成する
ため、結晶成長時にアモルファス層が結晶層に変換し、
新たに転位が発生するという問題があった。また、マイ
グレーションエンハストエピタキシー法では半導体積層
構造全体を低温で形成するため不純物が取り込まれ易
く、結晶性のよい膜が得られにくいので、例えば、高い
光電変換率を追求する半導体装置を作製する場合に用い
るのは不適当であるという問題があった。
The conventional substrate cleaning treatment requires a high temperature heat treatment at 800 ° C. or higher, and the thermal cycle annealing for reducing dislocations requires a treatment at 900 ° C. For this reason, in a semiconductor device having a pn junction and a heterogeneous semiconductor junction, dopant atoms or semiconductor constituent atoms diffuse and there is a problem that the steepness of the junction cannot be maintained. In addition, since the method of inserting the amorphous layer forms the amorphous layer at a low temperature and the crystal layer at a high temperature, the amorphous layer is converted into the crystal layer during crystal growth,
There was a problem that new dislocations were generated. Further, in the migration enhancement epitaxy method, since the entire semiconductor laminated structure is formed at a low temperature, impurities are easily taken in and it is difficult to obtain a film with good crystallinity. There was a problem that it was inappropriate to use for.

【0006】本発明の第1の目的は半導体基板上に、こ
れと格子定数が異なり、かつ高品質の化合物半導体層を
形成した半導体積層構造およびその製造方法を提供する
ことにある。
A first object of the present invention is to provide a semiconductor laminated structure in which a high-quality compound semiconductor layer having a lattice constant different from that of the semiconductor substrate is formed on a semiconductor substrate, and a manufacturing method thereof.

【0007】本発明の第2の目的は高品質の化合物半導
体層を形成した半導体積層構造を用いて構成した半導体
装置およびその製造方法を提供することにある。
A second object of the present invention is to provide a semiconductor device constituted by using a semiconductor laminated structure in which a high quality compound semiconductor layer is formed and a manufacturing method thereof.

【0008】[0008]

【課題を解決するための手段】第1の目的を達成するた
めに、本発明の半導体構造は水素で表面を終端化された
半導体基板上に形成された金属層と、上記金属層上に積
層された上記金属層の構成元素の少なくとも1種を含む
化合物半導体層よりなり、かつ上記半導体基板と化合物
半導体層はその格子定数が異なるものである。
In order to achieve the first object, a semiconductor structure of the present invention comprises a metal layer formed on a semiconductor substrate whose surface is terminated with hydrogen, and a metal layer laminated on the metal layer. The compound semiconductor layer contains at least one of the constituent elements of the metal layer, and the semiconductor substrate and the compound semiconductor layer have different lattice constants.

【0009】上記金属層は例えば、化合物半導体が、元
素周期律表のIII−V 族化合物半導体である場合、その
構成元素となるGa,Al,In等の金属層であればよ
い。この金属層がGaである場合、化合物半導体はGa
As等を用いればよい。そして、本発明の上記半導体積
層構造の製造方法は表面を水素で終端化した半導体基板
上に、所定の金属層を形成し、金属層の表面層を金属元
素を構成元素とし、しかも、半導体基板と異なる格子定
数を持つ化合物半導体層に変化させ、更に、化合物半導
体層を形成する工程を含むものである。
When the compound semiconductor is, for example, a III-V group compound semiconductor of the periodic table of elements, the metal layer may be a metal layer of Ga, Al, In or the like which is a constituent element thereof. When the metal layer is Ga, the compound semiconductor is Ga.
As or the like may be used. The method for manufacturing a semiconductor laminated structure according to the present invention comprises forming a predetermined metal layer on a semiconductor substrate whose surface is terminated with hydrogen, and using the metal layer as a constituent element in the surface layer of the metal layer. The step of changing to a compound semiconductor layer having a lattice constant different from the above and further forming a compound semiconductor layer is included.

【0010】表面を終端化させた半導体基板は基板表面
をフッ酸水溶液に曝すことにより、形成できる。また、
金属層は1原子層以上,50原子層以下、形成し、例え
ば、この金属層がGaであるとき、その金属層にAsを
照射すれば、金属の表面がGaAs層に変化する。この
GaAs層上にGaおよびAsを照射すれば、GaAsエピ
タキシャル層を形成することができる。
The surface-terminated semiconductor substrate can be formed by exposing the substrate surface to a hydrofluoric acid aqueous solution. Also,
The metal layer is formed to be 1 atomic layer or more and 50 atomic layers or less. For example, when the metal layer is Ga, if the metal layer is irradiated with As, the surface of the metal changes to a GaAs layer. By irradiating this GaAs layer with Ga and As, a GaAs epitaxial layer can be formed.

【0011】また、本発明の第2の目的を達成するため
に、本発明の半導体装置は半導体積層構造のいずれか一
つの構造と、この半導体積層構造の上に半導体素子を接
合した構成とするものである。半導体素子は半導体積層
構造の上部、あるいは金属層の下部の半導体基板に形成
してもよい。
In order to achieve the second object of the present invention, the semiconductor device of the present invention has a structure in which any one of the semiconductor laminated structures and a semiconductor element is bonded onto the semiconductor laminated structure. It is a thing. The semiconductor element may be formed on the semiconductor substrate above the semiconductor laminated structure or below the metal layer.

