JPH10286565A - Water treatment plant - Google Patents
Water treatment plantInfo
- Publication number
- JPH10286565A JPH10286565A JP10117097A JP10117097A JPH10286565A JP H10286565 A JPH10286565 A JP H10286565A JP 10117097 A JP10117097 A JP 10117097A JP 10117097 A JP10117097 A JP 10117097A JP H10286565 A JPH10286565 A JP H10286565A
- Authority
- JP
- Japan
- Prior art keywords
- water
- membrane
- washing
- tank
- sludge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 219
- 238000011282 treatment Methods 0.000 title claims abstract description 37
- 239000002351 wastewater Substances 0.000 claims abstract description 83
- 238000004062 sedimentation Methods 0.000 claims abstract description 68
- 239000010802 sludge Substances 0.000 claims abstract description 55
- 238000005374 membrane filtration Methods 0.000 claims abstract description 51
- 238000005406 washing Methods 0.000 claims description 116
- 239000012528 membrane Substances 0.000 claims description 67
- 230000015271 coagulation Effects 0.000 claims description 47
- 238000005345 coagulation Methods 0.000 claims description 47
- 239000000463 material Substances 0.000 claims description 45
- 238000001914 filtration Methods 0.000 claims description 43
- 238000009825 accumulation Methods 0.000 claims description 16
- 238000007599 discharging Methods 0.000 claims description 6
- 238000011221 initial treatment Methods 0.000 claims description 3
- 239000000701 coagulant Substances 0.000 abstract description 32
- 230000001112 coagulating effect Effects 0.000 abstract description 19
- 239000000243 solution Substances 0.000 abstract description 15
- 239000000126 substance Substances 0.000 abstract description 13
- 238000002156 mixing Methods 0.000 abstract description 12
- 238000002347 injection Methods 0.000 abstract description 10
- 239000007924 injection Substances 0.000 abstract description 10
- 238000011084 recovery Methods 0.000 abstract description 8
- 239000000725 suspension Substances 0.000 description 20
- 238000004140 cleaning Methods 0.000 description 17
- 238000000034 method Methods 0.000 description 16
- 238000000926 separation method Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 6
- 239000012510 hollow fiber Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000008235 industrial water Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003657 drainage water Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000011899 heat drying method Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、原水の膜濾過によ
り透過水を処理水として得るようにした膜濾過装置を有
する水処理装置に関し、更に詳細には、原水の膜濾過工
程と濾過膜の洗浄工程とを交互に行う膜濾過装置を有す
る水処理装置であって、洗浄工程から流出する洗浄排水
の後処理を必要とし、特に、懸濁物を多量に含む河川
水、湖沼水、ダム水、工業用水、下廃水処理水等を原水
としているために、濾過膜の目詰まりが速やかに進行
し、従って洗浄工程の頻度が高く、洗浄排水の量が多く
なる場合に最適な水処理装置に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water treatment apparatus having a membrane filtration apparatus for obtaining permeated water as treated water by membrane filtration of raw water. A water treatment apparatus having a membrane filtration device that alternately performs a washing step and requires a post-treatment of washing wastewater flowing out of the washing step, and in particular, river water, lake water, dam water, and dam water containing a large amount of suspended matter. Since the raw water is used as industrial water, sewage treated water, etc., clogging of the filtration membrane proceeds quickly, and therefore, the frequency of the washing process is high, and the optimal water treatment apparatus is used when the amount of washing wastewater is large. Things.
【0002】[0002]
【従来の技術】膜濾過装置は、濾過膜を使って被処理水
を膜透過させ、被処理水中の異物、例えば微細な粒子状
の懸濁物を濾過膜により捕捉しつつ透過水を処理水とし
て得る装置であって、異物が微細な固体粒子であっても
確実に補足して清浄な処理水を比較的効率良く得ること
ができることから、近年、上水及び排水の除濁処理等を
含む種々の分野で利用されている。ところで、被処理水
を膜濾過する過程で、濾過膜は捕捉した被処理水中の異
物のために徐々に目詰まりし、濾過膜を透過する被処理
水の通水差圧が上昇する。そこで、通水差圧が所定の差
圧に到達した時点、或いは膜濾過工程を所定時間行った
時点、更には所定の被処理水の水量を透過させた時点等
で、通常、濾過膜を洗浄して、膜濾過機能の回復を図っ
ている。2. Description of the Related Art In a membrane filtration apparatus, water to be treated is permeated through a filtration membrane, and foreign matter, for example, fine particulate suspensions in the water to be treated is captured by the filtration membrane while the permeated water is treated. In recent years, since it is possible to obtain clean treated water relatively efficiently by reliably capturing even foreign matter which is fine solid particles, the method includes the turbidity treatment of clean water and wastewater. It is used in various fields. By the way, in the process of membrane filtration of the water to be treated, the filtration membrane is gradually clogged by the foreign matter in the water to be treated that has been captured, and the pressure difference in the passage of the water to be treated passing through the filtration membrane increases. Therefore, the filtration membrane is usually washed at the time when the pressure difference reaches a predetermined pressure difference, when the membrane filtration step is performed for a predetermined time, and when a predetermined amount of water to be treated is permeated. Thus, the membrane filtration function is restored.
