JPH0959687A - Cleaning agent for wax removal - Google Patents
Cleaning agent for wax removalInfo
- Publication number
- JPH0959687A JPH0959687A JP21862695A JP21862695A JPH0959687A JP H0959687 A JPH0959687 A JP H0959687A JP 21862695 A JP21862695 A JP 21862695A JP 21862695 A JP21862695 A JP 21862695A JP H0959687 A JPH0959687 A JP H0959687A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- wax
- water
- cleaning agent
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 10
- -1 amide compound Chemical class 0.000 claims abstract description 14
- 239000003599 detergent Substances 0.000 claims description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 6
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 claims description 4
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- ABMDIECEEGFXNC-UHFFFAOYSA-N n-ethylpropanamide Chemical compound CCNC(=O)CC ABMDIECEEGFXNC-UHFFFAOYSA-N 0.000 claims description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims 2
- 239000001993 wax Substances 0.000 description 23
- 239000004200 microcrystalline wax Substances 0.000 description 8
- 239000012188 paraffin wax Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000002904 solvent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- GEWWCWZGHNIUBW-UHFFFAOYSA-N 1-(4-nitrophenyl)propan-2-one Chemical compound CC(=O)CC1=CC=C([N+]([O-])=O)C=C1 GEWWCWZGHNIUBW-UHFFFAOYSA-N 0.000 description 1
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 1
- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
- DCALJVULAGICIX-UHFFFAOYSA-N 1-propylpyrrolidin-2-one Chemical compound CCCN1CCCC1=O DCALJVULAGICIX-UHFFFAOYSA-N 0.000 description 1
- VVCMGAUPZIKYTH-VGHSCWAPSA-N 2-acetyloxybenzoic acid;[(2s,3r)-4-(dimethylamino)-3-methyl-1,2-diphenylbutan-2-yl] propanoate;1,3,7-trimethylpurine-2,6-dione Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O.CN1C(=O)N(C)C(=O)C2=C1N=CN2C.C([C@](OC(=O)CC)([C@H](C)CN(C)C)C=1C=CC=CC=1)C1=CC=CC=C1 VVCMGAUPZIKYTH-VGHSCWAPSA-N 0.000 description 1
- QMXPTUUFGSTIKK-UHFFFAOYSA-N 5-ethylpyrrolidin-2-one Chemical compound CCC1CCC(=O)N1 QMXPTUUFGSTIKK-UHFFFAOYSA-N 0.000 description 1
- IRGZEUUQSUZQJA-UHFFFAOYSA-N 5-propylpyrrolidin-2-one Chemical compound CCCC1CCC(=O)N1 IRGZEUUQSUZQJA-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229930007927 cymene Natural products 0.000 description 1
- PZDARDIDPSRLMQ-UHFFFAOYSA-M dibutyl(diethyl)azanium;hydroxide Chemical compound [OH-].CCCC[N+](CC)(CC)CCCC PZDARDIDPSRLMQ-UHFFFAOYSA-M 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- YVIVRJLWYJGJTJ-UHFFFAOYSA-N gamma-Valerolactam Chemical compound CC1CCC(=O)N1 YVIVRJLWYJGJTJ-UHFFFAOYSA-N 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- QVOFCQBZXGLNAA-UHFFFAOYSA-M tributyl(methyl)azanium;hydroxide Chemical compound [OH-].CCCC[N+](C)(CCCC)CCCC QVOFCQBZXGLNAA-UHFFFAOYSA-M 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】
【課題】 ワックス除去を短時間に行える洗浄剤の提
供。
【解決手段】 水溶性アミド化合物または水溶性ラクト
ン化合物を主体とし、これにアルカノールアミンを配合
したワックス除去用洗浄剤。(57) [Abstract] [PROBLEMS] To provide a cleaning agent capable of removing wax in a short time. A cleaning agent for removing wax, which is mainly composed of a water-soluble amide compound or a water-soluble lactone compound and is mixed with an alkanolamine.