【0012】そして、本発明の半導体装置の製造方法は
上述した半導体積層構造の製造方法のいずれか一つの方
法で作製した半導体積層構造の上に、接合する化合物半
導体の接合部を形成し、この接合部が少なくとも化合物
半導体素子の一部となるように構成するものである。
In the method for manufacturing a semiconductor device of the present invention, a bonding portion of a compound semiconductor to be bonded is formed on the semiconductor laminated structure manufactured by any one of the methods for manufacturing a semiconductor laminated structure described above. The bonding portion is configured to be at least a part of the compound semiconductor element.

【0013】本発明の半導体装置の製造方法で、半導体
基板に、例えば、光電変換素子を形成すれば、金属層の
上と下に、それぞれ光電変換素子が設けられた半導体装
置を作製することもできる。
If, for example, a photoelectric conversion element is formed on a semiconductor substrate by the method for manufacturing a semiconductor device of the present invention, a semiconductor device having photoelectric conversion elements above and below a metal layer can be manufactured.

【0014】本発明の積層構造で、半導体基板はSi
を、化合物半導体層は元素周期律表のIII−V 族元素か
らなる化合物半導体を用いる。
In the laminated structure of the present invention, the semiconductor substrate is made of Si.
For the compound semiconductor layer, a compound semiconductor made of a III-V group element of the periodic table of elements is used.

【0015】[0015]

【作用】説明の便宜をはかるために、半導体がSiから
なり、化合物半導体がGaAs,金属がGaよりなる場
合を例にあげて本発明の作用について説明する。
For convenience of explanation, the operation of the present invention will be described by taking as an example the case where the semiconductor is Si, the compound semiconductor is GaAs, and the metal is Ga.

【0016】従来の技術で説明したように、SiとGa
Asは格子定数が異なるために、Si上に直接GaAs
を形成すると、両者の界面およびGaAs層中に転位が
発生する。両者は同じ結晶系を持っているため、界面で
原子は一対一に結合することができる。GaAsが数原
子層程度の厚さではGaAs原子はSi原子の格子に合
わせて歪んでいる。しかし、この時、GaAs原子には
歪みによる応力が働いている。そのため、GaAs層が
厚くなると耐えられず、結合が切れて転位が発生する。
本発明ではこの転位の発生を抑制するために、SiとG
aAsの結合を排除した。すなわち、Si表面原子の結
合を水素で終端化した。また、Siとの結合が無くなっ
たGaAs層をエピタキシャル成長させるために、Ga
金属層を挿入した。Ga金属層は水素終端化されたSi
上ではアモルファス層であるがAsを照射すると容易に
表面がGaAs層となるために、その上にGaAs結晶
層を成長できる。また、GaはGaAs結晶成長条件で
結晶化しないため、積層形成時に新たな転位が発生しな
い。
As described in the prior art, Si and Ga are used.
Since As has a different lattice constant, As is directly on GaAs
The formation of dislocations causes dislocations at the interface between them and in the GaAs layer. Since both have the same crystal system, atoms can be bonded one to one at the interface. When the thickness of GaAs is about several atomic layers, the GaAs atoms are distorted according to the lattice of Si atoms. However, at this time, stress due to strain acts on the GaAs atom. Therefore, if the GaAs layer becomes thicker, the GaAs layer cannot withstand it, the bond is broken, and dislocation occurs.
In the present invention, in order to suppress the generation of this dislocation, Si and G
The binding of aAs was eliminated. That is, the bonds of Si surface atoms were terminated with hydrogen. Further, in order to epitaxially grow the GaAs layer that has lost the bond with Si, Ga
The metal layer was inserted. Ga metal layer is hydrogen-terminated Si
Although it is an amorphous layer above, the surface easily becomes a GaAs layer upon irradiation with As, so that a GaAs crystal layer can be grown on it. Further, since Ga does not crystallize under the GaAs crystal growth conditions, new dislocations do not occur during stack formation.

【0017】実際にはSi基板表面をフッ酸水溶液に曝
すことにより、表面原子を水素で終端化できる。これに
より、基板表面に形成されている酸化膜が除去でき、ま
た、酸化膜上に付着していた汚染物も同時に除去できる
とともに、Si表面が不活性化される。このため、不純
物の付着による再汚染が防止され、化合物半導体層形成
前に、高温熱処理による基板清浄化処理を行う必要もな
くなる。
In practice, the surface atoms can be terminated with hydrogen by exposing the surface of the Si substrate to an aqueous solution of hydrofluoric acid. As a result, the oxide film formed on the surface of the substrate can be removed, contaminants attached to the oxide film can be removed at the same time, and the Si surface is inactivated. Therefore, recontamination due to adhesion of impurities is prevented, and it is not necessary to perform substrate cleaning treatment by high temperature heat treatment before forming the compound semiconductor layer.

【0018】金属層はAsとの結合によってGaAsと
なり得るGaを採用するのが最適である。しかし、Ga
Asと格子定数の近いAlAsを用いることも可能であ
るので、Alでも同様の作用がある。
For the metal layer, it is optimal to use Ga that can become GaAs by coupling with As. However, Ga
Since it is possible to use AlAs having a lattice constant close to that of As, Al has the same effect.