【0003】濾過膜の洗浄工程では、膜濾過工程での水
の流れとは逆に、濾過膜の2次側、即ち透過水流出側か
ら濾過膜の1次側、即ち被処理水流入側に洗浄媒体、例
えば洗浄水を透過させ、それにより濾過膜の一次側の膜
面に付着した異物を濾過膜から剥離している。洗浄水に
は、主として透過水、或いは時として透過水と気体との
混合流体を使用し、透過水を濾過膜に透過させる際に
は、空気等の気体で透過水を押圧しつつ透過させること
もある。剥離した異物は、被処理水及び/又は洗浄水と
共に洗浄排水として外部に排出される。[0003] In the washing step of the filtration membrane, contrary to the flow of water in the membrane filtration step, from the secondary side of the filtration membrane, ie, the permeate outflow side, to the primary side of the filtration membrane, ie, the inflow side of the water to be treated. The washing medium, for example, washing water is permeated, and thereby foreign substances adhering to the membrane surface on the primary side of the filtration membrane are separated from the filtration membrane. For the washing water, use mainly permeated water or sometimes a mixed fluid of permeated water and gas, and when permeating the permeated water through the filtration membrane, allow the permeated water to permeate while being pressed by gas such as air. There is also. The separated foreign matter is discharged to the outside as cleaning wastewater together with the water to be treated and / or the cleaning water.
【0004】ここで、図4を参照して、膜濾過装置の構
成を説明する。膜濾過装置10は、被処理水を貯水する
被処理水タンク12と、被処理水を送水する被処理水ポ
ンプ14と、限外濾過膜(UF膜)を濾過膜とした中空
糸膜モジュール16と、処理水を貯水する処理水タンク
18と、洗浄水を送水する洗浄水ポンプ20とを備えて
いる。膜モジュール16は、クロスフロー型であって、
濾過膜の一次側の一方の端部(図4では、下端)には被
処理水を導入する被処理水管22が、二次側には透過水
を処理水として処理水タンク18に流出する処理水管2
4が、一次側の他方の端部(図4では、上端)には非透
過水、即ち懸濁物の濃度の高い濃縮水を被処理水タンク
12に戻す濃縮水管26がそれぞれ接続されている。ま
た、洗浄水を濾過膜の2次側に導入するために洗浄水管
28が処理水タンク18から洗浄水ポンプ20を経て処
理水管24に接続され、洗浄排水を外部に排出する洗浄
排水管30が被処理水管22から分岐している。Here, the configuration of the membrane filtration device will be described with reference to FIG. The membrane filtration device 10 includes a treated water tank 12 for storing the treated water, a treated water pump 14 for supplying the treated water, and a hollow fiber membrane module 16 having an ultrafiltration membrane (UF membrane) as a filtration membrane. And a treated water tank 18 for storing treated water, and a washing water pump 20 for sending washing water. The membrane module 16 is of a cross flow type,
A treated water pipe 22 for introducing treated water is provided at one end (lower end in FIG. 4) of the primary side of the filtration membrane, and a treated water flowing out to the treated water tank 18 as permeated water is treated on the secondary side. Water pipe 2
4 is connected to the other end of the primary side (the upper end in FIG. 4) of a concentrated water pipe 26 for returning non-permeated water, that is, concentrated water having a high concentration of suspended matter, to the treated water tank 12. . Further, a washing water pipe 28 is connected to the treatment water pipe 24 from the treatment water tank 18 via the washing water pump 20 to introduce washing water to the secondary side of the filtration membrane, and a washing drain pipe 30 for discharging washing waste water to the outside is provided. It branches off from the water pipe 22 to be treated.
【0005】膜濾過工程では、被処理水は、被処理水タ
ンク12から被処理水ポンプ14により中空糸膜モジュ
ール16に送水され、濾過膜を透過した透過水は処理水
として処理水タンク18に入り、洗浄水として使用され
た処理水以外の処理水は外部に送水される。濾過膜を透
過しなかった被処理水は濁度の高い濃縮水としてなって
原水タンク12に戻る。中空糸膜モジュール16の通水
差圧が上昇し、例えば所定圧力に達した時点で、膜濾過
工程から濾過膜の洗浄工程に移行する。洗浄工程では、
処理水を洗浄水として処理水タンク18から洗浄水ポン
プ20により導入して濾過膜の2次側から1次側に透過
させ、それにより濾過膜の一次側の膜面に付着した異物
を濾過膜から剥離する。剥離した異物は、洗浄水及び/
又は被処理水に同伴し、洗浄排水として洗浄排水管30
を経て外部に排出される。外部に排出された洗浄排水
は、濾過膜から剥離した異物を含んで濁度が高くなって
いるので、洗浄排水の排出量が極めて少量の場合を除い
て、後処理せずにそのまま河川等に放流することは、安
全上及び環境上から好ましくない。例えば、1リットル
当たりの原水のSS(固形の懸濁物)を10mg前後とす
ると、通常の膜濾過装置では、水回収率が90%前後で
あるから、洗浄排水のSSはおよそ1リットル当たり1
00mgとなり、汚泥濃度は0.01%程度になる。そこ
で、従来は、沈降分離又は機械的脱水により洗浄排水を
固形分と濁度の低い水とに固液分離したり、天日乾燥に
より水分を蒸発させて汚泥を濃縮したりしている。In the membrane filtration step, the water to be treated is sent from the water tank to be treated 12 to the hollow fiber membrane module 16 by the water pump 14 to be treated, and the permeated water that has passed through the filtration membrane is treated as treated water to the treated water tank 18. The treated water other than the treated water used as the entering and washing water is sent to the outside. The water to be treated that has not passed through the filtration membrane returns to the raw water tank 12 as concentrated water having high turbidity. When the differential pressure of water passing through the hollow fiber membrane module 16 rises and reaches, for example, a predetermined pressure, the flow shifts from the membrane filtration step to the filtration membrane washing step. In the cleaning process,
The treated water is introduced as washing water from the treated water tank 18 by the washing water pump 20 and is permeated from the secondary side of the filtration membrane to the primary side, whereby foreign substances adhering to the primary membrane surface of the filtration membrane are removed. Peel from The peeled foreign matter is washed water and / or
Alternatively, the washing drain pipe 30 accompanies the water to be treated and serves as washing drainage.
