JPH10132083A - Knitting yarn for packing - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain knitting yarns for a packing whose tensile strength and resistance are improved without deteriorating characteristics of expanded graphite excellent compressive resetting performance and sealability by adhering reinforcing fiber yarns arranged longitudinally with spacings to the expanded graphite due to adhesive and embedding them. SOLUTION: A packing 1 is composed of a core 2 and a braided body 3 for covering an outer periphery of the core 2, subjected to, for instance, braid over braid. The core 2 is formed by collecting knitting yarn 4 and longitudinally arranging them. The braided body 3 is formed by arranging the knitting yarn 4 in the state of braid over braid. The knitting yarn 4 is prepared by longitudinally arranging a plurality of reinforcing yarn 40 with spacings in a widthwise direction, and integrating both surfaces thereof with expanded graphites 41 composed of round expanded graphite powders by means of adhesive, for instance, acrylic ester. As the reinforcing yarn, organic fibers such as cotton, rayon, phenol, aramid and PBI or inorganic fibers such as glass fibers are used.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a knitting yarn for packing suitable for a gland packing material used for a shaft sealing portion of a fluid device.

[0002]

2. Description of the Related Art Conventionally, as a packing material for obtaining a gland packing used for, for example, a shaft sealing portion of a fluid device, an expanded graphite having a high compression restoring property and an excellent sealing property is used as a base material. It has been known.

[0003]

The gland packing formed by using such a packing material is as follows.
It is manufactured by a compression molding method such as a lamination type, a die molding type, a chip molding type, a ribbon pack type, etc., but these must be formed in a ring shape according to the shaft diameter to be used in advance. It cannot be used for other things. Therefore, versatility is poor,
In addition, since the expanded graphite itself has a weak tensile strength and is brittle, it is difficult to take out the one attached to a staffin box or the like for replacement, resulting in poor usability.

Further, as a problem of each of the above-mentioned compression molding methods, in the case of the laminate type, the yield is poor and the cost is increased. In the case of the die molding method and the chip molding method, the cost is increased as compared with the die molding, and the versatility is poor. In the case of the ribbon pack type, workability is poor.

[0005] These problems can be solved by forming the expanded graphite into a string so that it can be used by cutting it to a predetermined length in accordance with the shaft diameter, like other braided packings. The expanded graphite itself is a caterpillar-like particle (powder) in appearance, which is expanded in the C-axis direction of the crystal of the graphite particle. Therefore, these caterpillar-like particles can be aggregated and formed into a sheet by compression molding. Even if it is formed as described above, since it has a low tensile strength and is brittle as described above, it cannot be braided because it cannot be formed into a yarn. Therefore, it has been considered impossible to cut the wire into a predetermined length in accordance with the shaft diameter like other braided packings, wind the cut wire around the shaft outer periphery, and use it as a packing.

The present invention has been made in view of the above circumstances, and as a result of an intensive study based on a basic research on a knitting yarn made of expanded graphite necessary for a braid, that is, a knitting yarn structure using expanded graphite, has been developed. High tensile strength and toughness without compromising the characteristics of graphite that have high compression recovery and excellent sealing properties, and constitute a packing with excellent usability and versatility while ensuring high sealing properties. An object of the present invention is to provide a knitting yarn for packing that can be used.

[0007]

In order to achieve the above object, a packing knitting yarn according to the first aspect of the present invention comprises:
3. The method according to claim 2, wherein a plurality of reinforcing fiber yarns arranged in the longitudinal direction at a distance from each other are integrally bonded to the expanded graphite with an adhesive and embedded. The knitting yarn for packing according to the present invention is characterized in that a plurality of reinforcing fiber yarns arranged in the longitudinal direction at an interval from each other are integrally bonded to the expanded graphite with an adhesive, embedded, and twisted. It is assumed that.