Description
【０００１】[0001]
【発明の属する技術分野】本発明は一般機械、電気機
械、金属製品および精密機械等の成形品の接着、塗装な
どの二次加工前に使用されるワックス除去用洗浄剤に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wax-removing cleaning agent used before secondary processing such as adhesion and coating of molded products such as general machines, electric machines, metal products and precision machines.
【０００２】[0002]
【従来の技術】従来、一般機械、電気機械、金属製品お
よび精密機械等の成形品の接着、塗装などの二次加工前
に接着や塗装されない部分にワックスをコートして表面
を保護し、次いで接着、塗装後、表面保護剤のワックス
を溶剤で除去するか、電解法で除去していた。かかる溶
剤としては、フロン及びトリクロロエタン、トリクロロ
エチレンに代表される塩素系溶剤が用いられているが、
現在、フロン、塩素系溶剤は安全性、環境への影響が大
きな問題となっており使用が制限されつつある。又、電
解法は除去性能が不十分であるため代替の洗浄剤が求め
られている。2. Description of the Related Art Conventionally, before the secondary processing such as adhesion and coating of molded products such as general machines, electric machines, metal products and precision machines, the parts which are not adhered or painted are coated with wax to protect the surface, After adhesion and coating, the wax of the surface protective agent was removed by a solvent or an electrolytic method. As such a solvent, fluorocarbons, trichloroethane, and chlorine-based solvents represented by trichloroethylene are used.
At present, the use of CFCs and chlorine-based solvents has become a serious problem because of their safety and environmental impact, and their use is being restricted. Further, since the electrolytic method has insufficient removal performance, an alternative cleaning agent is required.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、環境への影
響をより少なくし、且つ、安全性と除去性を向上させ最
適なワックス除去用洗浄剤を提供することを目的とす
る。SUMMARY OF THE INVENTION It is an object of the present invention to provide an optimum cleaning agent for removing wax, which has less influence on the environment and improves safety and removability.
【０００４】[0004]
【課題を解決するための手段】本発明は、 （ａ）水溶性アミド化合物または水溶性ラクトン化合物 ６５〜９５重量％ （ｂ）アルカノールアミンおよび式（Ｉ）で示された四級低級アルキルアンモニ ウムヒドロキシドより選ばれた化合物 ０．０１〜１５重量％ （ｃ）水 ０〜２０重量％ （ｄ）炭素数が６〜１０の芳香族炭化水素 ０〜３０重量％ を含有するワックス除去用洗浄剤に関する。The present invention provides (a) a water-soluble amide compound or a water-soluble lactone compound 65 to 95% by weight (b) an alkanolamine and a quaternary lower alkylammonium represented by the formula (I). Compound selected from hydroxide 0.01 to 15% by weight (c) Water 0 to 20% by weight (d) Detergent for wax removal containing 0 to 30% by weight of aromatic hydrocarbon having 6 to 10 carbon atoms Regarding
【０００５】[0005]
【化２】 （式中、Ｒ1 、Ｒ2 、Ｒ3 およびＲ4 は炭素数が１〜４
のアルキル基である。）Embedded image (In the formula, R 1 , R 2 , R 3 and R 4 have 1 to 4 carbon atoms.
Is an alkyl group. )
【０００６】[0006]
【発明の実施の形態】以下に本発明の方法を詳しく説明
する。（ａ）水溶性アミド化合物または水溶性ラクトン化合
物： （ａ）成分の水溶性アミド化合物としては、Ｎ，
Ｎ′−ジメチルホルムアミド（ＤＭＦ）、Ｎ，Ｎ′−ジ
エチルホルムアミド（ＤＥＦ）、Ｎ，Ｎ′−ジメチルア
セトアミド（ＤＭＡＣ）などの鎖状アミド化合物やピロ
リドン化合物などの環状アミド化合物が用いられる。DESCRIPTION OF THE PREFERRED EMBODIMENTS The method of the present invention will be described below in detail. (A) Water-soluble amide compound or water-soluble lactone compound
Object: (a) The water-soluble amide compounds of component, N,
Chain amide compounds such as N'-dimethylformamide (DMF), N, N'-diethylformamide (DEF), N, N'-dimethylacetamide (DMAC) and cyclic amide compounds such as pyrrolidone compounds are used.