Is discharged to the outside. The washing wastewater discharged to the outside has high turbidity, including foreign substances that have been separated from the filtration membrane.Therefore, except for the case where the discharge amount of the washing wastewater is extremely small, it is directly used for rivers, etc. without post-treatment. Discharging is undesirable from a safety and environmental point of view. For example, if the SS (solid suspension) of raw water per liter is about 10 mg, the water recovery rate is about 90% in a normal membrane filtration device, so that the SS of the washing wastewater is about 1 per liter.
00 mg, and the sludge concentration becomes about 0.01%. Therefore, conventionally, washing wastewater is separated into solid and liquid with low turbidity by sedimentation separation or mechanical dehydration, or sludge is concentrated by evaporating water by solar drying.
【0006】[0006]
【発明が解決しようとする課題】ところで、従来の水処
理装置の膜濾過装置には、洗浄排水に関して次の問題が
あった。第1には、洗浄排水の後処理が技術的に難しい
という問題であった。すなわち、洗浄排水中の固形物濃
度、つまり汚泥濃度は、そのまま放流するには濃度が高
いものの、固液分離したり蒸発処理したりするには濃度
が低過ぎて、脱水処理や天日乾燥処理の効率が非常に悪
く、その結果、固液分離のために大きな設備と広い敷地
が必要になりコストが嵩んだ。そこで、新たな方法とし
て、回転式平膜や浸漬式膜等を用い、固形分を膜に堆積
させないように膜上の固形分を除去しつつ洗浄排水を濾
過処理する非ケーキ濾過法が提案されている。この方法
は、処理速度が主として水の膜透過速度に依存し、洗浄
排水の汚泥濃度が10数%程度までは、処理速度(乾燥
固形物の容積/膜の単位面積/単位時間)が汚泥濃度の
変化とは無関係にほぼ一定である。従って、回転式平膜
や浸漬式膜を用いた方法は、洗浄排水のように汚泥濃度
が低い場合には、処理効率が著しく低く、しかも、膜に
付着した固形分を除去するためにエネルギーの消費量が
洗浄排水の処理量に比べて多く、実用化を図るには経済
性が低いという問題があった。第2には、水処理装置の
水回収率が低いという問題である。従来の洗浄工程で
は、洗浄水として透過水を使用し、それを洗浄排水とし
て外部に排出している。洗浄水の所要水量は、被処理水
の水質、濾過膜の種類等により異なるが、通常、被処理
水の5〜20%に達するので、従って、それだけ、水処
理装置の水回収率が低くなる。By the way, the membrane filtration device of the conventional water treatment apparatus has the following problems regarding washing and drainage. First, there was a problem that post-treatment of the washing wastewater was technically difficult. In other words, the concentration of solids in the washing wastewater, that is, the sludge concentration, is too high to be discharged as it is, but too low for solid-liquid separation or evaporation, and dehydration or solar drying. Is very inefficient, and as a result, large equipment and a large site are required for solid-liquid separation, resulting in an increase in cost. Therefore, as a new method, a non-cake filtration method has been proposed in which a washing flat water is filtered while removing solids on the membrane so that solids are not deposited on the membrane by using a rotary flat membrane or an immersion membrane. ing. In this method, the treatment speed mainly depends on the membrane permeation speed of water, and the treatment speed (volume of dry solid matter / unit area of membrane / unit time) depends on the sludge concentration until the sludge concentration of the washing wastewater reaches about 10% or more. It is almost constant irrespective of the change of. Therefore, the method using the rotary flat membrane or the immersion membrane has a very low treatment efficiency when the sludge concentration is low as in the case of washing wastewater, and furthermore, energy is required to remove solids attached to the membrane. There is a problem that the consumption amount is larger than the treatment amount of the washing wastewater, and economical efficiency is low for practical use. The second problem is that the water recovery rate of the water treatment device is low. In the conventional cleaning process, permeated water is used as cleaning water, and is discharged to the outside as cleaning wastewater. The required amount of the washing water varies depending on the quality of the water to be treated, the type of the filtration membrane, and the like, but usually reaches 5 to 20% of the water to be treated, and accordingly, the water recovery rate of the water treatment apparatus decreases accordingly. .