【0019】[0019]

【実施例】 〈実施例1〉図1は本実施例の光電変換素子の断面図で
ある。この光電変換素子はp型Si基板1,Ga層2,
GaAs層3,高濃度p型GaAs層4,p型GaAs
層5,高濃度n型GaAs層6及びn型AlGaAs層
7の積層構造からなり、p型GaAs層5,高濃度n型
GaAs層6にpn構造をもつ光電変換部が形成され
る。さらに、p型Si基板1にp型電極10が、n型A
lGaAs層7表面に高濃度n型GaAs層8,n型電
極9が形成されている。以下に、この半導体装置の作製
方法を示す。
EXAMPLES Example 1 FIG. 1 is a sectional view of a photoelectric conversion element of this example. This photoelectric conversion element includes a p-type Si substrate 1, a Ga layer 2,
GaAs layer 3, high-concentration p-type GaAs layer 4, p-type GaAs
A photoelectric conversion part having a pn structure is formed in the p-type GaAs layer 5 and the high-concentration n-type GaAs layer 6, which has a laminated structure of the layer 5, the high-concentration n-type GaAs layer 6, and the n-type AlGaAs layer 7. Further, the p-type electrode 10 is formed on the p-type Si substrate 1 by the n-type A
A high concentration n-type GaAs layer 8 and an n-type electrode 9 are formed on the surface of the 1GaAs layer 7. The manufacturing method of this semiconductor device will be described below.

【0020】p型Si基板1として、p型,抵抗率0.
5Ωcm,厚さ0.4mmで、(001)面方位を持ち、
〈110〉方向に2゜オフ傾斜させた基板を使用する。
基板は有機洗浄,水洗した後、5%フッ酸水溶液中に3
0秒浸し、その後、10秒水洗し、直ちに分子線結晶成
長装置内に搬入する。この時、RHEEDパターンはバ
ルク構造と同じ周期を持つことを表す(1×1)パター
ンを示し、表面Si原子と水素原子が結合しているた
め、表面原子の再配列が起きていないことを示してい
る。
The p-type Si substrate 1 has p-type and a resistivity of 0.
5 Ωcm, thickness 0.4 mm, (001) plane orientation,
A substrate inclined by 2 ° off in the <110> direction is used.
Substrates are washed organically and with water, and then washed with 5% hydrofluoric acid in water.
Immerse for 0 seconds, then wash for 10 seconds with water, and immediately carry it into the molecular beam crystal growth apparatus. At this time, the RHEED pattern shows a (1 × 1) pattern showing that it has the same period as the bulk structure, and shows that the rearrangement of the surface atoms has not occurred because the surface Si atoms and the hydrogen atoms are bonded. ing.

【0021】ここで、基板温度を300℃に上げるが、
RHEEDパターンは変わらず、表面が水素で終端化さ
れていることを示している。基板上にGa層2を30原
子層を形成し、その後、Asセル温度を上げ、シャッタ
操作によりAs照射し、Ga層2の表面層のGaをGa
As層3に変える。Ga層形成により、RHEEDパタ
ーンはアモルファス状態を示すハローパターンになる
が、As照射により、表面が結晶化したことを示す周期
的なスポットパターンが重なる。
Here, the substrate temperature is raised to 300 ° C.,
The RHEED pattern remains unchanged, indicating that the surface is hydrogen terminated. After forming 30 atomic layers of Ga layer 2 on the substrate, the As cell temperature is raised and As irradiation is performed by a shutter operation, so that Ga on the surface layer of Ga layer 2 is Ga.
Change to As layer 3. By forming the Ga layer, the RHEED pattern becomes a halo pattern indicating an amorphous state, but the As irradiation causes overlapping of periodic spot patterns indicating that the surface is crystallized.

【0022】この後、高濃度p型GaAs層4を3μm
形成する。この時の基板温度は成長直後は300℃と
し、0.1μm 程度成長した後、600℃まで、徐々に
上げていく。ここまでに形成したGaAsはBe濃度1
×1019/cm3 の高濃度p型である。この後、基板温度
600℃で、p型GaAs層(Be濃度;8×1016
cm3)5を2.5μm、さらに高濃度n型GaAs層(Si
濃度;3×1018/cm3)6を0.5μm、順次積層す
る。積層構造形成は10-10torr程度の超高真空で行っ
てもよいが、水素を装置内導入し、10-5torr程度の真
空で行ってもよい。
After that, the high-concentration p-type GaAs layer 4 is set to 3 μm.
Form. The substrate temperature at this time is 300 ° C. immediately after the growth, and after the growth of about 0.1 μm, it is gradually raised to 600 ° C. GaAs formed so far has a Be concentration of 1
It is a high-concentration p-type of × 10 19 / cm 3 . Then, at a substrate temperature of 600 ° C., a p-type GaAs layer (Be concentration; 8 × 10 16 /
cm 3 ) 2.5 to 2.5 μm, and a high concentration n-type GaAs layer (Si
Concentration: 3 × 10 18 / cm 3 ) 6, 0.5 μm, are sequentially laminated. The laminated structure may be formed in an ultrahigh vacuum of about 10 -10 torr, but may be formed in a vacuum of about 10 -5 torr by introducing hydrogen into the apparatus.

