JPH0940534A - Hair dye composition of type mixed on employment - Google Patents
Hair dye composition of type mixed on employmentInfo
- Publication number
- JPH0940534A JPH0940534A JP7210167A JP21016795A JPH0940534A JP H0940534 A JPH0940534 A JP H0940534A JP 7210167 A JP7210167 A JP 7210167A JP 21016795 A JP21016795 A JP 21016795A JP H0940534 A JPH0940534 A JP H0940534A
- Authority
- JP
- Japan
- Prior art keywords
- component
- hair dye
- agent
- dye composition
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 239000000118 hair dye Substances 0.000 title claims abstract description 54
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 66
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 26
- 239000000194 fatty acid Substances 0.000 claims abstract description 26
- 229930195729 fatty acid Natural products 0.000 claims abstract description 26
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 24
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 24
- 239000000975 dye Substances 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 10
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 10
- 239000007800 oxidant agent Substances 0.000 claims abstract description 10
- -1 olefin sulfonates Chemical class 0.000 claims description 29
- 238000002360 preparation method Methods 0.000 claims description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 4
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 3
- 150000003512 tertiary amines Chemical class 0.000 claims description 3
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 2
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical class C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims 2
- 150000001408 amides Chemical class 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 27
- 238000005562 fading Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 description 23
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 15
- 235000019441 ethanol Nutrition 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 10
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 9
- 239000008213 purified water Substances 0.000 description 9
- 230000008719 thickening Effects 0.000 description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 6
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 6
- 239000005642 Oleic acid Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 239000003240 coconut oil Substances 0.000 description 5
- 235000019864 coconut oil Nutrition 0.000 description 5
- TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical compound [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 description 5
- 239000004973 liquid crystal related substance Substances 0.000 description 5
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 5
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 5
- 229960002216 methylparaben Drugs 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 229940079864 sodium stannate Drugs 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000002211 L-ascorbic acid Substances 0.000 description 4
- 235000000069 L-ascorbic acid Nutrition 0.000 description 4
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 4
- 229960005070 ascorbic acid Drugs 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000008363 phosphate buffer Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 229960001755 resorcinol Drugs 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 3
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 3
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 150000004671 saturated fatty acids Chemical class 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 2
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 2
- 229910001651 emery Inorganic materials 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- QOSATHPSBFQAML-UHFFFAOYSA-N hydrogen peroxide;hydrate Chemical compound O.OO QOSATHPSBFQAML-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- CNVZJPUDSLNTQU-SEYXRHQNSA-N petroselinic acid Chemical compound CCCCCCCCCCC\C=C/CCCCC(O)=O CNVZJPUDSLNTQU-SEYXRHQNSA-N 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003531 protein hydrolysate Substances 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- IHWGANISMYLGDC-UHFFFAOYSA-N (2-amino-5-nitrophenyl) hydrogen sulfate Chemical compound NC1=CC=C([N+]([O-])=O)C=C1OS(O)(=O)=O IHWGANISMYLGDC-UHFFFAOYSA-N 0.000 description 1
- GOAGYXMUVBZZQV-UHFFFAOYSA-N (5-amino-2-methylphenyl) hydrogen sulfate Chemical compound CC1=CC=C(N)C=C1OS(O)(=O)=O GOAGYXMUVBZZQV-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- ZVRMGCSSSYZGSM-CCEZHUSRSA-N (E)-hexadec-2-enoic acid Chemical compound CCCCCCCCCCCCC\C=C\C(O)=O ZVRMGCSSSYZGSM-CCEZHUSRSA-N 0.000 description 1
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- ICVRBKCRXNVOJC-UHFFFAOYSA-N 1-amino-4-(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2NC ICVRBKCRXNVOJC-UHFFFAOYSA-N 0.000 description 1
- IFBDFMPSOCGRKA-UHFFFAOYSA-N 1-octadecoxyoctadecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC IFBDFMPSOCGRKA-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- OXEDXHIBHVMDST-UHFFFAOYSA-N 12Z-octadecenoic acid Natural products CCCCCC=CCCCCCCCCCCC(O)=O OXEDXHIBHVMDST-UHFFFAOYSA-N 0.000 description 1
- VPMMJSPGZSFEAH-UHFFFAOYSA-N 2,4-diaminophenol;hydrochloride Chemical compound [Cl-].NC1=CC=C(O)C([NH3+])=C1 VPMMJSPGZSFEAH-UHFFFAOYSA-N 0.000 description 1
- KZTWOUOZKZQDMN-UHFFFAOYSA-N 2,5-diaminotoluene sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 description 1
- RMCCONIRBZIDTH-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 1,3-dioxo-2-benzofuran-5-carboxylate Chemical compound CC(=C)C(=O)OCCOC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 RMCCONIRBZIDTH-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- VLZVIIYRNMWPSN-UHFFFAOYSA-N 2-Amino-4-nitrophenol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1O VLZVIIYRNMWPSN-UHFFFAOYSA-N 0.000 description 1
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 description 1
- DABQDIXIAXPQFG-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]ethanesulfonic acid Chemical compound CCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O DABQDIXIAXPQFG-UHFFFAOYSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- JSQGOXTYKZBABW-UHFFFAOYSA-N 3-(3-hydroxyanilino)phenol Chemical compound OC1=CC=CC(NC=2C=C(O)C=CC=2)=C1 JSQGOXTYKZBABW-UHFFFAOYSA-N 0.000 description 1
- BMUDPLZKKRQECS-UHFFFAOYSA-K 3-[18-(2-carboxyethyl)-8,13-bis(ethenyl)-3,7,12,17-tetramethylporphyrin-21,24-diid-2-yl]propanoic acid iron(3+) hydroxide Chemical compound [OH-].[Fe+3].[N-]1C2=C(C)C(CCC(O)=O)=C1C=C([N-]1)C(CCC(O)=O)=C(C)C1=CC(C(C)=C1C=C)=NC1=CC(C(C)=C1C=C)=NC1=C2 BMUDPLZKKRQECS-UHFFFAOYSA-K 0.000 description 1
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 1
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- DGRGLKZMKWPMOH-UHFFFAOYSA-N 4-methylbenzene-1,2-diamine Chemical compound CC1=CC=C(N)C(N)=C1 DGRGLKZMKWPMOH-UHFFFAOYSA-N 0.000 description 1
- UIBDOIWJPGLGEJ-UHFFFAOYSA-N 4-n-(4-aminophenyl)benzene-1,4-diamine;sulfuric acid Chemical compound [O-]S([O-])(=O)=O.C1=CC(N)=CC=C1[NH2+]C1=CC=C(N)C=C1.C1=CC(N)=CC=C1[NH2+]C1=CC=C(N)C=C1 UIBDOIWJPGLGEJ-UHFFFAOYSA-N 0.000 description 1
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
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- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
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- 241000196324 Embryophyta Species 0.000 description 1
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- 239000001263 FEMA 3042 Substances 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
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- 206010040880 Skin irritation Diseases 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
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- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229920003118 cationic copolymer Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 235000019646 color tone Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- UKJLNMAFNRKWGR-UHFFFAOYSA-N cyclohexatrienamine Chemical group NC1=CC=C=C[CH]1 UKJLNMAFNRKWGR-UHFFFAOYSA-N 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- PSHRANCNVXNITH-UHFFFAOYSA-N dimethylamino acetate Chemical compound CN(C)OC(C)=O PSHRANCNVXNITH-UHFFFAOYSA-N 0.000 description 1
- WODOUQLMOIMKAL-FJSYBICCSA-L disodium;(2s)-2-(octadecanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O WODOUQLMOIMKAL-FJSYBICCSA-L 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 229940109738 hematin Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- PNEVDCGZQWFIKV-UHFFFAOYSA-N hydron;4-n-phenylbenzene-1,4-diamine;chloride Chemical compound Cl.C1=CC(N)=CC=C1NC1=CC=CC=C1 PNEVDCGZQWFIKV-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- OYHQOLUKZRVURQ-AVQMFFATSA-N linoelaidic acid Chemical compound CCCCC\C=C\C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-AVQMFFATSA-N 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical group [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N n,n-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 description 1
- ZTQDYDIRBKMMQB-UHFFFAOYSA-N n-(4-aminophenyl)nitramide Chemical compound NC1=CC=C(N[N+]([O-])=O)C=C1 ZTQDYDIRBKMMQB-UHFFFAOYSA-N 0.000 description 1
- PETZRPLPRZXTAD-UHFFFAOYSA-N n-(4-aminophenyl)nitramide;hydrochloride Chemical compound Cl.NC1=CC=C(N[N+]([O-])=O)C=C1 PETZRPLPRZXTAD-UHFFFAOYSA-N 0.000 description 1
- OUWSWIUKTXTNRI-UHFFFAOYSA-N n-(4-aminophenyl)nitramide;sulfuric acid Chemical compound OS(O)(=O)=O.NC1=CC=C(N[N+]([O-])=O)C=C1 OUWSWIUKTXTNRI-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000001024 permanent hair color Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000008055 phosphate buffer solution Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 229940116985 potassium lauryl sulfate Drugs 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 229950005425 sodium myristyl sulfate Drugs 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- UPUIQOIQVMNQAP-UHFFFAOYSA-M sodium;tetradecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCOS([O-])(=O)=O UPUIQOIQVMNQAP-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- BBECRFZLZMRJLF-UHFFFAOYSA-N tetradecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCCCOS(O)(=O)=O BBECRFZLZMRJLF-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- AQWHMKSIVLSRNY-UHFFFAOYSA-N trans-Octadec-5-ensaeure Natural products CCCCCCCCCCCCC=CCCCC(O)=O AQWHMKSIVLSRNY-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、用時混合型染毛剤
組成物に関する。より具体的には、本発明は、組み合わ
さった状態において、特定の成分を含んでなる染毛剤組
成物に関する。TECHNICAL FIELD The present invention relates to a before-use mixed type hair dye composition. More specifically, the present invention relates to a hair dye composition comprising specific components in a combined state.
【０００２】[0002]
【従来の技術】従来、用時混合型（すなわち、使用時に
２剤以上が組み合わされる）染毛剤としては、２液式の
ものが通常使用されており、芳香族アミノ化合物を初め
とする酸化染料を主剤として含む第１剤と、過酸化水素
等の酸化剤を主剤として含む第２剤を使用時に混合して
形成されるものが典型的である。使用に際してはこの混
合物を毛髪に塗布して用いるため、混合物は毛髪から垂
れ落ちない程度の粘度が必要である。このため従来の技
術では、非イオン性界面活性剤水溶液の液晶領域を利用
して混合時の増粘系を得ている。すなわち、液晶形成濃
度以上の濃厚な非イオン性界面活性剤及び低級アルコー
ルを染料と共に配合した第１剤を、酸化剤を含む第２剤
で稀釈して最終混合物の界面活性剤を液晶領域に濃度調
整することにより増粘系を得ていた。しかしながら、非
イオン性界面活性剤及び低級アルコールの濃厚な従来系
は、染色後の毛髪の感触がぱさつき、また、混合時は液
晶となるため染料の分散が悪く、染着性が悪いという欠
点があった。2. Description of the Related Art Conventionally, a two-pack type hair dye has been generally used as a mixed type hair dye (that is, two or more agents are combined at the time of use), and oxidation such as aromatic amino compounds is used. It is typically formed by mixing a first agent containing a dye as a main agent and a second agent containing an oxidizing agent such as hydrogen peroxide as a main agent at the time of use. Since this mixture is applied to hair before use, the mixture must have a viscosity such that it does not drip from the hair. Therefore, in the conventional technique, a thickening system at the time of mixing is obtained by utilizing the liquid crystal region of the nonionic surfactant aqueous solution. That is, the first agent in which a nonionic surfactant having a liquid crystal formation concentration or higher and a lower alcohol is mixed with a dye is diluted with a second agent containing an oxidizing agent to concentrate the surfactant of the final mixture in the liquid crystal region. A thickening system was obtained by adjusting. However, the conventional systems having a high concentration of nonionic surfactants and lower alcohols have a drawback that the hair after dyeing has a dry feel, and since it becomes a liquid crystal when mixed, the dispersion of the dye is poor and the dyeing property is poor. there were.