According to the first and second aspects of the present invention, a plurality of reinforcing fiber yarns, which are arranged at intervals in a brittle expanded graphite, are integrated with the expanded graphite by an adhesive. Adhering to and embedding into the material makes use of the adhesiveness between the expanded graphites to form an aggregate of a predetermined amount of expanded graphite, and maintains the high compression recovery property inherent in expanded graphite and excellent sealing properties In addition, the high tensile strength and toughness of the reinforcing fiber yarns are imparted, and the expanded graphite and the reinforcing fiber yarns are firmly bonded to each other so that the expanded graphite peels or falls off during braiding or twisting. A durable knitting yarn which does not cause breakage of the yarn can be obtained. Accordingly, a plurality of such knitting yarns are bundled and braided to form a braided body (square knitting) having high tensile strength and toughness, or twisted by twisting to have high tensile strength and toughness. It is possible to form a string-like body, and the string-like body has a predetermined length according to the shaft diameter while securing the high sealing property essential for packing due to the high compression resilience inherent in expanded graphite. It is easy to construct a packing excellent in versatility and usability, for example, by winding a material cut into a shape around the shaft and using it.

As the expanded graphite in the knitting yarn for packing according to the first and second aspects of the present invention, the caterpillar-like graphite powder as described in the third aspect may be used. Such a narrow sheet-like material as described above may be used.

Further, as the reinforcing fiber yarn in the packing yarn according to the first to fourth aspects of the invention, as described in the fifth aspect, cotton, rayon, phenol, aramid, PBI, PTEF , PPS, PEEK, etc., at least one selected from the group consisting of inorganic fibers such as glass fibers, carbon fibers, and ceramic fibers. At least one of them may be at least one selected from metal wires such as stainless steel, Inconel, Monel, etc., as described in claim 7, and also in claim 8, And a composite of at least one selected from the organic fibers and at least one selected from the inorganic fibers or the metal wires.

Further, as the reinforcing fiber yarn in the knitting yarn for packing according to the first to fourth aspects of the present invention, at least one selected from the inorganic fibers or the metal wires as described in the ninth aspect. Or the surface of a composite thereof coated with one short fiber selected from the above organic fibers or a composite short fiber yarn thereof,
The surface of one selected from the inorganic fibers or the metal wires or a composite thereof as described in claim 10 or a composite thereof, and the organic material as described in claim 11. A twisted fiber and an inorganic fiber or a metal wire, a knitted knit of the organic fiber or the inorganic fiber or the metal wire as described in claim 12, or a longitudinal fiber as described in claim 13. Any of a plurality of inorganic fibers or metal wires extending parallel to the direction and an organic fiber entangled therebetween and maintaining parallelism may be used.

[0012]

Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a partially cutaway perspective view showing an example of a packing formed by using the packing yarn according to the present invention. In FIG. 1, a packing 1 covers a core 2 and an outer periphery of the core 2. The core 2 is formed by bundling a plurality of knitting yarns 4 and arranging them in the longitudinal direction, and the braided body 3 is formed by knitting the knitting yarns 4. It is formed by.

As shown in FIG. 2, the knitting yarn 4 has a plurality of reinforcing fiber yarns 40 made of, for example, cotton, which are arranged in the longitudinal direction at intervals in the width direction, and are not shown on both surfaces thereof. The structure is such that it is integrally bonded and buried with the expanded graphite 41 made of caterpillar-like expanded graphite powder with an adhesive (for example, acrylic acid ester). Reinforcing fiber yarn 40
The cotton used as the material has an extremely short and fine fiber standing on its surface, and so-called fluffing is recognized, so that the adhesiveness with the adhesive is good, so that the reinforcing fiber yarn 40 and the expanded graphite 41 are firmly bonded to each other. When the braided yarn 4 is bonded and bag-knitted to form the braided body 3, the expanded graphite 41 can be prevented from peeling off or falling off from the reinforcing fiber yarn 40.

As described above, a knitting yarn in which a plurality of reinforcing fiber yarns 40 made of, for example, cotton, which are arranged in the longitudinal direction at intervals in the width direction, are integrally bonded and buried in the expanded graphite 41 with an adhesive. By configuring 4, the high tensile strength and toughness of the reinforcing fiber yarns 40 are imparted to the knitting yarn 4, so that the knitting yarn 4 can be braided without breaking. Therefore, a string-like body 5 in which the outer periphery of the core formed by the knitting yarn 4 is covered with the braided body 3 sack-knitted with the knitting yarn 4, that is, a string having a high tensile strength and rich in toughness Formed in the shape body 5,
Since the string 5 can be cut into a predetermined length according to the shaft diameter and used as the packing 1, versatility and usability are improved. Moreover, the core 2 and the braided body 3 constituting the packing 1 are given the high compression restoring property and the excellent sealing property inherent to the expanded graphite 41, so that the packing 1 is indispensable as the packing 1. High sealing characteristics can be secured.