【0023】この方法で作製した積層構造を持つ試料に
ついて、X線回折法により、GaAs(400)回折ピー
クの半値幅を測定した結果、通常の高温熱処理法より1
0%程度半値幅が減少し、結晶性の改善が見られた。図
2に示すように、Ga層の膜厚は50原子層以下で効果
が見られることがわかる。
The half value width of the GaAs (400) diffraction peak was measured by the X-ray diffraction method for the sample having the laminated structure produced by this method.
The full width at half maximum was reduced by about 0%, and the crystallinity was improved. As shown in FIG. 2, it can be seen that the effect is observed when the thickness of the Ga layer is 50 atomic layers or less.

【0024】光電変換素子を作製するために、高濃度n
型GaAs層6の上に、さらに、窓層としてn型AlG
aAs層(Si濃度;3×1018/cm3)7を300Å、
電極接続部として高濃度n型GaAs層(Si濃度;5
×1018/cm3)8を1000Å、積層する。その後、n
型電極部だけを残して、高濃度n型GaAs層8をエッ
チングし、n型電極9及びp型電極10を形成する。
In order to manufacture a photoelectric conversion element, a high concentration n
N-type AlG as a window layer on the n-type GaAs layer 6
aAs layer (Si concentration; 3 × 10 18 / cm 3 ) 7 300 Å,
High concentration n-type GaAs layer (Si concentration; 5
× 10 18 / cm 3 ) 8 of 1000 Å are laminated. Then n
The high-concentration n-type GaAs layer 8 is etched leaving only the type electrode portion to form an n-type electrode 9 and a p-type electrode 10.

【0025】作製した光電変換素子は汎用の転位密度1
4/cm3台のGaAs基板上に作製されたGaAs光電
変換素子の70〜80%の効率を示し、しかも、作製コ
ストが1桁近く低減する。
The prepared photoelectric conversion element has a general-purpose dislocation density of 1
The efficiency of the GaAs photoelectric conversion element manufactured on the 0 4 / cm 3 GaAs substrate is 70 to 80%, and the manufacturing cost is reduced by almost one digit.

【0026】なお、本実施例で、p型Si基板1をn型
に、高濃度p型GaAs層4を高濃度n型に、p型Ga
As層5をn型に、高濃度n型GaAs層6を高濃度p
型に、n型AlGaAs層7をp型に、高濃度n型Ga
As層8を高濃度p型に、n型電極9をp型に、p型電
極10をn型にしても同様に効果がある。
In this embodiment, the p-type Si substrate 1 is n-type, the high-concentration p-type GaAs layer 4 is high-concentration n-type, and p-type Ga is used.
The As layer 5 is n-type and the high-concentration n-type GaAs layer 6 is high-concentration p.
Type, n-type AlGaAs layer 7 to p-type, high concentration n-type Ga
The same effect can be obtained by using the As layer 8 of high concentration p-type, the n-type electrode 9 of p-type, and the p-type electrode 10 of n-type.

【0027】また、本実施例で、金属層2をAlに、G
aAs層3,4,5,6をAlGaAs層にしても同様の効
果がある。
In the present embodiment, the metal layer 2 is Al and G
Even if the aAs layers 3, 4, 5, 6 are AlGaAs layers, the same effect can be obtained.

【0028】また、本実施例で、金属層2をInに、G
aAs層3,4,5,6,8をInP層に、AlGaAs
層7をInAlP層にしても同様の効果がある。
In the present embodiment, the metal layer 2 is In and G
aAs layers 3, 4, 5, 6, 8 as InP layers, AlGaAs
Even if the layer 7 is an InAlP layer, the same effect can be obtained.

【0029】〈実施例2〉図3は本実施例の光電変換素
子の断面図である。この光電変換素子を備えた半導体装
置はp型GaAs層5,高濃度n型GaAs層6にpn
構造を持つGaAs光電変換部と、p型Si基板1,高濃
度n型Si層11にpn接合を持つSi光電変換部を形
成している。以下に、この半導体装置の作製方法につい
て説明する。
<Embodiment 2> FIG. 3 is a sectional view of a photoelectric conversion element of the present embodiment. A semiconductor device equipped with this photoelectric conversion element has a p-type GaAs layer 5, a high-concentration n-type GaAs layer 6, and a pn layer.
A GaAs photoelectric conversion portion having a structure, a p-type Si substrate 1, and a high-concentration n-type Si layer 11 are formed into a Si photoelectric conversion portion having a pn junction. Hereinafter, a method for manufacturing this semiconductor device will be described.

【0030】p型Si基板1に800℃でPを拡散し、
0.4μm の高濃度n型Si層11を形成する。その
後、p型Si基板1の裏面に形成されている高濃度n型
Si層をエッチングし、Alを蒸着し、約700℃で熱
処理することにより、高濃度p型Si層12を形成す
る。このSi基板上に、実施例1と同様の手法で表面の
水素終端化処理をした後、GaAs光電変換部を持つ光
電変換素子を作製する。
P is diffused into the p-type Si substrate 1 at 800 ° C.,
A high concentration n-type Si layer 11 having a thickness of 0.4 μm is formed. After that, the high-concentration n-type Si layer formed on the back surface of the p-type Si substrate 1 is etched, Al is vapor-deposited, and heat-treated at about 700 ° C. to form the high-concentration p-type Si layer 12. On this Si substrate, the surface is hydrogen-terminated by the same method as in Example 1, and then a photoelectric conversion element having a GaAs photoelectric conversion portion is manufactured.

