JPH10104809A - Method for developing silver halide color photographic sensitive material for photographing - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a color photographic sensitive material having high image quality and almost free from color stain, that is, a residual color due to a sensitizing dye after processing by using a processing soln. having fixing ability and contg. a specified compd. SOLUTION: A processing soln. having fixing ability used in a developing process contains a compd. represented by the formula, wherein each of L<1> and L<2> is -OR<1> or -NR<2> R<3> (each of R<1> -R<3> is H or alkyl) and the four substituents L<1> , L<2> satisfy at least one of the following three conditions; 1. the substituents L<1> , L<2> have four or more substituents in a group (A), 2. the substituents L<1> , L<2> have two or more substituents in the group A and two more substituents in a group (B) and 3. the substituents L<1> , L<2> have one substituent in the group A and three or more substituents in the group B. The group A include -SO3 M, -OSO3 M and -COOM (M is H, an alkali metal, etc.). The group B include -OR, -NR'R'' and -CN (each of R, R' and R'' is H or alkyl and R' and R'' may bond to each other to form a ring).

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silver halide color photographic light-sensitive material for photographing, and more particularly to an excellent method for forming an image of a silver halide color photographic light-sensitive material for photographing which has little color contamination due to residual sensitizing dye after processing. Things.

[0002]

2. Description of the Related Art Silver halide color photographic light-sensitive materials, in particular, photographic light-sensitive materials, have become highly sensitive and have excellent image quality due to the spread of compact cameras, autofocus single-lens reflex cameras and films with lenses. There is a strong demand for color photographic light-sensitive materials. At the same time, development processing is performed in various laboratories due to the recent spread of equipment such as mini-labs, and it is also important to provide images with uniform finish in any laboratory.

As a technique for supporting high sensitivity in a photographic light-sensitive material, there is a technique using tabular silver halide grains. Tabular silver halide grains have a larger surface area / volume ratio than other forms of silver halide grains, for example, cubic, octahedral, tetradecahedral, and spherical silver halide grains. The fact that the amount of sensitizing dye that can be produced is large has the effect of improving sensitivity and improving the relationship between sensitivity and granularity.

However, when the amount of the sensitizing dye is increased as described above, the sensitizing dye remaining in the light-sensitive material after processing cannot be ignored and causes color contamination (hereinafter, residual color).
Regarding the residual form of the sensitizing dye that causes the residual color, the sensitizing dye exists as its monomer and its aggregate,
For example, it is described in European Patent No. 0,654,702. It has been found that this color contamination is reduced by washing the processed photosensitive material with water. The washing out of the sensitizing dye is affected by the ionic strength of the washing bath. When the ionic strength is high, the sensitizing dye exists as an aggregate, and the diffusion coefficient in the gelatin film is estimated to be extremely low. Therefore, if the processing time of the processing solution, particularly the washing bath or the rinsing bath, and the composition of the processing solution are different, the degree of the residual color is not the same, and a difference between labs is caused by a difference in lab equipment and management conditions.

To solve the above-mentioned problem of residual color, the residual color due to the sensitizing dye is reduced to some extent by adding a water-soluble fluorescent whitening agent to a developer, a bleach-fixer or a washing / stabilizing bath. Are known and described, for example, in Research Disclosure 20733 (July, 1981). Also, for example, a method using a specific sensitizing dye and a fluorescent whitening agent described in JP-A-62-257154 and a specific water-soluble fluorescent whitening described in JP-A-4-249243 and JP-A-6-329936. A method using an agent and the like are disclosed as methods for reducing residual color.

In the case of a silver halide color photographic light-sensitive material used for color printing, the above-mentioned water-soluble brightener has a small amount of coated silver, that is, a small content of a sensitizing dye.
Any use in any of the processing steps is effective in reducing residual color to some extent. However, the coating amount of a sensitizing dye is extremely large in a silver halide color photographic light-sensitive material for photography, and when the above-mentioned known water-soluble whitening agent is used in a developer or a washing / stabilizing bath light-sensitive material, the residual color is reduced. The effect on the reduction was insufficient.

[0007]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide an excellent silver halide color photographic light-sensitive material for photographing which has high image quality and has little color contamination by a sensitizing dye after processing, that is, little residual color. Is to do.

[0008]

The present inventors have conducted intensive studies and as a result, the above objects have been achieved by the following silver halide color photographic materials. (1) A silver halide color photographic light-sensitive material for photography comprising at least two blue-sensitive silver halide emulsion layers, a green-sensitive silver halide emulsion layer, and a red-sensitive silver halide emulsion layer provided on a support. Wherein at least one of the processing solutions having a fixing ability used in the development processing step contains a compound represented by the following general formula (SR): Development processing method.

[0009]

Embedded image

In the general formula [SR], L ¹ and L ² may be the same or different, and may be -OR ¹ or -NR ² R
³ (R ¹ , R ² and R ³ are each a hydrogen atom or an alkyl group), and satisfy at least one of the following conditions. Four substituents L ¹ and L in the general formula [SR]
² has a total of four or more substituents selected from the general formula [A] group. Four substituents L ¹ and L in the general formula [SR]
² has a total of two substituents selected from the general formula [A] group, and has a total of two or more substituents selected from the general formula [B] group. Four substituents L ¹ and L in the general formula [SR]
² has one substituent selected from the general formula [A] group, and has a total of three or more substituents selected from the general formula [B] group.

General formula [A] group: -SO ₃ M, -OSO ₃
M, -COOM, -NR ₃ X General formula [B] group: -OR, -NR'R ", -CN, -N
In the HCONH ₂ general formula [A] group, X represents a halogen atom, and R represents an alkyl group. In the general formulas [SR] and [A],
M represents a hydrogen atom, an alkali metal, tetraalkylammonium or pyridinium. In the general formula [B] group,
R, R 'and R "are a hydrogen atom or an alkyl group, and R' and R" may be linked to each other to form a ring. (2) The total coating amount of the sensitizing dye contained in all of the blue-sensitive silver halide emulsion layer, the green-sensitive silver halide emulsion layer, and the red-sensitive silver halide emulsion layer is 30 μmol / m ² or more. The silver halide color photographic light-sensitive material according to claim 1, wherein the total coating amount of the sensitizing dye in the red-sensitive emulsion layer or the green-sensitive emulsion layer is 10 µmol / m ² or more. And a development processing method.

[0012]

BEST MODE FOR CARRYING OUT THE INVENTION The water-soluble fluorescent whitening agent represented by the general formula [SR] will be described in more detail. General formula [S
R], L ¹ and L ² represent —OR ¹ or —NR ² R
^And R ¹ , R ² and R ³ represent an alkyl group, which may be the same or different. The alkyl group is a linear or branched alkyl group, and a hydrogen atom of the alkyl group may be substituted with another group. The substitutable group may be any group, but is preferably a substituent selected from the general formula [A] group and the general formula [B] group. The alkyl group represented by R ¹ , R ² and R ³ preferably has 1 to 10 carbon atoms, more preferably 1 to 5 carbon atoms. The substituents in the general formula [A] group and the general formula [B] group are those generally known as hydrophilic groups. In particular, the substituents in the general formula [A] group are known as strong hydrophilic groups, so-called strongly hydrophilic groups.

In the present invention, the compound represented by the general formula [SR] has L ¹ and L ² satisfying at least one of the above conditions. General formula [SR]
Means that two triazine rings in the molecule are L ¹ and L, respectively.
^It is preferable to have a symmetry by having ² and, more specifically, to have a symmetry belonging to a so-called C2h point group having two rotation axes outside the molecular plane at the center of the molecule (center point on the double bond). . Here, the condition is a condition in which four substituents L ¹ and L ² in the general formula [SR] have a total of four or more substituents selected from the general formula [A] group. When the condition is satisfied, when the number of the two sulfo groups of the benzene ring constituting the stilbene in the compound of the general formula [SR] is combined, the compound has a total of six or more strongly hydrophilic groups in the molecule. Equivalent to. Here, the number of substituents selected from the general formula [A] group is preferably an even number, and the number is preferably 8 or less, more preferably 6 or less. As described above, if the number of the above-mentioned substituents is too large or too small, it is not preferable because the effect of preventing the residual color is reduced. The conditions are that the four substituents L ¹ and L ² in the general formula [SR] are a total of two substituents selected from the group [A] and a total of two or more substituents selected from the general formula [B] group. It is a condition having a group. When the conditions are satisfied, the compound represented by the general formula [SR], when combined with the number of two sulfo groups of the benzene ring constituting stilbene, has a total of four strongly hydrophilic groups and a total of two or more hydrophilic groups in the molecule. It is equivalent to having a functional group. Here, the number of substituents selected from the general formula [B] group is preferably an even number, and the number is preferably 10 or less, more preferably 4 or less. The condition is that four substituents L ¹ and L ² in the general formula [SR] are a substituent selected from one [A] group and a total of three or more substituents selected from a general formula [B] group. Is a condition having As described above, if the number of the above-mentioned substituents is too large or too small, it is not preferable because the effect of preventing the residual color is reduced. Among the compounds represented by the general formula [SR] according to the present invention, more preferred compounds satisfy the above conditions or conditions.
Those satisfying the conditions are more preferable.

Under the above-mentioned conditions, the compound represented by the general formula [SR] having a strongly hydrophilic group has a structure generally known as a stilbene-based fluorescent whitening agent.
However, for example, (I-30) and (I-31) described in JP-A-62-257154,
Conventional optical brighteners having a total of four or more strongly hydrophilic substituents in the molecule, such as the compound described in No. 9243 (Comparative-1), usually have two triazine rings in the molecule having an anilino group. There was a feature to have. Further, even with a conventional stilbene fluorescent brightener having a triazine ring having no anilino group, a specific compound satisfying any of the above conditions has not been known. The stilbene-based optical brightener represented by the general formula [SR], which satisfies the above-mentioned condition or any one of the present invention, has a triazine ring having a substituent L ¹
And JP-in that is characterized with a strong hydrophilic group without a anilino group as the L ² 4-249243
Different from the optical brightener described in No.

In the compound of the general formula [SR] in the present invention, the substituents L ¹ and L ² have the characteristics described above, and specific examples of L ¹ and L ² include methoxy,
Ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, pentyloxy, hexyloxy, methylamino, ethylamino, propylamino, isopropylamino, butylamino, isobutylamino, 2-hydroxyethoxy, 3-hydroxypropoxy, 4-hydroxybutoxy, 2-hydroxyethylamino, 3-hydroxypropylamino, 4-hydroxybutylamino,
2-hydroxyethylethylamino, 3-hydroxypropylpropylamino, 4-hydroxybutylbutylamino, dimethylamino, diethylamino, dipropylamino, diisopropylamino, dibutylamino, diisobutylamino, di2-hydroxyethylamino, di3-
Hydroxypropylamino, dihydroxybutylamino, 2-sulfoethoxy, 3-sulfopropoxy, 4-
Sulfobutoxy, 2-sulfoethylamino, 3-sulfopropylamino, 4-sulfobutylamino, di-2-sulfoethylamino, di-3-sulfopropylamino, di-4-
Sulfobutylamino, 2-sulfoethylmethylamino,
3-sulfopropylmethylamino, 4-sulfobutylmethylamino, 2-sulfoethylethylamino, 3-sulfopropylethylamino, 4-sulfobutylethylamino, 2-carboxyethoxy, 3-carboxypropoxy, 4-carboxybutoxy, 2-carboxyethylamino, 3-carboxypropylamino, 4-carboxybutylamino, di-2-carboxyethylamino, di3-
Carboxypropylamino, di-4-carboxybutylamino, 2-carboxyethylmethylamino, 3-carboxypropylmethylamino, 4-carboxybutylmethylamino, 2-carboxyethylethylamino, 3-carboxypropylethylamino, 4-carboxybutyl Ethylamino, 2-sulfoxyethoxy, 3-sulfoxypropoxy, 4-sulfoxybutoxy, 2-sulfoxyethylamino, 3-sulfoxypropylamino, 4-sulfoxybutylamino, di-2-sulfoxyethylamino,
Di-3-sulfoxypropylamino, di-4-sulfoxybutylamino, 2-sulfoxyethylmethylamino, 3-
Sulfoxypropylmethylamino, 4-sulfoxybutylmethylamino, 2-sulfoxyethylethylamino,
3-sulfoxypropylethylamino, 4-sulfoxybutylethylamino, trimethylammoniomethylamino, trimethylammonioethylamino, trimethylammoniopropylamino, triethylammoniomethylamino, triethylammonioethylamino, triethylammoniopropyl Amino and the like. More preferably, methoxy, ethoxy, 2-hydroxyethoxy, 2-hydroxyethylamino, 2-sulfoethylamino, di-2-sulfoethylamino, 2-carboxyethylamino, di-2-carboxyethylamino, di-2-hydroxyethyl Amino and the like.

