JPH0970880A - Blow molding method and device for hollow molded article - Google Patents
Blow molding method and device for hollow molded articleInfo
- Publication number
- JPH0970880A JPH0970880A JP7230862A JP23086295A JPH0970880A JP H0970880 A JPH0970880 A JP H0970880A JP 7230862 A JP7230862 A JP 7230862A JP 23086295 A JP23086295 A JP 23086295A JP H0970880 A JPH0970880 A JP H0970880A
- Authority
- JP
- Japan
- Prior art keywords
- mold
- parison
- powder
- blow molding
- closed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/24—Lining or labelling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/3064—Preforms or parisons made of several components having at least one components being applied using techniques not covered by B29C2949/3032 - B29C2949/3062
- B29C2949/3074—Preforms or parisons made of several components having at least one components being applied using techniques not covered by B29C2949/3032 - B29C2949/3062 said at least one component obtained by coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/04—Extrusion blow-moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2023/00—Tubular articles
- B29L2023/004—Bent tubes
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
(57)【要約】 (修正有)
【課題】 単層のブロー成形機で、簡便容易に一度の成
形で複雑に屈曲した2層の中空ブロー成形品を得るよう
にした。
【解決手段】 中空成形品のブロー成形方法において、
左右一対の金型を、型閉時に3次元的に屈曲したキャビ
ティ形状を有する形状に形成し、該密閉空間内部の気体
を下部より吸引しつつ、パリソンを吐出して該密閉空間
内の該キャビティ内に導入しながら、吐出途中の該パリ
ソンの外表面に、金型上端部より気体とともに供給され
た樹脂材料または無機材料の粉体を付着させるととも
に、該パリソンが所定の長さに達した後に該パリソンの
吐出降下を停止して金型上端部および金型下端部を閉
じ、あらかじめ金型キャビティ面を、該粉体樹脂材料ま
たは該パリソン樹脂材料のいずれかのうち高い方の軟化
点温度以上に加熱した後、型締してブローイングを行な
った。
(57) [Summary] (Correction) [PROBLEMS] A single-layer blow molding machine is used to easily and easily obtain a two-layer hollow blow-molded product which is complicatedly bent in one molding. SOLUTION: In a blow molding method of a hollow molded article,
A pair of left and right dies are formed in a shape having a cavity shape which is three-dimensionally bent when the dies are closed, and a parison is discharged by sucking a gas inside the closed space from a lower portion to form the cavity in the closed space. While being introduced into the inside, while adhering the powder of the resin material or the inorganic material supplied together with the gas from the upper end of the die to the outer surface of the parison during discharging, after the parison reaches a predetermined length. The discharge lowering of the parison is stopped, the upper end of the mold and the lower end of the mold are closed, and the mold cavity surface is previously set to the softening point temperature of the higher of the powder resin material and the parison resin material. After heating to, the mold was clamped and blown.
Description
【0001】[0001]
【発明の属する技術分野】本発明は、パリソン表面に粉
体を付着させた中空成形品を成形する中空成形品のブロ
ー成形方法および装置に係り、特に単層のブロー成形機
で、3次元的に屈曲した形状を有する成形品を得るとと
もに、パリソン表面に簡便容易にパリソンと同質または
異質の樹脂材料やあるいは無機材料の粉体を付着させる
ことの出来る中空成形品のブロー成形方法および装置に
関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a blow molding method and a blow molding product for molding a hollow molding product in which powder is adhered to the surface of a parison. BLOW MOLDING METHOD AND DEVICE FOR HOLLOW MOLDED PRODUCT, WHICH OBTAINS MOLDED ARTICLE HAVING BENDED SHAPE AND POSITIVELY EASILY DEPOSIT TO POWDER OF HALLOWETY OR DIFFERENT RESIN OR INORGANIC MATERIAL POWDER ON PARISON Is.
【0002】[0002]
【従来の技術】ダイスヘッドから筒状に射出または押し
出されたパリソンから中空状の樹脂製品をつくるブロー
成形では、ダイスヘッドからパリソンを射出または押し
出し、パリソンピンチによって袋状にされたパリソンに
プリブローを行なって僅かに膨らませ、開放された金型
内に入れて金型を閉じ、金型とパリソンとで形成される
キャビティ内のガスを抜いた後、金型表面に通じる小さ
な空気抜き穴より真空ポンプ装置を介して空気を吸引し
たうえ、パリソン内に高圧の空気吹き込みを行なってパ
リソンをキャビティに基づく所定の形状としたあと金型
で冷却して成形を完了する。このようにして、成形され
た樹脂製品は金型を開いて取り出される。図7に示すも
のは、従来のブロー成形機を示す。図7のものは溶融樹
脂をダイスヘッド2の側方1個所より供給する、いわゆ
る、サイドフィード方式のブロー成形機1を示し、射出
装置4により押圧された高温溶融状態の樹脂は樹脂供給
口2aを経由してダイスヘッド2とマンドレル3との間
に設けた環状の通路を通り、最下端の環状空間通路7よ
り吐出されてパリソンPを形成する。ダイスヘッド2の
樹脂供給口2aと180°隔たった位置には通路2bと
その外側に設けたバルブ5(またはプラグ)が配設され
る。そして、コア3aはマンドレル3を貫通したパリコ
ン用ロッド6aに接続され、パリコンシリンダ6の作動
により上下方向僅かに進退動され、パリソンPの肉厚を
制御するために環状空間通路7の間隙(ギャップ)を調
整できるようになっている。2. Description of the Related Art In blow molding for producing a hollow resin product from a parison injected or extruded into a cylindrical shape from a die head, a parison is injected or extruded from a die head, and a pre-blow is applied to a parison formed into a bag by a parison pinch. Line, inflate it slightly, put it in an open mold, close the mold, evacuate the gas in the cavity formed by the mold and the parison, and then vacuum pump the device through a small air vent hole to the mold surface Then, high-pressure air is blown into the parison to form the parison into a predetermined shape based on the cavity, and the parison is cooled with a mold to complete the molding. In this way, the molded resin product is opened and taken out. The thing shown in FIG. 7 shows the conventional blow molding machine. 7 shows a so-called side-feed type blow molding machine 1 in which molten resin is supplied from one side of the die head 2, and the high-temperature molten resin pressed by the injection device 4 is the resin supply port 2a. And passes through an annular passage provided between the die head 2 and the mandrel 3 and is discharged from the annular space passage 7 at the lowermost end to form a parison P. A passage 2b and a valve 5 (or plug) provided outside the passage 2b are disposed at a position 180 ° away from the resin supply port 2a of the die head 2. The core 3a is connected to the paricon rod 6a penetrating the mandrel 3 and is slightly moved up and down in the vertical direction by the operation of the paricon cylinder 6 to control the wall thickness of the parison P (gap). ) Can be adjusted.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、このよ