【0031】作製した光電変換素子は短波長から、順
次、GaAs,Siに対応した波長の太陽光を吸収する
ため、実施例1に示した半導体装置より、さらに30%
程度高い効率を得ることができた。
The produced photoelectric conversion element absorbs sunlight having wavelengths corresponding to GaAs and Si sequentially from a short wavelength. Therefore, the photoelectric conversion element is 30% more than that of the semiconductor device shown in the first embodiment.
It was possible to obtain a high efficiency.

【0032】なお、本実施例でも、p型Si基板1をn
型に、高濃度n型Si層11を高濃度p型に、高濃度p
型Si層12をn型に、高濃度p型GaAs層4を高濃
度n型に、p型GaAs層5をn型に、高濃度n型Ga
As層6を高濃度p型に、n型AlGaAs層7をp型
に、高濃度n型GaAs層8を高濃度p型に、n型電極
9をp型に、p型電極10をn型にしても同様に効果が
ある。
In this embodiment also, the p-type Si substrate 1 is n-type.
The high-concentration n-type Si layer 11 to the high-concentration p-type
-Type Si layer 12 is n-type, high-concentration p-type GaAs layer 4 is high-concentration n-type, p-type GaAs layer 5 is n-type, high-concentration n-type Ga
The As layer 6 is a high-concentration p-type, the n-type AlGaAs layer 7 is a p-type, the high-concentration n-type GaAs layer 8 is a high-concentration p-type, the n-type electrode 9 is a p-type, and the p-type electrode 10 is an n-type. However, it has the same effect.

【0033】また、本実施例で、金属層2をAlに、G
aAs層3,4,5,6をAlGaAs層にしても同様の効
果がある。
Also, in this embodiment, the metal layer 2 is made of Al and G
Even if the aAs layers 3, 4, 5, 6 are AlGaAs layers, the same effect can be obtained.

【0034】また、本実施例で、金属層2をInに、G
aAs層3,4,5,6,8をInP層に、AlGaAs
層7をInAlP層にしても同様の効果がある。
In the present embodiment, the metal layer 2 is In and G
aAs layers 3, 4, 5, 6, 8 as InP layers, AlGaAs
Even if the layer 7 is an InAlP layer, the same effect can be obtained.

【0035】〈実施例3〉図4は本実施例の光電変換素
子の断面図である。この光電変換素子はp型Si基板2
1,ピラミッド状の高濃度p型GaAs層25,p型G
aAs層26,高濃度n型GaAs層27およびn型A
lGaAs層28の積層構造からなり、p型GaAs層
26と、高濃度n型GaAs層27に、pn構造を持つ
光電変換部が形成される。さらに、p型Si基板21に
p型電極31が、n型AlGaAs層28表面の平坦部
に高濃度GaAs層29、高濃度GaAs層29上にn
型電極30が形成されている。以下に、この半導体装置
の作製方法を示す。
<Embodiment 3> FIG. 4 is a sectional view of a photoelectric conversion element of this embodiment. This photoelectric conversion element is a p-type Si substrate 2
1, pyramidal high-concentration p-type GaAs layer 25, p-type G
aAs layer 26, high-concentration n-type GaAs layer 27, and n-type A
A photoelectric conversion portion having a pn structure is formed in the p-type GaAs layer 26 and the high-concentration n-type GaAs layer 27, which has a laminated structure of the lGaAs layer 28. Furthermore, a p-type electrode 31 is formed on the p-type Si substrate 21, a high-concentration GaAs layer 29 is formed on a flat portion of the surface of the n-type AlGaAs layer 28, and an n-type is formed on the high-concentration GaAs layer 29.
The mold electrode 30 is formed. The manufacturing method of this semiconductor device will be described below.

【0036】p型Si基板21として、p型、抵抗率
0.5Ωcm,厚さ0.4mmで、(001)面方位を持ち、
〈110〉方向に2゜オフ傾斜させた基板を使用する。
この基板上に、SiO2膜を3000Å形成し、フォト
リソグラフ法により、〈110〉〈−110〉を辺とす
る四角形の開口部を形成する。開口部の長さ、開口部間
の間隔は入射光量あるいはSiO2 膜領域を除去して形
成される電極30の比抵抗に応じて変えることができ
る。ここでは開口部の長さを縦横とも50μm,開口部
の間隔を10μmとした(図5参照)。この方法で加工
用マスクを形成したSi基板を、5%フッ酸水溶液中に
30秒浸し、その後、10秒水洗し、直ちに有機金属気
相結晶成長装置に導入する。この時、Si表面のRHE
EDパターンを観察すれば、実施例と同様に(1×1)
パターンが観察される。
The p-type Si substrate 21 is p-type, has a resistivity of 0.5 Ωcm, a thickness of 0.4 mm, and has a (001) plane orientation.
A substrate inclined by 2 ° off in the <110> direction is used.
A SiO 2 film is formed on this substrate at a thickness of 3000 Å, and a quadrangular opening having sides of <110> and <−110> is formed by photolithography. The length of the openings and the distance between the openings can be changed according to the amount of incident light or the specific resistance of the electrode 30 formed by removing the SiO 2 film region. Here, the length of the openings is 50 μm in both length and width, and the interval between the openings is 10 μm (see FIG. 5). The Si substrate on which the processing mask is formed by this method is immersed in a 5% hydrofluoric acid aqueous solution for 30 seconds, then washed with water for 10 seconds, and immediately introduced into the metal-organic vapor phase crystal growth apparatus. At this time, RHE on the Si surface
If the ED pattern is observed, it is (1 × 1) as in the example.
The pattern is observed.