The preferable hydrophilicity of the compound represented by the general formula [SR] in the present invention is that the logP value is -30 or more and -4.
And more preferably -18 or more and -7 or less. Here, the logP value represents a value defined by a logarithmic value of a distribution ratio P (= [concentration in octanol] / [concentration in water]) of the compound in a binary system of octanol / water. If the logP value is -4 or more, it is difficult to elute from the light-sensitive material film into the processing solution, and the improvement in residual color is reduced. Is not preferred because it becomes smaller. Further, the compound of the general formula [SR] in the present invention desirably has a large diffusion coefficient in a gelatin film under various processing conditions. For example, if the diffusion coefficient in an aqueous solution of pH 5 is 1.0
It is preferably at least × 10 ⁻⁸ cm ² / sec, more preferably at least 2.0 × 10 ⁻⁸ cm ² / sec. In an aqueous solution of pH 10,
2.0 × 10 ^-8 cm ² / sec or more is preferable, and 5.0 × 10 ^-8 cm ² / se
c or more is more preferable. The diffusion coefficient can be measured by monitoring with a spectrophotometer how the optical brightener molecules in the optical brightener aqueous solution permeate and diffuse into the adjacent water across the gelatin film. Journal of Po
lymer Science, Vol. 30, 2075 (1985). Specific examples of the diaminostilbene-based fluorescent brightener of the general formula [SR] used in the present invention include those in which L ¹ and L ² are represented by the following atomic groups. Is not limited to these.

[0017]

[Table 1]

[0018]

[Table 2]

[0019]

[Table 3]

[0020]

[Table 4]

[0021]

[Table 5]

The compound of the general formula [SR] can be synthesized by a conventionally known method. For example, 4,4'-
Sodium 4,4'-bistriazinylaminostilbene-2,2'-disulfonate is synthesized by condensing sodium diaminostilbene-2,2'-disulfonate with cyanuric chloride, and then condensing alcohols or amines. Can be synthesized. Specifically, it can be synthesized by the following method. The synthesis example of the optical brightener is shown below. Synthesis of Compound (SR-13) 10.2 g of cyanuric chloride was dissolved in 100 ml of acetone, and 100 g of a 10% aqueous solution of sodium diaminostilbendisulfonate was added dropwise over 20 minutes while cooling with ice. During this time, the pH of the reaction solution was adjusted to 5 with an aqueous sodium carbonate solution.
~ 7. After stirring was continued for another 30 minutes, 100 g of an 18% aqueous solution of taurine was added. Thereafter, acetone was distilled off by heating, and the mixture was stirred at an internal temperature of 95 ° C for 3 hours.
During this time, the pH of the reaction solution was maintained at 6 or more with an aqueous sodium carbonate solution. After the completion of the reaction, the mixture was cooled and salted out to give pale yellow crystals 1
2 g were obtained. It has a mass spectrum and NMR
And it was confirmed to be Compound (SR-13). .lambda.max = 348 nm (.epsilon. = 4.65.times.10 @ _4, H2O)

Synthesis of Compound (SR-25) 10.2 g of cyanuric chloride was dissolved in 100 ml of acetone, and 100 g of a 10% aqueous solution of sodium diaminostilbendisulfonate was added dropwise over 20 minutes while cooling with ice. During this time, the pH of the reaction solution was adjusted to 5 with an aqueous sodium carbonate solution.
~ 7. After stirring for another 30 minutes, the internal temperature was reduced to 4
The temperature was raised to 0 ° C. and 35 g of an 18% aqueous solution of taurine was added.
After heating for 1 hour, acetone was distilled off, 50 g of a 20% aqueous solution of N-methyltaurine was added, and the mixture was stirred at an internal temperature of 95 ° C. for 3 hours. During this time, the pH of the reaction solution was maintained at 6 or more with an aqueous sodium carbonate solution. After completion of the reaction, the mixture was cooled and salted out to obtain 8.3 g of pale yellow crystals. This was confirmed to be a compound (SR-25) from mass spectrum and NMR. .lambda.max = 345 nm (.epsilon. = 4.38.times.10 @ _4, H2O) Other compounds and comparative compounds can be easily synthesized by the same method as described above. Industrial Chemistry Magazine, Vol. 60, No. 5, p. 604 (1957).

The compound of the general formula [SR] is effective both when used alone and when used in combination with a plurality of other diaminostilbene compounds. A compound of [SR],
Alternatively, a diaminostilbene compound represented by the following general formula [SR-c] is preferable.

[0025]

Embedded image

In the general formula [SR-c], L ³ , L ⁴ ,
L ^5, and L ⁶ are represented by -OR ⁸ or -NR ⁹ R ^10, it may be the same or different, respectively. Here, R ⁸ , R ⁹ and R ¹⁰ represent a hydrogen atom, an alkyl group or an alkyl group having a substituent. General formula [SR-
Specific examples of the compound represented by c) include the compounds in Table 6.

[0027]

[Table 6]

As the fluorescent whitening agent that can be used in combination with the compound of the general formula [SR], a commercially available diaminostilbene-based fluorescent whitening agent may be used. Examples of commercially available compounds include, for example, Dyeing Note, 19th Edition (Syokusha) 165-P. 168
And among the products listed here
Whitex RP or Whitex BRF liq. Is preferred.

The preferred concentration of the compound of the formula [SR] of the present invention in the processing solution is 1 × 10 ^-4 in the running solution.
~ 5 x ^10-2 mol / l, more preferably 1 x 1
0 ^over 3 to 1 × a 0 ^{- 2} mol / liter. Concentration needed to keep the concentration constant running solution at a concentration in the replenisher is preferably specifically a 2 × 10 ^{over 4} to 0.1 mol / liter.

The compounds of the general formula [SR] may be used as a mixture of two or more kinds.

The processing solution having fixing ability of the present invention is specifically a bleach-fixing solution or a fixing solution, and it is more preferable to add the compound of the general formula [SR] of the present invention to the fixing solution.

The coating amount of the sensitizing dye contained in the light-sensitive material of the present invention the sensitizing in either the total coating amount of the photosensitive material is 30μ mol / m ² or more, or the red-sensitive emulsion layer or a green-sensitive emulsion layer The total coating amount of the dye is 10 μmol / m ² or more.

The total coating amount of all sensitizing dyes in the light-sensitive material is preferably from 30 μmol / m ^{2 to} 100 μmol / m ² ,
The amount is more preferably from 40 μmol / m ^{2 to} 85 μmol / m ² . The total coating amount of the sensitizing dye in the red-sensitive emulsion layer or the green-sensitive emulsion layer is preferably from 10 μmol / m ^{2 to} 50 μmol / m ^2, more preferably from 15 μmol / m ^{2 to} 40 μmol / m ² .

The silver halide grains used in the photographic material of the present invention are preferably tabular grains.

Here, the tabular grain is a general term for grains having one twin plane or two or more parallel twin planes. In this case, the twin plane refers to the (111) plane when ions at all lattice points on both sides of the (111) plane are in a mirror image relationship. When viewed from above, the tabular grains have a triangular shape, a hexagonal shape or a rounded shape obtained by rounding them. The objects have circular outer surfaces parallel to each other.

The aspect ratio of a tabular grain refers to a value obtained by dividing the grain diameter of each tabular grain having a grain diameter of 0.1 μm or more by the thickness. The measurement of the particle thickness is performed by evaporating a metal from the diagonal direction of the particles together with the reference latex, measuring the shadow length on an electron micrograph, and calculating by referring to the shadow length of the latex. Easy.

The grain diameter is the diameter of a circle having an area equal to the projected area of the parallel outer surface of the grain.

The projected area of the particles can be obtained by measuring the area on an electron micrograph and correcting the projection magnification.

The diameter of the tabular grains is 0.15 to 5.0.
μm is preferred. The thickness of the tabular grains is preferably from 0.05 to 1.0 μm.

Tabular grains having an aspect ratio of 2 or more are preferably 60% or more of the total projected area of the silver halide grains, and more preferably tabular grains having an aspect ratio of 5 or more.

The proportion occupied by the tabular grains is preferably at least 60%, particularly preferably at least 80% of the total projected area.

When monodispersed tabular grains are used, more preferable results may be obtained. The structure and production method of monodisperse tabular grains are described in, for example, JP-A-63-151618.
However, if the shape is briefly described, 70% or more of the total projected area of the silver halide grains is the length of the side having the maximum length with respect to the side having the minimum length. Are hexagonal and less than 2
And the coefficient of variation of the grain size distribution of the hexagonal tabular silver halide grains (variation in grain size represented by the circle-converted diameter of the projected area thereof). Standard deviation)
(Value divided by the average particle size) is 20% or less.

The tabular grains preferably have dislocation lines, and the dislocations of the tabular grains are, for example, as described in JF Hamilton, Phot.
Sci. Eng., 11, 57, (1967) and T. Shiozawa, J.
Sci. Japan. 35, 213, (1972) can be observed by a direct method using a low-temperature transmission electron microscope. In other words, take care not to apply enough pressure from the emulsion to generate dislocations on the grains, place the silver halide grains on a mesh for observation with an electron microscope, and cool the sample to prevent damage (printout, etc.) by electron beams. Observation is carried out by a transmission method in the state where it has been made. At this time, the thicker the particles, the more difficult it is for an electron beam to pass through. Therefore, a clearer image can be observed by using a high-pressure electron microscope (200 kV or more for particles having a thickness of 0.25 μm). . From the photograph of the particles obtained by such a method, the position and number of dislocations for each particle when viewed from the direction perpendicular to the main plane can be determined.

It is preferable that 60% or more of the tabular grains contain dislocation lines. Preferably, particles having dislocation lines of 10, more preferably 20, and more preferably 30 or more account for 60% or more in number. More preferably, it accounts for 80% or more. When dislocation lines are densely present or when dislocation lines are observed to intersect each other, the number of dislocation lines per grain may not be clearly counted. However,
In these cases, about 10, 20, 3,
It is possible to count to about 0.

The dislocation lines can be introduced, for example, near the outer periphery of the tabular grains. In this case, the dislocation is almost perpendicular to the outer periphery, and a dislocation line is generated from the position of x% of the length from the center of the tabular grain to the side (outer periphery) to the outer periphery. The value of x is preferably 10 or more and less than 100, more preferably 30 or more and less than 99, and most preferably 50 or more and less than 98. At this time, the shape formed by connecting the dislocation starting positions is close to the particle shape, but may not be perfect perfect shape and may be distorted.
This type of dislocation is not found in the central region of the grain. The direction of the dislocation lines is approximately (211) crystallographically, but often meanders, and may intersect each other.

The tabular grains may have dislocation lines almost uniformly over the entire area on the outer circumference, or may have dislocation lines at local positions on the outer circumference. That is, in the case of hexagonal tabular silver halide grains as an example, dislocation lines may be limited only near six vertices, or dislocation lines may be limited only near one of the vertices. . Conversely, it is also possible that the dislocation lines are limited only to the sides excluding the vicinity of the six vertices.

Further, dislocation lines may be formed over a region including the center of two parallel main planes of the tabular grain. When dislocation lines are formed over the entire area of the main plane, the direction of the dislocation lines may be crystallographically approximately (211) when viewed from a direction perpendicular to the main plane. In some cases, the dislocation lines are randomly formed, and each dislocation line and length are also random. When observed as a short line on the main plane, and when observed as a length line reaching the side (outer circumference) There is. Dislocation lines are sometimes straight or meandering. They also often intersect with each other.

As described above, the position of the dislocation may be limited to an outer periphery, a main plane, or a local position.
These may be combined and formed. That is, they may be present simultaneously on the outer periphery and on the main plane.

The introduction of dislocation lines on the periphery of tabular grains can be achieved by providing a specific high silver iodide layer inside the grains. Here, the high silver iodide layer includes a case where a high silver iodide region is provided discontinuously. Specifically, it is obtained by preparing a base grain, providing a high silver iodide layer, and covering the outside with a layer having a lower silver iodide content than the high silver iodide layer. The tabular grains of the base have a lower silver iodide content than the high silver iodide layer,
Preferably it is 0-20 mol%, more preferably 0-15 mol%.

The high silver iodide layer in the grain is a silver halide solid solution containing silver iodide. The silver halide in this case is preferably silver iodide, silver iodobromide, or silver chloroiodobromide, but is preferably silver iodide or silver iodobromide (silver iodide content: 10 to 40 mol%). More preferred. In order for the high silver iodide layer inside the grains (hereinafter referred to as the internal silver high iodide layer) to be selectively present anywhere on the sides or corners of the base grains, the conditions for forming the base grains and the internal It can be controlled by the conditions for forming the high silver iodide layer. As the conditions for forming the base grains, pAg (the logarithm of the reciprocal of silver ion concentration) and the presence / absence, type, amount, and temperature of the silver halide solvent are important factors. By controlling the pAg at the time of growth of the base grains to 8.5 or less, more preferably 8 or less, the internal high silver iodide layer can be selectively present near the apex of the base grains. On the other hand, when the pAg at the time of growing the base grains is 8.5 or more, more preferably 9 or more, the internal high silver iodide layer can be present on the sides of the base grains.