うな従来の単層構造のダイを有するブロー成形機1で
は、一度の成形によって同時に2層の中空成形品を得る
ことはできない。このため、吐出されたパリソンと金型
キャビティとの間に樹脂シート(樹脂フィルム)を介在
させたうえ金型を型締めし、表面に樹脂シートを貼り合
わせたブロー成形品を生産することが、従来、実施され
ていた。しかし、この方法では、パリソンと樹脂シート
との間に空気溜まりが発生して平滑な表面を備えた成形
品を得ることが難しく、樹脂シートに脱気用の微細貫通
孔を設ける等の配慮を必要とし必然的にコストアップの
要因となる。However, in the blow molding machine 1 having such a conventional single-layer structure die, it is not possible to obtain a two-layer hollow molded product at the same time by molding once. Therefore, it is possible to produce a blow-molded product in which a resin sheet (resin film) is interposed between the discharged parison and the mold cavity, the mold is clamped, and the resin sheet is bonded to the surface. Conventionally, it was implemented. However, in this method, it is difficult to obtain a molded product having a smooth surface due to air pockets generated between the parison and the resin sheet, and consideration should be given to providing the resin sheet with fine through holes for deaeration. It is necessary and inevitably causes a cost increase.
【0004】一方、パリソン表面に樹脂または無機物の
粉体を付着することによって、2層の中空成形品を得る
方法もある。たとえば、特開平05−096610号公
報には、ダイス装置と金型装置の間に粉体を吹き出す粉
体付着装置を設ける方法が開示されている。しかしなが
ら、この方法では、装置が大型化して設備費が増大する
ばかりでなく、パリソン自体も長くなり不経済であり、
歩留まりが悪くなる難点がある。また、3次元的に屈曲
した異形の成形品を得る場合には、これに伴って金型キ
ャビティ形状も複雑に屈曲しており、垂下されるパリソ
ンが所定の金型空間内に円滑に収まりにくいという問題
もあった。On the other hand, there is also a method of obtaining a two-layer hollow molded article by adhering resin or inorganic powder on the surface of the parison. For example, Japanese Patent Laid-Open No. 05-096610 discloses a method of providing a powder adhering device for blowing out powder between a die device and a die device. However, in this method, not only is the device increased in size and equipment costs are increased, but also the parison itself is lengthened and uneconomical,
There is a drawback that the yield becomes poor. Further, in the case of obtaining a three-dimensionally bent irregularly shaped product, the mold cavity shape is also complicatedly bent accordingly, and it is difficult for the suspended parison to smoothly fit in a predetermined mold space. There was also a problem.
【0005】[0005]
【課題を解決するための手段】以上のような課題を解決
して、複雑に屈曲した形状を有する成形品を成形する場
合であって、設備費が安価で、簡便容易にパリソン表面
に粉体を付着することの出来る中空成形品のブロー成形
方法および装置を提供するために、本発明においては、
第1の発明では、ダイスヘッドとマンドレルの下端に取
り付けたコアとの間の環状の樹脂通路から吐出されたパ
リソンを左右一対の金型で挟んでブロー成形する中空成
形品のブロー成形方法において、左右一対の金型を、型
閉時に3次元的に屈曲したキャビティ形状を有する形状
に形成し、任意の型開量に型開された両該金型間で形成
された空間を両側面、頂面ならびに底面で囲繞されほぼ
密閉された密閉空間とするとともに、該密閉空間内部の
気体を下部より吸引しつつ、パリソンを吐出して該密閉
空間内の該キャビティ内に導入しながら、吐出途中の該
パリソンの外表面に、金型上端部より気体とともに供給
された樹脂材料または無機材料の粉体を付着させるとと
もに、該パリソンが所定の長さに達した後に該パリソン
の吐出降下を停止して金型上端部および金型下端部を閉
じ、あらかじめ金型キャビティ面を、該粉体樹脂材料ま
たは該パリソン樹脂材料のいずれかのうち高い方の軟化
点温度以上に加熱した後、型締してブローイングを行な
った後に成形品が取り出せるに十分な温度に冷却して成
形品を取り出すこととした。さらに、第2の発明では、
射出装置と該射出装置により供給された溶融樹脂を下端
よりパリソンとして吐出するダイス装置と該パリソンを
挟んでブロー成形する左右一対の金型装置からなるブロ
ー成形装置において、左右一対の金型を、型閉時に3次
元的に屈曲したキャビティ形状を有する形状に形成し、
金型内部に、金型を加熱または冷却する媒体通路を設
け、金型の外側面に金型進退動方向に伸縮開閉自在な前
後一対の側面シャッタを配設するとともに、金型上端部
と金型下端部にそれぞれ金型進退動方向に伸縮開閉自在
な左右一対の頂面シャッタと昇降自在な底面シャッタを
配設して型開時の金型空間を密閉空間に形成し、該底面
シャッタ直下に該密閉空間内の気体を吸引するととも
に、粉体ホッパに貯溜された粉体を空気搬送する排出管
を配設し、かつ、吐出された粉体を含有する気体を吸引
し集塵する集塵装置を該排出管に接続してなる構成とし
た。[Means for Solving the Problems] In the case of forming a molded product having a complicatedly bent shape by solving the above problems, the equipment cost is low, and the powder is easily and easily formed on the parison surface. In order to provide a blow molding method and device for a hollow molded article capable of adhering, in the present invention,
In a first aspect of the present invention, in a blow molding method for a hollow molded article, the parison discharged from an annular resin passage between a die head and a core attached to a lower end of a mandrel is sandwiched by a pair of left and right molds and blow molded, A pair of left and right dies are formed in a shape having a cavity shape that is three-dimensionally bent when the dies are closed, and the space formed between the dies opened to an arbitrary opening amount is set on both side surfaces and the top. While making a closed space that is surrounded by the surface and the bottom surface and is almost closed, while sucking the gas inside the closed space from the lower part and discharging the parison into the cavity in the closed space, On the outer surface of the parison, powder of a resin material or an inorganic material supplied together with gas from the upper end of the die is attached, and after the parison reaches a predetermined length, the discharge drop of the parison is stopped. The mold upper end and the mold lower end, and the mold cavity surface is heated in advance to the softening point temperature of the higher of either the powder resin material or the parison resin material, and then the mold is clamped. After blowing, the molded article was taken out after cooling to a temperature sufficient for taking out the molded article. Further, in the second invention,