【０００３】一方、毛髪の染色又は色調付与と同時に、
洗浄及びコンディショニングを可能にする染毛剤を提供
することを目的に、カチオン性重合体とアニオン性界面
活性剤と両性又は両性イオン界面活性剤を、それぞれ特
定割合で含む染毛剤が提案されている（例えば、特公平
４−２２８８４号参照）。On the other hand, at the same time as dyeing or coloring the hair,
For the purpose of providing a hair dye that enables cleaning and conditioning, a hair dye containing a cationic polymer, an anionic surfactant, and an amphoteric or zwitterionic surfactant in specific proportions has been proposed. (See, for example, Japanese Patent Publication No. 4-22884).
【０００４】しかし、混合前の分離された形態にある調
製組成物において、物性が安定しており、かつ相対的に
低い粘性を示すが、使用時、すなわちすべての成分が混
合された場合には、その混合組成物が毛髪から垂れ落ち
せず、かつ所望の染色、染色後の毛髪の感触等に優れる
染毛剤を安定に提供することは困難であった。However, in the prepared composition in a separated form before mixing, the physical properties are stable and the viscosity is relatively low, but at the time of use, that is, when all the components are mixed, However, it has been difficult to stably provide a hair dye whose mixed composition does not drip from the hair and which is excellent in desired dyeing and feeling of the dyed hair.
【０００５】たとえば、上記の低級アルコールを使用す
る染毛剤によると、染色後の毛髪の感触に劣る傾向があ
った。For example, the above-mentioned hair dyes using lower alcohols tend to give poor feeling to the hair after dyeing.
【０００６】[0006]
【発明が解決しようとする課題】したがって、本発明の
目的は使用時の各成分が混合された組成物から、低級ア
ルコールの一部又はその全部を除去でき、しかも各成分
が一定の群として分離された形態にあるときは、相対的
に低粘度を示すが、それらの各成分がそれぞれ独立して
いるか、又は一体となって混合された状態では適度な粘
性を示す、用時混合型染毛剤組成物を提供することにあ
る。Therefore, the object of the present invention is to remove a part or all of the lower alcohol from the composition in which each component is mixed at the time of use, and to separate each component as a certain group. When it is in a mixed form, it has a relatively low viscosity, but when each of these components is independent or mixed together, it shows an appropriate viscosity. To provide an agent composition.
【０００７】[0007]
【課題を解決するための手段】染毛剤の技術分野に属す
るものでないが、アニオン界面活性剤と、両性界面活性
剤及び／又は半極性界面活性剤と、高級脂肪酸とを含有
する組成物は、皮膚洗浄剤として、適度な粘度を有する
ことが知られている（例えば、特開平５−１７３４２号
及び特開平６−６５５９６号公報参照）。Although not belonging to the technical field of hair dyes, a composition containing an anionic surfactant, an amphoteric surfactant and / or a semipolar surfactant, and a higher fatty acid is It is known that it has an appropriate viscosity as a skin cleanser (see, for example, JP-A-5-17342 and JP-A-6-65596).
【０００８】本発明者らは、かかる組成物中の各成分
は、用時混合型染毛剤の必須成分である染料及び過酸化
物と、それぞれ単独又は特定の組み合わせで調製した場
合には、それぞれ安定で相対的に低粘度の調製物を与え
るが、それらの全てを混合した場合には、染毛剤として
の使用目的上過度な粘性を示す混合組成物が提供できる
ことを見い出した。[0008] The inventors of the present invention, when the respective components in such a composition are prepared individually or in a specific combination with a dye and a peroxide which are essential components of a mixing type hair dye at the time of use, It has been found that each gives stable and relatively low viscosity preparations, but when all of them are mixed, a mixed composition can be provided which exhibits an excessive viscosity for the purpose of use as a hair dye.
【０００９】したがって、上記目的は、本発明による、
使用時に染料と酸化剤とが組み合わされる用時混合型染
毛剤組成物であって、（ａ） 前記組み合わさった組成
物が、染料（Ｉ）と、任意成分である両性界面活性剤及
び半極性界面活性剤からなる群より選ばれる界面活性の
１種以上（ＩＩ）と、高級脂肪酸の１種以上（ＩＩＩ）
と、アニオン性界面活性剤の１種以上（ＩＶ）と、酸化
剤（Ｖ）と、カチオン性重合体（ＶＩ）と、水（ＶＩ
Ｉ）とを含んでなり、そして（ｂ） 使用前には、成分
（Ｉ）、（ＩＩ）、（ＩＩＩ）及び（ＩＶ）からなる群
より選ばれる成分が、成分（Ｖ）及び（ＶＩ）からなる
群より選ばれる成分から分離された形態におかれる、染
毛剤組成物を提供することにより、達成される。Therefore, the above object is according to the present invention:
A fresh-use type hair dye composition in which a dye and an oxidizing agent are combined at the time of use, wherein the combined composition is (a) a dye (I), an optional amphoteric surfactant and a semi-active agent. One or more kinds of surfactants (II) selected from the group consisting of polar surfactants, and one or more kinds of higher fatty acids (III)
, At least one anionic surfactant (IV), an oxidizing agent (V), a cationic polymer (VI), and water (VI).
I) and (b) prior to use, a component selected from the group consisting of components (I), (II), (III) and (IV) comprises components (V) and (VI) It is achieved by providing a hair dye composition which is placed in a form separated from a component selected from the group consisting of:
【００１０】本発明の好ましい態様では、使用時の各成
分が組み合わさった混合組成分が、ｐＨ６〜１２をもつ
ように調整される。In a preferred embodiment of the present invention, the mixed composition in which the respective components at the time of use are combined is adjusted to have a pH of 6-12.
【００１１】[0011]
【発明の具体的な態様】本明細書にいう「用時混合型」
の語は、予め調製された２種以上の調製物が、使用時、
すなわち毛髪処理に際して混合される様式を意味する。
そのため、本発明は、一般に、永久染毛剤と称されてい
る染毛剤への適用が好都合である。Specific Embodiments of the Invention "Mixed-before-use type" referred to in the present specification
Means that when two or more pre-prepared preparations are used,
That is, it means a mode that is mixed in the hair treatment.
Therefore, the present invention is conveniently applied to a hair dye, which is generally called a permanent hair dye.
【００１２】したがって、本発明で使用する染料（成分
（Ｉ））としては、化合物自体の酸化により発色する染
料前駆体及び染料前駆体との組み合わせにより種々の色
調を呈するカップラーとの組み合わせ物が挙げられる。
限定されるものでないが、このような染料の具体的なも
のとしては、５−アミノオルトクレゾール（別名 パラ
アミノオルトクレゾール）、２−アミノ−４−ニトロフ
ェノール、２−アミノ−５−ニトロフェノール、１−ア
ミノ−４−メチルアミノアントラキノン、３,３′−イ
ミノジフェノール、塩酸２,４−ジアミノフェノール、
塩酸トルエン−２,５−ジアミン、塩酸ニトロパラフェ
ニレンジアミン、塩酸パラフェニレンジアミン、塩酸Ｎ
−フェニルパラフェニレンジアミン、塩酸メタフェニレ
ンジアミン、オルトアミノフェノール、酢酸Ｎ−フェニ
ルパラフェニレンジアミン、１,４−ジアミノアントラ
キノン、２,６−ジアミノピリジン、ジフェニルアミ
ン、トルエン−２,５−ジアミン、トルエン−３,４−ジ
アミン、ニトロパラフェニレンジアミン、パラアミノフ
ェニルスルファミン酸、パラアミノフェノール、パラニ
トロオルトフェニレンジアミン、パラフェニレンジアミ
ン、パラメチルアミノフェノール、Ｎ,Ｎ′−ビス（４
−アミノフェニル）−２,５−ジアミノ−１,４−キノン
ジイミン（別名 バンドロフスキーベース）、２−ヒド
ロキシ−５−ニトロ−２′,４′−ジアミノアゾベンゼ
ン−５−スルホン酸ナトリウム（別名クロムブラウンＲ
Ｈ）、Ｎ−フェニルパラフェニレンジアミン、メタアミ
ノフェノール、メタフェニレンジアミン、硫酸５−アミ
ノオルトクレゾール（別名 硫酸パラアミノオルトクレ
ゾール）、硫酸２−アミノ−５−ニトロフェノール、硫
酸オルトアミノフェノール、硫酸オルトクロルパラフェ
ニレンジアミン、硫酸４,４′−ジアミノジフェニルア
ミン、硫酸トルエン−２,５−ジアミン、硫酸ニトロパ
ラフェニレンジアミン、硫酸パラアミノフェノール、硫
酸パラニトロオルトフェニレンジアミン、硫酸パラニト
ロメタフェニレンジアミン、硫酸パラフェニレンジアミ
ン、硫酸パラメチルアミノフェノール、硫酸メタアミノ
フェノール、硫酸メタフェニレンジアミン、及び又は植
物染料と呼ばれるヘマティン、タンニン酸、カテコー
ル、レゾルシン等の芳香族多価アルコールが挙げられ
る。Therefore, examples of the dye (component (I)) used in the present invention include a dye precursor that develops color by the oxidation of the compound itself and a combination with a coupler that exhibits various color tones by combination with the dye precursor. To be
Specific examples of such dyes include, but are not limited to, 5-aminoorthocresol (also known as paraaminoorthocresol), 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 1 -Amino-4-methylaminoanthraquinone, 3,3'-iminodiphenol, 2,4-diaminophenol hydrochloride,
Toluene-2,5-diamine hydrochloride, nitroparaphenylenediamine hydrochloride, paraphenylenediamine hydrochloride, hydrochloric acid N
-Phenylparaphenylenediamine, metaphenylenediamine hydrochloride, orthoaminophenol, N-phenylparaphenylenediamine acetate, 1,4-diaminoanthraquinone, 2,6-diaminopyridine, diphenylamine, toluene-2,5-diamine, toluene-3 , 4-diamine, nitroparaphenylenediamine, paraaminophenylsulfamic acid, paraaminophenol, paranitroorthophenylenediamine, paraphenylenediamine, paramethylaminophenol, N, N'-bis (4
-Aminophenyl) -2,5-diamino-1,4-quinonediimine (also known as Bandrovsky base), 2-hydroxy-5-nitro-2 ', 4'-diaminoazobenzene-5-sulfonate sodium (also known as chrome brown) R
H), N-phenylparaphenylenediamine, metaaminophenol, metaphenylenediamine, 5-aminoorthocresol sulfate (also known as paraaminoorthocresol sulfate), 2-amino-5-nitrophenol sulfate, orthoaminophenol sulfate, orthochlor sulfate. Paraphenylenediamine, 4,4'-diaminodiphenylamine sulfate, toluene-2,5-diamine sulfate, nitroparaphenylenediamine sulfate, paraaminophenol sulfate, paranitroorthophenylenediamine sulfate, paranitrometaphenylenediamine sulfate, paraphenylenediamine sulfate , Paramethylaminophenol sulfate, metaaminophenol sulfate, metaphenylenediamine sulfate, and / or fragrance of hematin, tannic acid, catechol, resorcin, etc. called plant dyes Polyhydric alcohol, and the like.
【００１３】上記の染料は所望の染毛色に応じて、適宜
使用され、また場合により組み合わせて使用してもよ
い。染料の配合量は、通常、０.００１〜１０重量％で
あり、好ましくは０.０１〜５重量％である。The above dyes are appropriately used depending on the desired hair color, and may be used in combination depending on the case. The compounding amount of the dye is usually 0.001 to 10% by weight, preferably 0.01 to 5% by weight.