【0007】以上のような事情に応えて、本発明の目的
は、洗浄排水を効率的に後処理する装置を備え、しかも
水回収率が高い水処理装置を提供することである。[0007] In view of the above circumstances, an object of the present invention is to provide a water treatment apparatus having a device for efficiently post-treating washing wastewater and having a high water recovery rate.
【0008】[0008]
【課題を解決するための手段】本発明者は、洗浄排水を
経済的に後処理するためには、洗浄排水を濃縮して汚泥
濃度の高い汚泥水を取り出し、汚泥水から更に汚泥分を
分離することが有効であると考えた。ところで、従来の
遠心濃縮装置や膜濃縮装置は、設置面積が比較的小さい
ものの、エネルギー消費量が高く、常用の凝集沈澱装置
は、広い設置面積を必要とするので、洗浄排水の濃縮方
法としては不都合である。また、上述の回転式平膜や浸
漬式膜等を用いて経済的に引き合うベースで洗浄排水を
濃縮するためには、数%の汚泥濃度が必要であるから、
洗浄排水を予め100倍以上に濃縮する前処理が必要が
あって、プロセスが複雑になると共に費用が嵩むので、
これらの方法も洗浄排水の濃縮方法としては不適当であ
る。そこで、本発明者は、洗浄排水の濃縮には、通常の
凝集沈澱法に代えて、沈降分離作用と充填材による凝集
作用とを相互補完的に行って効率良く洗浄排水を濃縮す
る接触材充填型凝集沈澱装置を採用することを着想し、
実験を重ねて本発明を完成するに到った。In order to economically post-process the washing wastewater, the present inventor concentrated the washing wastewater to take out sludge water having a high sludge concentration, and further separated the sludge from the sludge water. I thought it would be effective. By the way, conventional centrifugal concentrators and membrane concentrators have a relatively small installation area, but consume a large amount of energy, and conventional coagulation and sedimentation apparatuses require a large installation area. It is inconvenient. Further, in order to concentrate the washing wastewater on the basis of economical attractiveness using the above-mentioned rotary flat membrane or immersion membrane, a sludge concentration of several% is necessary,
Pretreatment of concentrating the washing wastewater to 100 times or more is necessary, which complicates the process and increases the cost.
These methods are also unsuitable as a method for concentrating washing wastewater. Therefore, the present inventor concluded that, instead of the usual coagulation and sedimentation method, the cleaning wastewater is concentrated by performing the sedimentation separation action and the coagulation action by the filler in a mutually complementary manner to efficiently concentrate the washing wastewater. Conceived to adopt a coagulating sedimentation device,
Through repeated experiments, the present invention has been completed.
【0009】上記目的を達成するために、本発明に係る
水処理装置は、被処理水を濾過膜により膜濾過し、被処
理水中の異物を濾過膜で捕捉しつつ処理水として透過水
を得る膜濾過工程と、濾過膜を洗浄水で洗浄して濾過膜
から捕捉された異物を剥離し、更に剥離した異物を含む
洗浄排水を排出する洗浄工程とを交互に行う膜濾過装置
を備えた水処理装置において、膜濾過装置から排出され
た洗浄排水を送水する送水手段と、洗浄排水に凝集剤を
添加する添加手段と、大きな空隙率を有する小片接触材
を集積させてなる接触材集積層を有し、凝集剤の添加さ
れた洗浄排水を導入して接触材集積層内を上向流で通水
し、洗浄排水中の懸濁物を凝集、分離して、洗浄排水を
清浄化し、一次処理水として流出すると共に分離した懸
濁物を含有する汚泥水を底部から流出させる凝集沈澱槽
とを有する凝集沈澱装置を備えることを特徴としてい
る。In order to achieve the above object, a water treatment apparatus according to the present invention filters water to be treated with a filtration membrane, and obtains permeated water as treated water while capturing foreign substances in the water to be treated by the filtration membrane. Water provided with a membrane filtration device for alternately performing a membrane filtration step and a washing step of washing the filtration membrane with washing water to separate foreign matters trapped from the filtration membrane and further discharging a washing wastewater containing the separated foreign matters. In the treatment device, a water supply means for supplying the cleaning wastewater discharged from the membrane filtration device, an addition means for adding a coagulant to the cleaning wastewater, and a contact material accumulation layer formed by accumulating small piece contact materials having a large porosity. The washing wastewater to which the coagulant has been added is introduced, the water flows through the contact material accumulation layer in an upward flow, the suspended matter in the washing wastewater is coagulated and separated, and the washing wastewater is purified, and Sewage discharged as treated water and containing separated suspension It is characterized in that it comprises a coagulation-sedimentation device and a coagulation-sedimentation tank to flow out of water from the bottom.