In a blow molding device consisting of an injection device and a die device for discharging the molten resin supplied by the injection device from the lower end as a parison and a pair of left and right mold devices for blow molding with the parison sandwiched, a pair of left and right molds, Formed into a shape that has a three-dimensionally bent cavity shape when the mold is closed,
A medium passage for heating or cooling the mold is provided inside the mold, and a pair of front and rear side shutters that can be freely opened and closed in the mold advancing and retracting direction are provided on the outer surface of the mold, and the upper end of the mold and the metal mold are connected. A pair of left and right top shutters that can be freely opened and closed in the mold advancing and retracting directions and a bottom shutter that can be moved up and down are provided at the lower end of the mold to form a closed mold space when the mold is opened. Is provided with a discharge pipe for sucking gas in the closed space and for carrying the powder stored in the powder hopper by air, and for collecting gas containing the discharged powder by suction to collect dust. A dust device was connected to the discharge pipe.
【0006】[0006]
【発明の実施の形態】本発明においては、中空成形品の
ブロー成形方法において、左右一対の金型を、型閉時に
3次元的に屈曲したキャビティ形状を有する形状に形成
し、任意の型開量に型開された両該金型間で形成された
空間を両側面、頂面ならびに底面で囲繞されほぼ密閉さ
れた密閉空間とするとともに、該密閉空間内部の気体を
下部より吸引しつつ、パリソンを吐出して該密閉空間内
の該キャビティ内に導入しながら、吐出途中の該パリソ
ンの外表面に、金型上端部より気体とともに供給された
樹脂材料または無機材料の粉体を付着させるとともに、
該パリソンが所定の長さに達した後に該パリソンの吐出
降下を停止して金型上端部および金型下端部を閉じ、あ
らかじめ金型キャビティ面を、該粉体樹脂材料または該
パリソン樹脂材料のいずれかのうち高い方の軟化点温度
以上に加熱した後、型締してブローイングを行なった後
に成形品が取り出せるに十分な温度に冷却して成形品を
取り出すようにしたので、パリソンが気体の吸引力に引
っ張られて複雑なキャビティ内に円滑に導入され、粉体
が高温の溶融状態にあるパリソン外表面に十分に付着
し、その後に樹脂の軟化点温度温度以上に加熱された金
型にブローイングにより押圧され、平滑で強固に結合さ
れた2層の中空成形品が出来上がる。第2の発明では、
粉体を噴射する際、両金型で囲まれた空間は、ともに伸
縮自在な側面シャッタ、頂面シャッタ、底面シャッタで
ほぼ完全密閉され、なおかつ、密閉空間の気体を下部よ
り吸引しつつパリソンを導入するからパリソンの降下が
円滑であり、粉体も負圧状態の密閉空間内に噴射される
から、周囲の作業環境を汚染することがない。また、放
出された余分の粉体は集塵装置で回収されるから、経済
的であるとともに、パリソンの外表面に所望の粉体層を
必要に応じて自動的に形成できる。BEST MODE FOR CARRYING OUT THE INVENTION According to the present invention, in a blow molding method for a hollow molded product, a pair of left and right molds are formed into a shape having a cavity shape which is three-dimensionally bent when the mold is closed, and the mold is arbitrarily opened. While forming a space between the two molds opened in a quantity on both side surfaces, a top surface and a bottom surface to be a closed space which is almost closed, while sucking the gas inside the closed space from the lower part, While discharging the parison and introducing it into the cavity in the closed space, while adhering the powder of the resin material or the inorganic material supplied together with the gas from the upper end of the mold to the outer surface of the parison during the discharging, ,
After the parison reaches a predetermined length, the discharge lowering of the parison is stopped to close the mold upper end and the mold lower end, and the mold cavity surface is preliminarily set to the powder resin material or the parison resin material. After heating above the softening point temperature, whichever is higher, the mold was clamped and blown, and then the molded product was taken out by cooling to a temperature sufficient to take out the molded product. It is pulled by the suction force and smoothly introduced into the complex cavity, and the powder adheres sufficiently to the outer surface of the parison in the high temperature molten state, and then the mold heated to the softening point temperature of the resin or higher. A two-layer hollow molded product that is pressed by blowing and is smoothly and firmly bonded is completed. In the second invention,
When spraying powder, the space surrounded by both molds is almost completely sealed by a side shutter, a top shutter, and a bottom shutter that are both expandable and contractible, and the parison is sucked while sucking the gas in the sealed space from the bottom. Since the parison is smoothly introduced, the powder is also injected into the closed space in the negative pressure state, so that the surrounding work environment is not polluted. Further, since the discharged extra powder is collected by the dust collector, it is economical and a desired powder layer can be automatically formed on the outer surface of the parison as needed.