【００１４】また、酸化剤（成分（Ｖ））としては、前
記酸化染料と接触することにより、染料に基づく発色を
もたらすように作用し、本発明の目的に悪影響を及ぼさ
ない化合物又は系であれば、いずれも使用することがで
きる。通常、そのような化合物としては、過酸化水素を
使用するのが好ましい。また、前記系として、染料の発
色を初め毛髪の脱色をも促進するように作用する、過酸
化水素と過硫酸アンモニウムやその他の過硫酸塩とを組
み合わせた系、或いは過酸化水素とピロ亜硫酸ナトリウ
ムの組み合わせた酸化還元系を使用してもよい。このよ
うな系では使用前は過酸化水素と他の過酸化物等とが分
離した形態におかれる。The oxidant (component (V)) may be any compound or system that acts to bring about color development based on the dye when brought into contact with the oxidative dye, and does not adversely affect the object of the present invention. Both can be used. It is usually preferred to use hydrogen peroxide as such compound. In addition, as the system, a system in which hydrogen peroxide and ammonium persulfate or other persulfate are combined, which acts to promote color development of dye as well as decolorization of hair, or hydrogen peroxide and sodium pyrosulfite are used. A combination of redox systems may be used. In such a system, hydrogen peroxide and other peroxide are separated before use.
【００１５】酸化剤の使用量は、使用する染料の種類並
びに使用時の混合組成分を構成する各成分の種類及びｐ
Ｈ等によって、最適量が異なるので限定できるものでな
いが、過酸化水素を使用する場合、一般に、総組成物重
量基準で０.２〜２０重量％、好ましくは１〜５重量％
となるように選ぶことが好ましい。The amount of the oxidizing agent used is the type of dye used, the type of each component constituting the mixed composition at the time of use, and p.
Although it cannot be limited because the optimum amount varies depending on H etc., when hydrogen peroxide is used, it is generally 0.2 to 20% by weight, preferably 1 to 5% by weight based on the total weight of the composition.
It is preferable to select
【００１６】本発明で使用する両性界面活性剤（成分
（ＩＩ））は、通常の化粧品基剤等に用いられる両性界
面活性剤のであればいずれでもよい。具体例を挙げるな
らば、一般式（Ａ）The amphoteric surfactant (component (II)) used in the present invention may be any amphoteric surfactant used in ordinary cosmetic bases and the like. To give a specific example, the general formula (A)
【００１７】[0017]
【化１】 Embedded image
【００１８】で表されるアミドベタイン型両性界面活性
剤［市販品としてレボン２０００（三洋化成製）、アノ
ンＢＤＦ（日本油脂製）等が該当］、一般式（Ｂ）Amidobetaine-type amphoteric surfactant represented by the formula [commercially available products include Levon 2000 (manufactured by Sanyo Kasei), Anon BDF (manufactured by NOF CORPORATION), general formula (B)
【００１９】[0019]
【化２】 Embedded image
【００２０】で表されるアミドスルフォベタイン型両性
界面活性剤［市販品としてロンザイン−ＣＳ（ロンザ
製）、ミラタインＣＢＳ（ミラノール製）等が該当］、
一般式（Ｃ）Amidosulfobetaine-type amphoteric surfactant represented by the formula [commercially available products include Lonzain-CS (manufactured by Lonza) and Miratain CBS (manufactured by Milanol)]
General formula (C)
【００２１】[0021]
【化３】 Embedded image
【００２２】で表されるベタイン型両性界面活性剤［市
販品としてアノンＢＬ（日本油脂製）、デハイントンＡ
Ｂ−３０（ヘンケル製）等が該当］、一般式（Ｄ）A betaine-type amphoteric surfactant represented by the formula [Anon BL (manufactured by NOF CORPORATION), Deheinton A as a commercial product]
B-30 (manufactured by Henkel), etc.], general formula (D)
【００２３】[0023]
【化４】 Embedded image
【００２４】で表されるスルフォベタイン型両性界面活
性剤［市販品としてロンザイン１２ＣＳ（ロンザ製）等
が該当］、一般式（Ｅ）A sulfobetaine-type amphoteric surfactant represented by the formula [Lonzaine 12CS (manufactured by Lonza) as a commercial product is applicable], a general formula (E)
【００２５】[0025]
【化５】 Embedded image
【００２６】で表されるイミダゾリニウム型両性界面活
性剤［市販品としてオバゾリン６６２−Ｎ（東邦化学
製）、アノンＧＬＭ（日本油脂製）等が該当］等であ
る。Examples include imidazolinium-type amphoteric surfactants [commercially available products include Obazoline 662-N (manufactured by Toho Chemical Co., Ltd.) and Anon GLM (manufactured by NOF CORPORATION)].
【００２７】また、半極性界面活性剤（成分（ＩＩ））
としては、一般式（Ｆ）Further, a semipolar surfactant (component (II))
As the general formula (F)
【００２８】[0028]
【化６】 [Chemical 6]
【００２９】で表される第三級アミンオキサイド型半極
性界面活性剤（市販品としてユニセーフＡ−ＬＭ（日本
油脂製）、ワンダミンＯＸ−１００（新日本理化製）等
が該当）等が例示される。A tertiary amine oxide type semipolar surfactant represented by the formula (commercially available products such as Unisafe A-LM (manufactured by NOF Corporation) and Wandamine OX-100 (manufactured by Shin Nippon Rika)) are exemplified. It
【００３０】ただし、一般式（Ａ）〜（Ｆ）中、Ｒ
1は、平均炭素原子数９ないし２１のアルキル基又はア
ルケニル基が好ましく、平均炭素原子数１１ないし１７
のアルキル基又はアルケニル基がより好ましく、平均炭
素原子数１１ないし１３のアルキル基又はアルケニル基
が最も好ましい。平均炭素原子数が９未満では、９以上
の場合と比較して親水性が強く、最終混合組成物の増粘
が低くなる傾向がある。一方、２１を超えると、２１以
下の場合と比較して、水への溶解性が悪くなり、最終混
合組成物中で、また使用前のこれらの各成分を含む調製
物中でこれらの成分の相分離が生じる傾向があり、組成
物の安定性が悪くなる。However, in the general formulas (A) to (F), R
1 is preferably an alkyl group or an alkenyl group having an average carbon number of 9 to 21, and an average carbon number of 11 to 17
Is more preferable, and an alkyl group or alkenyl group having an average carbon number of 11 to 13 is most preferable. When the average number of carbon atoms is less than 9, the hydrophilicity is stronger than that in the case of 9 or more, and the viscosity of the final mixed composition tends to be low. On the other hand, when it exceeds 21, the solubility in water becomes poor as compared with the case of 21 or less, and these components are contained in the final mixed composition and in the preparation containing each of the components before use. Phase separation tends to occur, resulting in poor stability of the composition.
【００３１】Ｒ2は平均炭素原子数１０ないし１８のア
ルキル基又はアルケニル基を表す。ｘは２ないし４の整
数であり、ｙは０ないし３の整数であり、ｚは１または
２の整数である。R 2 represents an alkyl group or an alkenyl group having an average of 10 to 18 carbon atoms. x is an integer of 2 to 4, y is an integer of 0 to 3, and z is an integer of 1 or 2.
【００３２】本発明においては、これらの両性界面活性
剤及び半極性界面活性剤のうちの任意の一種又は二種以
上を選んで用いることができる。二種以上の組み合わせ
で好ましいものとして、イミダゾリニウムベタイン型両
性界面活性剤と、他の型の少なくとも１種との組み合わ
せを挙げることができる。In the present invention, any one or more of these amphoteric surfactants and semipolar surfactants can be selected and used. As a preferable combination of two or more kinds, a combination of an imidazolinium betaine type amphoteric surfactant and at least one kind of another type can be mentioned.
【００３３】なお、後述するが、組み合わせ使用される
アニオン界面活性剤の特定の種類を選ぶと、成分（Ｉ
Ｉ）は必ずしも本発明の染毛剤組成物に含めなくてもよ
い場合がある。As will be described later, when a specific type of anionic surfactant used in combination is selected, the component (I
I) may not necessarily be included in the hair dye composition of the present invention.
【００３４】本発明で使用する高級脂肪酸（成分（ＩＩ
Ｉ））としては、例えば、下記の一般式（Ｇ）で表され
る高級脂肪酸で、通常の化粧品基剤等に用いられている
高級脂肪酸であれば、いずれも対象とすることができ
る。The higher fatty acid (component (II
As I)), for example, any higher fatty acid represented by the following general formula (G) can be used as long as it is a higher fatty acid used in a general cosmetic base or the like.
【００３５】一般式（Ｇ） Ｒ3ＣＯＯＨ （Ｇ） ここでＲ3は、平均炭素数７〜２５の直鎖又は分岐鎖又
は水銀基を有する飽和、不飽和炭化水素が好ましく、平
均炭素数９〜２３の直鎖又は分岐鎖又は水酸基を有する
飽和、不飽和炭化水素がより好ましく、平均炭素数１１
〜２１の直鎖又は分岐鎖又は水酸基を有する飽和、不飽
和炭化水素が最も好ましい。平均炭素数が７未満では、
それ以上の場合と比較して、混合時の増粘が弱い。一
方、２５を超えると、それ以下の場合と比較して、１剤
中での溶解度が小さく、相分離し、高粘度になってしま
う。General formula (G) R 3 COOH (G) Here, R 3 is preferably a straight chain or branched chain having an average carbon number of 7 to 25, or a saturated or unsaturated hydrocarbon having a mercury group, and an average carbon number of 9 To 23 saturated or unsaturated hydrocarbons having a linear or branched chain or a hydroxyl group, and having an average carbon number of 11
Most preferred are saturated and unsaturated hydrocarbons having a straight chain or branched chain or hydroxyl group of -21. If the average carbon number is less than 7,
Compared to the case of more than that, the thickening at the time of mixing is weak. On the other hand, when it exceeds 25, the solubility in one agent is small, phase separation occurs and the viscosity becomes high as compared with the case of less than 25.
【００３６】高級脂肪酸の具体的なものとしては、ラウ
リン酸、ミリスチン酸、パルミチン酸、ステアリン酸、
アラキン酸、ベヘン酸等の飽和脂肪酸；２−パルミトレ
イン酸、ペトロセリン酸、オレイン酸、エライジン酸、
リシノール酸、リノール酸、リノエライジン酸、リノレ
ン酸、アラキドン酸等の不飽和脂肪酸、イソステアリン
酸等の分枝脂肪酸；１２−ヒドロキシステアリン酸等の
ヒドロキシカルボン酸等を挙げることができる。これら
の内、安定性及び皮膚刺激性の観点から、炭素数１８の
飽和脂肪酸が好ましく、中でも分岐を有するものが好ま
しく、さらに好ましくは室温で液状の脂肪酸、例えば、
メチル分岐を有する炭素数１８の飽和脂肪酸又はオレイ
ン酸がよい。市販品としては、例えば、イソステアリン
酸（エメリー＃８７１、＃８７５（エメリー社製））、
オレイン酸（エクストラオイレン９０、９９（日本油脂
製））等が挙げられる。Specific examples of the higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid,
Saturated fatty acids such as arachidic acid and behenic acid; 2-palmitoleic acid, petroselinic acid, oleic acid, elaidic acid,
Examples thereof include unsaturated fatty acids such as ricinoleic acid, linoleic acid, linoelaidic acid, linolenic acid, and arachidonic acid, branched fatty acids such as isostearic acid, and hydroxycarboxylic acids such as 12-hydroxystearic acid. Of these, from the viewpoints of stability and skin irritation, saturated fatty acids having 18 carbon atoms are preferable, those having a branched chain are preferable, and more preferable fatty acids that are liquid at room temperature, for example,
A saturated fatty acid having 18 carbon atoms having a methyl branch or oleic acid is preferable. Examples of commercially available products include isostearic acid (Emery # 871, # 875 (manufactured by Emery)),
Examples thereof include oleic acid (extra oil 90, 99 (manufactured by NOF CORPORATION)).