【0037】ここで、基板温度を300℃に上げ、実施
例1と同様に基板上にGa層23を30原子層形成し、
その後、Asセル温度を上げ、シャッタ操作によりAs
照射し、Ga層23の表面層のGaをGaAs化した層
24を形成する。
Here, the substrate temperature was raised to 300 ° C., and 30 atomic layers of the Ga layer 23 was formed on the substrate in the same manner as in Example 1.
After that, raise the As cell temperature and operate As
Irradiation is performed to form a layer 24 in which Ga in the surface layer of the Ga layer 23 is GaAs.

【0038】この後、Zn濃度1×1019/cm3 の高濃
度p型GaAsを成長させる。この時の基板温度は成長
直後は300℃とし、0.1μm 成長した後、600℃
まで徐々に温度を上げていく。図5で示すように、Ga
AsはSiO2 膜22上には成長せず、Si上(開口
部)のみに成長し、しかも、ピラミッド状の高濃度p型
GaAs層25が形成される。この後、SiO2 膜22
を除去し、p型GaAs層(Zn濃度:8×1016/cm
3)26を2.5μm、さらに高濃度n型GaAs層(S
e濃度:3×1018/cm3)27を0.5μmを順次積層
する。
After that, high-concentration p-type GaAs having a Zn concentration of 1 × 10 19 / cm 3 is grown. The substrate temperature at this time is 300 ° C. immediately after growth, and 600 ° C. after 0.1 μm growth.
Gradually raise the temperature until. As shown in FIG.
As does not grow on the SiO 2 film 22, but only on Si (opening), and a pyramidal high-concentration p-type GaAs layer 25 is formed. After this, the SiO 2 film 22
Of the p-type GaAs layer (Zn concentration: 8 × 10 16 / cm
3 ) 26 to 2.5 μm, and a high concentration n-type GaAs layer (S
e Concentration: 3 × 10 18 / cm 3 ) 27 is sequentially laminated to 0.5 μm.

【0039】光電変換素子を作製するために、高濃度n
型GaAs層27の上に、さらに窓層としてn型AlG
aAs(Se濃度:3×1018/cm3)28を300Å、
電極接続部として高濃度n型GaAs層(Se濃度:5
×1018/cm3)29を1000Åの厚さに積層する。その
後、ピラミッド部の高濃度n型GaAs層29のみをエ
ッチングし、n型電極30を、また、基板裏面にp型電
極31を形成する。なお、p型GaAs層26形成前
に、上述のフッ酸によるSi基板処理を再度行ってもよ
い。
In order to manufacture a photoelectric conversion element, a high concentration n
N-type AlG as a window layer on the n-type GaAs layer 27
aAs (Se concentration: 3 × 10 18 / cm 3 ) 28 300 Å,
A high-concentration n-type GaAs layer (Se concentration: 5)
× 10 18 / cm 3 ) 29 is laminated to a thickness of 1000Å. After that, only the high-concentration n-type GaAs layer 29 in the pyramid portion is etched to form the n-type electrode 30 and the p-type electrode 31 on the back surface of the substrate. The Si substrate treatment with hydrofluoric acid may be performed again before the p-type GaAs layer 26 is formed.

【0040】なお、本実施例でも、p型Si基板21を
n型に、高濃度p型GaAs層25を高濃度n型に、p
型GaAs層26をn型に、高濃度n型GaAs層27
を高濃度p型に、n型AlGaAs層28をp型に、高
濃度n型GaAs層29を高濃度p型に、n型電極30
をp型に、p型電極31をn型にしても同様に効果があ
る。
Also in this embodiment, the p-type Si substrate 21 is n-type, the high-concentration p-type GaAs layer 25 is high-concentration n-type, and
N-type GaAs layer 26 and high-concentration n-type GaAs layer 27
To the high-concentration p-type, the n-type AlGaAs layer 28 to the p-type, the high-concentration n-type GaAs layer 29 to the high-concentration p-type, and the n-type electrode 30.
Is also p-type and the p-type electrode 31 is n-type, the same effect is obtained.

【0041】また、本実施例で、金属層23をAlに、
GaAs層24,25,26,27をAlGaAs層に
しても同様の効果がある。
Further, in this embodiment, the metal layer 23 is made of Al,
Even if the GaAs layers 24, 25, 26 and 27 are AlGaAs layers, the same effect can be obtained.

【0042】また、本実施例で、金属層23をInに、
GaAs層24,25,26,27,29をInP層
に、AlGaAs層28をInAlP層にしても同様の
効果がある。
In the present embodiment, the metal layer 23 is In,
The same effect can be obtained by using the GaAs layers 24, 25, 26, 27 and 29 as InP layers and the AlGaAs layer 28 as InAlP layers.