【0007】[0007]
【実施例】以下、図面に基づいて本発明の実施例の詳細
について説明する。図1〜図5は本発明の実施例に係
り、図1はブロー成形装置の型開時の全体縦断面図、図
2はブロー成形装置の型閉時の全体縦断面図、図3は図
1のA−A視の平面図、図4は図1のB−B視の平面
図、図5は図3のC−C視の側面図、図6はブロー成形
方法の金型温度変化を説明するグラフである。図1〜図
5において、ブロー成形装置100のダイスヘッド11
の下方には、金型装置20が有り、左右一対の可動プラ
テン22、22とこれに各々取り付けられた金型24、
24が型締シリンダ23を介して接離自在に配設され
る。金型24の頂部には、金型開閉方向にエアシリンダ
32を介して進退動する左右一対の頂面シャッタ30が
配設されるとともに、金型24の下端部にも上下方向に
エアシリンダ52を介して一体的に形成された昇降自在
な底面シャッタ50が配設される。また、図4に示すよ
うに、金型24の側面部を被覆し金型開閉方向にエアシ
リンダ62を介して進退動する前後一対の側面シャッタ
60が配設される。このようにして、金型を、パリソン
Pが支障なく降下できる任意の型開量に保持した型開状
態のとき、両金型で囲まれる空間は,前後一対の側面シ
ャッタ60、60と左右一対の頂面シャッタ30、30
と一体型の底面シャッタ50とで密閉され周囲と隔離さ
れた密閉空間Qが形成される。Embodiments of the present invention will be described below in detail with reference to the drawings. 1 to 5 relate to an embodiment of the present invention, FIG. 1 is an overall vertical cross-sectional view of a blow molding device when a mold is opened, FIG. 2 is an overall vertical cross-sectional view of a blow molding device when a mold is closed, and FIG. 1 is a plan view taken along line AA, FIG. 4 is a plan view taken along line BB of FIG. 1, FIG. 5 is a side view taken along line CC of FIG. 3, and FIG. 6 is a mold temperature change of the blow molding method. It is a graph to explain. 1 to 5, the die head 11 of the blow molding apparatus 100
A mold device 20 is provided below the pair of right and left movable platens 22, 22 and a mold 24 attached to each of them.
24 is disposed via the mold clamping cylinder 23 so as to be freely contactable and separable. At the top of the mold 24, a pair of left and right top surface shutters 30 that move forward and backward through the air cylinder 32 in the mold opening / closing direction are disposed, and at the lower end of the mold 24, the air cylinder 52 is also vertically arranged. A bottom shutter 50 that is integrally formed via a bottom and is freely movable is provided. Further, as shown in FIG. 4, a pair of front and rear side shutters 60 that cover the side surface of the mold 24 and move back and forth through the air cylinder 62 in the mold opening / closing direction are provided. In this way, in the mold open state in which the mold is held at an arbitrary mold opening amount that allows the parison P to descend without any hindrance, the space surrounded by both molds has a pair of front and rear side shutters 60, 60 and a pair of left and right side shutters. Top shutter 30, 30
And an integrated bottom shutter 50 form a closed space Q that is isolated from the surroundings.
【0008】頂部シャッタ30の内部下方には、粉体タ
ンク40に貯溜された粉体を供給管44を経由してエア
コンプレッサ42で注入される圧縮エアで空気搬送する
よう構成され、図1、図3ならびに図5に示すように、
頂面シャッタ30の両側に配設された粉体供給ダクト3
0aを通じてで金型空間内に注入される。粉体ダクト3
0aの内部には、図5に示すように、複数枚の整流板3
0bが設けられ、粉体を密閉空間Q内に均等に散布する
ようになっている。一方、底面シャッタ50には、密閉
空間Q内の気体を吸入し、かつ、密閉空間Qに注入され
パリソンPに付着されなかった残りの粉体を回収するた
めの集塵装置74および真空ポンプ(または吸引ファ
ン)72が接続されるフレキシブル管を含む排出管70
が取り付けられる。Below the top shutter 30, the powder stored in the powder tank 40 is pneumatically conveyed by compressed air injected by an air compressor 42 via a supply pipe 44, as shown in FIG. As shown in FIGS. 3 and 5,
Powder supply ducts 3 arranged on both sides of the top shutter 30
It is injected into the mold space through 0a. Powder duct 3
In the inside of 0a, as shown in FIG.
0b is provided so that the powder is evenly dispersed in the closed space Q. On the other hand, the bottom shutter 50 sucks the gas in the closed space Q and collects the remaining powder that has been injected into the closed space Q and not attached to the parison P and a vacuum pump ( (Or a suction fan) 72 is connected to a discharge pipe 70 including a flexible pipe.
Is attached.
【0009】金型24、24のキャビティ面に対向する
部分には、必要に応じて熱媒体や冷媒体を切り替えて流
し、金型24、24のキャビティ面を加熱または冷却す
る媒体通路24aが配設され、図示しない媒体(熱媒体
または冷媒体)切替供給装置と接続される。A medium passage 24a for heating or cooling the cavity surfaces of the molds 24, 24 is arranged in a portion of the molds 24, 24 facing the cavity surfaces by switching a heat medium or a coolant as needed. It is installed and connected to a medium (heat medium or refrigerant body) switching supply device (not shown).
【0010】さらに、頂面シャッタ30と金型24の上
端部との間にエアシリンダ82により金型開閉方向に進
退動自在に開閉する割り型80が配設される。また、同
様に、底面シャッタ50と金型24の下端部との間にエ
アシリンダ92により金型開閉方向に進退動自在に開閉
する割り型90が配設される。割り型80、90の役割
は、後述するように、パリソンPの吐出垂下とその途中
の粉体付着が完了した後、型締してパリソンPにブロー
イングする前に割り型80、90を閉じることによっ
て、パリソンPを複雑に屈曲したキャビティ形状に合致
させるものであるが、金型の型閉によりパリソンPの上
端部と下端部をそれぞれ十分に合着できる場合には、割
り型80、90を省略し得る。Further, a split mold 80 is provided between the top shutter 30 and the upper end of the mold 24 so as to be opened and closed by an air cylinder 82 so as to be movable back and forth in the mold opening and closing direction. Similarly, a split mold 90 that is opened and closed by an air cylinder 92 so as to be movable back and forth in the mold opening / closing direction is disposed between the bottom shutter 50 and the lower end of the mold 24. The role of the split molds 80 and 90 is to close the split molds 80 and 90 before clamping and blowing on the parison P after completion of discharge hanging of the parison P and adhesion of powder on the way, as described later. By this, the parison P is matched with the complicatedly curved cavity shape. However, when the upper end and the lower end of the parison P can be sufficiently bonded by closing the mold, the split molds 80 and 90 are used. It can be omitted.