The tabular grains are described in Cleve, Photography Theory and Practice (19).
30)), page 131; Photographic
Science and Engineering (Gutoff, Photo
graphic Sceience and Engineering), Vol. 14, 248
257 (1970); U.S. Patent No. 4,434,2.
No. 26, No. 4,414,310, No. 4,433,04
8 and 4,439,520 and British Patent 2,1
It can be easily prepared by the method described in JP-A No. 12,157 or the like.

The light-sensitive material of the present invention may have at least one light-sensitive layer provided on a support. A typical example is a silver halide photographic light-sensitive material having at least one light-sensitive layer comprising a plurality of silver halide emulsion layers having substantially the same color sensitivity but different sensitivities on a support. It is. The photosensitive layer is a unit photosensitive layer having color sensitivity to any of blue light, green light, and red light, and in a multilayer silver halide color photographic material, the arrangement of the unit photosensitive layers is generally A red-sensitive layer, a green-sensitive layer, and a blue-sensitive layer are provided in this order from the support side. However, depending on the purpose, the order of installation may be reversed, or the order of installation may be such that different photosensitive layers are sandwiched between layers of the same color sensitivity. A non-light-sensitive layer may be provided between the silver halide light-sensitive layers and as the uppermost layer and the lowermost layer. These may contain a coupler, a DIR compound, a color mixing inhibitor and the like described below. As described in DE 1,121,470 or GB 923,045, a plurality of silver halide emulsion layers constituting each unit light-sensitive layer are formed by sequentially exposing two layers of a high-speed emulsion layer and a low-speed emulsion layer toward a support. It is preferable to arrange them so that the degree is low. Also, JP-A-57-112751, 62-200350, 62-2
As described in JP-A Nos. 06541 and 62-206543, a low-speed emulsion layer may be provided on the side farther from the support, and a high-speed emulsion layer may be provided on the side closer to the support. As specific examples, from the farthest side from the support, a low-sensitivity blue-sensitive layer (BL) / a high-sensitivity blue-sensitive layer (BH) / a high-sensitivity green-sensitive layer (GH) / a low-sensitivity green-sensitive layer (GL) / High-sensitivity red-sensitive layer (RH) / low-sensitivity red-sensitive layer (RL), or BH / BL / GL / GH / RH / RL, or BH / BL / GH / GL / RL / RH And so on. Also, as described in JP-B-55-34932, the blue-sensitive layer / GH / RH / GL starts from the side farthest from the support.
/ RL can be arranged in this order. JP-A-56-2573
8, as described in JP-A-62-63936, the layers may be arranged in the order of blue-sensitive layer / GL / RL / GH / RH from the side farthest from the support. Also, as described in JP-B-49-15495, the upper layer is the most sensitive silver halide emulsion layer, the middle layer is the silver halide emulsion layer of lower sensitivity, and the lower layer is more sensitive than the middle layer. An example is an arrangement in which a low silver halide emulsion layer is arranged and three layers of different sensitivities are sequentially reduced in sensitivity toward a support. Even when such three layers having different sensitivities are used, as described in JP-A-59-202464, the medium-sensitive emulsion layer / high The layers may be arranged in the order of a light-sensitive emulsion layer / a light-sensitive emulsion layer. In addition, a high-speed emulsion layer / low-speed emulsion layer / medium-speed emulsion layer, or a low-speed emulsion layer / medium-speed emulsion layer / high-speed emulsion layer may be arranged in this order. The arrangement may be changed as described above even in the case of four or more layers. In order to improve color reproducibility, BL, GL, described in US 4,663,271, 4,705,744, 4,707,436, JP-A-62-160448 and 63-89850, are described.
It is preferable that a donor layer (CL) having a multilayer effect having a spectral sensitivity distribution different from that of the main photosensitive layer such as RL is disposed adjacent to or close to the main photosensitive layer.

Preferred silver halides for use in the present invention are silver iodobromide, silver iodochloride, or silver iodochlorobromide containing up to about 30 mole percent silver iodide. Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mol% to about 10 mol% silver iodide. The silver halide grains used in the present invention have regular crystals such as cubic, octahedral, and tetradecahedral in addition to tabular grains, and have irregular crystal forms such as spherical and tabular. And those having crystal defects such as twin planes, or a composite form thereof. The silver halide may be fine grains having a grain size of about 0.2 μm or less or large grains having a projected area diameter of about 10 μm, and may be a polydisperse emulsion or a monodisperse emulsion. Silver halide photographic emulsions that can be used in combination with the present invention include, for example, Research Disclosure (hereinafter abbreviated as RD) No. 17643 (December 1978), pp. 22-23, "I. Emulsion preparation and types) ”and N
o. 18716 (November 1979), p. 648, No. 307105 (November 1989)
Pp. 863-865, and Grafkid, "Physics and Chemistry of Photography", published by Paul Montell (P. Glafkides, Chimie et.
PhisiquePhotographiques, Paul Montel, 1967), "Photographic Emulsion Chemistry" by Duffin, published by Focal Press (G.
F. Duffin, Photographic Emulsion Chemistry, Focal P
ress, 1966), "Production and Coating of Photographic Emulsion" by Zelikman et al., Published by Focal Press (VL Zelikman, et a.
l., Making and Coating Photographic Emulsion, Foca
lPress, 1964).

US 3,574,628, US 3,655,394 and GB 1,4
Monodisperse emulsions described in 13,748 are also preferred. The crystal structure may be uniform, the inside and the outside may be composed of different halogen compositions, or may have a layered structure. Silver halides having different compositions may be joined by epitaxial joining, or may be joined to a compound other than silver halide, such as, for example, silver rhodanate or lead oxide. Also, a mixture of particles of various crystal forms may be used. The above emulsion is a surface latent image type in which a latent image is mainly formed on the surface,
Either an internal latent image type formed inside the grains or a type having a latent image on both the surface and the inside may be used, but a negative emulsion is required. Of the internal latent image type,
The emulsion may be a core / shell type internal latent image type emulsion described in 3-264740, and its preparation method is described in JP-A-59-133542. The thickness of the shell of this emulsion varies depending on the development process, but is preferably 3 to 40 nm, particularly preferably 5 to 20 nm.

As the silver halide emulsion, usually, those subjected to physical ripening, chemical ripening and spectral sensitization are used. Additives used in such a process are RD No. 17643 and RD No. 187.
16 and No. 307105, and the relevant portions are summarized in the table below. In the light-sensitive material of the present invention, two or more types of emulsions having at least one characteristic different from each other in the grain size, grain size distribution, halogen composition, grain shape, and sensitivity of the photosensitive silver halide emulsion are mixed in the same layer. Can be used. U.S. Pat.No.4,082,553.
The silver halide grains covered with the grains according to 4852,
It is preferred to apply colloidal silver to the light-sensitive silver halide emulsion layer and / or to the substantially light-insensitive hydrophilic colloid layer. The term “silver halide particles having a fogged inside or surface” refers to silver halide grains which can be uniformly (non-imagewise) developed regardless of the unexposed portions and exposed portions of the photosensitive material. Its preparation is described in US Pat. No. 4,626,498, JP-A-59-214852. The silver halide forming the internal nucleus of the core / shell type silver halide grain having the inside of the grain fogged may have a different halogen composition.
As the silver halide having the inside or surface of the grain fogged, any of silver chloride, silver chlorobromide, silver iodobromide and silver chloroiodobromide can be used. The average grain size of these fogged silver halide grains is 0.01 to 0.75 μm,
Particularly, the thickness is preferably 0.05 to 0.6 μm. The grains may be regular grains or polydispersed emulsions, but may be monodisperse (at least 95% of the weight or the number of silver halide grains).
% Having a particle diameter within ± 40% of the average particle diameter).

In the present invention, it is preferable to use non-photosensitive fine grain silver halide. Non-photosensitive fine grain silver halide is silver halide fine grains that are not exposed during imagewise exposure to obtain a dye image and are not substantially developed in the developing process, and are preferably not fogged in advance. . The fine grain silver halide has a silver bromide content of 0 to 100 mol%, and may contain silver chloride and / or silver iodide as needed. Preferably, it contains 0.5 to 10 mol% of silver iodide. Fine grain silver halide, average grain size (average value of projected area equivalent circle diameter)
Is preferably 0.01 to 0.5 μm, more preferably 0.02 to 0.2 μm. Fine grain silver halide can be prepared by the same method as that for ordinary photosensitive silver halide. The surface of the silver halide grains does not need to be optically sensitized, and no spectral sensitization is required. However, prior to adding this to the coating solution, it is preferable to add a known stabilizer such as a triazole-based, azaindene-based, benzothiazolium-based, or mercapto-based compound or a zinc compound in advance. Colloidal silver can be contained in the layer containing fine silver halide grains. Coated silver amount of the light-sensitive material of the present invention is preferably 6.0 g / m ² or less, 4.5 g / m ² or less is most preferred.

The photographic additives that can be used in the present invention are also described in RD, and the relevant portions are shown in the following table. Type of additive RD17643 RD18716 RD307105 Chemical sensitizer page 23, page 648, right column, page 866 2. Sensitivity enhancer page 648, right column 3. Spectral sensitizer, page 23-24 page 648, right column 866-868 superstrong sensitizer ~ page 649, right column 4. Brightener 24 page 647, right column page 868 5 Light absorbers, pages 25 to 26, page 649, right column, page 873 Filters, page 650, left column Dyes, ultraviolet absorbers 6. Binders, page 26, page 651, left column 873 to 874 7. Plasticizers, page 27, page 650, right Column 876 Lubricant 8. Coating aid, pages 26 to 27 Page 650 Right column 875 to 876 Surfactant 9. Static 27 page 650 650 Right column 876 to 877 Inhibitor 10. Mast agent 878 to 879

Although various dye-forming couplers can be used in the light-sensitive material of the present invention, the following couplers are particularly preferred. Yellow couplers: couplers represented by formulas (I) and (II) in EP 502,424A; couplers represented by formulas (1) and (2) in EP 513,496A (especially Y-28 on page 18); EP 568,037A Claim 1
A coupler represented by the general formula (I) in column 1, line 45 to 55 of US 5,066,576; a coupler represented by the general formula (I) in paragraph 0008 of JP-A-4-274425; Couplers described in claim 1 on page 40 of EP 498,381 A1 (especially D-35 on page 18); Couplers of the formula (Y) on page 4 of EP 447,969A1 (especially Y-1 (page 17), Y- 54 (p. 41)); US
4,476,219 couplers represented by formulas (II) to (IV) in columns 7 to 36 to 58 (particularly II-17, 19 (column 17), II-24 (column 19)). Magenta coupler; JP-A-3-39737 (L-57 (page 11, lower right), L-
68 (lower right of page 12), L-77 (lower right of page 13); EP 456,257 (A-4
-63 (p. 134), (A-4) -73, -75 (p. 139); EP486,965
M-4, -6 (page 26), M-7 (page 27); EP 571,959A M-45 (19
(M-1) of JP-A-5-204106 (page 6); M-22 of paragraph 0237 of JP-A-4-32631. Cyan coupler: CX-1,3,4,5,11,12,1 of JP-A-4-204843
4,15 (pages 14 to 16); JP-A-4-43345, C-7,10 (page 35), 3
4, 35 (page 37), (I-1), (I-17) (pages 42 to 43); JP-A-6-67385
A coupler represented by the general formula (Ia) or (Ib) according to claim 1. Polymer coupler: P-1, P-5 (p. 11) of JP-A-2-44345.