【0043】[0043]

【発明の効果】本発明の半導体積層構造を有する半導体
装置は水素終端化により表面を不活性化した半導体基板
を用いるため、高温熱処理による基板表面の清浄化処理
を必要とせず、基板内に不純物拡散層による接合を持つ
Si基板あるいは加工用マスクを形成したSi基板を用
いてGaAs積層構造が形成できる。また、その基板上
に設けた金属表面を、GaAs,AlAsあるいはIn
P等に変えることにより、Si基板と結合を持たないG
aAs,InPがエピタキシャル成長できるため、格子
不整合による転位の発生を抑制した積層構造が形成でき
る。
Since the semiconductor device having the semiconductor laminated structure of the present invention uses the semiconductor substrate whose surface is inactivated by hydrogen termination, it is not necessary to clean the surface of the substrate by high temperature heat treatment, and impurities in the substrate are not required. A GaAs laminated structure can be formed using a Si substrate having a junction with a diffusion layer or a Si substrate on which a processing mask is formed. In addition, the metal surface provided on the substrate is replaced with GaAs, AlAs or In.
By changing to P etc., G which has no bond with Si substrate
Since aAs and InP can be epitaxially grown, it is possible to form a laminated structure in which the generation of dislocations due to lattice mismatch is suppressed.

【0044】このため、作製された光電変換素子はGa
As基板上あるいはInP基板上に作製されたものに近
い高性能が得られる。しかも基板材料として安価なSi
を使用しているため、価格を従来の1/10以下に低減
できる。
Therefore, the manufactured photoelectric conversion element is Ga
High performance close to that produced on an As substrate or an InP substrate can be obtained. Moreover, Si is an inexpensive substrate material
Since it uses, the price can be reduced to 1/10 or less of the conventional price.

【0045】また、Si光電変換素子上にGaAs光電
変換素子が電気的,結晶学的に接続されているタンデム
型光電変換素子が作製できるため、作製プロセスが簡素
化でき、しかも、効率が30〜50%向上する。
Since a tandem type photoelectric conversion element in which a GaAs photoelectric conversion element is electrically and crystallographically connected to a Si photoelectric conversion element can be manufactured, the manufacturing process can be simplified and the efficiency is 30 to 30. Improve by 50%.

【0046】また、Si基板表面を加工マスクで覆うこ
とにより、ピラミッド構造のGaAs光電変換素子を作製
できる。この光電変換素子は入射光をピラミッド内で多
重反射させることにより光路長を長くとれるため、効率
が20〜30%向上する。
By covering the surface of the Si substrate with a processing mask, a GaAs photoelectric conversion element having a pyramid structure can be manufactured. This photoelectric conversion element can increase the optical path length by multiply reflecting the incident light in the pyramid, so that the efficiency is improved by 20 to 30%.

【図面の簡単な説明】[Brief description of drawings]

【図1】本実施例1で示した表面を水素で終端化したS
i基板上に、Ga層,GaAs層を形成して構成したG
aAs光電変換素子の断面図。
FIG. 1 is an S-terminated surface of the surface shown in Example 1 with hydrogen.
G formed by forming Ga layer and GaAs layer on i substrate
Sectional drawing of aAs photoelectric conversion element.

【図2】表面を水素で終端化したSi基板上に形成した
Ga層膜厚とその上に形成したGaAs層からのX線回
折線半値幅の関係を示す特性図。
FIG. 2 is a characteristic diagram showing the relationship between the thickness of a Ga layer formed on a Si substrate whose surface is terminated with hydrogen and the half width of the X-ray diffraction line from a GaAs layer formed thereon.

【図3】本実施例2で示した光電変化部を持つSi基板
上に、実施例1のGaAs光電変換素子を形成した光電
変換素子の断面図。
FIG. 3 is a cross-sectional view of a photoelectric conversion element in which the GaAs photoelectric conversion element of Example 1 is formed on the Si substrate having the photoelectric conversion portion shown in Example 2;

【図4】本実施例3で示したSi基板上に形成したピラ
ミッド状GaAs光電変換素子の断面図。
FIG. 4 is a sectional view of a pyramidal GaAs photoelectric conversion element formed on a Si substrate shown in the third embodiment.

【図5】加工用マスクを用いてピラミッド状GaAs層
を形成したSi基板の断面図。
FIG. 5 is a cross-sectional view of a Si substrate on which a pyramidal GaAs layer is formed using a processing mask.

【符号の説明】[Explanation of symbols]

1…p型Si基板、2…Ga層、3…GaAs層、4…
高濃度p型GaAs層、5…p型GaAs層、6…高濃
度n型GaAs層、7…n型AlGaAs層、8…高濃
度n型GaAs層、9…n型電極、10…p型電極。
1 ... p-type Si substrate, 2 ... Ga layer, 3 ... GaAs layer, 4 ...
High-concentration p-type GaAs layer, 5 ... p-type GaAs layer, 6 ... high-concentration n-type GaAs layer, 7 ... n-type AlGaAs layer, 8 ... high-concentration n-type GaAs layer, 9 ... n-type electrode, 10 ... p-type electrode .