【0011】金型24、24の一方には、型閉後のパリ
ソンPの内部にブローイングする際に使用されるブロー
ピン26が可動プラテン22および金型24を貫通して
進退動自在に配設される。On one of the molds 24, 24, a blow pin 26 used for blowing inside the parison P after the mold is closed is provided so as to pass through the movable platen 22 and the mold 24 so as to be movable back and forth. It
【0012】以上のように構成された本発明の中空品の
ブロー成形装置100における作動について説明する。
まず、金型24、24を型開し、図1に示すように、割
り型80、90を開状態に保持したまま頂面シャッタ3
0、30や底面シャッタ50、50を移動して閉状態に
するとともに、側面シャッタ60、60も図4にように
上昇させて閉状態とする。次に、真空ポンプ(または吸
引ファン)72を可動して密閉空間Q内の気体を吸引し
つつダイス装置20よりパリソンPを吐出しながら、エ
アコンプレッサ42を稼働し粉体タンク40の粉体を供
給管44を経由して空気搬送し、粉体供給ダクト30a
より密閉空間Q内へ噴出させ、下降中のパリソンPの外
表面に順次粉体を付着させる。粉体の付着量は、粉体タ
ンク下部に付属の供給器の容量やエアコンプレッサ42
の風量を制御して調節する。パリソンPの降下中の粉体
吹きつけの際、真空ポンプ(または吸引ファン)72の
吸引力に導入されて屈曲したキャビティ空間に円滑に降
下する。付着しなかった粉体は、底面シャッタ50の下
の排出管70を経由して集塵装置74で集塵され、回収
される。このようにして、パリソンPの吐出垂下が終わ
ると、粉体の噴射を停止し、頂面シャッタ30、側面シ
ャッタ60、底面シャッタ50をそれぞれ後退退避さ
せ、割り型80および割り型90を前進させて閉状態に
してから、図2に示すように型閉し、パリソンPを両金
型24、24で挟んでブローイングし成形する。The operation of the blow molding apparatus 100 for hollow articles of the present invention having the above-described structure will be described.
First, the molds 24, 24 are opened, and as shown in FIG. 1, the top shutter 3 is held with the split molds 80, 90 held open.
The shutters 0 and 30 and the bottom shutters 50 and 50 are moved to the closed state, and the side shutters 60 and 60 are also raised to the closed state as shown in FIG. Next, while moving the vacuum pump (or suction fan) 72 to suck the gas in the closed space Q and discharge the parison P from the die device 20, the air compressor 42 is operated to remove the powder in the powder tank 40. Air is conveyed via the supply pipe 44, and the powder supply duct 30a
The powder is further ejected into the closed space Q, and the powder is sequentially attached to the outer surface of the descending parison P. The amount of powder adhered depends on the capacity of the feeder attached to the bottom of the powder tank and the air compressor 42.
Control and adjust the air volume of. When the powder is sprayed while the parison P is descending, it is smoothly introduced into the bent cavity space by being introduced by the suction force of the vacuum pump (or suction fan) 72. The powder that has not adhered is collected and collected by the dust collector 74 via the discharge pipe 70 under the bottom shutter 50. In this way, when the drooping of the parison P ends, the powder injection is stopped, the top shutter 30, the side shutter 60, and the bottom shutter 50 are retracted and retracted, and the split mold 80 and split mold 90 are moved forward. After closing the mold, the mold is closed as shown in FIG. 2, and the parison P is sandwiched between both molds 24, 24 and blown to mold.
【0013】金型型閉後のブローイングのブロー圧力
は、パリソンP表面と接する金型キャビティ面との間の
空気を完全に排除し、両者間に空気が残存して成形品表
面に気泡の生成などの不良を防止するため、少なくとも
4kgf/cm2 の圧力とする。The blowing pressure of the blowing after closing the mold completely eliminates the air between the surface of the parison P and the surface of the mold cavity in contact with the parison P, and the air remains between them to form bubbles on the surface of the molded product. In order to prevent such defects, the pressure is at least 4 kgf / cm 2 .
【0014】金型24、24は型閉する前にあらかじめ
加熱する。金型24の加熱温度や冷却温度はパリソンP
やこれに付着させる粉体の樹脂材料の樹脂種類に応じて
適正な温度を選択する。すなわち、ブロー成形品の表面
性を改善するために、換言すれば、成形品の表面転写性
を向上するために、パリソン樹脂もしくは粉体樹脂のう
ち高い方の軟化点温度以上に加熱し、表面転写が十分行
なわれた後、速やかに冷却する。なお、粉体が無機材料
に場合には、金型24をパリソン樹脂の軟化点温度以上
に加熱する。The molds 24, 24 are preheated before the molds are closed. The heating temperature and cooling temperature of the mold 24 are the parison P
The proper temperature is selected according to the resin type of the resin material of the powder or the powder to be attached thereto. That is, in order to improve the surface property of the blow-molded product, in other words, in order to improve the surface transferability of the molded product, the parison resin or the powder resin is heated to a temperature higher than the softening point temperature of the higher one, After the transfer is sufficiently performed, it is cooled immediately. When the powder is an inorganic material, the mold 24 is heated to the softening point temperature of the parison resin or higher.