【０００７】上記ピロリドン化合物としては２−ピロリ
ドン、Ｎ−アルキル−２−ピロリドン（例えば、Ｎ−メ
チル−２−ピロリドン、Ｎ−エチル−２−ピロリドン、
Ｎ−プロピル−２−ピロリドン）、５−アルキル−２−
ピロリドン（例えば、５−メチル−２−ピロリドン、５
−エチル−２−ピロリドン、５−プロピル−２−ピロリ
ドン）、Ｎ−ビニル−２−ピロリドン等が例示される
が、特にＮ−メチル−２−ピロリドンが有効である。As the above-mentioned pyrrolidone compound, 2-pyrrolidone, N-alkyl-2-pyrrolidone (for example, N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone,
N-propyl-2-pyrrolidone), 5-alkyl-2-
Pyrrolidone (eg, 5-methyl-2-pyrrolidone, 5
-Ethyl-2-pyrrolidone, 5-propyl-2-pyrrolidone), N-vinyl-2-pyrrolidone and the like are exemplified, but N-methyl-2-pyrrolidone is particularly effective.
【０００８】又、水溶性ラクトン化合物としては、γ−
ブチロラクトン（ＧＢＬ）が挙げられる。これら成分
は、単独で用いてもよく、また、２種以上混合して用い
てもよい。この（ａ）成分は、ワックスの剥離、溶解に
有効に作用する。洗浄剤中の（ａ）成分の割合は６５〜
９５重量％である。洗浄剤中、（ａ）成分が６５重量％
未満ではワックスへの浸透作用が小さくなり、金型等に
付着しているワックスの除去性能が薄れる。又、９５重
量％を越えてはワックスへの浸透作用のみが先行し、ワ
ックスの粘性が増し金型等から除去しづらくなる欠点が
ある。As the water-soluble lactone compound, γ-
Butyrolactone (GBL). These components may be used alone or in combination of two or more. The component (a) effectively acts on the peeling and dissolution of the wax. The ratio of the component (a) in the detergent is 65-
95% by weight. 65% by weight of component (a) in the detergent
If it is less than the above range, the effect of penetrating into the wax becomes small, and the removal performance of the wax adhering to the mold or the like becomes weak. Further, if it exceeds 95% by weight, there is a drawback that only the action of penetrating into the wax precedes, the viscosity of the wax increases, and it becomes difficult to remove it from the mold or the like.
【０００９】（ｂ）アルカノールアミンまたは４級低級
アルキルアンモニウムヒドロキシド：（ｂ）成分は、洗
浄剤のワックスへの浸透性を向上させるもので、洗浄剤
中０．０１〜１５重量％、好ましくは０．０５〜１０重
量％の割合で用いられる。０．０１重量％未満ではその
効果が薄く、１５重量％を越えては（ａ）成分の浸透効
果が小さくなる。 (B) Alkanolamine or quaternary lower
Alkylammonium hydroxide: The component (b) improves the permeability of the detergent into the wax, and is used in the detergent in an amount of 0.01 to 15% by weight, preferably 0.05 to 10% by weight. . If it is less than 0.01% by weight, the effect is weak, and if it exceeds 15% by weight, the permeation effect of the component (a) becomes small.
【００１０】かかる（ｂ）成分としては、モノエタノー
ルアミン、ジエタノールアミン、トリエタノールアミン
のアルカノールアミン；式（Ｉ）で示されるテトラメチ
ルアンモニウムヒドロキシド、テトラエチルアンモニウ
ムヒドロキシド、テトラブチルアンモニウムヒドロキシ
ド、トリエチルメチルアンモニウムヒドロキシド、トリ
ブチルメチルアンモニウムヒドロキシド、ジエチルジブ
チルアンモニウムヒドロキシド等の４級アンモニウムヒ
ドロキシドが挙げられる。Examples of the component (b) include monoethanolamine, diethanolamine and triethanolamine alkanolamines; tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrabutylammonium hydroxide and triethylmethyl represented by the formula (I). Examples thereof include quaternary ammonium hydroxides such as ammonium hydroxide, tributylmethylammonium hydroxide and diethyldibutylammonium hydroxide.