Examples of couplers in which the coloring dye has an appropriate diffusibility include US Pat. No. 4,366,237, GB 2,125,570, EP 96,873B,
Those described in DE 3,234,533 are preferred. Couplers for correcting unnecessary absorption of color-forming dyes are yellow colored cyan couplers represented by the formulas (CI), (CII), (CIII), and (CIV) described on page 5 of EP 456,257A1 (especially on page 84). YC-86), the EP
Yellow colored magenta coupler ExM-7 (202
), EX-1 (page 249), EX-7 (page 251), US 4,833,069
Magenta colored cyan coupler CC-9 (column
8), CC-13 (column 10), (2) of US 4,837,136 (column 8),
Colorless masking couplers of formula (A) in claim 1 of WO 92/11575 (especially the exemplified compounds on pages 36 to 45) are preferred. Examples of the compound (including a coupler) which releases a photographically useful compound residue by reacting with an oxidized developing agent include the following. Development inhibitor releasing compound: EP 37
Compounds represented by the formulas (I), (II), (III) and (IV) described on page 11 of 8,236A1 (especially T-101 (page 30), T-104 (page 31), T-113 ( 36
T-131 (p. 45), T-144 (p. 51), T-158 (p. 58)), EP436, 93
Compounds of formula (I) described on page 7 of 8A2 (particularly D-4
9 (page 51)), the compound of formula (1) of EP 568,037A (especially (23) (page 11)), and the compounds of formulas (I), (II), Compounds represented by (III) (especially I-
(1)); Bleaching accelerator releasing compounds: compounds represented by formulas (I) and (I ′) on page 5 of EP 310,125A2 (especially (60) and (6) on page 61)
1)) and the compound represented by formula (I) of claim 1 of JP-A-6-59411 (particularly (7) (page 7)); Ligand releasing compound: US
A compound represented by LIG-X described in claim 1 of 4,555,478 (especially a compound on line 21 to 41 of column 12); a leuco dye-releasing compound: compound 1 of column 3 to 8 of US 4,749,641
~ 6; Fluorescent dye releasing compound: Claim 4, C of US 4,774,181
Compound represented by OUP-DYE (especially compounds 1 to 11 in columns 7 to 10); Development accelerator or fogging agent releasing compound: US
4,656,123, the compounds of formulas (1), (2) and (3) in column 3 (especially (I-22) in column 25) and EP 450,637A2
ExZK-2, p. 75, lines 36-38; Compound which releases a group which becomes a dye only when it is cleaved: Formula (I) of claim 1 of US 4,857,447
(Especially Y-1 to Y-19 in columns 25 to 36)
.

As the additives other than the coupler, the following are preferable. Dispersion medium of oil-soluble organic compound: P-3,5, JP-A-62-215272
16,19,25,30,42,49,54,55,66,81,85,86,93 (140-144
Page); Latex for impregnation of oil-soluble organic compounds: US 4,199,
Latex according to No. 363; oxidized developing agent scavenger: a compound represented by the formula (I) in columns 2, 54 to 62 of US Pat. No. 4,978,606 (especially I-, (1), (2), (6), (12 ) (Column 4 ~
5), US Pat. No. 4,923,787, columns 5 to 10 of formula (particularly compound 1 (column 3); stain inhibitor: EP 298321A 4
Formulas (I) to (III) on page 30-33, especially I-47, 72, III-1, 27 (24
-48 pages); Anti-fading agent: A-6, 7, 20, 21, 23, 2 of EP 298321A
4,25,26,30,37,40,42,48,63,90,92,94,164 (69-118
P.), US 5,122,444, columns 25-38 II-1 to III-23, especially
III-10, EP 471347A I-1 to III-4 on pages 8 to 12, especially II-
2, US 5,139,931 columns 32-40 A-1 to 48, especially A-39,
42; Material that reduces the amount of color enhancer or color mixture inhibitor used: I-1 to II-15 on pages 5 to 24 of EP 411324A, especially I-4
6; formalin scavenger: SCV-1 to 28 on pages 24 to 29 of EP 477932A, especially SCV-8; hardener: JP-A 1-214845
Formula of columns 13-23 of H-1,4,6,8,14, US 4,618,573 on page 17
Compounds (H-1 to 54) represented by (VII) to (XII),
Compound represented by the formula (6) at the lower right of page 8 of 214852 (H-1 to 7
6), especially compounds described in claim 1 of H-14, US Pat. No. 3,325,287; development inhibitor precursor: P-2 of JP-A-62-168139
No. 4,37,39 (pages 6 to 7); compounds described in claim 1 of US Pat. No. 5,019,492, especially 28, 29 of column 7;
4,923,790 columns 3 to 15 I-1 to III-43, especially II-1,
9,10,18, III-25; Stabilizer, antifoggant: US 4,923,79
3 columns 6 to 16 I-1 to (14), especially I-1,60, (2), (13), U
Compounds 1-65 of columns 25-32 of S 4,952,483, especially 36:
Chemical sensitizer: triphenylphosphine selenide, compound 50 of JP-A-5-40324; dye: 15-18 of JP-A-3-156450
Page a-1 to b-20, especially a-1,12,18,27,35,36, b-5,27 to 29
Page V-1 to 23, especially V-1, EP 445627A, page 33 to 55 FI-
1 to F-II-43, especially FI-11, F-II-8, 17 to 28 of EP 457153A
Pages III-1 to 36, especially III-1,3, WO 88/04794
Microcrystal dispersion of Dye-1 to 124, Compounds 1 to 22 on pages 6 to 11 of EP 319999A, in particular Compounds D-1 to 87 (3) of Compound 1, EP 519306A represented by formulas (1) to (3) ~ 28 pages), US 4,26
8,622 compounds represented by the formula (I) (columns 3 to 1)
0), compounds (1) to (4) of US Pat.
(31) (Columns 2 to 9); UV absorber: Formula of JP-A-46-3335
Compounds (18b) to (18r), 101 to 427 (6 to
9), and the compounds (3) to (6) represented by the formula (I) in EP 520938A.
6) (Pages 10 to 44) and compound HBT-1 represented by formula (III)
~ 10 (page 14), a compound represented by formula (1) in EP 521823A
(1) to (31) (columns 2 to 9).

The present invention can be applied to various color photographic materials such as color negative films for general use or movies, color reversal films for slides or televisions, color papers, color positive films and color reversal papers. In addition, Tokuhei 2-32615, actual fairness
It is suitable for a film unit with a lens described in 3-39784. Suitable supports that can be used in the present invention are
For example, page 28 of RD. No. 17643 and 6 of RD.
No. 307105, page 879 from page 47 right column to page 648 left column. In the light-sensitive material of the present invention, the total thickness of all the hydrophilic colloid layers on the side having the emulsion layer is preferably 28 μm or less, more preferably 23 μm or less, and 18 μm or less.
m or less, more preferably 16 μm or less. Further, the film swelling speed T _1/2 is preferably 30 seconds or less, more preferably 20 seconds or less. T _1/2 is the time required for the film thickness to reach 1/2 when the saturated film thickness is 90% of the maximum swollen film thickness reached when the color developing solution is processed at 30 ° C. for 3 minutes and 15 seconds. Is defined. The film thickness means a film thickness measured under humidity control at 25 ° C. and a relative humidity of 55% (2 days), and T _1/2 is A.Gr.
een) et al., Photographic Science and Engineering (Photogr.Sci.Eng.), Vol. 19, 2,124-
It can be measured by using a serometer (swelling meter) of the type described on page 129. T _1/2 can be adjusted by adding a hardening agent to gelatin as a binder or by changing the aging conditions after coating. The swelling ratio is preferably from 150 to 400%. The swelling ratio can be calculated from the maximum swelling film thickness under the conditions described above by the following formula: (maximum swelling film thickness-film thickness) / film thickness. In the light-sensitive material of the present invention, a hydrophilic colloid layer (referred to as a back layer) having a total dry film thickness of 2 μm to 20 μm is preferably provided on the side opposite to the side having the emulsion layer. The back layer preferably contains the above-mentioned light absorber, filter dye, ultraviolet absorber, antistatic agent, hardener, binder, plasticizer, lubricant, coating aid, and surfactant. The swelling ratio of the back layer is preferably from 150 to 500%.

The light-sensitive material of the present invention is obtained by using the above-mentioned RD.
No. 18716, No. 18716, 651 left column to right column, and No. 18716
No. 307105, pages 880 to 881 can be used for development. Next, the processing solution for a color negative film used in the present invention will be described.
The compounds described in JP-A-4-21739, page 9, upper right column, line 1 to page 11, lower left column, line 4 can be used in the color developing solution used in the present invention. Particularly as a color developing agent for performing rapid processing, 2-methyl-4- [N-ethyl-
N- (2-hydroxyethyl) amino] aniline, 2-
Methyl-4- [N-ethyl-N- (3-hydroxypropyl) amino] aniline and 2-methyl-4- [N-ethyl-N- (4-hydroxybutyl) amino] aniline are preferred. These color developing agents are preferably used in the range of 0.01 to 0.08 mol per liter of the color developing solution, particularly preferably in the range of 0.015 to 0.06 mol, more preferably 0.02 to 0.05 mol. The replenisher of the color developing solution preferably contains a color developing agent having a concentration of 1.1 to 3 times, more preferably 1.3 to 2.5 times the concentration.

As a preservative for the color developing solution, hydroxylamine can be used widely. However, when higher preservation is required, substitution with an alkyl group, a hydroxyalkyl group, a sulfoalkyl group, a carboxyalkyl group, etc. A hydroxylamine derivative having a group is preferable, and specifically, N, N-di (sulfoethyl) hydroxylamine, monomethylhydroxylamine, dimethylhydroxylamine, monoethylhydroxylamine, diethylhydroxylamine, N, N-di (carboxyethyl) Hydroxylamines are preferred. Among the above, N, N-di (sulfoethyl) hydroxylamine is particularly preferred. These may be used in combination with hydroxylamine, but it is preferable to use one or more of them instead of hydroxylamine. 0.02 per liter of preservative
It is preferable to use in the range of 0.2 mol, particularly 0.03 to
It is preferably used in an amount of 0.15 mol, more preferably in the range of 0.04 to 0.1 mol. As in the case of the color developing agent, the replenisher preferably contains a preservative at a concentration of 1.1 to 3 times the concentration of the mother liquor (processing tank solution). In the color developing solution, sulfite is used as an anti-tarring agent for the oxide of the color developing agent. Sulfite is 0.01 per liter
It is preferably used in the range of ~ 0.05 mol, particularly 0.02
A range of .about.0.04 mol is preferred. In the replenisher, it is preferable to use the replenisher at a concentration 1.1 to 3 times the above. The pH of the color developing solution is preferably in the range of 9.8 to 11.0, particularly preferably 10.0 to 10.5, and the replenisher may be set to a higher value in the range of 0.1 to 1.0 from these values. preferable. In order to stably maintain such a pH, a known buffer such as carbonate, phosphate, sulfosalicylate, and borate is used.

The replenishment amount of the color developing solution is preferably 80 to 1300 ml per 1 m ² of the light-sensitive material, but is preferably smaller from the viewpoint of reducing the environmental pollution load.
80-600 ml, more preferably 80-400 ml. The bromide ion concentration in the color developer is usually
It is 0.01 to 0.06 mol per liter, but it is set to 0.015 to 0.03 mol per liter for the purpose of suppressing fog while improving sensitivity, improving discrimination, and improving graininess. Is preferred.
When setting the bromide ion concentration in such a range,
The replenisher may contain bromide ions calculated by the following formula. However, when C becomes negative, it is preferred that the replenisher does not contain bromide ions. C = A−W / V C: Bromide ion concentration in the color developing replenisher (mol / liter) A: Target bromide ion concentration in the color developing solution (mol / liter) W: Coloring of 1 m ² photosensitive material Amount (mol) of bromide ion eluted from the light-sensitive material to the color developing solution when developed. V: Replenishment amount (liter) of color-developing replenisher for 1 m ² of the light-sensitive material. When the bromide ion concentration is set, 1-phenyl-3-pyrazolidone or 1-phenyl-2-methyl-2
It is also preferable to use a development accelerator such as pyrazolidones represented by -hydroxymethyl-3-pyrazolidone and thioether compounds represented by 3,6-dithia-1,8-octanediol.

The compounds and processing conditions described in JP-A-4-125558, page 4, lower left column, line 16 to page 7, lower left column, line 6 can be applied to the processing solution having bleaching ability in the present invention. . The bleaching agent preferably has an oxidation-reduction potential of 150 mV or more, and specific examples thereof include JP-A-5-72694 and JP-A-5-7333.
The compounds described in No. 12 are preferred, and 1,3-diaminopropanetetraacetic acid, particularly, a ferric complex salt of the compound of Specific Example 1 on page 7 of JP-A-5-73312 is preferred. Further, in order to improve the biodegradability of the bleach, JP-A-4-218845, JP-A-4-268552, EP588,
289, 591,934 and JP-A-6-208213 are preferably used as a bleaching agent. The concentration of these bleaching agents per liter of bleaching solution
It is preferably from 0.05 to 0.3 mol, and particularly preferably from 0.1 to 0.15 mol for the purpose of reducing the amount of discharge into the environment. When the bleaching solution is a bleaching solution, 1
It is preferred to contain from 0.2 mol to 1 mol of bromide per liter, particularly preferably from 0.3 to 0.8 mol. The replenisher of the solution having the bleaching ability basically contains the concentration of each component calculated by the following formula. Thereby, the concentration in the mother liquor can be kept constant. CR = CT × (V1 + V2 ) / V1 + CP CR: concentration of the component in the replenisher CT: concentrations of components in the mother liquor (processing tank solution) CP: component concentration consumed during processing V1: exposure of 1 m ² amount of replenisher having bleaching ability to the material (ml) V2: amount carried from previous bath by the photographic material of 1 m ² (ml) other, preferably contains a pH buffering agent, the bleaching solution, in particular succinic acid It is preferable to include a dicarboxylic acid having a low odor such as maleic acid, malonic acid, glutaric acid, and adipic acid. Also, JP-A-53-95630, RDN
It is also preferable to use known bleaching accelerators described in O. 17129, US 3,893,858. The bleaching solution is preferably replenished with 50 to 1000 ml of a bleaching replenisher per m ² of the light-sensitive material, and particularly preferably 80 to 500 ml, more preferably 100 to 500 ml.
It is preferred to replenish ~ 300 ml. Further, it is preferable to perform aeration on the bleaching solution.