【００３７】作用機作により、拘束されるものでない
が、これらの高級脂肪酸を、上記成分（Ｉ）、任意成分
である成分（ＩＩ）及び後述するアニオン性界面活性剤
と組み合わせて使用すると、これらを含有する調製組成
物（一般に、第１剤）の低温安定性を著しく向上させる
だけでなく、使用時の混合組成物の粘度向上にも有意に
作用する。Although not restricted by the mechanism of action, when these higher fatty acids are used in combination with the above component (I), the optional component (II) and the anionic surfactant described below, It not only significantly improves the low temperature stability of the prepared composition (generally the first agent) containing but also significantly improves the viscosity of the mixed composition at the time of use.
【００３８】本発明においては、以上の高級脂肪酸のう
ちの任意の一種又は二種以上が選ばれて用いられる。In the present invention, any one or more of the above higher fatty acids are selected and used.
【００３９】使用時の混合組成物における粘性は高級脂
肪酸の配合量とともに高まり、特に、０.１〜５重量％
配合することが好ましい。The viscosity of the mixed composition at the time of use increases with the amount of the higher fatty acid compounded, and especially 0.1 to 5% by weight.
It is preferable to mix them.
【００４０】イソステアリン酸、オレイン酸等の室温で
液状の高級脂肪酸を用いると効果がより一層増大すると
ともに、−５℃以下の低温においても安定であった。When higher fatty acids which are liquid at room temperature, such as isostearic acid and oleic acid, are used, the effect is further enhanced and the stability is stable even at a low temperature of -5 ° C or lower.
【００４１】本発明で使用できるアニオン性界面活性剤
（成分（ＩＶ））としては、例えば、セッケン用素地、
ラウリン酸ナトリウム、パルミチン酸ナトリウム等の脂
肪酸セッケン、ラウリル硫酸ナトリウム、ラウリル硫酸
カリウム等の高級アルキル硫酸エステル塩、ＰＯＥラウ
リル硫酸トリエタノールアミン、ＰＯＥラウリル硫酸ナ
トリウム等のアルキルエーテル硫酸塩、ラウロイルサル
コシンナトリウム等のＮ−アシルサルコシン酸、Ｎ−ミ
リストイル−Ｎ−メチルタウリンナトリウム、Ｎ−ラウ
ロイル−Ｎ−メチルタウリンナトリウム等のアルキロイ
ルアルキルタウリン塩、ヤシ油脂肪酸メチルタウリッド
ナトリウム、ラウリルメチルタウリッドナトリウム等の
高級脂肪酸アミドスルホン酸塩、ＰＯＥオレイルエーテ
ルリン酸ナトリウム、ＰＯＥステアリルエーテルリン酸
等のリン酸エステル塩、ジ−２−エチルヘキシルスルホ
コハク酸ナトリウム、モノラウロイルモノエタノールア
ミドポリオキシエチレンスルホコハク酸ナトリウム、ラ
ウリルポリプロピレングリコールスルホコハク酸ナトリ
ウム等のスルホコハク酸塩、リニアドデシルベンゼンス
ルホン酸ナトリウム、リニアドデシルベンゼンスルホン
酸トリエタノールアミン、リニアドデシルベンゼンスル
ホン酸等のアルキルベンゼンスルホン酸塩、Ｎ−ラウロ
イルグルタミン酸モノナトリウム、Ｎ−ステアロイルグ
ルタミン酸ジナトリウム、Ｎ−ミリストイル−Ｌ−グル
タミン酸モノナトリウム等のＮ−アシルグルタミン酸
塩、硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム等の高
級脂肪酸エステル硫酸エステル塩、ロート油等の硫酸化
油、ＰＯＥアルキルエーテルカルボン酸、ＰＯＥアルキ
ルアリルエーテルカルボン酸塩、α−オレフィンスルホ
ン酸塩、高級脂肪酸エステルスルホン酸塩、二級アルコ
ール硫酸エステル塩、高級脂肪酸アルキロールアミド硫
酸エステル塩、ラウロイルモノエタノールアミドコハク
酸ナトリウム、Ｎ−パルミトイルアスパラギン酸ジトリ
エタノールアミン、カゼインナトリウム等が挙げられ
る。The anionic surfactant (component (IV)) that can be used in the present invention is, for example, a base for soap,
Fatty acid soaps such as sodium laurate and sodium palmitate, higher alkyl sulfate ester salts such as sodium lauryl sulfate and potassium lauryl sulfate, POE lauryl sulfate triethanolamine, alkyl ether sulfates such as POE sodium lauryl sulfate and sodium lauroyl sarcosine Alkyloylalkyl taurine salts such as N-acyl sarcosinic acid, N-myristoyl-N-methyl taurine sodium and N-lauroyl-N-methyl taurine sodium, higher fatty acids such as coconut oil fatty acid methyl tauride sodium and lauryl methyl tauride sodium. Amidosulfonate, sodium phosphate ester of POE oleyl ether phosphate, phosphate ester salt of POE stearyl ether phosphate, sodium di-2-ethylhexyl sulfosuccinate , Monolauroyl monoethanolamide sodium polyoxyethylene sulfosuccinate, lauryl polypropylene glycol sulfosuccinate such as sodium sulfosuccinate, sodium linear dodecylbenzene sulfonate, triethanolamine linear dodecyl benzene sulfonate, alkylbenzene sulfone such as linear dodecyl benzene sulfonate Acid salts, monosodium N-lauroylglutamate, disodium N-stearoylglutamate, N-acylglutamates such as N-myristoyl-L-monosodium glutamate, and higher fatty acid ester sulfates such as hydrogenated coconut oil fatty acid glycerin sodium sulfate; Sulfated oil such as funnel oil, POE alkyl ether carboxylic acid, POE alkyl allyl ether carboxylate, α-o Examples include reffin sulfonate, higher fatty acid ester sulfonate, secondary alcohol sulfate ester salt, higher fatty acid alkylolamide sulfate ester salt, lauroyl monoethanolamide sodium succinate, N-palmitoyl aspartate ditriethanolamine, sodium caseinate and the like. To be
【００４２】なお、上記例示中の「ＰＯＥ」は、ポリオ
キシエチレンを意味し、エチレンオキシド単位が、通
常、１〜２０のものを包含する。"POE" in the above examples means polyoxyethylene, and usually includes ethylene oxide units having 1 to 20.
【００４３】これらのうち、特に、使用時の混合組成物
の粘度を向上させるのに都合よく使用できるのは、ＰＯ
Ｅラウリル硫酸ナトリウム、ＰＯＥラウリル硫酸トリエ
タノールアミン、ＰＯＥミリスチル硫酸トリエタノール
アミン、及びＰＯＥミリスチル硫酸ナトリウム等のＰＯ
Ｅアルキルエーテル硫酸塩、ならびにＮ−ラウロイル−
Ｎ−メチルタウリン塩、Ｎ−ミリスチル−Ｎ−メチルタ
ウリン塩等のアルキロイルアルキルタウリン塩であっ
て、アルキル鎖の炭素数が１０〜１８内のいずれかの偶
数である界面活性剤、さらにα−オレフィンスルホン酸
塩である。Of these, PO is particularly useful for improving the viscosity of the mixed composition at the time of use.
PO such as E sodium lauryl sulfate, POE lauryl sulfate triethanolamine, POE myristyl sulfate triethanolamine, and POE sodium myristyl sulfate
E alkyl ether sulfate, and N-lauroyl-
Alkyloylalkyl taurine salts such as N-methyl taurine salt and N-myristyl-N-methyl taurine salt, wherein the alkyl chain has a carbon number of any of even numbers from 10 to 18, and further α- It is an olefin sulfonate.
【００４４】これらの都合よく使用できるものは、成分
（ＩＩ）を併用することなく所期の目的を達成できる。These conveniently usable ones can achieve the intended purpose without using the component (II) together.
【００４５】本発明によれば、これらのアニオン性界面
活性剤は１種以上を適宜組み合わせて使用できるが、使
用前の調製物においては、特に、成分（ＩＩ）及び成分
（ＩＩＩ）とは分離した形態で使用される。これは、そ
れらの少量を成分（ＩＩ）及び成分（ＩＩＩ）と組み合
わせて使用し、さらに主重量を成分（ＩＩ）及び成分
（ＩＩＩ）とは分離した形態で使用前の調製物を調製し
てもよい。According to the present invention, one or more of these anionic surfactants can be used in an appropriate combination, but in the preparation before use, in particular, it is separated from the component (II) and the component (III). Used in the form. This uses a small amount of them in combination with component (II) and component (III), and prepares a pre-use preparation in a form in which the main weight is separated from component (II) and component (III). Good.
【００４６】本発明で用いられる陽イオン性重合体（成
分（ＶＩ））は、通常の化粧品基剤等に用いられる陽イ
オン性重合体の全てを適用することができる。具体例を
挙げるならば、一般式（Ｈ）：As the cationic polymer (component (VI)) used in the present invention, all the cationic polymers used for ordinary cosmetic bases and the like can be applied. If a specific example is given, general formula (H):
【００４７】[0047]
【化７】 [Chemical 7]
【００４８】で表される第４級窒素含有セルロースエー
テル誘導体（市販品として、ポリマーＪＲ−４００、Ｊ
Ｒ−３０Ｍ及びＪＲ１２５（ユニオンカーバイド社製）
等が該当）、一般式（Ｉ）：A quaternary nitrogen-containing cellulose ether derivative represented by the formula (polymers JR-400, J are commercially available products).
R-30M and JR125 (made by Union Carbide)
Etc.), general formula (I):
【００４９】[0049]
【化８】 Embedded image
【００５０】で表されるジアリルジメチルアンモニウム
塩・アクリルアミド共重合体（市販品として、マーコー
ト５５０（メルク社、カルゴン社製）等が該当）、一般
式（Ｊ）：A diallyldimethylammonium salt-acrylamide copolymer represented by (commercially available product such as Mercoat 550 (manufactured by Merck & Calgon)), general formula (J):
【００５１】[0051]
【化９】 Embedded image
【００５２】で表されるポリ（ジアリルジメチルアンモ
ニウム塩）誘導体（市販品として、マーコート１００
（メルク社、カルゴン社製）等が該当）、また、以下に
示す陽イオン性重合体、一般式（Ｋ）：Poly (diallyldimethylammonium salt) derivative represented by
(Manufactured by Merck & Calgon Co., Ltd.) and the following cationic polymers, general formula (K):
【００５３】[0053]
【化１０】 Embedded image
【００５４】（式中、Ｒ1は水素原子またはメチル基、
Ｒ2およびＲ3はそれぞれ独立して水素原子、メチル基、
エチル基またはｔ−ブチル基、Ａは酸素原子または−Ｎ
Ｈ−基、Ｂは直鎖状または側鎖を有する炭素数１〜４の
アルキレン基を示す）で表わされるアミン含有（メタ）
アクリル系モノマー１５〜９０重量％、一般式（Ｌ）：(In the formula, R 1 is a hydrogen atom or a methyl group,
R 2 and R 3 are each independently a hydrogen atom, a methyl group,
Ethyl group or t-butyl group, A is an oxygen atom or -N
H-group, B is an amine-containing (meth) represented by a straight-chain or side-chain alkylene group having 1 to 4 carbon atoms)
Acrylic monomer 15 to 90% by weight, general formula (L):
【００５５】[0055]
【化１１】 Embedded image
【００５６】（式中、Ｒ1は前記と同じ、Ｒ4は一般式：(Wherein R 1 is the same as above, R 4 is a general formula:
【００５７】[0057]
【化１２】 [Chemical 12]
【００５８】（式中、ｐは３または４を示す）で表わさ
れる基または式：A group represented by the formula (wherein p represents 3 or 4) or a formula:
【００５９】[0059]
【化１３】 Embedded image
【００６０】で表わされる基を示す）で表わされるビニ
ルモノマー０〜８０重量％、一般式（Ｍ）：A vinyl monomer represented by the following formula: 0 to 80% by weight, represented by the general formula (M):
【００６１】[0061]
【化１４】 Embedded image
【００６２】（式中、Ｒ1およびＡは前記と同じ、Ｒ5は
直鎖状または側鎖を有する炭素数１〜１７のアルキレン
基または一般式（Ｎ）：(Wherein R 1 and A are the same as described above, R 5 is a linear or side chain alkylene group having 1 to 17 carbon atoms or the general formula (N):
【００６３】[0063]
【化１５】 Embedded image
【００６４】（式中、ｎは１〜４の整数、ｑは１〜２５
の整数を示す）で表わされる基、Ｒ6は水素原子または
メチル基を示す）で表わされる（メタ）アクリロイル基
含有モノマー１〜６０重量％ならびに架橋性ビニルモノ
マー０.１〜２５重量％を含有した増粘剤用モノマー組
成物を重合してなるカチオン性共重合体等が例示され
る。(Where n is an integer of 1 to 4 and q is 1 to 25)
A group represented by an integer) of, R 6 is contained 0.1 to 25% by weight represented by (meth) acryloyl group-containing monomer 1 to 60% by weight and crosslinking vinyl monomers in a hydrogen atom or a methyl group) Examples include cationic copolymers obtained by polymerizing the above-mentioned thickener monomer composition.