FIG. 3 shows a packing yarn 4 according to the present invention.
FIG. 3 is a perspective view showing another example of the packing 1 configured using (FIG. 2), and the same or corresponding parts as those of the packing shown in FIG. 1 are denoted by the same reference numerals, and detailed description thereof is omitted. . In FIG. 3, the packing 1 forms a cord-like body 5 by a braided body 3 </ b> A formed by eight-pitch knitting using eight knitting yarns 4.

Also in the case of the packing 1 shown in FIG. 3, since the high tensile strength and toughness of the reinforcing fiber yarn 40 are imparted to the knitting yarn 4, it is necessary to cut the knitting yarn 4. Can be braided (square knitting). Therefore,
A string 5 is formed from a braided body 3A having high tensile strength and rich in toughness, and this string 5 is cut into a predetermined length, for example, according to the shaft diameter, and used as the packing 1. Therefore, versatility and usability are improved. Moreover, the braided body 3A constituting the packing 1 is provided with the high compression restoring property and the excellent sealing property inherent to the expanded graphite 41.
As a result, it is possible to secure high sealing characteristics which are indispensable.

FIG. 4 shows a knitting yarn 4 for packing according to the present invention.
It is a perspective view which shows another example of the packing 1 comprised using (FIG. 2), the same code | symbol is attached | subjected to the same or corresponding part as each said example, and those detailed description is abbreviate | omitted. FIG.
In the packing 1, a bundle of six knitting yarns 4
Roll forming is performed while performing a twisting operation of times / m to form a twisted string-like body 5.

Also in the case of the packing 1 shown in FIG. 4, since the high tensile strength and toughness of the reinforcing fiber yarn 40 are imparted to the knitting yarn 4, it is necessary to cut the knitting yarn 4. Without any twisting. Therefore, the twisted string 5 having high tensile strength and rich toughness is formed, and the string 5 is cut into a predetermined length in accordance with, for example, the shaft diameter to obtain the packing 1. The versatility and usability are improved. In addition, the twisted string-like body 5 constituting the packing 1 is provided with the high compression restoring property and the excellent sealing property inherent to the expanded graphite 41, so that it is indispensable as the packing 1. High sealing characteristics can be secured.

In the above-described knitting yarns 4 for packing, a description has been given of a case in which caterpillar-like graphite powder is used as the expanded graphite 41, but the sheet-like material cut into a narrow width (width dimension, for example, 5 mm or less) is used. May be used. Also,
Only one surface of the plurality of reinforcing fiber yarns 40 may be integrally bonded and buried in the expanded graphite 41 with an adhesive to form the knitting yarn 4, and the knitting yarn 4 may be twisted as shown in FIG. May be applied.

The reinforcing fiber yarn 4 constituting the knitting yarn 4
0 is one selected from organic fibers such as rayon, phenol, aramid, PBI, PTFE, PPS, and PEEK, or inorganic fibers such as glass fibers, carbon fibers, and ceramic fibers, in place of the cotton. Or one selected from metal wires such as stainless steel, inconel, and monel, and at least one selected from the organic fibers and the inorganic fiber. It may be a composite with at least one selected from fibers.

FIGS. 6 to 10 each show a modification of the reinforcing fiber yarn 40. The reinforcing fiber yarn 40 shown in FIG. 6 includes one of the organic fibers 40A (cotton or aramid),
One selected from the inorganic fibers or metal wires 40
B (glass fiber, carbon fiber or stainless wire). In the reinforcing fiber yarn 40, the adhesion to the adhesive can be improved by the organic fiber, and the tensile strength and the toughness can be improved by the inorganic fiber or the metal wire.

The reinforcing fiber yarn 40 shown in FIG. 7 is formed of at least one of the inorganic fibers or metal wires 40B.
The surface of (glass fiber, carbon fiber, or stainless steel wire) is covered with one (cotton or aramid) short fiber 6 selected from organic fibers. In the reinforcing fiber yarn 40, the adhesion layer with the adhesive and the toughness are improved by the coating layer of the short fibers 6, and the tensile strength and toughness are improved by at least one 4OB selected from inorganic fibers or metal wires. be able to. The coating layer of the short fibers 6 may be formed by a composite short fiber yarn in which two or more short fibers selected from organic fibers are composited.