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】表面を水素によって終端化された半導体基
板上に所定の金属層と、上記金属層上に上記金属層の構
成元素の少なくとも一つを含む化合物半導体層からな
り、上記半導体基板と上記化合物半導体とは格子定数が
異なり、上記金属層は少なくとも一原子層であることを
特徴とする半導体積層構造。
1. A semiconductor substrate comprising a predetermined metal layer on a semiconductor substrate whose surface is terminated by hydrogen, and a compound semiconductor layer containing at least one of the constituent elements of the metal layer on the metal layer. A semiconductor multi-layer structure having a lattice constant different from that of the compound semiconductor, wherein the metal layer is at least one atomic layer.
【請求項2】請求項1において、上記化合物半導体層は
元素周期律表のIII−V 族元素からなる半導体積層構
造。
2. The semiconductor laminated structure according to claim 1, wherein the compound semiconductor layer is made of a III-V group element of the periodic table of elements.
【請求項3】請求項1または2において、上記半導体基
板はシリコンからなり、表面を水素によって終端化され
ている半導体積層構造。
3. The semiconductor laminated structure according to claim 1, wherein the semiconductor substrate is made of silicon and the surface of which is terminated by hydrogen.
【請求項4】請求項3において、上記化合物半導体はG
aAsからなり、上記金属層はGaあるいはAlからな
る半導体積層構造。
4. The compound semiconductor according to claim 3, wherein the compound semiconductor is G.
The semiconductor layered structure is made of aAs and the metal layer is made of Ga or Al.
【請求項5】請求項3において、上記化合物半導体はI
nPからなり、上記金属層はInからなる半導体積層構
造。
5. The compound semiconductor according to claim 3, wherein the compound semiconductor is I.
A semiconductor laminated structure made of nP and the metal layer made of In.
【請求項6】請求項1,2,3,4または5において、
上記半導体積層構造上に半導体素子を配設してなる半導
体装置。
6. The method of claim 1, 2, 3, 4, or 5,
A semiconductor device in which a semiconductor element is disposed on the semiconductor laminated structure.
【請求項7】所定の半導体基板の表面を水素で終端化す
る第1の工程と、上記半導体基板上に金属層を形成する
第2の工程と、上記金属層の表面を化合物半導体に変化
させる第3の工程と、上記化合物半導体の表面上に化合
物半導体層を形成する第4の工程を含むことを特徴とす
る半導体積層構造の製造方法。
7. A first step of terminating the surface of a predetermined semiconductor substrate with hydrogen, a second step of forming a metal layer on the semiconductor substrate, and converting the surface of the metal layer into a compound semiconductor. A method of manufacturing a semiconductor laminated structure, comprising: a third step; and a fourth step of forming a compound semiconductor layer on the surface of the compound semiconductor.
【請求項8】請求項7において、上記半導体基板の表面
を水素で終端する第1の工程は、上記半導体基板をフッ
酸水溶液中に浸漬する工程を含む半導体積層構造の作製
方法。
8. The method for manufacturing a semiconductor laminated structure according to claim 7, wherein the first step of terminating the surface of the semiconductor substrate with hydrogen includes a step of immersing the semiconductor substrate in a hydrofluoric acid aqueous solution.
【請求項9】請求項7または請求項8において、上記金
属層の表面を上記化合物半導体に変化させる第3の工程
は、上記金属層上に、上記化合物半導体の構成元素で上
記金属層の構成元素とは異なる元素を照射する工程を含
む半導体積層構造の製造方法。
9. The method according to claim 7 or 8, wherein the third step of converting the surface of the metal layer into the compound semiconductor comprises forming the metal layer on the metal layer with a constituent element of the compound semiconductor. A method for manufacturing a semiconductor laminated structure, comprising the step of irradiating an element different from the element.
【請求項10】請求項7,請求項8または請求項9にお
いて、上記化合物半導体は元素周期律表のIII−V 族化
合物半導体により構成される半導体積層構造の製造方
法。
10. The method for manufacturing a semiconductor laminated structure according to claim 7, 8 or 9, wherein the compound semiconductor is a III-V group compound semiconductor of the periodic table of elements.
【請求項11】請求項7から請求項10のいずれか1項
に記載の方法により作製した上記半導体積層構造上に、
上記半導体積層構造とは異なる異種の化合物半導体素子
の接合部を形成し、上記化合物半導体素子の接合部を半
導体素子の一部とする半導体装置の製造方法。
11. On the semiconductor laminated structure produced by the method according to claim 7,
A method of manufacturing a semiconductor device, wherein a junction of a compound semiconductor element of a different type different from the semiconductor laminated structure is formed, and the junction of the compound semiconductor element is a part of the semiconductor element.
【請求項12】請求項6に記載の上記半導体装置を複数
種電気的に接続して構成した半導体装置。
12. A semiconductor device formed by electrically connecting a plurality of types of the semiconductor device according to claim 6.
JP7169524A 1995-07-05 1995-07-05 Semiconductor laminated structure, manufacturing method thereof, and semiconductor device using the same Pending JPH0922872A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7169524A JPH0922872A (en) 1995-07-05 1995-07-05 Semiconductor laminated structure, manufacturing method thereof, and semiconductor device using the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7169524A JPH0922872A (en) 1995-07-05 1995-07-05 Semiconductor laminated structure, manufacturing method thereof, and semiconductor device using the same

Publications (1)

Publication Number Publication Date
JPH0922872A true JPH0922872A (en) 1997-01-21

Family

ID=15888107

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7169524A Pending JPH0922872A (en) 1995-07-05 1995-07-05 Semiconductor laminated structure, manufacturing method thereof, and semiconductor device using the same

Country Status (1)

Country Link
JP (1) JPH0922872A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002203981A (en) * 2000-12-28 2002-07-19 Kyocera Corp Semiconductor light receiving element

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002203981A (en) * 2000-12-28 2002-07-19 Kyocera Corp Semiconductor light receiving element

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