【００６５】本発明においては、以上のカチオン性重合
体のうちの任意の一種又は二種以上が選ばれて用いられ
る。In the present invention, any one kind or two or more kinds of the above cationic polymers are selected and used.
【００６６】混合時における増粘効果は、陽イオン性重
合体の配合量とともに高まるが、混合時に５％を越えて
配合した場合、逆に増粘効果は低下する。配合量として
は、０.０１〜５％が好ましく、増粘効果から、特に、
０.１〜１％が好ましい。The thickening effect at the time of mixing increases with the amount of the cationic polymer compounded, but if the amount exceeds 5% at the time of mixing, the thickening effect decreases. The blending amount is preferably 0.01 to 5%, and from the thickening effect, in particular,
0.1 to 1% is preferable.
【００６７】過酸化物（成分（Ｖ））及びカチオン性重
合体（成分（ＶＩ））の性質上、本発明の使用前の調製
物は、成分（Ｉ）、任意成分である成分（ＩＩ）及び成
分（ＩＩＩ）と成分（Ｖ）および成分（ＶＩ）との組み
合わせ使用は避けることが望ましい。したがって、本発
明の使用時に混合される染毛剤組成物は、第１剤を、成
分（Ｉ）、成分（ＩＩ）、成分（ＩＩＩ）、成分（Ｉ
Ｖ）及び水（成分ＶＩＩ）とから調製し、第２剤を成分
（Ｖ）と、成分（ＶＩ）と、成分（ＶＩＩ）とから調製
した２剤型で提供することが取り扱い上便利である。Due to the nature of the peroxide (component (V)) and the cationic polymer (component (VI)), the preparation before use according to the invention is a component (I), an optional component (II). And the combined use of component (III) with component (V) and component (VI) should be avoided. Therefore, the hair dye composition mixed at the time of use of the present invention comprises the first agent as the component (I), the component (II), the component (III) and the component (I).
V) and water (component VII), and it is convenient in terms of handling to provide the second agent in a two-part form prepared from component (V), component (VI) and component (VII). .
【００６８】こうして各成分が組み合わされた使用時の
混合組成分中では、それらの総重基準で、成分（ＩＶ）
と（ＩＩ）を５〜５０重量％含み、そして成分（ＩＩ
Ｉ）を０.１〜５重量含み、そして成分（ＶＩ）を０.０
１〜５重量％含めると、使用前の調製物（例えば、上記
第１剤及び第２剤）の粘度を相対的に低く（通常、２０
０ｃｐｓ以下）維持できるのにもかかわらず、使用時の
混合組成物の粘度を有意（一般的に５００〜１００００
ｃｐｓ、好ましくは５００〜５０００ｃｐｓ、より好ま
しくは１０００〜３０００ｃｐｓ）に高めることができ
る。なお、上記粘度は３０℃下で測定した値を意味す
る。成分（ＩＶ）と（ＩＩ）の総量が５％未満では、使
用時の混合組成物の粘度を十分に高めることができず、
またそれらの総量が５０％を越えると混合組成分の系が
液晶を形成した挙動を示すようになり、好ましくない。Thus, in the mixed composition at the time of use in which the respective components are combined, the component (IV) is calculated on the basis of their total weight.
And (II) in an amount of 5 to 50% by weight, and the component (II
I) 0.1 to 5% by weight, and component (VI) 0.0.
Including 1 to 5% by weight makes the viscosity of the preparation (eg, the above-mentioned first and second agents) relatively low (usually 20%).
Even though it can be maintained at 0 cps or less, the viscosity of the mixed composition at the time of use is significantly (generally 500 to 10,000).
cps, preferably 500-5000 cps, more preferably 1000-3000 cps). In addition, the said viscosity means the value measured at 30 degreeC. If the total amount of components (IV) and (II) is less than 5%, the viscosity of the mixed composition at the time of use cannot be sufficiently increased,
On the other hand, if the total amount exceeds 50%, the system of the mixed composition exhibits the behavior of forming a liquid crystal, which is not preferable.
【００６９】さらに、アニオン性界面活性剤（成分（Ｉ
Ｖ））と、両性界面活性剤及び／又は半極性界面活性剤
（成分（ＩＩ））との混合時の重量比は、４／６〜１０
／０となるように選ぶことができる。この重量比範囲内
では、上記のような第１剤と第２剤の混合時においてよ
り幅広いｐＨ範囲内（具体的にはｐＨ６〜１２）で高い
増粘効果が得られ、白髪の染着及びその均一性の高い染
毛剤となる。また、いわゆるおしゃれ染めといわれる明
るい色へ染色することも可能となる。特に、ｐＨ６以
上、８未満では白髪の染着に、そしてｐＨ８〜１２では
おしゃれ染めに適する。第１剤及び第２剤、並びにそれ
らの混合物は、それぞれ望ましい粘度、安定性を示す。
さらに望ましいのは、成分（ＩＶ）と成分（ＩＩ）との
重量比を４／６〜６／４に調整することである。Further, an anionic surfactant (component (I
V)) and the amphoteric surfactant and / or semipolar surfactant (component (II)) are mixed in a weight ratio of 4/6 to 10
It can be chosen to be / 0. Within this weight ratio range, a high thickening effect can be obtained within a wider pH range (specifically, pH 6 to 12) when mixing the first agent and the second agent as described above, and dyeing of gray hair and It becomes a hair dye with high uniformity. It is also possible to dye a bright color, which is so-called fashionable dyeing. Particularly, it is suitable for dyeing gray hair at a pH of 6 or more and less than 8, and for fashionable dyeing at a pH of 8 to 12. The first agent, the second agent, and the mixture thereof exhibit desirable viscosity and stability, respectively.
More desirable is to adjust the weight ratio of component (IV) and component (II) to 4/6 to 6/4.
【００７０】本発明によれば、各成分の上記組み合わせ
に加え、使用時の混合組成物のｐＨが６〜１２をもつよ
うに調整されることも重要である。このようなｐＨの調
整によって、混合組成物（すなわち、使用時の染毛剤組
成物）の粘度が、適度に保たれ、しかも染色特性を向上
させることができるからである。According to the present invention, in addition to the above combination of the respective components, it is also important that the pH of the mixed composition at the time of use is adjusted to have 6 to 12. By adjusting the pH in this manner, the viscosity of the mixed composition (that is, the hair dye composition at the time of use) can be appropriately maintained, and the dyeing property can be improved.
【００７１】上述のように、本発明に従えば、使用前に
は、少なくとも、成分（Ｉ）、任意成分である成分（Ｉ
Ｉ）、成分（ＩＩＩ）及び成分（ＶＩＩ）の組み合わせ
からなる調製物は、成分（Ｖ）、成分（ＶＩ）及び成分
（ＶＩＩ）との組み合わせからなる調製物と分離された
形態におかれる。したがって、仮りに前者の調製物を第
１剤とし、後者の調製物を第２剤とすると、第１剤をア
ルカリ性として、第２剤を、第１剤と組み合わせ（混合
し）たとき、ｐＨが上記の範囲内にくるように調整する
ことができる。As described above, according to the present invention, at least the component (I) and the optional component (I) are used before use.
The preparation consisting of the combination of I), component (III) and component (VII) is placed in separate form from the preparation consisting of the combination of component (V), component (VI) and component (VII). Therefore, assuming that the former preparation is the first agent and the latter preparation is the second agent, when the first agent is made alkaline and the second agent is combined (mixed) with the first agent, the pH is Can be adjusted to fall within the above range.
【００７２】第１剤をアルカリ性とするにはアルカリ性
のｐＨ調整剤を配合する。このｐＨ調整剤の具体例とし
ては、通常、アンモニア水、モノエタノールアミン等の
アルカノールアミン、水酸化ナトリウム、水酸化カリウ
ム等の水酸化アルカリ、炭酸ナトリウム等の炭酸アルカ
リ、ケイ酸ナトリウム等のケイ酸アルカリが挙げられ
る。また、硫酸アンモニウム、硝酸アンモニウム、塩化
アンモニウム、炭酸アンモニウム、リン酸第一アンモニ
ウム、リン酸第二アンモニウム等の無機アンモニウム塩
等も使用可能である。To make the first agent alkaline, an alkaline pH adjuster is added. Specific examples of the pH adjusting agent are usually ammonia water, alkanolamines such as monoethanolamine, alkali hydroxides such as sodium hydroxide and potassium hydroxide, alkali carbonates such as sodium carbonate, and silicic acid such as sodium silicate. Examples include alkali. Also, inorganic ammonium salts such as ammonium sulfate, ammonium nitrate, ammonium chloride, ammonium carbonate, primary ammonium phosphate and secondary ammonium phosphate can be used.
【００７３】なお、使用時の染毛剤組成物のｐＨは、上
述したように、ｐＨ調整剤を第１剤と第２剤の混合前に
配合しておく他に、混合時に添加することにより調整す
ることも可能である。この場合、混合時とは、混合中も
しくは混合後のことをいうが、混合中に配合するのが好
ましい。The pH of the hair dye composition at the time of use can be adjusted by adding the pH adjusting agent before mixing the first agent and the second agent as described above, or by adding it at the time of mixing. It is also possible to adjust. In this case, the time of mixing means during or after mixing, but it is preferable to mix during mixing.
【００７４】また、本発明においては、低級アルコール
を本発明の効果に影響しない範囲（即ち染毛剤第１剤中
に３重量％以下が好ましい）で配合させてもよい。低級
アルコールの具体例としては、通常エチルアルコール、
ｎ−プロパノール、イソプロパノール、ブタノール等の
炭素数２〜５の１価アルコールが挙げられる。低級アル
コールを含有させることにより、染料の毛髪への浸透が
促進されるが、それに伴って毛髪の感触が低下するため
配合しない方が好ましい場合がよくある。一方、従来の
染毛剤は、第１剤に低級アルコールを多量に配合される
が、本発明はその含有量をゼロ又は少なくすることがで
きるため、すすぎ時においても使用感の優れた染毛剤と
なる。Further, in the present invention, lower alcohol may be blended within a range that does not affect the effect of the present invention (that is, 3% by weight or less is preferable in the first hair dye agent). Specific examples of the lower alcohol are usually ethyl alcohol,
Examples include monohydric alcohols having 2 to 5 carbon atoms such as n-propanol, isopropanol, butanol and the like. Incorporation of a lower alcohol promotes the penetration of the dye into the hair, but the feel of the hair is reduced accordingly, and therefore it is often preferable not to mix. On the other hand, in the conventional hair dye, a large amount of lower alcohol is added to the first agent, but since the present invention can reduce the content thereof to zero or less, hair dye excellent in usability even during rinsing. Become an agent.