The processing solution having a fixing ability is described in
The compounds and processing conditions described on page 7, lower left column, line 10 to page 8, lower right column, line 19 of 4-125558 can be applied. Particularly, in order to improve the fixing speed and the preservability, the compounds represented by the general formulas (I) and (II) of JP-A-6-301169 are contained alone or in combination in a processing solution having a fixing ability. Is preferred. In addition to p-toluenesulfinic acid salts, it is also possible to use the sulfinic acid described in JP-A-1-2224762.
It is preferable from the viewpoint of improvement in preservation. It is preferable to use ammonium as a cation in the solution having the bleaching ability or the solution having the fixing ability from the viewpoint of improving the desilvering property, but from the viewpoint of reducing environmental pollution, it is preferable to reduce or eliminate ammonium. . In the bleaching, bleach-fixing, and fixing steps, it is particularly preferable to perform jet stirring described in JP-A-1-309590. The replenishment rate of the replenisher in the bleach-fixing or fixing step is from 100 to 1000 ml, preferably from 150 to 700 ml, particularly preferably from 200 to 600 ml, per m ² of the light-sensitive material. In the bleach-fixing or fixing step, it is preferable to install various silver recovery devices in-line or off-line to recover silver. By installing in-line, the processing can be carried out with a reduced silver concentration in the solution, so that the replenishment amount can be reduced. It is also preferable to recover silver off-line and reuse the remaining liquid as a replenisher. The bleach-fixing step and the fixing step can be composed of a plurality of processing tanks, and each tank is preferably a cascade pipe to have a multistage countercurrent system. From the balance with the size of the developing machine, a two-tank cascade configuration is generally efficient, and the ratio of the processing time in the former tank and the latter tank is preferably in the range of 0.5: 1 to 1: 0.5. In particular, the range of 0.8: 1 to 1: 0.8 is preferable. The bleach-fixing solution and the fixing solution preferably contain a free chelating agent that is not a metal complex from the viewpoint of improving the preservability. Preferably, a chelating agent is used.

The washing and stabilizing steps are described in the above-mentioned JP-A-4-125558, page 12, lower right column, line 6 to page 13, lower right column, line 16.
The contents described in the line can be preferably applied. In particular, EP 504,60 replaces formaldehyde in stabilizers.
9. Use of the azolylmethylamines described in 519,190 and N-methylolazoles described in JP-A-4-362943, or the use of an interface free of image stabilizers such as formaldehyde by dimerizing a magenta coupler. It is preferable to use a liquid of the activator from the viewpoint of preserving the working environment. In order to reduce the adhesion of dust to the magnetic recording layer applied to the photosensitive material, a stabilizing solution described in JP-A-6-289559 can be preferably used. The amount of washing and replenishment of the stabilizing solution is preferably 80 to 1000 ml per 1 m ² of the light-sensitive material.
The range of from 00 to 500 ml, and more preferably from 150 to 300 ml, is a preferable range in terms of both securing a washing or stabilizing function and reducing waste liquid for environmental protection. In the treatment carried out with such a replenishing amount, a known method such as thiabendazole, 1,2-benzisothiazolin-3-one and 5-chloro-2-methylisothiazolin-3-one is used to prevent the growth of bacteria and fungi. It is preferable to use water deionized with an antifungal agent, an antibiotic such as gentamicin, or an ion exchange resin. It is more effective to use a combination of deionized water and a bactericide or antibiotic. Also, the liquid in the washing or stabilizing liquid tank is disclosed in Japanese Patent Application Laid-Open No. 3-46652.
, 3-53246, 3-355542, 3-121448, 3-26030
It is also preferable to reduce the replenishment rate by performing the reverse osmosis membrane treatment described in (1), and in this case, the reverse osmosis membrane is preferably a low-pressure reverse osmosis membrane.

In the process of the present invention, it is particularly preferable to carry out the correction of evaporation of the processing solution disclosed in Hatsumei Kyokai Disclosure No. 94-4992. In particular, a method of performing correction using temperature and humidity information of a developing machine installation environment based on (Equation 1) on page 2 is preferable. The water used for evaporation correction is preferably collected from a replenishment tank for washing,
In that case, it is preferable to use deionized water as the washing replenishing water.

As the treating agent used in the present invention, those described in page 3, right column, line 15 to page 4, left column, line 32 of the above-mentioned published technical report are preferable. In addition, as a developing machine used for this,
The film processor described on page 22, right column, lines 22 to 28 is preferred. Specific examples of preferred processing agents, automatic developing machines, and evaporation correction methods for carrying out the present invention are described in the above-mentioned published technical report from page 5, right column, line 11 to page 7, right column, last line. .

The supply form of the treating agent used in the present invention is as follows.
It may be in any form, such as a liquid preparation in the form of a liquid used or a concentrated form, or granules, powders, tablets, pastes, and emulsions. As an example of such a treating agent, JP-A-63-1
7453 discloses a liquid agent contained in a container having low oxygen permeability,
19655, 4-230748, vacuum-packed powders or granules, 4-221951, granules containing a water-soluble polymer,
JP-A-51-61837 and JP-A-6-102628 describe tablets and JP-A-57-5
Discloses a paste-like treating agent, which can be preferably used, but from the viewpoint of simplicity at the time of use,
It is preferable to use a liquid that has been prepared in advance in a concentration for use. For the container for storing these treating agents, polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate, nylon or the like is used alone or as a composite material. These are selected according to the required level of oxygen permeability. For an easily oxidizable liquid such as a color developing solution, a material having low oxygen permeability is preferable, and specifically, a polyethylene terephthalate or a composite material of polyethylene and nylon is preferable. These materials are used in containers having a thickness of 500 to 1500 μm, and preferably have an oxygen permeability of 20 ml / m ² · 24 hrs · atm or less.

Next, the processing solution for a color reversal film used in the present invention will be described. For the processing for the color reversal film, see page 6, line 5 to page 10, line 5 and page 15, line 8 to page 24, 2 of the publicly known technique No. 6 (April 1, 1991) issued by Aztec Co., Ltd. Each row is described in detail, and any of the contents can be preferably applied. In processing color reversal films, the image stabilizer is contained in a conditioning or final bath. Examples of such image stabilizers include, in addition to formalin, sodium formaldehyde sodium sulfite and N-methylolazoles.
From the viewpoint of working environment, sodium formaldehyde sodium bisulfite or N-methylolazole is preferable, and N-methyloltriazole is particularly preferable as N-methylolazole. Further, the contents relating to the color developing solution, the bleaching solution, the fixing solution, the washing water and the like described in the processing of the color negative film can be preferably applied to the processing of the color reversal film. As a preferred color reversal film treating agent containing the above contents, E-manufactured by Eastman Kodak Company
6 processing agents and CR-56 processing agents of Fuji Photo Film Co., Ltd.

In the present invention, a magnetic recording layer may be used.
The magnetic recording layer is obtained by coating an aqueous or organic solvent-based coating solution in which magnetic particles are dispersed in a binder on a support. Magnetic particles include ferromagnetic iron oxide such as γFe ₂ O _3, Co deposited γFe ₂ O _3, Co coated magnetite ,, Co-containing magnetite, ferromagnetic chromium dioxide, ferromagnetic metal, ferromagnetic alloy, hexagonal system Ba ferrite, Sr ferrite, Pb ferrite, Ca ferrite etc. can be used. Co deposited γFe ₂ O
Co-coated ferromagnetic iron oxides such as ₃ are preferred. The shape may be any of needle shape, rice grain shape, spherical shape, cubic shape, plate shape and the like. Preferably at least 20 m ² / g in SBET is the specific surface area, 30 m ² /
g or more is particularly preferred. The saturation magnetization (σs) of a ferromagnetic material is
It is preferably from 3.0 × 10 ⁴ to 3.0 × 10 ⁵ A / m, and particularly preferably from 4.0 × 10 ^{4 to} 2.5 × 10 ⁵ A / m. The ferromagnetic particles may be subjected to a surface treatment with silica and / or alumina or an organic material. Further, magnetic particles are disclosed in
The surface may be treated with a silane coupling agent or a titanium coupling agent as described in 161032. Further, magnetic particles having a surface coated with an inorganic or organic substance described in JP-A-4-259911 and JP-A-5-81652 can also be used.

The binder used for the magnetic particles may be a thermoplastic resin, a thermosetting resin, a radiation-curable resin, a reactive resin, an acid, an alkali or a biodegradable polymer, or a natural material described in JP-A-4-219569. Combinations (cellulose derivatives, sugar derivatives, etc.) and mixtures thereof can be used. The above resin has a Tg of -40 ° C to 300 ° C and a weight average molecular weight of 2,000 to 1,000,000. Examples thereof include vinyl copolymers, cellulose diacetate, cellulose triacetate, cellulose derivatives such as cellulose acetate propionate, cellulose acetate butyrate, and cellulose tripropionate, acrylic resins and polyvinyl acetal resins, and gelatin is also preferable. Particularly, cellulose di (tri) acetate is preferable. The binder can be cured by adding an epoxy-based, aziridine-based, or isocyanate-based crosslinking agent. Examples of the isocyanate-based crosslinking agent include isocyanates such as tolylene diisocyanate, 4,4'-diphenylmethane diisocyanate, hexamethylene diisocyanate, and xylylene diisocyanate, and reaction products of these isocyanates with polyalcohol (for example, 3mol of isocyanate and 1m of trimethylolpropane
ol reaction product), and polyisocyanates formed by condensation of these isocyanates.
For example, it is described in JP-A-6-59357.

As a method for dispersing the above-mentioned magnetic substance in the binder, a kneader, a pin type mill, an annular type mill and the like are preferably used, as in the method described in JP-A-6-35092. Dispersants described in JP-A-5-088283 and other known dispersants can be used. The thickness of the magnetic recording layer is 0.1 μm to 10 μm, preferably 0.2 μm to 5 μm.
m, more preferably 0.3 μm to 3 μm. The weight ratio between the magnetic particles and the binder is preferably 0.5: 100 to 60: 100.
And more preferably from 1: 100 to 30: 100. The coating amount of the magnetic particles 0.005~ 3g / m ^2, preferably from 0.01 to 2
g / m ² , more preferably 0.02 to 0.5 g / m ² . The transmission yellow density of the magnetic recording layer is preferably 0.01 to 0.50,
03 to 0.20 is more preferable, and 0.04 to 0.15 is particularly preferable.
The magnetic recording layer can be provided on the entire back surface of the photographic support by coating or printing, or in a stripe shape. As a method of applying the magnetic recording layer, an air doctor, a blade, an air knife, a squeeze, an impregnation, a reverse roll,
Transfer rolls, gravure, kisses, casts, sprays, dips, bars, extrusions and the like can be used, and the coating solutions described in JP-A-5-341436 are preferred.

In the magnetic recording layer, lubricity improvement, curl control,
It may have functions such as antistatic, antiadhesion, and head polishing, or may provide another functional layer to provide these functions. At least one of the particles has a Mohs hardness of 5 or more. Abrasives of the above non-spherical inorganic particles are preferred. As the composition of the non-spherical inorganic particles, oxides such as aluminum oxide, chromium oxide, silicon dioxide, titanium dioxide and silicon carbide, carbides such as silicon carbide and titanium carbide, and fine powders such as diamond are preferable. These abrasives may have their surfaces treated with a silane coupling agent or a titanium coupling agent. These particles may be added to the magnetic recording layer, or may be overcoated (for example, a protective layer, a lubricant layer, etc.) on the magnetic recording layer. As the binder used at this time, the above-mentioned binders can be used, and the same binder as the binder for the magnetic recording layer is preferable. For photosensitive materials having a magnetic recording layer, see US Pat.
5,229,259, 5,215,874 and EP 466,130.

In the present invention, a polyester support may be used. The details of the polyester support, including the light-sensitive material, treatment, cartridge and examples described later, are described in Published Technical Report, Official Technique No. 94-6023 (Invention Association; 1994.3.15.). Polyester is formed with diol and aromatic dicarboxylic acid as essential components, and 2,6-, 1,5-, 1,4-, and 2,7-naphthalenedicarboxylic acid as aromatic dicarboxylic acid, terephthalic acid, isophthalic acid, Examples of phthalic acid and diol include diethylene glycol, triethylene glycol, cyclohexanedimethanol, bisphenol A, and bisphenol. Examples of the polymer include homopolymers such as polyethylene terephthalate, polyethylene naphthalate, and polycyclohexanedimethanol terephthalate. Particularly preferred are polyesters containing 50 to 100 mol% of 2,6-naphthalenedicarboxylic acid. Among them, polyethylene-2,6-naphthalate is particularly preferred. Average molecular weight ranges from about 5,000 to 200,000
It is. Tg of the polyester of the present invention is 50 ° C. or more,
Further, the temperature is preferably 90 ° C. or higher.