【0010】本水処理装置で処理する被処理水は、河川
水、湖沼水、ダム水、工業用水、下廃水処理水等であ
る。本発明で使用する膜濾過装置は、精密濾過膜(M
F)、限外濾過膜(UF)等の濾過膜を濾材として使用
し、洗浄水を使って濾過膜を洗浄することにより濾過膜
の濾過機能を回復する方式の膜濾過装置であれば良い。
濾過形式は、全量濾過式又はクロスフロー式のいずれで
も良い。また、濾過膜の材料は、例えばセラミック等の
無機系、或いはポリアクリルニトリル、酢酸セルロース
等の有機系のいずれでも良く、また濾過膜の構造は、チ
ューブ状、中空糸状、平膜状、スパイラル状のいずれで
も良い。The water to be treated by the present water treatment apparatus is river water, lake water, dam water, industrial water, sewage treated water, or the like. The membrane filtration device used in the present invention is a microfiltration membrane (M
F), a membrane filtration device of a type that uses a filtration membrane such as an ultrafiltration membrane (UF) as a filter medium and restores the filtration function of the filtration membrane by washing the filtration membrane with washing water.
The filtration type may be either a total filtration type or a cross flow type. The material of the filtration membrane may be any of inorganic materials such as ceramics or organic materials such as polyacrylonitrile and cellulose acetate. The structure of the filtration membrane may be tubular, hollow fiber, flat membrane, or spiral. Any of
【0011】本発明で洗浄排水の濃縮装置とした凝集沈
澱装置は、例えば出願人が特開平6−304411号公
報で開示しているような凝集沈澱装置であって、洗浄排
水を効率的に濃縮する。本凝集沈澱装置の主要部は、凝
集沈澱槽である。凝集沈澱槽は、沈降分離領域と、短尺
チューブ型接触材等の空隙率の大きな小片接触材を多数
ランダムに集積してなる層高が数10cmから数100cm
の接触材集積層を有する凝集沈澱領域とを有し、洗浄排
水は先ず沈降分離領域に流入し、次いで上向き流で凝集
沈澱領域を通水する。凝集沈澱槽に入る前に、洗浄排水
には凝集剤が添加されて、懸濁物が凝集しているので、
洗浄排水が流入した沈降分離領域で、先ず、大きな凝集
フロックが分離沈澱する。次いで、洗浄排水が凝集沈澱
領域を通過することにより、小さな流れ淀み領域が接触
材集積層内の接触材の下流領域に多数形成される。流れ
淀み領域内の懸濁物の顕著な凝集、沈澱作用により、洗
浄排水中に含まれる比較的大きな懸濁物(SS)が沈澱
し、更には、添加した凝集剤の凝集作用が助長されて、
懸濁物が集塊化し、懸濁物のフロックを形成して沈澱す
る。また、短尺チューブ型接触材の中空部及び短尺チュ
ーブ間に、懸濁物が付着、捕捉され、固液分離する。接
触材は、集積した状態で、接触材容積1m3 当たりの表
面積が200m2 以上、好ましくは300m2 以上にな
るような大きな空隙率と表面積を持つ内部中空状の接触
材が望ましく、例えば直径4〜12mm程度で長さが15
〜20mm程度のプラスチック製の短尺チューブ型の接触
材、内部が中空の球体で球面に多数の孔を穿った球型の
充填材、あるいはテラレットパッキン等を使用できる。The coagulating sedimentation apparatus used as the apparatus for concentrating the washing wastewater in the present invention is, for example, the coagulating sedimentation apparatus disclosed by the applicant in Japanese Patent Application Laid-Open No. 6-304411. I do. The main part of the present coagulation settling apparatus is a coagulation settling tank. The coagulating sedimentation tank has a sedimentation separation area and a layer height of several tens to several hundreds of centimeters formed by randomly accumulating a large number of small piece contact materials having a high porosity such as a short tube type contact material.
The washing wastewater first flows into the sedimentation / separation area, and then flows upward through the coagulation / sedimentation area. Before entering the coagulation sedimentation tank, a coagulant is added to the washing wastewater, and the suspension is coagulated.
First, large flocculated flocs are separated and settled in the settling separation area into which the washing wastewater flows. Next, a large number of small flow stagnation regions are formed in the downstream region of the contact material in the contact material accumulation layer as the washing wastewater passes through the coagulation sedimentation region. Due to the remarkable flocculation and sedimentation of the suspension in the flow stagnation region, a relatively large suspension (SS) contained in the washing wastewater precipitates, and the flocculation effect of the added flocculant is promoted. ,
The suspension agglomerates and precipitates forming flocs of the suspension. In addition, the suspension adheres and is trapped between the hollow portion of the short tube type contact material and the short tube, and solid-liquid separation is performed. The contact material is desirably an internal hollow contact material having a large porosity and surface area such that the surface area per 1 m 3 of the contact material volume is 200 m 2 or more, preferably 300 m 2 or more in an accumulated state. ~ 12mm and length 15
A short tube type contact material made of plastic having a size of about 20 mm, a spherical filler having a hollow spherical body and a large number of holes formed in a spherical surface, a teralet packing, or the like can be used.
【0012】凝集剤の種類には、制約はないが、経済性
及び無害性から無機系凝集剤、例えばアルミニウム系の
凝集剤を使用する。アルミニウム系の凝集剤の添加率
は、ALT比(洗浄排水濁度に対するアルミニウムの注
入量(mg/リットル)比)で0.001〜0.05の範
囲が適当である。The type of the coagulant is not limited, but an inorganic coagulant, for example, an aluminum coagulant is used from the viewpoint of economy and harmlessness. The addition rate of the aluminum-based flocculant is suitably in the range of 0.001 to 0.05 in terms of the ALT ratio (the ratio of the injection amount (mg / liter) of aluminum to the washing turbidity).