【００１１】（ｃ）水 水は、洗浄剤の可燃性防止、洗浄剤の長期保存のために
添加される。三成分系の場合、（ａ）成分６５〜９１．
９９重量％、（ｂ）成分０．０１〜１５重量％、（ｃ）
成分８〜２０重量％である。[0011] (c) water water flammable prevention of detergents, are added for long term storage of the detergent. In the case of a ternary system, the components (a) 65 to 91.
99% by weight, component (b) 0.01 to 15% by weight, (c)
The component is 8 to 20% by weight.
【００１２】（ｄ）芳香族炭化水素 芳香族炭化水素としては、ベンゼン、トルエン、キシレ
ン、エチルベンゼン、シメン、エチルトルエン、トリメ
チルベンゼン、ジエチルベンゼン等の炭素数が６〜１０
の芳香族炭化水素が用いられる。この芳香族炭化水素は
ワックスの溶解性を速める効果がある。三成分系の場
合、（ａ）成分６５〜９４重量％、（ｂ）成分０．０１
〜１５重量％、（ｄ）成分１〜３０重量％である。 (D) Aromatic hydrocarbons As aromatic hydrocarbons, benzene, toluene, xylene, ethylbenzene, cymene, ethyltoluene, trimethylbenzene, diethylbenzene and the like have 6 to 10 carbon atoms.
Aromatic hydrocarbons of This aromatic hydrocarbon has the effect of accelerating the solubility of the wax. In the case of a three-component system, (a) component 65 to 94% by weight, (b) component 0.01
˜15% by weight, component (d) 1 to 30% by weight.
【００１３】（ｅ）任意成分 その他必要により、界面活性剤を洗浄剤中、１〜５重量
％配合してもよい。 (E) Optional components and others If necessary, a surfactant may be added to the detergent in an amount of 1 to 5% by weight.
【００１４】ワックス ワックスはろうそく、マッチ軸木含浸剤、紙加工剤、ゴ
ム老化防止剤、段ボール耐水化剤、化成肥料遅効剤、蓄
熱温湿布剤、電気絶縁剤等、産業用途毎にその需要はさ
まざまあり、その種類も天然ワックス、合成ワックス、
配合ワックスと多岐にわたる。その中で一般機械、電気
機械、金属製品および精密機械等の成形品の接着、塗装
などの二次加工前、特に精密加工を要する成形品には天
然ワックスが主に使用される。天然ワックスは更に植物
系、動物系、鉱物系、石油系に分類されるが、その中で
石油系ワックスのパラフィンワックス、マイクロワック
ス、ペトロラクタムが主に使用される。 Wax Wax is demanded for each industrial application such as candle, match stem impregnating agent, paper processing agent, rubber anti-aging agent, corrugated sheet waterproofing agent, chemical fertilizer retarding agent, heat storage compress, electric insulating agent, etc. There are various types of natural wax, synthetic wax,
A wide variety of compounded waxes. Among them, natural wax is mainly used for general machinery, electric machinery, metal products and precision machinery before secondary processing such as adhesion and painting, especially for precision molded products. Natural waxes are further classified into plant-based, animal-based, mineral-based, and petroleum-based waxes. Among them, petroleum-based waxes such as paraffin wax, microwax, and petrolactam are mainly used.