【００７５】その他、本発明の混合型染毛料には、その
調製物の段階で、或いは調製物が混合された段階で、本
発明の目的を損なわない範囲で、その他の毛髪保護剤、
安定化剤、香料、保湿剤等を組み入れることができる。In addition, in the mixed hair dye of the present invention, at the stage of its preparation, or at the stage of mixing the preparations, other hair protecting agents within the range not impairing the object of the present invention,
Stabilizers, perfumes, humectants and the like can be incorporated.
【００７６】以上のように、使用前の調製物と、使用時
にそれらの調製物を組み合わせた染毛剤組成物は、最終
製品を毛髪に適用した時、毛髪からの垂れを実質的にも
たらすことなく、優れた染毛特性を示す。さらに、各調
製物は保存安定性に優れ、取り扱い上簡便で相対的に低
粘度の組成物として提供することが可能になる。As described above, the hair dye composition obtained by combining the preparations before use and the preparations at the time of use substantially causes sagging from the hair when the final product is applied to the hair. And shows excellent hair dyeing properties. Furthermore, each preparation has excellent storage stability, is easy to handle, and can be provided as a composition having a relatively low viscosity.
【００７７】[0077]
【実施例】以下、具体例を挙げて、本発明をより具体的
に説明する。なお、例中で使用する部又はパーセンテー
ジ（％）は、特記しない限り（重量／重量）部又は（重
量／重量）％を意味する。EXAMPLES The present invention will be described in more detail with reference to specific examples. The parts or percentages (%) used in the examples mean (weight / weight) parts or (weight / weight)% unless otherwise specified.
【００７８】まず、本発明の効果の評価法を示す。First, a method of evaluating the effect of the present invention will be shown.
【００７９】１） 毛髪ストランドによる染着性テスト 予めブリーチ（脱色）した２ｇの毛髪ストランドに対し
て１０ｇの染毛剤を塗布し、放置時間とＬ値との関係か
ら評価した。なお、Ｌ値とはハンターの色差式における
Ｌの値を示す。1) Dyeing test with hair strands: 10 g of a hair dye was applied to 2 g of hair strands that had been bleached (decolorized) in advance, and evaluated from the relationship between the standing time and the L value. The L value is the value of L in the Hunter color difference formula.
【００８０】２） パネラーによる染着性、ぱさつき感
比較テスト 専門パネラー１０名を用いて、一連の染毛操作を行った
場合の頭髪の染着性、及び乾燥後のぱさつき感を下記の
基準により評価した。2) Dyeability and dryness comparison test by panelists According to the following criteria, the dyeability of hair and the dryness after drying when a series of hair dyeing operations were performed by 10 professional panelists. evaluated.
【００８１】＜染着性＞ ＋＋・・・染着性が著しく良好で均一に染まる ＋ ・・・染着性が良好で均一に染まる ± ・・・やや染着性が劣る − ・・・むらに染まり染着性がない ＜ぱさつき感＞ ＋＋・・・ぱさつかず、なめらかな感触を与える ＋ ・・・ぱさつかない ± ・・・ややぱさつく − ・・・著しくぱさつく ３） 混合液の粘度 第１剤と第２剤を混合した場合の粘度をＢ型粘度計を用
いて測定した（３０℃）。<Dyeing property> ++ ... Remarkably good dyeing property and uniform dyeing + ... Good dyeing property and uniform dyeing +/- Somewhat poor dyeing property -... unevenness Stainless and non-staining <Smoothness> ++ ・ ・ ・ Gives a smooth feel without touching ＋ ・ ・ ・ No touching ± ・ ・ ・ Slightly touching- ・ ・ ・ Remarkably touching 3) Mixing liquid Viscosity The viscosity when the first agent and the second agent were mixed was measured using a B-type viscometer (30 ° C.).
【００８２】４） 低温安定性 １剤（１００ｇ）を−５℃の恒温槽に１ケ月保存した後
の状態を目視により観察し、下記の基準により評価し
た。4) Low Temperature Stability One agent (100 g) was stored in a constant temperature bath at -5 ° C for 1 month, and then visually observed for the condition, and evaluated according to the following criteria.
【００８３】＋＋・・・当初と全く変わらない ＋ ・・・当初と全く変わらないが僅かに増粘 ± ・・・僅かに濁りを生じる − ・・・分離を生じる実施例１、比較例１（従来系） 下記に示した本発明と従来系の第１剤と第２剤を１：１
で混合して染毛剤を調整し、毛髪ストランドを用いて本
発明と従来系の染着性の違いを放置時間とＬ値との関係
から評価した。++ ... No change from the beginning ++ ... No change from the beginning, but a slight increase in viscosity ± ... Slight turbidity --... Separation Example 1, Comparative Example 1 ( (Conventional system) The first agent and the second agent of the present invention and the conventional system shown below are 1: 1.
Was mixed to prepare a hair dye, and a hair strand was used to evaluate the difference in dyeing property between the present invention and the conventional system from the relationship between the standing time and the L value.
【００８４】また、第１剤、第２剤、及び両者を混合後
の粘度を測定した。Further, the viscosities of the first agent, the second agent, and the mixture of both agents were measured.
【００８５】 ［第１剤］（処方１−Ａ） （重量％） ポリオキシエチレン（１.５）アルキル（１２、１４） エーテル硫酸ナトリウム １０.０ ウンデシル−Ｎ−ヒドロキシエチル−Ｎ−カルボキシ メチルイミダゾリニウムベタイン ５.０ ヤシ油脂肪酸アミドプロピルジメチルアミン ５.０ オレイン酸 ３.０ プロピレングリコール ５.０ モノエタノールアミン ２.０ アンモニア水 ２８％ １０.０ Ｌ−アスコルビン酸 ０.５ パラフェニレンジアミン １.０精製水 バランス 合計 １００.０ ［第１剤］（処方１−Ｂ） ポリオキシエチレン（３）オレイルエーテル １５.０ ポリオキシエチレン（４）オクチルフェニルエーテル ５.０ エチルアルコール １０.０ モノエタノールアミン ２.０ アンモニア水（２８％） ５.０ パラフェニレンジアミン ２.０精製水 バランス 合計 １００.０ ［第２剤］（処方２−Ａ） ３０％過酸化水素水 ２０.０ メチルパラベン ０.１ 錫酸ナトリウム ０.１ 塩化Ｏ−［２−ヒドロキシ−３−（トリメチルアンモ ニアプロピル］ヒドロキシセルロース［ポリマー ＪＲ−４００（ユニオンカーバイド社製）］ １.０ リン酸緩衝液 ｐＨ２に調整精製水 バランス 合計 １００.０ ［第２剤］（処方２−Ｂ） ３０％過酸化水素水 ２０.０ メチルパラベン ０.１ 錫酸ナトリウム ０.１ リン酸緩衝液 ｐＨ２に調整精製水 バランス 合計 １００.０ 実施例１ 比較例１ 比較例２ 第１剤 処方１−Ａ 処方１−Ｂ 処方１−Ａ 第２剤 処方２−Ａ 処方２−Ｂ 処方２−Ｂ 第１剤粘度 １５０ ７０ １５０ 第２剤粘度 ４０ ４０ １５ 混合時粘度 ２８００ ２５００ ４５０ 染着性 ＋＋ ± ＋＋ ぱさつき感 ＋＋ − ＋＋ 低温安定性 ＋＋ ＋ ＋＋ 実施例１による処理後２０分のＬ値は１２.９、比較例
１では１６.１であり、また目視によっても、従来系に
比較して本発明品は染着性が優れていることが分かっ
た。[First Agent] (Formulation 1-A) (% by Weight) Polyoxyethylene (1.5) Alkyl (12, 14) Sodium Ether Sulfate 10.0 Undecyl-N-hydroxyethyl-N-carboxymethylimidazo Linium betaine 5.0 Coconut oil fatty acid amide propyldimethylamine 5.0 Oleic acid 3.0 Propylene glycol 5.0 Monoethanolamine 2.0 Ammonia water 28% 10.0 L-Ascorbic acid 0.5 Paraphenylenediamine 1 0.0 Purified water Balanced total 100.0 [First agent] (Formulation 1-B) Polyoxyethylene (3) oleyl ether 15.0 Polyoxyethylene (4) octylphenyl ether 5.0 Ethyl alcohol 10.0 Monoethanol Amine 2.0 Ammonia water (28%) 5.0 Paraphenylenediamine 2.0 Pure Water-making balance 100.0 [Second agent] (formulation 2-A) 30% hydrogen peroxide water 20.0 Methylparaben 0.1 Sodium stannate 0.1 O- [2-hydroxy-3- (trimethylammonium chloride) chloride Near Propyl] Hydroxycellulose [Polymer JR-400 (manufactured by Union Carbide Co.)] 1.0 Phosphate buffer adjusted to pH 2 Purified water Balance total 100.0 [Second agent] (formulation 2-B) 30% hydrogen peroxide solution 20.0 Methylparaben 0.1 Sodium stannate 0.1 Phosphate buffer Adjusted to pH 2 Purified water Balance total 100.0 Example 1 Comparative Example 1 Comparative Example 2 1st agent Formulation 1-A Formulation 1-B Formulation 1- A 2nd agent Formulation 2-A Formulation 2-B Formulation 2-B 1st agent viscosity 150 70 150 2nd agent viscosity 40 40 15 Mixing viscosity 2800 2500 450 Dyeing property ++ ± ++ Stickiness ++-++ Low temperature stability ++ ++ The L value of 20 minutes after the treatment according to Example 1 was 12.9, Comparative Example 1 was 16.1, and the present invention was visually compared with the conventional system. The product was found to have excellent dyeability.
【００８６】また、実施例１の第１剤は、ｐＨ＝１１.
２、粘度＝１５０ｃｐｓ、第２剤は、ｐＨ＝２.０、粘
度＝４０ｃｐｓであり、両者を混合した後は、ｐＨ＝
９.５、粘度＝２８００ｃｐｓとなり、顕著な増粘効果
が認められた。The first agent of Example 1 had a pH of 11.
2, viscosity = 150 cps, second agent has pH = 2.0, viscosity = 40 cps, and after mixing both, pH =
The viscosity was 9.5 and the viscosity was 2800 cps, and a remarkable thickening effect was recognized.
【００８７】次に、実施例１の第１剤及び第２剤を用
い、混合時にｐＨ調整剤（アンモニア水またはリン酸）
を適宜加えてｐＨ５、６、１２の染毛剤を調合し、粘度
を測定したところ、それぞれ３００ｃｐｓ、１５００ｃ
ｐｓ、６５０ｃｐｓとなり、ｐＨを６〜１２とした染毛
剤では優れた増粘効果が得られることが分かった。ま
た、染毛処理２０分後のＬ値はそれぞれ２４.０、１２.
０、１５.２となり、ｐＨ６〜１２の範囲で染着性が高
いことが分かった。Next, using the first and second agents of Example 1, a pH adjusting agent (ammonia water or phosphoric acid) was added during mixing.
Was added to prepare a hair dye having a pH of 5, 6, or 12, and the viscosity was measured. The results were 300 cps and 1500 c, respectively.
It was found that the hair dye having a ps and 650 cps and a pH of 6 to 12 has an excellent thickening effect. The L values after 20 minutes of hair dyeing treatment are 24.0 and 12.
It was 0, 15.2, and it was found that the dyeing property was high in the range of pH 6-12.
【００８８】実施例２〜２５及び比較例３〜１０ 表１〜表４に示す種々の組成の第１剤と第２剤を混合し
て得た染毛剤について、前記した評価法により評価し
た。なお、表１〜表３における染毛剤のｐＨは全て６〜
１２であった。 Examples 2 to 25 and Comparative Examples 3 to 10 Hair dyes obtained by mixing the first agent and the second agent having various compositions shown in Tables 1 to 4 were evaluated by the above-described evaluation methods. . In addition, the pH of the hair dye in Tables 1 to 3 is 6 to all.