【0013】膜濾過装置から排出された洗浄排水を凝集
沈澱装置に送水する送水手段は、制約はなく、例えばポ
ンプ、膜濾過装置からの直接圧入、又は膜濾過装置との
高低差による自然流入等である。洗浄排水タンクを設
け、一旦貯水するようにしても良い。洗浄排水に凝集剤
を添加する添加手段は、既知の手段であって、例えば凝
集沈澱装置に送水する洗浄排水送水管に凝集剤溶液を添
加しても良く、また混合槽を設け、そこで洗浄排水と凝
集剤溶液と混合するようにしても良い。必要に応じて、
凝集剤添加手段と凝集沈澱装置の間に懸濁物の凝結ない
し凝集を促進する手段、例えばラインミキサー、攪拌機
付き急速混和槽等を設けても良い。汚泥水を処理して汚
泥水を更に濃縮する濃縮手段を水処理装置に設ける際に
は、濃縮手段に制約はなく、従来の濃縮手段、例えば遠
心分離器、プレス式脱水機、回転式平膜、浸漬式膜等の
機械的脱水機、或いは天日乾燥法、加熱乾燥法等を使用
できる。The water supply means for supplying the washing wastewater discharged from the membrane filtration device to the coagulation sedimentation device is not limited. For example, a pump, direct injection from the membrane filtration device, or natural inflow due to a height difference from the membrane filtration device, etc. It is. A washing and drainage tank may be provided to temporarily store water. The adding means for adding the coagulant to the washing wastewater is a known means, for example, a coagulant solution may be added to a washing drainage water pipe for sending water to the coagulating sedimentation apparatus, or a mixing tank is provided, where the washing drainage is provided. And a coagulant solution. If necessary,
A means for promoting coagulation or aggregation of the suspension, for example, a line mixer, a rapid mixing tank with a stirrer, or the like may be provided between the means for adding a flocculant and the apparatus for coagulation and precipitation. When the water treatment apparatus is provided with a concentration means for treating the sludge water and further concentrating the sludge water, there is no restriction on the concentration means, and the conventional concentration means, for example, a centrifuge, a press-type dehydrator, a rotary flat membrane A mechanical dehydrator such as a immersion type membrane, a solar drying method, a heat drying method, or the like can be used.
【0014】凝集沈澱槽での洗浄排水の上向流の通水速
度は、200m/日〜800m/日(8〜33m3/m2
/hr)、好ましくは、300m/日〜500m/日で
ある。凝集沈澱槽から流出する一次処理水中の懸濁物の
大きさは、おおよそ100μm 以下になる。逆に言え
ば、洗浄排水中の100μm 以上の懸濁物は、全て凝集
沈澱槽で捕捉されたことになる。本凝集沈澱装置は、従
来の高速凝集沈澱池等の2〜5m3/m2/hr程度の通
水速度に比べ、著しく高負荷で洗浄排水の濃縮処理がで
きるので、装置が小型化し、従って設置面積も小さい。
また、動力も殆ど必要としないので、従来の濃縮装置に
比べて運転費が嵩まない。The upward flow rate of the washing wastewater in the coagulating sedimentation tank is 200 m / day to 800 m / day (8 to 33 m 3 / m 2).
/ Hr), preferably from 300 m / day to 500 m / day. The size of the suspension in the primary treatment water flowing out of the coagulation sedimentation tank is about 100 μm or less. Conversely, all suspensions of 100 μm or more in the washing wastewater are captured in the coagulation sedimentation tank. The present coagulating sedimentation apparatus can concentrate the washing wastewater with a remarkably high load, compared with a conventional high-speed coagulating sedimentation basin or the like with a water flow rate of about 2 to 5 m 3 / m 2 / hr. The installation area is also small.
Further, since almost no power is required, the operation cost is not increased as compared with the conventional concentrator.
【0015】本発明では、凝集沈澱装置から流出した一
次処理水を被処理水と共に膜濾過装置に導入することに
より、従来は外部に排出していた洗浄排水から水を回収
し、水処理装置の水回収率を高めることもできる。In the present invention, the primary treated water flowing out of the coagulation and sedimentation device is introduced into the membrane filtration device together with the water to be treated, whereby the water is recovered from the washing wastewater which has conventionally been discharged to the outside, and the water treatment device is used. Water recovery can also be increased.