【0015】樹脂の軟化温度は、非晶性樹脂の場合には
ガラス転移温度に等しく、ABS樹脂では110℃〜1
30℃であり、変性PPO樹脂では120℃〜140℃
程度である。これに対して、結晶性樹脂の場合には、結
晶化温度から融点までの間の温度が適当で、PPの場合
には130℃〜160℃、PEの場合には100℃〜1
30℃、ナイロン6では180℃〜230℃となる。一
方、冷却温度は80℃〜100℃程度とし、1工程中の
金型温度の温度変化は、例えば、図6に示すように、温
度カーブAと温度カーブBのように変化させる2通りの
方法が有り、いずれを使用してもよい。温度カーブA
は、パリソンPを射出して型閉する際に金型温度が低い
「クールスタート」法と呼び、温度カーブBは逆に型閉
時に金型温度が高い「ホットスタート」法と呼ぶ。熱媒
体と冷媒体は、種々のオイル、水、加圧水(スチーム)
が使用され、望ましくは温度の異なる同一物質を使用す
ることが望ましい。以上のように金型24を加熱、冷却
する場合のほか、パリソンPを外部から直接光源や熱源
で表面加熱する方法も採用し得る。The softening temperature of the resin is equal to the glass transition temperature in the case of the amorphous resin, and 110 ° C. to 1 in the case of the ABS resin.
30 ° C., 120 ° C. to 140 ° C. for modified PPO resin
It is a degree. On the other hand, in the case of a crystalline resin, the temperature between the crystallization temperature and the melting point is suitable, 130 ° C to 160 ° C for PP and 100 ° C to 1 ° C for PE.
The temperature is 30 ° C and 180 ° C to 230 ° C for nylon 6. On the other hand, the cooling temperature is set to about 80 ° C. to 100 ° C., and the temperature change of the mold temperature during one step is, for example, as shown in FIG. 6, two methods of changing the temperature curve A and the temperature curve B. There is, and either may be used. Temperature curve A
Is called the "cool start" method in which the mold temperature is low when the parison P is injected and the mold is closed, and the temperature curve B is called the "hot start" method in which the mold temperature is high when the mold is closed. Various types of oil, water, and pressurized water (steam) can be used as the heat carrier and refrigerant.
Is preferably used, and it is desirable to use the same substance at different temperatures. In addition to the case of heating and cooling the mold 24 as described above, a method of directly heating the surface of the parison P from the outside with a light source or a heat source may be adopted.
【0016】本発明の方法では、以上のようにして、パ
リソンPの外表面に粉体を付着させて2層の中空品を簡
便容易に成形できるが、加飾性を増加させるため、さら
に付着粉体層の外側に樹脂シートを貼り合わせることも
できる。この場合の貼り合わせブロー成形品に使用する
樹脂シートは、押出成形で生産された通常の市販品を使
用してもよいが、片面(ブロー成形品表面側)に加飾模
様や加飾文様を印写した、例えば、ABS押出シートを
使用すれば、高光沢で任意の色彩や模様を有する種々の
パネル状成形品が得られる。その用途としては、 空調用エアダクト たとえば、空気取入口から室内までの各種送気・換気用
エアダクト、ウィンドの曇り止め、または、凍結防止用
のデフロスタノズルやデフロスタ アンダーフード用ダクト、リゾネータ たとえば、エンジンルーム内の空気取入口からエアクリ
ーナまでのエアインテーク用各種ダクトとリゾネータ、
エアクリーナ以後のダクトとリゾネータ チューブ、ホース類 たとえば、ヒューエルチューブ、ヒューエルフィラーハ
ウジング、ラジエータチューブ などが有る。According to the method of the present invention, as described above, the powder can be attached to the outer surface of the parison P to easily and easily form a two-layer hollow article. A resin sheet may be attached to the outside of the powder layer. In this case, the resin sheet used for the laminated blow-molded product may be an ordinary commercial product produced by extrusion molding, but one side (blow-molded product surface side) may have a decorative pattern or a decorative pattern. By using, for example, an ABS extruded sheet, which has been printed, various panel-shaped molded articles having high gloss and arbitrary colors and patterns can be obtained. Its applications include air ducts for air conditioning, for example, various air ducts for air supply and ventilation from the air intake to the room, anti-fog for the wind, or defroster nozzles for defrosting, defroster underhood ducts, resonators, for example, engine rooms. Various ducts and resonators for air intake from the inside air intake to the air cleaner,
Ducts after the air cleaner, resonator tubes, hoses, etc. For example, there are fuel tubes, fuel filler housings, radiator tubes, etc.
【0017】粉体は、樹脂材料に限定されることなく、
種々のセラミックや金属粉などの無機材料を採用するこ
とにより、より強度や加飾性を増した広がりの有る製品
を得ることができる。The powder is not limited to the resin material,
By adopting inorganic materials such as various ceramics and metal powders, it is possible to obtain a product having a wider range with more strength and decorativeness.
【0018】本発明の方法によれば、ブロー成形の型閉
時に金型加熱を行なっているので、パリソンPや粉体樹
脂は、半溶融状態にまで昇温軟化しており、成形品表面
は、段差のない平滑な表面を形成し得る。According to the method of the present invention, since the mold is heated at the time of closing the mold for blow molding, the parison P and the powdered resin are heated and softened to a semi-molten state, and the surface of the molded product is A smooth surface without steps can be formed.