It was 12.
【００８９】[0089]
【表１】 [Table 1]
【００９０】[0090]
【表２】 [Table 2]
【００９１】[0091]
【表３】 [Table 3]
【００９２】[0092]
【表４】 [Table 4]
【００９３】表１〜表４に示された結果より、本発明の
染毛剤は染着性に優れ、ぱさつき感が無く、第１剤及び
第２剤の粘度が低く、混合後の粘度も適度であり、低温
安定性にも優れていることがわかる。また、従来の染毛
剤で、第１剤を低粘度として第２剤との混合時に高い粘
度を得るためには、比較例１に示すように、非イオン界
面活性剤を高濃度に配合し、１価のアルコール（イソプ
ロパノール）を加えて粘度を下げ混合時に高粘度化する
よう調整しているが、本発明では第１剤を１価アルコー
ルを含まずに低粘度とし、混合時に高粘度化を達成する
ことができる。 実施例２６〜２８ 以下に示す実施例１８〜２４の組成の第１剤と第２剤と
を用いて染毛剤を作製したところ、いずれも粘度が５０
０ｃｐｓ以上となり、染着性、ぱさつき感、退色性、低
温安定性、使用性のいずれも優れた効果があることを確
認した。From the results shown in Tables 1 to 4, the results of the present invention are shown.
The hair dye has excellent dyeing properties and has no dry feeling,
The viscosity of the second agent is low, the viscosity after mixing is moderate, and the viscosity is low.
It can be seen that the stability is also excellent. Also conventional hair dyeing
The first agent has a low viscosity and a high viscosity when mixed with the second agent.
To obtain the degree, as shown in Comparative Example 1,
A surface active agent is mixed in a high concentration, and a monovalent alcohol (isoprene
(Lopanol) is added to lower the viscosity to increase the viscosity during mixing.
However, in the present invention, the first agent is a monovalent alcohol.
A low viscosity without the use of a wax to achieve high viscosity during mixing
be able to. Examples 26-28 The first agent and the second agent having the compositions of Examples 18 to 24 shown below
When a hair dye was prepared using
Over 0 cps, dyeability, dryness, fading, low
It is confirmed that both temperature stability and usability have excellent effects.
I accepted.
【００９４】実施例２６ （第１剤） ウンデシル−Ｎ−ヒドロキシエチル−Ｎ−カルボキシメチ ルイミダゾリニウムベタイン ４.０ ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン ４.０ ラウリルジメチルアミノ酢酸ベタイン ４.０ イソステアリン酸 ３.０ ケラチン蛋白加水分解物 １.０ アミノ変性シリコーン （東レ（株）社製；ＳＭ−８７０２Ｃ） ３.０ モノエタノールアミン ２.０ アンモニア水（２８％） １０.０ Ｌ−アスコルビン酸 ０.５ パラフェニレンジアミン １.０ レゾルシン １.０ パラアミノフェノール ０.５ 香料 適量精製水 バランス 合計 １００.０ （第２剤） α−アルケニル（１２、１３）スルホン酸ナトリウム １２ ラウロイルメチルタウリンナトリウム ８ 塩化Ｏ−［２−ヒドロキシ−３−（トリメチルアンモ ニウム）プロピル］ヒドロキシエチルセルロース ０.５ 過酸化水素水（３０％） ２０ メチルパラベン 適量 錫酸ナトリウム 適量 リン酸緩衝液 ｐＨ３に調整精製水 バランス 合計 １００実施例２７ （第１剤） （重量％） ウンデシル−Ｎ−ヒドロキシエチル−Ｎ−カルボキシメチ ルイミダゾリニウムベタイン ５.０ ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン ３.０ オレイン酸 ２.０ 流動パラフィン ２.０ グリセリン ４.０ ジメチルポリシロキサン １００ｃｓ １.０ 水酸化ナトリウム １.０ アンモニア水（２８％） １０.０ Ｌ−アスコルビン酸 ０.５ パラフェニレンジアミン １.０ レゾルシン ０.２ オルソアミノフェノール ０.８ 香料 適量精製水 バランス 合計 １００.０ （第２剤） ポリオキシエチレン（１.５）アルキル（１２、１４） エーテル硫酸ナトリウム １５ カルボキシビニルポリマー（「ハイビスワコー１０５」、 和光純薬社製） ０.５ 過酸化水素水（３０％） ２０ メチルパラベン 適量 錫酸ナトリウム 適量 リン酸緩衝液 ｐＨ３に調整精製水 バランス 合計 １００実施例２８ （第１剤） （重量％） ウンデシル−Ｎ−ヒドロキシエチル−Ｎ−カルボキシメチ ルイミダゾリニウムベタイン １.０ ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン ８.０ イソステアリン酸 ３.０ ４級化コラーゲン蛋白加水分解物 １.５ ミリスチン酸 ４.０ ジメチルポリシロキサン ６ｃｓ ２.０ モノエタノールアミン ４.０ アンモニア水（２８％） １２.０ Ｌ−アスコルビン酸 ０.５ パラフェニレンジアミン ０.５ レゾルシン ０.４ メタアミノフェノール ０.３ パラアミノオルソクレゾール ０.２ 香料 適量精製水 バランス 合計 １００.０ （第２剤） α−アルケニル（１２、１３）スルホン酸ナトリウム １５ アミノ変性シリコーン（「シリコーンＳＭ−８７０２Ｃ」、 東レ社製） １ 塩化Ｏ−［２−ヒドロキシ−３−（トリメチルアンモニオ） プロピル］ヒドロキシエチルセルロース ０.５ 過酸化水素水（３０％） ２０ メチルパラベン 適量 錫酸ナトリウム 適量 リン酸緩衝液 ｐＨ３に調整精製水 バランス 合計 １００ Example 26 (First agent) Undecyl-N-hydroxyethyl-N-carboxymethyl ruthyimidazolinium betaine 4.0 Coconut oil fatty acid amidopropyl dimethylamino acetic acid betaine 4.0 Lauryl dimethylamino acetic acid betaine 4.0 Isostearic acid 3.0 Keratin protein hydrolyzate 1.0 Amino-modified silicone (manufactured by Toray Industries, Inc .; SM-8702C) 3.0 Monoethanolamine 2.0 Ammonia water (28%) 10.0 L-ascorbic acid 0.5 Para-phenylenediamine 1.0 Resorcin 1.0 Para-aminophenol 0.5 Perfume Suitable amount Purified water Balance total 100.0 (Second agent) Sodium α-alkenyl (12,13) sulfonate 12 Lauroylmethyl taurine sodium 8 Chloride O- [2-hydroxy-3- (trimethylammonium Um) propyl] hydroxyethyl cellulose 0.5 hydrogen peroxide (30%) 20 Methylparaben qs sodium stannate qs phosphate buffer pH3 adjustment Purified water balance Total 100 Example 27 (first agent) (wt%) undecyl - N-hydroxyethyl-N-carboxymethyl rumidazolinium betaine 5.0 Coconut oil fatty acid amidopropyl dimethylamino acetic acid betaine 3.0 Oleic acid 2.0 Liquid paraffin 2.0 Glycerin 4.0 Dimethylpolysiloxane 100cs 1.0 Sodium hydroxide 1.0 Ammonia water (28%) 10.0 L-Ascorbic acid 0.5 Paraphenylenediamine 1.0 Resorcin 0.2 Orthoaminophenol 0.8 Fragrance Purified water Balance total 100.0 (2nd) Agent) Polyoxyethylene (1.5) alkyl (12 , 14) Sodium ether sulfate 15 Carboxyvinyl polymer (“Hibiswako 105”, manufactured by Wako Pure Chemical Industries, Ltd.) 0.5 Hydrogen peroxide water (30%) 20 Methylparaben Suitable amount Sodium stannate Suitable amount Phosphate buffer pH 3 Purified water Balance total 100 Example 28 (First agent) (wt%) Undecyl-N-hydroxyethyl-N-carboxymethyl rumidazolinium betaine 1.0 Palm oil fatty acid amidopropyl dimethylaminoacetate betaine 8.0 Isostearic acid 3. 0 Quaternized collagen protein hydrolyzate 1.5 myristic acid 4.0 dimethyl polysiloxane 6cs 2.0 monoethanolamine 4.0 ammonia water (28%) 12.0 L-ascorbic acid 0.5 paraphenylenediamine 0 .5 resorcin 0.4 meta aminophenol 0.3 para Roh ortho-cresol 0.2 Perfume Appropriate amount Purified water Balance Total 100.0 (second agent) alpha-alkenyl (12,13) sodium sulfonate 15 amino-modified silicone ( "Silicone SM-8702C", made by Toray Industries, Inc.) 1 chloride O -[2-Hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose 0.5 Hydrogen peroxide solution (30%) 20 Methylparaben Suitable amount Sodium stannate Suitable amount Phosphate buffer solution Adjusted to pH 3 Purified water Balance total 100
【００９５】[0095]
【発明の効果】本発明により、毛髪への染着性が良好
で、染毛後の毛髪の感触に優れた染毛剤を提供すること
が可能となる。特に、本発明は、白髪の染毛剤として優
れた効果を示すものである。EFFECTS OF THE INVENTION According to the present invention, it is possible to provide a hair dye which has good dyeability on hair and is excellent in the feel of the hair after dyeing. In particular, the present invention exhibits excellent effects as a hair dye for gray hair.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 山口 道広 神奈川県横浜市港北区新羽町1050番地 株 式会社資生堂第一リサーチセンター内 (72)発明者 安田 正明 神奈川県横浜市港北区新羽町1050番地 株 式会社資生堂第一リサーチセンター内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Michihiro Yamaguchi 1050 Shinba-cho, Kohoku-ku, Yokohama-shi, Kanagawa Inside Shiseido Daiichi Research Center (72) Inventor Masaaki Yasuda 1050 Shinba-cho, Kohoku-ku, Yokohama-shi, Kanagawa Shiseido Daiichi Research Center Co., Ltd.
Claims (17)
る用時混合型染毛剤組成物であって、（ａ） 前記組み
合わさった組成物が、染料（Ｉ）と、任意成分である両
性界面活性剤及び半極性界面活性剤からなる群より選ば
れる界面活性の１種以上（ＩＩ）と、高級脂肪酸の１種
以上（ＩＩＩ）と、アニオン性界面活性剤の１種以上
（ＩＶ）と、酸化剤（Ｖ）と、カチオン性重合体（Ｖ
Ｉ）と、水（ＶＩＩ）とを含んでなり、そして（ｂ）
使用前には、成分（Ｉ）、（ＩＩ）、（ＩＩＩ）及び
（ＩＶ）からなる群より選ばれる成分が、成分（Ｖ）及
び（ＶＩ）からなる群より選ばれる成分から分離された
形態におかれる、前記染毛剤組成物。1. An in-use mixed hair dye composition in which a dye and an oxidizing agent are combined at the time of use, wherein the combined composition (a) is an amphoteric amphoteric dye (I) and an optional component. One or more kinds of surfactants (II) selected from the group consisting of surfactants and semipolar surfactants, one or more kinds of higher fatty acids (III), and one or more kinds of anionic surfactants (IV); , An oxidizing agent (V) and a cationic polymer (V
I) and water (VII), and (b)
Before use, a component selected from the group consisting of components (I), (II), (III) and (IV) is separated from a component selected from the group consisting of components (V) and (VI). The above-mentioned hair dye composition, which is placed in.
もつように調整された請求項１記載の染毛剤組成物。2. A hair dye composition according to claim 1, wherein the combined composition is adjusted to have a pH of 6-12.