【0016】[0016]
【発明の実施の形態】以下に、添付図面を参照し、実施
例を挙げて、本発明の実施の形態を具体的かつ詳細に説
明する。実施例 本実施例は、本発明に係る水処理装置の実施例の一つで
あって、図1は本実施例の水処理装置の要部を構成する
凝集沈澱装置40の構成を示すフローシートである。本
実施例の水処理装置では、図4に示した膜濾過装置10
と、膜濾過装置10に付属させる凝集沈澱装置40とか
ら構成されている。膜濾過装置10の構成は、前述の通
りであって、ここでは説明を省略する。凝集沈澱装置4
0は、膜濾過装置10から流出した洗浄排水を濃縮する
装置であって、膜濾過装置10から出た洗浄排水を貯水
する洗浄排水タンク42、洗浄排水タンク42から洗浄
排水を送水する洗浄排水ポンプ44、凝集剤溶液を収容
する凝集剤溶液タンク46及び凝集剤溶液を送液する凝
集剤注入ポンプ48からなる凝集剤注入設備、薬品混和
槽50、並びに凝集沈澱槽52を備えている。更に、凝
集沈澱装置40は、凝集沈澱槽52の底部から排出した
汚泥水を収容する汚泥水タンク54、汚泥水を脱水して
固形分を分離、濃縮するプレス式脱水機56、及び、汚
泥水タンク54から脱水機56に汚泥水を送水する汚泥
水ポンプ58を備えている。Embodiments of the present invention will be described below in detail with reference to the accompanying drawings by way of examples. Embodiment This embodiment is one of embodiments of a water treatment apparatus according to the present invention, and FIG. 1 is a flow sheet showing a configuration of a coagulation / sedimentation apparatus 40 constituting a main part of the water treatment apparatus of this embodiment. It is. In the water treatment apparatus of the present embodiment, the membrane filtration device 10 shown in FIG.
And a coagulation / sedimentation device 40 attached to the membrane filtration device 10. The configuration of the membrane filtration device 10 is as described above, and the description is omitted here. Coagulation sedimentation device 4
Reference numeral 0 denotes a device for concentrating the washing wastewater flowing out of the membrane filtration device 10, a washing drainage tank 42 for storing the washing wastewater flowing out of the membrane filtration device 10, and a washing drainage pump for feeding the washing wastewater from the washing drainage tank 42. 44, a coagulant injecting facility including a coagulant solution tank 46 for accommodating a coagulant solution and a coagulant injecting pump 48 for feeding the coagulant solution, a chemical mixing tank 50, and a coagulating sedimentation tank 52. Further, the coagulation / sedimentation apparatus 40 includes a sludge water tank 54 for storing the sludge water discharged from the bottom of the coagulation / sedimentation tank 52, a press-type dehydrator 56 for dewatering the sludge water to separate and concentrate solids, and A sludge water pump 58 for feeding sludge water from the tank 54 to the dehydrator 56 is provided.
【0017】凝集剤溶液は、凝集剤溶液を貯液した凝集
剤タンク46から凝集剤注入ポンプ48によって薬品混
和槽50内の洗浄排水に注入される。薬品混和槽50
は、攪拌機60を備え、凝集沈澱槽52より高所に設置
された容器であって、洗浄排水を一次的に滞留させ、攪
拌機60により洗浄排水を攪拌しながら洗浄排水と凝集
剤とを急速混和させ、凝集剤と混和した洗浄排水を高低
差により流入管62を介して凝集沈澱槽52に流入させ
る。The coagulant solution is injected from the coagulant tank 46 storing the coagulant solution into the washing wastewater in the chemical mixing tank 50 by the coagulant injection pump 48. Chemical mixing tank 50
Is a container provided with a stirrer 60 and installed at a higher position than the coagulation sedimentation tank 52, in which washing wastewater is temporarily retained, and the washing wastewater and the flocculant are rapidly mixed while the washing wastewater is stirred by the stirrer 60. The washing wastewater mixed with the coagulant is caused to flow into the coagulation sedimentation tank 52 via the inflow pipe 62 at a height difference.
【0018】凝集沈澱槽52は、凝集剤添加によって洗
浄排水中に生成した微細凝集フロックを沈降分離、更に
凝集分離する槽であって、図2に示すように、下から、
順次、区画された洗浄排水の流入ゾーン64、接触材集
積ゾーン66、及び集水ゾーン68から構成されてい
る。接触材集積ゾーン66は、ゾーンの上部及び下部に
設けられた目板状の流出防止板70、72で区画され、
その間の領域に、図3に示すような空隙率の大きい短尺
チューブ形状の比較的比重の小さいプラスチック製小片
接触材74を多数収容し、洗浄排水の上向流により上部
流出防止板70の下に接触材集積層76を形成するよう
になっている。集水ゾーン68は、接触材集積ゾーン6
6を通過して処理された処理水を集水する領域であっ
て、接触材集積ゾーン66の流出防止板70の直ぐ上に
設けられた集水部78と、集水部78の上端から溢流す
る処理水を集める集水トラフ80と、集水トラフ80に
接続して処理水を流出させる流出管82とから構成され
ている。流出した処理水は、原水タンク12に戻され
る。The coagulation sedimentation tank 52 is a tank for sedimenting and separating and coagulating and separating fine flocculants generated in the washing wastewater by the addition of the coagulant. As shown in FIG.