Next, the polyester support is heat-treated at a heat treatment temperature of 40 ° C. or more and less than Tg, more preferably Tg−20 ° C. or more and less than Tg, in order to make it difficult to form a curl. The heat treatment may be performed at a constant temperature within this temperature range, or may be performed while cooling. The heat treatment time is 0.1 to 1500 hours, more preferably 0.5 to 200 hours. The heat treatment of the support may be performed in the form of a roll, or may be performed while transporting the support in the form of a web.
Surface irregularities may be imparted (for example, conductive inorganic fine particles such as SnO ₂ or Sb ₂ O ₅ may be applied) to improve the surface state. It is also desirable to take measures such as applying knurls to the ends and raising the ends only slightly to prevent cut-out of the core. These heat treatments are performed after forming the support, after surface treatment,
It may be carried out at any stage after application of the back layer (antistatic agent, slip agent, etc.) and after application of the undercoat. Preferably after application of the antistatic agent. An ultraviolet absorber may be incorporated into this polyester. Also, to prevent light piping,
The purpose can be achieved by kneading dyes or pigments commercially available for polyesters such as Diaresin manufactured by Mitsubishi Kasei and Kayaset manufactured by Nippon Kayaku.

Next, in the present invention, it is preferable to perform a surface treatment in order to bond the support and the light-sensitive material constituting layer. Chemical treatment, mechanical treatment, corona discharge treatment, flame treatment, ultraviolet treatment, high frequency treatment, glow discharge treatment, active plasma treatment,
Surface activation treatments such as laser treatment, mixed acid treatment, ozone oxidation treatment and the like can be mentioned. Among the surface treatments, ultraviolet irradiation treatment, flame treatment, corona treatment, and glow treatment are preferable. Next, the undercoating method will be described. It may be a single layer or two or more layers. Undercoat layer binders include vinyl chloride, vinylidene chloride, butadiene, methacrylic acid,
Examples include a copolymer using a monomer selected from acrylic acid, itaconic acid, maleic anhydride and the like as a starting material, polyethylene imine, epoxy resin, grafted gelatin, nitrocellulose, and gelatin. Compounds that swell the support include resorcinol and p-chlorophenol. In the undercoat layer, gelatin hardeners such as chromium salts (chrome alum, etc.), aldehydes (formaldehyde, glutaraldehyde, etc.), isocyanates, and active halogen compounds (2,4-dichloro-6-
Hydroxy-S-triazine, etc.), epichlorohydrin resin, active vinyl sulfone compound and the like. SiO ₂ , TiO ₂ , inorganic fine particles or polymethyl methacrylate copolymer fine particles (0.01 to 10 μm) may be contained as a matting agent.

In the present invention, antistatic agents are preferred.
It is used well. Carbohydrate is one of those antistatic agents.
Polymers containing acid, carboxylate and sulfonate,
Thionic polymers, ionic surfactant compounds
Can be. The most preferred antistatic agent is Z
nO, TiO_Two, SnO_Two, Al_TwoO_Three, In_TwoO_Three, SiO_Two, MgO, BaO,
MoO_Three, V_TwoO_FiveAt least one volume resistivity selected from
Is 10 ⁷Ωcm or less, more preferably 10^FiveΩcm or less
Particle size 0.001 ~ 1.0μm crystalline metal oxide
Of these composite oxides (Sb, P, B, In, S, Si, C, etc.)
Particles, sol-like metal oxides or composites thereof
These are oxide fine particles. The content in the photosensitive material should be between 5 and
500mg / m^TwoIs particularly preferably 10 to 350 mg / m^TwoIn
You. Conductive crystalline oxide or its composite oxide and vine
The ratio of the amount of the brewer is preferably from 1/300 to 100/1, more preferably
Or 1/100 to 100/5.

The light-sensitive material of the present invention preferably has a slip property. The slip agent-containing layer is preferably used on both the photosensitive layer surface and the back surface. A preferable slip property is a dynamic friction coefficient of 0.
It is 25 or less and 0.01 or more. The measurement at this time represents the value when transported at 60 cm / min against a stainless steel ball with a diameter of 5 mm (25
° C, 60% RH). In this evaluation, even if the surface of the photosensitive layer is replaced as the partner material, the values are almost the same level. Examples of the slip agent usable in the present invention include polyorganosiloxanes, higher fatty acid amides, higher fatty acid metal salts, esters of higher fatty acids and higher alcohols, and polyorganosiloxanes such as polydimethyl siloxane, polydiethyl siloxane, and polydiethyl siloxane. Styrylmethylsiloxane, polymethylphenylsiloxane, or the like can be used. The additional layer is preferably the outermost layer of the emulsion layer or the back layer. Particularly, polydimethylsiloxane or an ester having a long-chain alkyl group is preferable.

The light-sensitive material of the present invention preferably contains a matting agent. The matting agent may be on either the emulsion side or the back side, but is particularly preferably added to the outermost layer on the emulsion side.
The matting agent may be soluble in the processing solution or insoluble in the processing solution, and preferably both are used in combination. For example, polymethyl methacrylate, poly (methyl methacrylate / methacrylic acid = 9/1 or 5/5 (molar ratio)), polystyrene particles and the like are preferable. The particle size is preferably 0.8 to 10 μm, and the particle size distribution is preferably narrow, and the average particle size is 0.9 to 1.
It is preferable that 90% or more of the total number of particles be contained in one time. It is also preferable to simultaneously add fine particles having a size of 0.8 μm or less in order to enhance the matting property. For example, polymethyl methacrylate (0.2 μm), poly (methyl methacrylate /
Methacrylic acid = 9/1 (molar ratio, 0.3 µm)), polystyrene particles (0.25 µm), colloidal silica (0.03 µm).

Next, the film cartridge used in the present invention will be described. The main material of the patrone used in the present invention may be metal or synthetic plastic. Preferred plastic materials are polystyrene, polyethylene, polypropylene, polyphenyl ether and the like. Further, the patrone of the present invention may contain various antistatic agents, and carbon black, metal oxide particles, nonionic, anionic, cationic and betaine surfactants or polymers can be preferably used. These antistatic patrones are described in JP-A 1-312537 and JP-A 1-312538. Particularly, the resistance at 25 ° C. and 25% RH is preferably 10 ¹² Ω or less. Usually, a plastic patrone is manufactured using a plastic into which carbon black, a pigment, or the like is kneaded in order to impart light shielding properties. The size of the patrone may be 135 size at present, and for miniaturization of the camera,
It is also effective to reduce the diameter of the current 135 size 25 mm cartridge to 22 mm or less. The volume of the patrone case is preferably 30 cm ³ or less, more preferably 25 cm ³ or less. The weight of the plastic used for the patrone and the patrone case is preferably 5 g to 15 g.

Further, in the present invention, a patrone for rotating the spool and feeding the film may be used. Further, a structure may be employed in which the leading end of the film is housed in the patrone main body, and the leading end of the film is sent out from the port portion of the patrone by rotating the spool shaft in the film sending direction. These are disclosed in US Pat. Nos. 4,834,306 and 5,226,613. The photographic film used in the present invention may be a so-called raw film before development or a photographic film that has been subjected to development processing. Further, the raw film and the developed photographic film may be stored in the same new patrone, or may be different patrones.

The color photographic light-sensitive material of the present invention has an advanced photo system (hereinafter referred to as an AP system).
NEXIA A, NEXI manufactured by Fuji Photo Film Co., Ltd. (hereinafter referred to as Fuji Film).
Films processed into the AP system format such as AF and NEXIA H (in order, ISO 200/100/400) and stored in a special cartridge can be mentioned. These AP system cartridge films are used by loading them into an AP system camera such as the EPION series (EPION 300Z, etc.) manufactured by Fujifilm. Further, the color photographic light-sensitive material of the present invention is also suitable for a film with a lens such as a super color slim made by Fujifilm. The film photographed by these is printed through the following steps in the minilab system. (1) Reception (exposed cartridge film received from customer) (2) Detaching process (transfer film from cartridge to intermediate cartridge for developing process) (3) Film development (4) Retouching process (developed negative (Return the film to the original cartridge.) (5) Print (continuous automatic printing of C / H / P 3 type prints and index prints on color paper (preferably SUPER FA8 made by FUJIFILM)) (6) Verification and shipment (The cartridge and index print are collated by ID number and shipped together with the print.) These systems include Fujifilm Minilab Champion Super FA-298 / FA-278 / FA-258 / FA-238 and Fujifilm Digital Lab System Frontier. preferable. Minilab Champion's film processors include FP922AL / FP562B / FP562B, AL / FP362B / FP362B, AL, and the recommended chemical is Fujicolor Justit CN-1.
6L and CN-16Q. As a printer processor,
PP3008AR / PP3008A / PP1828AR / PP1828A / PP1258AR / PP1258A
/ PP728AR / PP728A, and the recommended treatment chemicals are Fujicolor Justit CP-47L and CP-40FAII. Frontier System, Scanner & Image Processor
SP-1000 and laser printer & paper processor
LP-1000P or laser printer LP-1000W is used. The detacher used in the detaching step and the rear toucher used in the rear attaching step are preferably DT200 / DT100 and AT200 / AT100 of Fujifilm, respectively.

The AP system can also be enjoyed by a photo joy system centered on Fujifilm's Aladdin 1000 digital image workstation. For example, Aladdin 1000 can be directly loaded with a developed AP system cartridge film, or the image information of negative film, positive film, and print can be transferred to a 35mm film scanner FE.
The digital image data obtained by inputting using the -550 or PE-550 flat head scanner can be easily processed and edited. The data are stored in a digital color printer NC-550AL using a light fixing type thermal color printing system and a pictograph 3000 using a laser exposure thermal development transfer system.
Or as prints by existing laboratory equipment through a film recorder. The Aladdin 1000 can also transfer digital information directly to a floppy disk or Zip disk, or via a CD writer.
You can also output to CD-R. On the other hand, at home, you can enjoy your photos on TV just by loading the developed AP system cartridge film into the Fujifilm Photo Player AP-1, and use the Fujifilm Photo Scanner AS
If it is loaded in the -1, the image information can be taken into the PC continuously at high speed. To input a film, print, or three-dimensional object to a personal computer, a Fuji Vision PhotoVision FV-10 / FV-5 can be used. Furthermore, image information recorded on a floppy disk, Zip disk, CD-R, or hard disk can be variously processed and enjoyed on a personal computer using Fujifilm's application software Photo Factory. To output high-quality prints from a personal computer, use the Fuji-Film Digital Color Printer NC-2, which uses a light-fixing thermal color print system.
/ NC-2D is preferred. To store the developed AP system cartridge film, a Fujicolor Pocket Album AP-5 POP L, AP-1 POP L, AP-1 POP KG or cartridge file 16 is preferred.

[0086]

EXAMPLES The present invention will be described in more detail with reference to specific examples, but the present invention is not limited to the examples unless it exceeds the gist of the present invention. (Example 1) 1) Support The support used in this example was prepared by the following method. Polyethylene-2,6-naphthalate polymer 100
After drying 2 parts by weight of Tinuvin P.326 (manufactured by Ciba-Geigy) as an ultraviolet absorber, 300 ° C.
After being melted at, it was extruded from a T-die, stretched 3.3 times in length at 140 ° C, then stretched 3.3 times in width at 130 ° C, and heat-fixed at 250 ° C for 6 seconds to obtain a 90 μm thick PEN.
I got a film. The PEN film has a blue dye, a magenta dye, and a yellow dye (public technical report: I-1, I-4, I-6, I-24, I-26, I-26 described in the official gazette number 94-6023). 27, II-5)
Was added in an appropriate amount. Further, the support was wound around a stainless steel core having a diameter of 20 cm to give a heat history of 110 ° C. and 48 hours, thereby providing a support that was not easily curled.

2) Coating of Undercoat Layer The support was subjected to a corona discharge treatment, a UV irradiation treatment, and a glow discharge treatment on both surfaces, and then gelatin 0.1 g / m ² , sodium α-sulfodine was applied to each surface. -2-ethylhexyl succinate 0.01 g / m ² , salicylic acid 0.04 g / m ² , p
-Chlorophenol 0.2 g / m ² , (CH ₂ = CHSO ₂ CH ₂ CH ₂ NHCO) ₂
CH ^₂ 0.012g / m _2, polyamide - epichlorohydrin polycondensate was coated an undercoat solution ^{0.02g / m 2 (10cc / m} 2, a bar coater used), provided with a subbing layer hotter side at the time of stretching. Drying is 1
The test was carried out at 15 ° C for 6 minutes (all rollers and transport devices in the drying zone were at 115 ° C). 3) Coating of Back Layer An antistatic layer, a magnetic recording layer and a sliding layer having the following composition were coated as a back layer on one surface of the support after the undercoat.