【００１５】洗浄 対象物からのワックスの除去は、例えば洗浄槽にこの洗
浄液を仕込み、常温もしくは常温から６０℃程度に昇温
し、ワックスが付いた材料を浸漬もしくはエアーバブリ
ング、超音波、液流、噴流、バレル回転等の機械力を単
独もしくは組み合わせて処理を行う。もちろん洗浄法と
して洗浄剤を含浸したウエス、スポンジ等による拭き取
りによる方法も可能である。洗浄後は水リンス、乾燥を
行い材料に付着した洗浄剤の除去を行う。拭き取りによ
る方法の場合は自然乾燥もしくは水をしみ込ませたウエ
ス、スポンジ等により洗浄剤を除去し、水を自然乾燥も
しくは乾いたウエス、スポンジ等で拭き取り自然乾燥さ
せる。[0015] Removal of wax from the cleaning object, for example to a washing vessel was charged the cleaning liquid, the temperature was raised to about 60 ° C. from ambient or room temperature, dipping or air bubbling the wax with materials, ultrasonic, liquid flow , Jet flow, barrel rotation, and other mechanical forces are used alone or in combination. Of course, as a cleaning method, a method of wiping off with a waste cloth or sponge impregnated with a cleaning agent is also possible. After washing, rinse with water and dry to remove the detergent adhering to the material. In the case of the wiping method, the cleaning agent is removed by a waste cloth, a sponge or the like that is naturally dried or soaked with water, and the water is naturally dried or wiped and naturally dried by a waste cloth or a sponge.
【００１６】[0016]
【実施例】以下の実施例、比較例は二次加工前のオーデ
ィオ磁気ヘッドに付着したパラフィンワックスの除去と
メッキ前の金型に付着したマイクロワックスの除去を行
ったものである。表に示す洗浄剤を使用し、超音波（４
００Ｗ，２８ＫＨｚ）洗浄を行い、オーディオ磁気ヘッ
ドに付着したパラフィンワックスの除去とメッキ前の金
型に付着したマイクロワックスの除去程度について洗浄
の状況および洗浄後の観察を行った。尚、パラフィンワ
ックスの洗浄は３分、マイクロワックスの洗浄は３０分
実施した。EXAMPLES In the following examples and comparative examples, the paraffin wax adhering to the audio magnetic head before secondary processing was removed and the microwax adhering to the die before plating was removed. Ultrasonic wave (4
(00 W, 28 KHz), and cleaning conditions and post-cleaning observations were performed on the degree of removal of paraffin wax attached to the audio magnetic head and the degree of removal of microwax attached to the mold before plating. The paraffin wax was washed for 3 minutes and the microwax was washed for 30 minutes.
【００１７】表１または２においてパラフィンワックス
およびマイクロワックス洗浄後の観察結果を以下の記号
で示した。 ○…パラフィンワックスおよびマイクロワックスが完全
に除去されている。 △…パラフィンワックスおよびマイクロワックスがわず
かに残存しているが実用上問題ないレベル ×…パラフィンワックスおよびマイクロワックスの大部
分が残存している。In Tables 1 and 2, the observation results after washing with paraffin wax and microwax are shown by the following symbols. ○: Paraffin wax and micro wax are completely removed. B: Paraffin wax and microwax slightly remain, but there is no problem in practical use X: Most of paraffin wax and microwax remain.
【００１８】[0018]
【表１】 [Table 1]
【００１９】[0019]
【表２】 [Table 2]
【００２０】[0020]
【発明の効果】ワックスの除去を短時間に行うことがで
きる洗浄剤である。EFFECT OF THE INVENTION A cleaning agent capable of removing wax in a short time.
Claims (2)
のアルキル基である。）1. A water-soluble amide compound or a water-soluble lactone compound, 65 to 95% by weight. (B) A compound selected from an alkanolamine and a quaternary lower alkylammonium hydroxide represented by the formula (I). 0.01 to 15% by weight (c) Water 0 to 20% by weight (d) Detergent for wax removal containing 0 to 30% by weight of aromatic hydrocarbon having 6 to 10 carbon atoms. Embedded image (In the formula, R 1 , R 2 , R 3 and R 4 have 1 to 4 carbon atoms.