重量基準で、成分（ＩＶ）と（ＩＩ）を５〜５０重量％
含み、成分（ＩＩＩ）を０.１〜５重量％含むみ、そし
て成分（ＶＩ）を０.０１〜５重量％含む、請求項１又
は２記載の染毛剤組成物。3. The combined composition, based on its total weight, comprises 5 to 50% by weight of components (IV) and (II).
The hair dye composition according to claim 1 or 2, which comprises 0.1 to 5% by weight of component (III) and 0.01 to 5% by weight of component (VI).
（ＩＶ）と成分（ＩＩ）との重量比が、４／６〜１０／
０である請求項１〜３のいずれかに記載の染毛剤組成
物。4. The combined composition, wherein the weight ratio of component (IV) to component (II) is 4/6 to 10 /.
It is 0, The hair dye composition in any one of Claims 1-3.
重量基準で炭素数２〜５の１価アルコールの含有量が３
重量％以下である請求項１〜３のいずれかに記載の染毛
剤組成物。5. The combined composition has a content of monohydric alcohol having 2 to 5 carbon atoms of 3 based on the total weight thereof.
The hair dye composition according to any one of claims 1 to 3, which is contained in an amount of not more than 5% by weight.
と、（ＩＶ）と、（ＶＩＩ）とからなる調製物を第１剤
とし、そして成分（Ｖ）と、（ＶＩ）と、（ＶＩＩ）と
からなる調製物を第２剤とする請求項１〜５のいずれか
に記載の染毛剤組成物。6. Components (I), (II) and (III)
A preparation comprising :, (IV) and (VII) as a first agent, and a preparation comprising components (V), (VI) and (VII) as a second agent. 6. The hair dye composition according to any one of to 5.
イン型両性界面活性剤、アミドベタイン型両性界面活性
剤、アミドスルフォベタイン型両性界面活性剤、ベタイ
ン型両性界面活性剤、スルフォベタイン型両性界面活性
剤及び第３級アミンオキサイド型半極性界面活性剤の群
から選択される界面活性剤の少なくとも１種を含む請求
項１〜３のいずれかに記載の染毛剤組成物。7. The component (II) comprises an imidazolinium betaine-type amphoteric surfactant, an amidobetaine-type amphoteric surfactant, an amide sulfobetaine-type amphoteric surfactant, a betaine-type amphoteric surfactant, and a sulfobetaine-type surfactant. The hair dye composition according to any one of claims 1 to 3, which comprises at least one surfactant selected from the group of amphoteric surfactants and tertiary amine oxide type semipolar surfactants.
イン型両性界面活性剤の少なくとも１種と、アミドベタ
イン型両性界面活性剤、アミドスルフォベタイン型両性
界面活性剤、ベタイン型両性界面活性剤、スルフォベタ
イン型両性界面活性剤及び第３級アミンオキサイド型半
極性界面活性剤からなる群より選ばれる少なくとも１種
との混合物である請求項１〜３のいずれかに記載の染毛
剤組成物。8. The component (II) comprises at least one imidazolinium betaine-type amphoteric surfactant, an amidobetaine-type amphoteric surfactant, an amidesulfobetaine-type amphoteric surfactant, and a betaine-type amphoteric surfactant. The hair dye composition according to any one of claims 1 to 3, which is a mixture with at least one selected from the group consisting of a sulfobetaine-type amphoteric surfactant and a tertiary amine oxide-type semipolar surfactant. Stuff.
場合によって水酸基を有していてもよい、直鎖又は分枝
鎖の飽和又は不飽和炭化水素から構成される高級脂肪酸
の１種以上を含む請求項１〜３のいずれかに記載の染毛
剤組成物。9. The component (III) has 7 to 25 carbon atoms,
The hair dye according to any one of claims 1 to 3, comprising at least one higher fatty acid composed of a straight chain or branched chain saturated or unsaturated hydrocarbon optionally having a hydroxyl group. Composition.
ンアルキルエーテル硫酸アルキルエーテル硫酸塩、α−
オレフィンスルホン酸塩及びアルキロイルアルキルタウ
リン塩からなる群より選ばれる界面活性剤の１種以上を
含む請求項１〜３のいずれかに記載の染毛剤組成物。10. Component (IV) is polyoxyalkylene alkyl ether sulfate alkyl ether sulfate, α-
The hair dye composition according to any one of claims 1 to 3, which comprises one or more surfactants selected from the group consisting of olefin sulfonates and alkyloylalkyl taurine salts.
中のいずれかの偶数であるアルキル鎖をもつポリオキシ
エチレンアルキルエーテル硫酸塩及びアルキルエーテル
硫酸塩からなる群から選ばれる界面活性剤の１種以上を
含む請求項１〜３のいずれかに記載の染毛剤組成物。11. A surfactant selected from the group consisting of polyoxyethylene alkyl ether sulfates and alkyl ether sulfates, wherein component (IV) has an even numbered alkyl chain of 10 to 18 carbon atoms. The hair dye composition according to any one of claims 1 to 3, which comprises at least one of the following.
ロース誘導体、ジアリルジメチルアンモニウム塩・アク
リルアミド共重合体及びポリ（ジアリルジメチルアンモ
ニウム塩）誘導体からなる群より選ばれる重合体の１種
以上を含む請求項１〜３のいずれかに記載の染毛剤組成
物。12. The component (VI) comprises one or more polymers selected from the group consisting of quaternary nitrogen-containing cellulose derivatives, diallyldimethylammonium salt / acrylamide copolymers and poly (diallyldimethylammonium salt) derivatives. The hair dye composition according to any one of claims 1 to 3, which comprises:
（ＩＶ）と成分（ＩＩ）との重量比が、４／６〜６／４
であり、ｐＨが６〜８である請求項１〜３のいずれかに
記載の染毛剤組成物。13. The combined composition, wherein the weight ratio of component (IV) to component (II) is from 4/6 to 6/4.
And pH is 6-8, The hair dye composition in any one of Claims 1-3.
（ＩＶ）と成分（ＩＩ）との重量比が４／６〜６／４で
あり、ｐＨが８〜１２である請求項８記載の染毛剤組成
物。14. The hair dye according to claim 8, wherein the combined composition has a weight ratio of component (IV) to component (II) of 4/6 to 6/4 and a pH of 8 to 12. Agent composition.
（ＩＶ）と成分（ＩＩ）との重量比が６／４〜１０／０
である請求項１１記載の染毛剤組成物。15. The combined composition, wherein the weight ratio of component (IV) to component (II) is 6/4 to 10/0.
The hair dye composition according to claim 11, which is
Ｉ）を含まない請求項１５記載の染毛剤組成物。16. The combined composition comprises the components (I
The hair dye composition according to claim 15, which does not contain I).
℃の下で５００ｃｐｓである請求項１〜１６のいずれか
に記載の染毛剤組成物。17. The combined composition has a viscosity of 30.
The hair dye composition according to any one of claims 1 to 16, which has a temperature of 500 cps at a temperature of ° C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7210167A JPH0940534A (en) | 1995-07-27 | 1995-07-27 | Hair dye composition of type mixed on employment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7210167A JPH0940534A (en) | 1995-07-27 | 1995-07-27 | Hair dye composition of type mixed on employment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0940534A true JPH0940534A (en) | 1997-02-10 |
Family
ID=16584886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7210167A Pending JPH0940534A (en) | 1995-07-27 | 1995-07-27 | Hair dye composition of type mixed on employment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0940534A (en) |
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|---|---|---|---|---|
| JP2003095896A (en) * | 2001-09-25 | 2003-04-03 | Hoyu Co Ltd | Oxidation hairdye composition |
| JP2003095902A (en) * | 2001-09-27 | 2003-04-03 | Hoyu Co Ltd | Hair cosmetic composition |
| JP2009051856A (en) * | 2003-04-25 | 2009-03-12 | Kao Corp | Hair cosmetics |
| US8152858B2 (en) | 2007-10-24 | 2012-04-10 | Kao Corporation | Head hair dyeing method |
| JP2012106952A (en) * | 2010-11-18 | 2012-06-07 | Mandom Corp | Bleaching agent or oxidation hair dye and method for bleaching or dying hair |
| JP2012106950A (en) * | 2010-11-18 | 2012-06-07 | Mandom Corp | Bleaching agent or oxidation hair dye and method for bleaching or dyeing hair |
| US8349022B2 (en) | 2009-03-11 | 2013-01-08 | Kao Corporation | Two-part hair dye |
| US8388696B2 (en) | 2007-04-27 | 2013-03-05 | Kao Corporation | Two-part hair dye or bleach composition |
| US8394151B2 (en) | 2007-10-24 | 2013-03-12 | Kao Corporation | Head hair dyeing method |
| JP2013527133A (en) * | 2010-05-07 | 2013-06-27 | ロレアル | Ready-to-use cosmetic composition for oxidative dyeing of keratin fibers |
| JP2013541570A (en) * | 2010-11-02 | 2013-11-14 | ロレアル | Dye composition with low ammonia content |
| US8636812B2 (en) | 2010-08-31 | 2014-01-28 | Kao Corporation | Two-part foam hair dye |
| EP2879649B1 (en) | 2012-08-02 | 2018-11-07 | L'oreal | Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant |
| US10226649B2 (en) | 2007-04-27 | 2019-03-12 | Kao Corporation | Hair dyeing or bleaching method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2003095896A (en) * | 2001-09-25 | 2003-04-03 | Hoyu Co Ltd | Oxidation hairdye composition |
| JP2003095902A (en) * | 2001-09-27 | 2003-04-03 | Hoyu Co Ltd | Hair cosmetic composition |
| US8277784B2 (en) | 2003-04-25 | 2012-10-02 | Kao Corporation | Hair cosmetic product |
| JP2009051856A (en) * | 2003-04-25 | 2009-03-12 | Kao Corp | Hair cosmetics |
| US8153108B2 (en) | 2003-04-25 | 2012-04-10 | Kao Corporation | Hair cosmetic product |
| US8158112B2 (en) | 2003-04-25 | 2012-04-17 | Kao Corporation | Hair cosmetic product |
| US8246936B2 (en) | 2003-04-25 | 2012-08-21 | Kao Corporation | Hair cosmetic product |
| US10226649B2 (en) | 2007-04-27 | 2019-03-12 | Kao Corporation | Hair dyeing or bleaching method |
| US8388696B2 (en) | 2007-04-27 | 2013-03-05 | Kao Corporation | Two-part hair dye or bleach composition |
| US8529638B2 (en) | 2007-10-24 | 2013-09-10 | Kao Corporation | Head hair dyeing composition |
| US8394151B2 (en) | 2007-10-24 | 2013-03-12 | Kao Corporation | Head hair dyeing method |
| US8152858B2 (en) | 2007-10-24 | 2012-04-10 | Kao Corporation | Head hair dyeing method |
| US8349022B2 (en) | 2009-03-11 | 2013-01-08 | Kao Corporation | Two-part hair dye |
| US8449627B2 (en) | 2009-03-11 | 2013-05-28 | Kao Corporation | Two-part hair dye |
| JP2013527133A (en) * | 2010-05-07 | 2013-06-27 | ロレアル | Ready-to-use cosmetic composition for oxidative dyeing of keratin fibers |
| US8636812B2 (en) | 2010-08-31 | 2014-01-28 | Kao Corporation | Two-part foam hair dye |
| JP2013541570A (en) * | 2010-11-02 | 2013-11-14 | ロレアル | Dye composition with low ammonia content |
| JP2012106950A (en) * | 2010-11-18 | 2012-06-07 | Mandom Corp | Bleaching agent or oxidation hair dye and method for bleaching or dyeing hair |
| JP2012106952A (en) * | 2010-11-18 | 2012-06-07 | Mandom Corp | Bleaching agent or oxidation hair dye and method for bleaching or dying hair |
| EP2879649B1 (en) | 2012-08-02 | 2018-11-07 | L'oreal | Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant |
| EP2879649B2 (en) † | 2012-08-02 | 2022-08-24 | L'oreal | Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant |
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