3-1) Coating of antistatic layer Tin oxide-antimony oxide composite having an average particle diameter of 0.005 μm has a specific resistance of 5 Ω · cm, a dispersion of fine particle powder (secondary aggregated particle diameter of about 0.08 μm). 0.2 g / m ^2, gelatin 0.05g / m ^2, (C
H ₂ = CHSO ₂ CH ₂ CH ₂ NHCO) ₂ CH ₂ 0.02 g / m ² , poly (degree of polymerization 1
0) Oxyethylene-p-nonylphenol 0.005 g / m ²
And resorcinol. 3-2) Coating of magnetic recording layer 3-poly (degree of polymerization 15) Cobalt-γ-iron oxide coated with oxyethylene-propyloxytrimethoxysilane (15% by weight) (specific surface area 43 m ² / g, Long axis 0.14μm, single axis 0.03μm, saturation magnetization 89emu / g, Fe ^{+ 2} / Fe ⁺³ = 6/94, surface treated with silicon oxide aluminum oxide with 2% by weight of iron oxide) 0.06g / m ² diacetyl cellulose 1.2 g / m ² (dispersion of the iron oxide was carried out using an open kneader and a sand _{mill), C 2 H 5 C (} CH 2 OCONH-C 6 H 3 (CH 3) NCO) as a curing agent ₃
0.3 g / m ² was applied with a bar coater using acetone, methyl ethyl ketone, cyclohexanone as a solvent,
A magnetic recording layer having a thickness of 1.2 μm was obtained. Abrasive aluminum oxide (0.15 μm) coated with silica particles (0.3 μm) and 3-poly (degree of polymerization 15) oxyethylene-propyloxytrimethoxysilane (15% by weight) as matting agents, respectively
It was added to 10 mg / m ² . Drying was carried out at 115 ° C for 6 minutes.
° C). X- write saturation magnetization moment of the magnetic recording layer of the D color density increment of about 0.1 of ^B, also the magnetic recording layer is 4.2 emu / g, coercive force 7.3 × 10 ⁴ A / m, the squareness ratio in (blue filter) Was 65%.

3-3) Preparation of Sliding Layer Diacetylcellulose (25 mg / m ² ), C ₆ H ₁₃ CH (OH) C ₁₀ H ₂₀ C
OOC ₄₀ H ₈₁ (compound a, 6 mg / m ² ) / C ₅₀ H ₁₀₁ O (CH ₂ CH ₂ O) ₁₆ H
(Compound b, 9 mg / m ² ) mixture was applied. This mixture was melted at 105 ° C in xylene / propylene glycol monomethyl ether (1/1), poured and dispersed in propylene glycol monomethyl ether (10 times the volume) at room temperature, and then dispersed in acetone. (Average particle size: 0.01 μm). As a matting agent, silica particles (0.3 μm) and abrasive 3-poly (degree of polymerization 15) oxyethylene-propyloxytrimethoxysilane (aluminum oxide (0.15 μm) coated with 15% by weight) are each 15 mg / m ² . Drying was performed at 115 ° C for 6 minutes (all rollers and conveyors in the drying zone were 115 ° C.) The sliding layer had a dynamic friction coefficient of 0.06 (5 mmφ stainless steel hard spheres, load of 100 g, speed)
6 cm / min), the coefficient of static friction was 0.07 (clip method), and the coefficient of kinetic friction between the emulsion surface and the sliding layer described later was 0.12, which were excellent characteristics.

4) Coating of photosensitive layer Next, on the opposite side of the back layer obtained above, each layer having the following composition was applied in a multi-layered manner to prepare a color negative film.
This is designated as Sample 101.

(Composition of photosensitive layer) The main materials used in each layer are classified as follows: ExC: cyan coupler UV: ultraviolet absorber ExM: magenta coupler HBS: high boiling point organic solvent ExY: yellow coupler H: Gelatin hardener ExS: Sensitizing dye The number corresponding to each component indicates the coating amount in g / m ² , and the silver halide indicates the coating amount in terms of silver. However, as for the sensitizing dye, the coating amount is shown in mol unit with respect to 1 mol of silver halide in the same layer.

(Sample 1) First layer (first antihalation layer) Black colloidal silver silver 0.08 gelatin 0.70 Second layer (second antihalation layer) Black colloidal silver silver 0.09 gelatin 1.00 ExM-1 0.12 ExF-1 2.0 × 10 ^-3 Solid disperse dye ExF-2 0.030 Solid disperse dye ExF-3 0.040 HBS-1 0.15 HBS-2 0.02

Third layer (intermediate layer) ExC-2 0.05 Polyethyl acrylate latex 0.20 Gelatin 0.70

Fourth layer (low-sensitivity red-sensitive emulsion layer) Silver iodobromide emulsion A silver 0.20 silver iodobromide emulsion B silver 0.23 silver iodobromide emulsion C silver 0.10 ExS-1 3.8 × 10 ^-4 ExS-2 1.6 × 10 ^-5 ExS-3 5.2 × 10 ^-4 ExC-1 0.17 ExC-2 0.02 ExC-3 0.030 ExC-4 0.10 ExC-5 0.020 ExC-6 0.010 Cpd-2 0.025 HBS-1 0.10 Gelatin 1.10

Fifth layer (medium-speed red-sensitive emulsion layer) Silver iodobromide emulsion C silver 0.15 silver iodobromide emulsion D silver 0.46 ExS-1 3.9 × 10 ^-4 ExS-2 2.1 × 10 ^-5 ExS-3 5.8 × 10 ^-4 ExC-1 0.14 ExC-2 0.02 ExC-3 0.03 ExC-4 0.090 ExC-5 0.02 ExC-6 0.01 Cpd-4 0.030 Cpd-2 0.05 HBS-1 0.10 Gelatin 0.75

Sixth layer (high-sensitivity red-sensitive emulsion layer) Silver iodobromide emulsion E 1.30 ExS-1 2.4 × 10 ^-4 ExS-2 1.1 × 10 ^-5 ExS-3 3.7 × 10 ^-4 ExC-1 0.12 ExC-3 0.11 ExC-6 0.020 ExC-7 0.010 Cpd-2 0.050 Cpd-4 0.020 Cpd-5 0.010 HBS-1 0.22 HBS-2 0.050 Gelatin 1.40

Seventh layer (intermediate layer) Cpd-1 0.060 Cpd-5 0.010 Solid disperse dye ExF-4 0.030 HBS-1 0.040 Polyethyl acrylate latex 0.15 Gelatin 1.10

Eighth layer (low-sensitivity green-sensitive emulsion layer) Silver iodobromide emulsion F silver 0.22 silver iodobromide emulsion G silver 0.35 ExS-7 1.3 × 10 ^-4 ExS-8 6.2 × 10 ^-4 ExS-4 2.9 × 10 ^-5 ExS-5 7.0 × 10 ^-5 ExS-6 2.6 × 10 ^-4 ExM-3 0.410 ExM-4 0.086 ExY-1 0.070 ExY-5 0.0070 HBS-1 0.30 HBS-3 0.015 Cpd-4 0.010 Gelatin 0.95

Ninth layer (medium-sensitivity green-sensitive emulsion layer) Silver iodobromide emulsion G silver 0.48 silver iodobromide emulsion H silver 0.48 ExS-4 4.8 × 10 ^-5 ExS-7 2.1 × 10 ^-4 ExS-8 9.3 × 10 ^-4 ExC-8 0.0020 ExM-3 0.115 ExM-4 0.035 ExY-1 0.010 ExY-4 0.010 ExY-5 0.0050 Cpd-4 0.011 HBS-1 0.13 HBS-3 4.4 × 10 ^-3 Gelatin 0.80

Tenth layer (high-sensitivity green-sensitive emulsion layer) Silver iodobromide emulsion I silver 1.30 ExS-4 4.5 × 10 ^-5 ExS-7 1.3 × 10 ^-4 ExS-8 5.2 × 10 ^-4 ExC-1 0.021 ExM-1 0.010 ExM-2 0.030 ExM-5 0.0070 ExM-6 0.0050 Cpd-3 0.017 Cpd-4 0.040 Cpd-5 0.010 HBS-1 0.25 Polyethyl acrylate latex 0.15 Gelatin 1.33

Eleventh layer (yellow filter layer) Yellow colloidal silver silver 0.015 Cpd-1 0.16 Cpd-5 0.010 solid disperse dye ExF-5 0.060 solid disperse dye ExF-6 0.060 oil-soluble dye ExF-7 0.010 HBS-1 0.60 gelatin 0.60

12th layer (low-sensitivity blue-sensitive emulsion layer) Silver iodobromide emulsion J silver 0.09 silver iodobromide emulsion K silver 0.10 silver iodobromide emulsion L silver 0.25 ExS-9 8.4 × 10 ^-4 ExC-1 0.03 ExC-8 7.0 × 10 ^-3 ExY-1 0.050 ExY-2 0.75 ExY-3 0.40 ExY-4 0.040 Cpd-2 0.10 Cpd-4 0.01 Cpd-3 4.0 × 10 ^-3 HBS-1 0.28 Gelatin 2.10

13th layer (high-sensitivity blue-sensitive emulsion layer) Silver iodobromide emulsion M silver 0.58 ExS-9 3.5 × 10 ^-4 ExY-2 0.070 ExY-3 0.070 ExY-4 0.0050 Cpd-2 0.10 Cpd-3 1.0 × 10 ^-3 Cpd-4 0.02 HBS-1 0.075 Gelatin 0.55

Fourteenth layer (first protective layer) Silver iodobromide emulsion N silver 0.10 UV-1 0.13 UV-2 0.10 UV-3 0.16 UV-4 0.025 Cpd-5 0.010 ExF-8 0.001 ExF-9 0.002 HBS- 1 5.0 × 10 ^-2 HBS-4 5.0 × 10 ^-2 gelatin 1.8

Fifteenth layer (second protective layer) H-1 0.40 B-1 (1.7 μm in diameter) 0.04 B-2 (1.7 μm in diameter) 0.09 B-3 0.13 ES-1 0.20 Gelatin 0.70

Further, W-1 to W-3, B-4 to B- may be added to each layer to improve the storability, processability, pressure resistance, fungicide / bacteriostatic property, antistatic property and coatability. 6, F
-1 to F-18, and iron salts, lead salts, gold salts, platinum salts,
Contains palladium, iridium and rhodium salts.

[0107]

[Table 7]

In Table 7, (1) Emulsions J to M were prepared according to the examples in JP-A-2-91938.
Reduction sensitization was performed using thiourea dioxide and thiosulfonic acid during the preparation of the particles. (2) Emulsions CE, GI, and M were subjected to gold sensitization and sulfur sensitization in the presence of the spectral sensitizing dye described in each photosensitive layer and sodium thiocyanate according to the examples of JP-A-3-237450. And selenium sensitization. (3) For preparing tabular grains, low molecular weight gelatin is used according to the examples of JP-A-1-158426. (4) When a high-pressure electron microscope is used for the tabular grains, dislocation lines as described in JP-A-3-237450 are observed. (5) Emulsions A to E, G, H and J to M are Rh, Ir, F
e in an optimal amount. The tabularity is defined as Dc / t ² , where Dc is the average equivalent circle diameter in the projected area of the tabular grains and t is the average thickness of the tabular grains.

Preparation of Dispersion of Organic Solid Disperse Dye ExF-2 shown below was dispersed by the following method. That is, water 21.7
Milliliter and 3% of a 5% aqueous solution of sodium p-octylphenoxyethoxyethoxyethoxyethanesulfonate and 0.5 g of a 5% aqueous solution of p-octylphenoxypolyoxyethylene ether (degree of polymerization: 10) were placed in a 700 milliliter pot mill, followed by dyeing. 5.0 g of ExF-2 and 500 ml of zirconium oxide beads (diameter 1 mm) were added, and the contents were dispersed for 2 hours. For this dispersion, a BO type vibration ball mill manufactured by Chuo Koki was used. After dispersion, the contents were taken out, added to 8 g of a 12.5% gelatin aqueous solution, and the beads were removed by filtration to obtain a gelatin dispersion of the dye. The average particle size of the fine dye particles was 0.44 μm.

Similarly, solid dispersions of ExF-3, ExF-4 and ExF-6 were obtained. The average particle diameters of the fine dye particles were 0.24 μm, 0.45 μm, and 0.52 μm, respectively.
ExF-5 is a microprecipitation described in Example 1 of EP-A-549,489A.
Dispersed by a dispersion method. The average particle size was 0.06 μm.