Is an alkyl group. )
２−ピロリドン、Ｎ，Ｎ′−ジメチルホルムアミド、
Ｎ，Ｎ′−ジエチルホルムアミド、Ｎ，Ｎ′−ジメチル
アセトアミド、ガンマ−ブチロラクトンより選ばれた化
合物であり、（ｂ）成分がモノエタノールアミン、ジエ
タノールアミン、トリエタノールアミン、テトラブチル
アンモニウムヒドロキシドより選ばれた化合物である請
求項１記載のワックス除去用洗浄剤。2. The component (a) is N-methylpyrrolidone,
2-pyrrolidone, N, N'-dimethylformamide,
A compound selected from N, N'-diethylformamide, N, N'-dimethylacetamide and gamma-butyrolactone, and the component (b) is selected from monoethanolamine, diethanolamine, triethanolamine and tetrabutylammonium hydroxide. The cleaning agent for removing wax according to claim 1, which is a compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21862695A JPH0959687A (en) | 1995-08-28 | 1995-08-28 | Cleaning agent for wax removal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21862695A JPH0959687A (en) | 1995-08-28 | 1995-08-28 | Cleaning agent for wax removal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0959687A true JPH0959687A (en) | 1997-03-04 |
Family
ID=16722908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21862695A Pending JPH0959687A (en) | 1995-08-28 | 1995-08-28 | Cleaning agent for wax removal |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0959687A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006328212A (en) * | 2005-05-26 | 2006-12-07 | Tokuyama Corp | Detergent for wax |
| JP2010189635A (en) * | 2009-01-26 | 2010-09-02 | Kaken Tec Kk | Stock solution for detergent composition, detergent composition, and washing method |
| CN112808684A (en) * | 2020-12-30 | 2021-05-18 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN115418647A (en) * | 2022-08-19 | 2022-12-02 | 广东红日星实业有限公司 | Wax removing water and preparation method and application thereof |
-
1995
- 1995-08-28 JP JP21862695A patent/JPH0959687A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006328212A (en) * | 2005-05-26 | 2006-12-07 | Tokuyama Corp | Detergent for wax |
| JP2010189635A (en) * | 2009-01-26 | 2010-09-02 | Kaken Tec Kk | Stock solution for detergent composition, detergent composition, and washing method |
| CN112808684A (en) * | 2020-12-30 | 2021-05-18 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN112808684B (en) * | 2020-12-30 | 2022-05-03 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN115418647A (en) * | 2022-08-19 | 2022-12-02 | 广东红日星实业有限公司 | Wax removing water and preparation method and application thereof |
| CN115418647B (en) * | 2022-08-19 | 2024-01-05 | 广东红日星实业有限公司 | Wax removing water and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2382600C (en) | Environmentally friendly solvent | |
| US6096699A (en) | Environmentally friendly solvent | |
| CA2049594C (en) | Environmentally safe cleaning process and cleaning composition useful therin | |
| JP3452406B2 (en) | Composition having performance of removing organic deposits | |
| US6057276A (en) | Graffiti remover which comprises an active solvent, a secondary solvent, an emollient and a particulate filler and method for its use | |
| CA2803389A1 (en) | Carboxy ester ketal removal compositions, methods of manufacture, and uses thereof | |
| JPS63258974A (en) | Paint release composition low in toxity | |
| CA1308634C (en) | Aqueous-based composition for removing coatings | |
| WO2019191245A1 (en) | Compositions and methods for cleaning and stripping | |
| JPH0959687A (en) | Cleaning agent for wax removal | |
| WO1992018600A1 (en) | Low voc cleaning compositions and methods | |
| AU671521B2 (en) | Cleaning composition | |
| JPH0341170A (en) | Ink-cleaning agent | |
| Wollbrinck | The composition of proprietary paint strippers | |
| US5334256A (en) | Paint stripping composition | |
| JPH06296941A (en) | Method and device for precision cleaning | |
| CN105964511A (en) | Technological method for removing rustproof material packing of precision-machined metal part without solvent | |
| CA1320675C (en) | Paint stripping composition containing five membered ring lactone | |
| KR970001232B1 (en) | Detergent composition | |
| US5700330A (en) | Process for cleaning water and organic solvent based lacquer from equipment using a single solvent mixture | |
| JPH0959689A (en) | Cleaning agent for removing abrasives | |
| JPH0959683A (en) | Cleaning agent for flux removal | |
| JP2001137792A (en) | Cleaning method | |
| US5939371A (en) | Stripping composition for urethane conformal coatings | |
| JPH0925496A (en) | Detergent for wax and water-soluble processing liquid |