The reinforcing fiber yarn 40 shown in FIG. 8 is formed of at least one of the inorganic fibers or metal wires 40B.
The surface of (glass fiber, carbon fiber or stainless steel wire) is coated with, for example, a pulp papermaking product 7. In the reinforcing fiber yarn 40, adhesion to the adhesive and toughness are improved by the coating layer of the pulp papermaking 7, and tensile strength and toughness are improved by at least one of the inorganic fibers or metal wires 40B. Can be done.

The reinforcing fiber yarn 40 shown in FIG. 9 is one of the organic fibers 40A (cotton or aramid) or the inorganic fiber, or one of the metal wires 40B (glass fiber, carbon fiber). Or stainless steel wire). In the reinforcing fiber yarn 40, the adhesiveness with the adhesive is improved by the unevenness formed by the stitches of the knitted knitted structure, and the tensile force can be absorbed by the stretching function possessed by the knitted knitted structure itself. As a result, the tolerance for tension is increased, and the toughness is improved.

In the reinforcing fiber yarn 40 shown in FIG. 10, a plurality of inorganic fibers or metal wires 40B (glass fiber, carbon fiber or stainless steel wire) selected from the metal wires are arranged in parallel in the longitudinal direction. 40A (cotton or aramid) selected from the organic fibers is entangled between a plurality of fibers to maintain parallelism. In the reinforcing fiber yarn 40, the adhesion to the adhesive and the toughness can be improved by the organic fiber, and the tensile strength and the toughness can be improved by the inorganic fiber or the metal wire.

As described above, the reinforcing fiber yarns 4 embedded in the expanded graphite 41, which are arranged in the longitudinal direction at intervals in the width direction and are integrally bonded to the expanded graphite 41 with an adhesive.
Since the high tensile strength and toughness having a value of 0 are imparted to the knitting yarn 4, the knitting yarn 4 can be cut without breaking.
Further, the expanded graphite 41 can be easily braided or twisted without peeling or falling off from the reinforcing fiber yarn 40.

That is, as shown in FIGS. 11A and 11B, a plurality of yarn bobbins 9, 9 which pivot on a locus indicated by broken lines.
And the length 1a from the yarn bobbins 9, 9 to the knitting point P at the time when the yarn bobbins 9, 9 are located outside the locus as in the case where The difference between the length 1b from the yarn bobbins 9, 9 to the knitting point P when the yarn bobbins 9, 9 are located inside the locus is small, and therefore, the yarn 4 is relatively small. FIGS. 12 (A) and 12 (B) show the case where a tensile force is applied.
As in the case where the knitting yarn 4 is unwound from a plurality of yarn bobbins 9 and 9 that move on a diagonal locus indicated by a broken line and is square knitted, the yarn bobbins 9 and 9 are positioned outside the locus. The length 1a from the yarn bobbins 9 and 9 to the knitting point P at the time when the knitting is performed, and the knitting point from the yarn bobbins 9 and 9 when the yarn bobbins 9 and 9 are located at the center of the locus. The difference from the length 1b up to P is large, so that braiding is possible even when a relatively large tensile force is applied to the knitting yarn 4.

[0028]

As described above, claims 1 and 2 are as described above.
According to the invention described in the above, a plurality of reinforcing fiber yarns arranged at a distance from each other in the brittle expanded graphite are integrally bonded to the expanded graphite with an adhesive and embedded, so that the expanded graphite A predetermined amount of expanded graphite aggregate is formed by utilizing the adhesiveness to maintain the original properties of expanded graphite, that is, high compressive restorability and excellent sealing property, and high tensile strength of the reinforcing fiber yarn. And toughness, and the adhesive can not only strengthen the bonding between the reinforcing fiber yarn and the expanded graphite, but also improve the bonding strength of the expanded graphite itself near the reinforcing fiber yarn. Thus, a durable knitting yarn that does not cause exfoliated graphite to peel or fall off during the manufacturing process of a packing on which a complex stress acts, and that does not cause yarn breakage, can be obtained. Accordingly, a plurality of such knitting yarns are bundled and braided to form a braided body (square knitting) having high tensile strength and toughness,
It is possible to form a twisted string with high tensile strength and toughness by twisting, and secure the high sealing characteristics that are essential as packing due to the high compression recovery characteristic inherent to expanded graphite. On the other hand, there is an effect that it is easy to form a packing excellent in versatility and usability such that a string-shaped body cut to a predetermined length according to the shaft diameter is wound around the shaft outer periphery and used.