[0111]

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[0112]

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[0113]

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[0114]

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[0115]

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[0116]

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[0117]

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[0118]

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[0119]

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[0120]

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[0121]

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[0122]

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[0123]

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[0124]

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[0125]

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[0126]

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[0127]

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Sample 1 was cut into a width of 24 mm and a size of 160 cm.
Two square perforations are provided at 5.8mm intervals.
These two sets were prepared at intervals of 32 mm and stored in a plastic film cartridge described in FIGS. 1 to 7 of U.S. Pat. No. 5,296,887.
The following evaluation was performed on the sample manufactured as described above.

After processing the unexposed sample by the following processing method A, the magenta color image density was measured.
Washing was performed with running water of 1 liter / min for 1 hour. The density difference between the magenta color images before and after washing was determined, and the result was shown as a residual color density. The fixing solutions 102 to 110 were prepared in the same manner as the fixing solution 101 except that the fluorescent whitening agent of the present invention was added as shown in Table 8. The larger the value of the residual color density is, the larger the potential measure of the difference between laboratories.

Table 8 summarizes the results.

[0131]

[Table 8]

[0132]

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(Processing method A) Process Processing time Processing temperature Color development 3 minutes 15 seconds 38 ° C. Bleaching 3 minutes 00 seconds 38 ° C. Water washing 30 seconds 24 ° C. Fixing 3 minutes 00 seconds 38 ° C. Water washing (1) 30 seconds 24 ° C water washing (2) 30 seconds 24 ° C Stabilized 30 seconds 38 ° C Drying 4 minutes 20 seconds 55 ° C

Next, the composition of the processing solution will be described. (Color developing solution 101) (Unit g) Diethylenetriaminepentaacetic acid 1.0 1-Hydroxyethylidene-1,1-diphosphonic acid 2.0 Sodium sulfite 4.0 Potassium carbonate 30.0 Potassium bromide 1.4 Potassium iodide 1 2.5 mg hydroxylamine sulfate 2.4 4- [N-ethyl-N- (β-hydroxyethyl) amino] -2-methylaniline sulfate 4.5 Add water and add 1.0 liter pH (potassium hydroxide And adjusted with sulfuric acid) 10.05

(Bleaching Solution 101) (Unit g) Ferric N- (2-carboxyphenyl) iminodiacetic acid pentahydrate 25.0 Ferric ammonium 1,3-diaminopropanetetraacetate dihydrate 25.0 1,3-diaminopropanetetraacetic acid 2.0 malonic acid 7.0 succinic acid 60.0 glutaric acid 15.0 sodium bromide 40.0 sodium nitrate 30.0 sodium hydroxide 30.0 diethanolamine 20.0 1.0 liter pH (adjusted with sodium hydroxide and nitric acid) 4.2

(Fixing solution 101) (Unit g) 1,3-diaminopropanetetraacetic acid 6.0 Ammonium sulfite 20.0 Ammonium thiosulfate aqueous solution (750 g / L) 270.0 mL Acetic acid (90%) 5.0 Water was added. In addition, 1.0 liter pH (adjusted with ammonia water and acetic acid) 6.4

(Stabilizing Solution 101) (Unit g) p-nonylphenoxypolyglycidol 0.2 (glycidol average polymerization degree 10) ethylenediaminetetraacetic acid 0.05 1,2,4-triazole 1.3 1,4-bis ( 1,2,4-triazol-1-ylmethyl) piperazine 0.75 hydroxyacetic acid 0.02 hydroxyethylcellulose (Daicel Chemical HEC SP-2000) 0.1 1,2-benzoisothiazolin-3-one 0.05 water In addition, 1.0 liter pH 8.5

As can be seen from Table 8, it is clear that the diaminostilbene compounds of the present invention have a higher residual color reducing effect than the other comparative compounds. It is considered that the diaminostilbene compound of the present invention has some interaction with the sensitizing dye in the π plane and wash out the sensitizing dye from the light-sensitive material. Therefore, the level of interaction and the hydrophilicity of the compound itself must be balanced.

Example 2 The sample 1 of Example 1 was left unexposed and developed by the following processing method B, and the residual color density of magenta was determined in the same manner as in Example 1. As shown in Table 9, bleach-fix solutions 202 to 208 were prepared in the same manner as bleach-fix solution 201 except that the fluorescent brightener of the present invention was added.

(Processing method B) Process Processing time Processing temperature Color development 3 minutes 15 seconds 38 ° C. Bleaching 1 minute 00 seconds 38 ° C. Bleach fixing 3 minutes 15 seconds 38 ° C. Rinse (1) 40 seconds 35 ° C. 1 minute 00 seconds 35 ° C Stability 40 seconds 38 ° C Drying 1 minute 15 seconds 55 ° C

Next, the composition of the processing solution will be described. (Color developing solution) (Unit g) Diethylenetriaminepentaacetic acid 1.0 1-Hydroxyethylidene-1,1-diphosphonic acid 2.0 Sodium sulfite 4.0 Potassium carbonate 30.0 Potassium bromide 1.4 Potassium iodide 5 mg hydroxylamine sulfate 2.4 4- [N-ethyl-N- (β-hydroxyethyl) amino] -2-methylaniline sulfate 4.5 Add water and add 1.0 liter pH (with potassium hydroxide Adjusted with sulfuric acid) 10.05

(Bleaching solution) (unit: g) Ferric ammonium ethylenediaminetetraacetate dihydrate 120.0 Ethylenediaminetetraacetic acid disodium salt 10.0 Ammonium bromide 100.0 Ammonium nitrate 10.0 Bleaching fixer 0.005 mol _{(CH 3) 2 N-CH} 2 -CH 2 -SS-CH 2 -CH 2 -N (CH 3) 2 · 2HCl aqueous ammonia (27%) of 15.0 ml water was added to 1.0 l pH (ammonia (Adjust with water and nitric acid) 6.3

(Bleach-fixing solution) (Unit: g) Ferric ammonium ethylenediaminetetraacetate dihydrate 50.0 Disodium ethylenediaminetetraacetate 5.0 Sodium sulfite 12.0 Aqueous ammonium thiosulfate solution (700 g / liter) 240.0 Milliliter ammonia water (27%) 6.0 milliliters add water 1.0 liter pH (adjusted with ammonia water and acetic acid) 7.2

(Washing solution) Tap water was washed with H-type strongly acidic cation exchange resin (Amberlite IR- manufactured by Rohm and Haas Company).
120B) and water through a mixed-bed column filled with an OH-type anion exchange resin (Amberlite IR-400) to treat the calcium and magnesium ion concentrations to 3 mg / l or less, followed by isocyanuric dichloride 20 mg / liter of sodium and 0.15 g / liter of sodium sulfate were added. The pH of this solution was in the range of 6.5 to 7.5.

(Stabilizing Solution) (Unit g) Sodium p-toluenesulfinate 0.03 Polyoxyethylene-p-monononylphenyl ether (Average degree of polymerization 10) 0.2 Disodium ethylenediaminetetraacetate 0.05 1, 2,4-triazole 1.3 1,4-bis (1,2,4-triazol-1-ylmethyl) piperazine 0.75 1,2-benzisothiazolin-3-one 0.10 Add water 1.0 Liters pH 8.5

From Table 9, it can be seen that the fluorescent whitening agent of the present invention has a high residual color reducing effect even when added to the bleach-fix solution. As compared with the case where the toner was added to the fixing solution of Example 1, it can be seen that the residual color can be reduced by adding the toner to the fixing solution.

[0147]

[Table 9]

Example 3 (Preparation of processing solution) In processing method A of Example 1, the processing solution of each step of the color developing solution 101, the bleaching solution 101, the fixing solution 101, and the stabilizing solution 101 was added to the compound SR- of the present invention. 13
Process A except that only 5 mmol / l was added
Each of the processing solutions was prepared in the same manner as in the above processing solution, and the color developing solution 301, the bleaching solution 301, the fixing solution 301, and the stabilizing solution 3 were prepared.
01. Sample 1 of Example 1 was developed with processing methods A and C1 to C4 without exposure. Processing method C1
-C4 are the same as the processing method A except that the processing liquid is changed as described below. (Processing method) Color developing solution Bleaching solution Fixing solution Stabilizing solution A 101 101 101 101 C1 301 101 101 101 C2 101 301 101 101 C3 101 101 301 101 C4 101 101 101 301 Same as Example 1 from the obtained processed sample. And the residual color densities of magenta and yellow were determined.

[0149]

[Table 10]

As shown in Table 10, the method of using the fluorescent brightener of the present invention in the fixing solution has the highest effect of reducing residual color. In the fixing solution, after the sensitizing dye is desorbed, washing out of the light-sensitive material film is inhibited by interaction with gelatin or oil droplets (containing a coupler or the like). It is presumed that the competitive relationship between the above-mentioned interaction and the hydrophobic interaction between the fluorescent whitening agent and the dye works advantageously for the fluorescent whitening agent by adding the fluorescent whitening agent to the fixing solution. After the fixing position of the fluorescent whitening agent is fixed, the hydrophobicity must be increased in order to cut off the interaction with oil droplets and the like.
The hydrophilicity of the dye-whitening agent interacting substance is reduced, and the effect of promoting the washing out of the dye is reduced. On the other hand, before fixing, the fluorescent whitening agent permeated into the photographic material and taken in elutes before the fixing solution, which is disadvantageous in terms of the effective density.

Example 4 (Preparation of Samples 401 to 404) In Sample 1 of Example 1, the amounts of sensitizing dyes in Emulsions A to D and E to I were uniformly increased and decreased at a constant rate. Samples 401 to 404 were produced in the same manner as in Sample 1, except for the following. While the sample prepared as described above was left unexposed, development processing was performed by the processing method using the fixing solutions 101 and 103 in Example 1, and a red-sensitive sensitizing dye (ExS-1,
ExS-2 and ExS-3) and (ExS-5, ExS
S-6, ExS-7 and ExS-8) were quantified to determine the residual amount. (Quantitative method of sensitizing dye) The sensitizing dye remaining in the treated sample was extracted with methanol / water (4/6), quantified by high performance liquid chromatography, and the residual amount (μmol /
m ² ). The residual amount was represented by the total mole number of each of the red-sensitive sensitizing dye and the green-sensitive sensitizing dye.

[0152]

[Table 11]

As shown in Table 11, it can be seen that the residual amount of the sensitizing dye can be reduced by the diaminostilbene compound of the present invention. Sample 4 containing less than 10 μmol / m ^{2 of} sensitizing dye
In No. 02, the residual color change is relatively small and the residual amount is small even without using a diaminostilbene compound. However, when the actual shooting was performed, the sample 402 was inferior in sharpness and color reproducibility to other samples, and was insufficient in image quality.

[0154]

According to the silver halide photographic light-sensitive material of the present invention, it is possible to provide a method of forming a photographic image having excellent image quality with little residual color and small difference in processing.

Claims (2)

[Claims] 1. A support comprising at least two blue-sensitive silver halide emulsion layers, two green-sensitive silver halide emulsion layers,
And a method for developing a silver halide color photographic light-sensitive material for photography provided with a red-sensitive silver halide emulsion layer, wherein at least one of the processing solutions having a fixing ability used in the developing step is represented by the following general formula (SR). A method for developing a silver halide color photographic light-sensitive material for photography, comprising: Embedded image In the general formula [SR], L ¹ and L ² may be the same or different and are represented by —OR ¹ or —NR ² R ³ (R ¹ , R ² and R ³ are each a hydrogen atom or an alkyl group); And at least one of the following conditions is satisfied. Four substituents L ¹ and L in the general formula [SR]
² has a total of four or more substituents selected from the general formula [A] group. Four substituents L ¹ and L in the general formula [SR]
² has a total of two substituents selected from the general formula [A] group, and has a total of two or more substituents selected from the general formula [B] group. Four substituents L ¹ and L in the general formula [SR]
² has one substituent selected from the general formula [A] group, and has a total of three or more substituents selected from the general formula [B] group. Formula (A) _{Group: -SO 3 M, -OSO 3 M} , -COO
M, -NR ₃ X General formula [B] group: -OR, -NR'R ", -CN, -N
In the HCONH ₂ general formula [A] group, X represents a halogen atom, and R represents an alkyl group. In the general formulas [SR] and [A],
M represents a hydrogen atom, an alkali metal, tetraalkylammonium or pyridinium. In the general formula [B] group,
R, R 'and R "are a hydrogen atom or an alkyl group, and R' and R" may be linked to each other to form a ring. 2. The total coating amount of the sensitizing dye contained in all of the blue-sensitive silver halide emulsion layer, the green-sensitive silver halide emulsion layer, and the red-sensitive silver halide emulsion layer is 30 μmol / m ² or more. ^{2. The} silver halide color photographic light-sensitive material according to claim 1, wherein the total coating amount of the sensitizing dye in the red-sensitive emulsion layer or the green-sensitive emulsion layer is 10 μmol / m ² or more. Material development processing method.