【0019】[0019]
【発明の効果】以上述べたように、本発明においては、
中空成形品のブロー成形方法において、左右一対の金型
を、型閉時に3次元的に屈曲したキャビティ形状を有す
る形状に形成し、任意の型開量に型開された両該金型間
で形成された空間を両側面、頂面ならびに底面で囲繞さ
れほぼ密閉された密閉空間とするとともに、該密閉空間
内部の気体を下部より吸引しつつ、パリソンを吐出して
該密閉空間内の該キャビティ内に導入しながら、吐出途
中の該パリソンの外表面に、金型上端部より気体ととも
に供給された樹脂材料または無機材料の粉体を付着させ
るとともに、該パリソンが所定の長さに達した後に該パ
リソンの吐出降下を停止して金型上端部および金型下端
部を閉じ、あらかじめ金型キャビティ面を、該粉体樹脂
材料または該パリソン樹脂材料のいずれかのうち高い方
の軟化点温度以上に加熱した後、型締してブローイング
を行なった後に成形品が取り出せるに十分な温度に冷却
して成形品を取り出すようにしたので、3次元的に屈曲
した複雑な成形品を成形する際、単層のブロー成形機に
より一度の成形で同時に、表面性の優れた高転写の2層
の中空成形品が簡便容易に得られ、かつ、設備費も低廉
であり、パリソンの歩留まりもよく生産性の高い操業が
できる。また、粉体の色彩を自由に選択することによ
り、単層ブロー成形機で色替えすることなく多色、多層
成形品を簡便容易に安価に生産できる。また、加飾模
様、加飾文様を付加した樹脂シートを採用することによ
り意匠、デザインの多様性を享受できる。また、パリソ
ン降下途中の粉体噴射の際、金型空間を密閉空間とし、
かつ、その内部気体を吸引して負圧状態としたため、パ
リソンが円滑に複雑なキャビティ空間に導入され、しか
も、周囲の作業環境を汚染することなく操業できる。さ
らに、本発明の方法では、金型を成形時加熱冷却するの
で、金型キャビティ面に接している粉体樹脂の表面が軟
化再溶融され、粉体樹脂とパリソン表面の境目に段差の
ない優れた2層の中空ブロー成形品が得られる。As described above, in the present invention,
In a blow molding method for a hollow molded product, a pair of left and right dies are formed into a shape having a cavity shape that is three-dimensionally bent when the dies are closed, and the dies are opened to an arbitrary opening amount. The formed space is a closed space which is surrounded by both side surfaces, a top surface and a bottom surface and is substantially sealed, and while discharging the gas inside the closed space from the lower part, discharging the parison, the cavity in the closed space. While being introduced into the inside, while adhering the powder of the resin material or the inorganic material supplied together with the gas from the upper end of the die to the outer surface of the parison during discharging, after the parison reaches a predetermined length. The discharge lowering of the parison is stopped, the upper end of the mold and the lower end of the mold are closed, and the mold cavity surface is previously set to the softening point temperature of the higher of the powder resin material and the parison resin material. After heating, the mold is clamped and blown, and then the molded product is taken out by cooling to a temperature sufficient for taking out the molded product. Therefore, when molding a three-dimensionally bent complex molded product, With a single layer blow molding machine, it is possible to easily and easily obtain a two-layer hollow molded product with excellent surface properties and high transfer at the same time, the equipment cost is low, the yield of the parison is good, and the productivity is high. High operation is possible. In addition, by freely selecting the color of the powder, it is possible to easily, easily, and inexpensively produce a multicolor, multi-layer molded product without changing the color with a single-layer blow molding machine. Further, by adopting a resin sheet to which a decorative pattern and a decorative pattern are added, a variety of designs and designs can be enjoyed. In addition, when the powder is sprayed while the parison is descending, the mold space is a closed space,
Moreover, since the internal gas is sucked into a negative pressure state, the parison can be smoothly introduced into the complicated cavity space, and further, the parison can be operated without contaminating the surrounding work environment. Further, in the method of the present invention, since the mold is heated and cooled during molding, the surface of the powder resin in contact with the mold cavity surface is softened and remelted, and there is no step at the boundary between the powder resin and the parison surface. A two-layer hollow blow molded product is obtained.
【図1】本発明の実施例に係るブロー成形装置の型開時
の全体縦断面図である。FIG. 1 is an overall vertical sectional view of a blow molding device according to an embodiment of the present invention when a mold is opened.
【図2】本発明の実施例に係るブロー成形装置の型閉時
の全体縦断面図である。FIG. 2 is an overall vertical cross-sectional view of a blow molding device according to an embodiment of the present invention when a mold is closed.
【図3】図3は図1のA−A視の平面図である。FIG. 3 is a plan view taken along the line AA of FIG.
【図4】図1のB−B視の平面図である。FIG. 4 is a plan view taken along the line BB of FIG.
【図5】図3のC−C視の側面図である。5 is a side view taken along the line CC of FIG.
【図6】本発明に係るブロー成形方法の金型温度変化を
説明するグラフである。FIG. 6 is a graph illustrating a mold temperature change of the blow molding method according to the present invention.
【図7】従来のブロー成形機の全体縦断面図である。FIG. 7 is an overall vertical sectional view of a conventional blow molding machine.