[Brief description of the drawings]

FIG. 1 is a partially cutaway perspective view showing an example of a packing formed by using a packing yarn according to the present invention.

FIG. 2 is a partially cut perspective view showing a knitting yarn constituting the packing.

FIG. 3 is a partially cut perspective view showing another example of the packing constituted by using the knitting yarn for packing according to the present invention.

FIG. 4 is a partially cut perspective view showing another example of the packing constituted by using the packing knitting yarn according to the present invention.

FIG. 5 is a perspective view showing a modified example of a knitting yarn.

FIG. 6 is an explanatory view showing a modified example of the reinforcing fiber yarn.

FIG. 7 is an explanatory view showing a modified example of the reinforcing fiber yarn.

FIG. 8 is an explanatory view showing a modified example of the reinforcing fiber yarn.

FIG. 9 is an explanatory view showing a modified example of the reinforcing fiber yarn.

FIG. 10 is an explanatory view showing a modified example of the reinforcing fiber yarn.

FIG. 11A is a front view showing a state in which a knitting yarn fed from a knitting yarn bobbin to a knitting point is bag-knitted, and FIG.
FIG. 4 is a side view for explaining a change in length of a knitting yarn when bag-knitting a knitting yarn fed from a knitting bobbin to a knitting point.

FIG. 12A is a front view showing a state in which a knitting yarn fed from a yarn bobbin to a knitting point is square-knitted, and FIG.
FIG. 3 is a side view for explaining a change in length of a knitting yarn when a knitting yarn fed from a knitting yarn bobbin to a knitting point is squarely knitted.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Packing 3,3A braided body 4 Knitting yarn for packing 6 Short fiber 7 Pulp papermaking 8 Knitting 40 Reinforcing fiber yarn 41 Expanded graphite

Claims (13)

[Claims] 1. A knitting yarn for packing, wherein a plurality of reinforcing fiber yarns arranged in the longitudinal direction at a distance from each other are integrally bonded to expanded graphite with an adhesive and embedded. 2. A packing for packing, wherein a plurality of reinforcing fiber yarns arranged in the longitudinal direction at a distance from each other are integrally bonded to an expanded graphite with an adhesive, embedded and twisted. Knitting yarn. 3. The packing yarn according to claim 1, wherein the expanded graphite is a caterpillar-like graphite powder. 4. The packing yarn according to claim 1, wherein the expanded graphite is in the form of a narrow sheet. 5. The reinforcing fiber yarn is made of cotton, rayon, phenol, aramid, PBI, PTEF, PPS, PEE.
The knitting yarn for packing according to claim 1, 2, 3, or 4, which is at least one selected from organic fibers such as K. 6. The reinforcing fiber yarn is at least one selected from inorganic fibers such as glass fibers, carbon fibers, and ceramic fibers.
The knitting yarn for packing according to 1. 7. The packing knitting yarn according to claim 1, wherein the reinforcing fiber yarn is at least one selected from metal wires such as stainless steel, Inconel and Monel. 8. The reinforcing fiber yarn is a composite of at least one selected from the organic fibers and at least one selected from the inorganic fibers or the metal wires. The knitting yarn for packing according to 1. 9. The method according to claim 1, wherein the reinforcing fiber yarn has a surface of at least one selected from the inorganic fibers or metal wires or a composite of these at least one selected from the organic fibers.
5. The knitting yarn for packing according to claim 1, which is coated with one short fiber or a composite short fiber yarn thereof. 10. The reinforcing fiber yarn wherein one of the inorganic fibers or the metal wires or a composite of these is coated with a papermaking material. The knitting yarn for packing according to 1. 11. The reinforcing fiber yarn according to claim 1, wherein the organic fiber and the inorganic fiber or metal wire are twisted.
5. The packing yarn according to 2, 3, or 4. 12. The knitting yarn for packing according to claim 1, wherein the reinforcing fiber yarn is obtained by knitting the organic fiber, the inorganic fiber, or the metal wire. 13. The reinforcing fiber yarn comprises a plurality of inorganic fibers or metal wires extending in parallel in the longitudinal direction, and organic fibers entangled therebetween to maintain the parallelism. 5. The packing yarn according to 3 or 4.