1 ブロー成形機 2 ダイスヘッド(ダイス) 2a 樹脂供給口 3 マンドレル 3a コア 4 射出装置 5 バルブ 6 パリコンシリンダ 6a パリコン用ロッド 7 環状空間通路 8 金型 10 ダイス装置 11 ダイスヘッド 12 プリピンチ 20 金型装置 22 可動プラテン 23 型締シリンダ 24 金型 24a 媒体通路 26 ブローピン 30 頂面シャッタ 30a 粉体供給ダクト 30b 整流板 32 エアシリンダ 40 粉体タンク 42 エアコンプレッサ 44 供給管 50 底面シャッタ 52 エアシリンダ 60 側面シャッタ 62 エアシリンダ 70 排出管 72 真空ポンプ 74 集塵装置 80 割り型 82 エアシリンダ 90 割り型 92 エアシリンダ 100 ブロー成形装置 P パリソン Q 密閉空間 1 Blow Molding Machine 2 Die Head (Die) 2a Resin Supply Port 3 Mandrel 3a Core 4 Injection Device 5 Valve 6 Paricon Cylinder 6a Paricon Rod 7 Annular Space Passage 8 Die Device 11 Dice Head 12 Pre-pinch 20 Mold Device 22 Movable platen 23 Mold clamping cylinder 24 Mold 24a Medium passage 26 Blow pin 30 Top shutter 30a Powder supply duct 30b Rectifier plate 32 Air cylinder 40 Powder tank 42 Air compressor 44 Supply pipe 50 Bottom shutter 52 Air cylinder 60 Side shutter 62 Air Cylinder 70 Discharge pipe 72 Vacuum pump 74 Dust collector 80 Split mold 82 Air cylinder 90 Split mold 92 Air cylinder 100 Blow molding device P Parison Q Closed space
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 // B29K 101:00 101:12 103:04 B29L 22:00 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Office reference number FI technical display location // B29K 101: 00 101: 12 103: 04 B29L 22:00
Claims (2)
付けたコアとの間の環状の樹脂通路から吐出されたパリ
ソンを左右一対の金型で挟んでブロー成形する中空成形
品のブロー成形方法において、 左右一対の金型を、型閉時に3次元的に屈曲したキャビ
ティ形状を有する形状に形成し、 任意の型開量に型開された両該金型間で形成された空間
を両側面、頂面ならびに底面で囲繞されほぼ密閉された
密閉空間とするとともに、 該密閉空間内部の気体を下部より吸引しつつ、パリソン
を吐出して該密閉空間内の該キャビティ内に導入しなが
ら、吐出途中の該パリソンの外表面に、金型上端部より
気体とともに供給された樹脂材料または無機材料の粉体
を付着させるとともに、 該パリソンが所定の長さに達した後に該パリソンの吐出
降下を停止して金型上端部および金型下端部を閉じ、 あらかじめ金型キャビティ面を、該粉体樹脂材料または
該パリソン樹脂材料のいずれかのうち高い方の軟化点温
度以上に加熱した後、型締してブローイングを行なった
後に成形品が取り出せるに十分な温度に冷却して成形品
を取り出す中空成形品のブロー成形方法。1. A blow molding method for a hollow molded product, wherein a parison discharged from an annular resin passage between a die head and a core attached to the lower end of a mandrel is sandwiched between a pair of left and right molds and blow molded. A pair of molds are formed into a shape having a cavity shape which is three-dimensionally bent when the molds are closed, and the space formed between the molds opened to an arbitrary mold opening amount is defined by both side surfaces and top surface. And a substantially enclosed space enclosed by the bottom surface, while sucking the gas inside the enclosed space from the lower part and discharging the parison into the cavity in the sealed space, The powder of resin material or inorganic material supplied together with gas from the upper end of the die is attached to the outer surface of the parison, and the discharge lowering of the parison is stopped after the parison reaches a predetermined length. And close the upper and lower ends of the mold and heat the mold cavity surface to the softening point temperature of the higher of either the powder resin material or the parison resin material in advance, and then clamp the mold. A blow molding method for a hollow molded product, in which the molded product is taken out by cooling to a temperature sufficient to remove the molded product after blowing.
溶融樹脂を下端よりパリソンとして吐出するダイス装置
と該パリソンを挟んでブロー成形する左右一対の金型装
置からなるブロー成形装置において、 左右一対の金型を、型閉時に3次元的に屈曲したキャビ
ティ形状を有する形状に形成し、 金型内部に、金型を加熱または冷却する媒体通路を設
け、 金型の外側面に金型進退動方向に伸縮開閉自在な前後一
対の側面シャッタを配設するとともに、金型上端部と金
型下端部にそれぞれ金型進退動方向に伸縮開閉自在な左
右一対の頂面シャッタと昇降自在な底面シャッタを配設
して型開時の金型空間を密閉空間に形成し、 該底面シャッタ直下に該密閉空間内の気体を吸引すると
ともに、粉体ホッパに貯溜された粉体を空気搬送する排
出管を配設し、かつ、吐出された粉体を含有する気体を
吸引し集塵する集塵装置を該排出管に接続してなる中空
成形品のブロー成形装置。2. A blow molding device comprising an injection device, a die device for discharging molten resin supplied from the injection device as a parison from the lower end, and a pair of left and right mold devices for blow molding sandwiching the parison. Is formed into a shape having a three-dimensionally curved cavity shape when the mold is closed, a medium passage for heating or cooling the mold is provided inside the mold, and the mold is moved back and forth on the outer surface of the mold. A pair of front and rear side shutters that can be expanded and contracted in any direction are provided, and a pair of left and right top shutters that can be expanded and contracted in the mold advancing and retracting directions and a bottom shutter that can be moved up and down are provided at the upper and lower mold ends Is provided to form a mold space in a closed space when the mold is opened, and a discharge pipe for sucking gas in the closed space just below the bottom surface shutter and carrying the powder stored in the powder hopper by air. Distribute And, and, a hollow molded article blow molding apparatus formed by connecting a dust collector for dust collection sucking gas containing exhaled powder exhaust extraction tube.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7230862A JPH0970880A (en) | 1995-09-08 | 1995-09-08 | Blow molding method and device for hollow molded article |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7230862A JPH0970880A (en) | 1995-09-08 | 1995-09-08 | Blow molding method and device for hollow molded article |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0970880A true JPH0970880A (en) | 1997-03-18 |
Family
ID=16914478
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7230862A Pending JPH0970880A (en) | 1995-09-08 | 1995-09-08 | Blow molding method and device for hollow molded article |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0970880A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001021380A1 (en) * | 1999-09-21 | 2001-03-29 | Idemitsu Petrochemical Co., Ltd. | Molding method for blow molded product |
| JP2008178618A (en) * | 2007-01-26 | 2008-08-07 | Kyoraku Co Ltd | Hollow repulsive member for joint supporter and its manufacturing method |
-
1995
- 1995-09-08 JP JP7230862A patent/JPH0970880A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001021380A1 (en) * | 1999-09-21 | 2001-03-29 | Idemitsu Petrochemical Co., Ltd. | Molding method for blow molded product |
| US6746643B1 (en) | 1999-09-21 | 2004-06-08 | Idemitsu Petrochemical Co., Ltd. | Molding method for blow molded product |
| JP2008178618A (en) * | 2007-01-26 | 2008-08-07 | Kyoraku Co Ltd | Hollow repulsive member for joint supporter and its manufacturing method |
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