The cleaning drain water inflow zone 64, the contact material accumulation zone 66, and the water collecting zone 68 are sequentially formed. The contact material accumulation zone 66 is defined by eyelet-shaped outflow prevention plates 70 and 72 provided at the upper and lower portions of the zone,
In the area between them, a large number of small-sized plastic contact members 74 having a relatively small specific gravity in the form of a short tube having a large porosity as shown in FIG. The contact material accumulation layer 76 is formed. The water collecting zone 68 is a contact material collecting zone 6
6 is a region for collecting the treated water that has passed through and treated, the water collecting portion 78 provided immediately above the outflow prevention plate 70 in the contact material accumulation zone 66, and an overflow from the upper end of the water collecting portion 78. It comprises a collecting trough 80 for collecting the flowing treated water, and an outflow pipe 82 connected to the collecting trough 80 and allowing the treated water to flow out. The treated water that has flowed out is returned to the raw water tank 12.
【0019】流入ゾーン64には、薬品混和槽50から
出た洗浄排水が流入管62を介して流入する。流入管6
2は、流入ゾーン64の中央に貫入し、先端に下向きの
開口を備えている。流入管62の開口の下方には、下向
きに流入した洗浄排水の向きを上方に変えるために、傘
を逆にした形状の変流板84が設けてある。また、流入
管62には、アルカリ剤注入管86が接続され、必要に
応じてアルカリ溶液を注入して洗浄排水のpHを調整す
るようになっている。流入ゾーン64の底部、即ち変流
板84の下方は、汚泥を集積するために逆円錐状に形成
された汚泥貯留ゾーン88として構成され、汚泥水を排
出する汚泥水管90がその最下部に接続されている。ま
た、流入ゾーン64の上部には、上方に向け空気を噴射
する空気ノズルを多数備えた空気供給管92が設けら
れ、空気ブロアー94で送入された空気を噴出して、接
触材集積ゾーン66の接触材74を攪拌洗浄するように
なっている。The washing drainage from the chemical mixing tank 50 flows into the inflow zone 64 via the inflow pipe 62. Inflow pipe 6
2 penetrates the center of the inflow zone 64 and has a downward opening at the tip. Below the opening of the inflow pipe 62, a current changing plate 84 having an inverted umbrella is provided in order to change the direction of the washing drainage that has flowed downward upward. Further, an alkali agent injection pipe 86 is connected to the inflow pipe 62, and an alkali solution is injected as needed to adjust the pH of the washing wastewater. The bottom of the inflow zone 64, that is, below the current plate 84, is configured as a sludge storage zone 88 formed in an inverted cone shape for accumulating sludge, and a sludge water pipe 90 for discharging sludge water is connected to the lowermost portion. Have been. Further, an air supply pipe 92 provided with a large number of air nozzles for injecting air upward is provided above the inflow zone 64. The air supply pipe 92 blows out the air fed in by the air blower 94 to form the contact material accumulation zone 66. Of the contact material 74 is stirred and washed.
【0020】凝集剤を添加された洗浄排水は、先ず、凝
集沈澱槽52の流入ゾーン64に流入する。流入ゾーン
64では、洗浄排水中の懸濁物が凝集して形成されたフ
ロックのうち比較的大きなフロックが、先ず、沈降分離
する。次いで、洗浄排水は接触材集積ゾーン66に流入
する。そこでは、洗浄排水中の残りの微細なフロック
が、流れ淀み領域で凝集沈澱したり、接触材と接触して
接触材表面に付着したり、あるいは接触材と接触材との
間隙に捕捉されたりして、洗浄排水から分離される。除
濁された処理水は上部の集水ゾーンから外部に流出す
る。特に、接触材集積ゾーン66では、流れ淀み領域が
接触材74の下流領域に多数形成され、流れよどみ領域
で懸濁物の顕著な凝集、沈澱作用が進行する。接触材に
付着した、あるいは接触材間に捕捉されたフロックは、
後続する微細フロックとの接触等によって徐々に成長
し、フロック径が大きくなって洗浄排水の上昇流速より
沈降速度が大きいフロックが形成されるに従って、この
フロックが洗浄排水の流れによって接触材から剥離し、
洗浄排水の流れに逆らって沈降して、汚泥貯留ゾーン8
8に堆積する。このように、洗浄排水中の懸濁物は、フ
ロックとして汚泥貯留ゾーン88に集積し、汚泥水管9
0により排出される。The washing wastewater to which the coagulant has been added first flows into the inflow zone 64 of the coagulation / sedimentation tank 52. In the inflow zone 64, relatively large flocs of flocs formed by agglomeration of suspended matter in the washing wastewater first settle and separate. Next, the washing wastewater flows into the contact material accumulation zone 66. There, the remaining fine flocs in the washing wastewater are coagulated and settled in the flow stagnation region, adhere to the contact material by contact with the contact material, or are trapped in the gap between the contact materials. And separated from the washing wastewater. The clarified treated water flows out from the upper water collection zone. In particular, in the contact material accumulation zone 66, a large number of flow stagnation regions are formed in the downstream region of the contact material 74, and remarkable flocculation and sedimentation of the suspension proceeds in the flow stagnation region. Flock that adheres to or is trapped between contact materials,
As the floc grows gradually due to the contact with the subsequent fine floc, etc., and the floc diameter increases and flocs whose sedimentation velocity is higher than the rising flow velocity of the cleaning drainage are formed, the floc separates from the contact material by the flow of the cleaning drainage. ,
Sludge is settled against the flow of washing wastewater, and sludge storage zone 8
8 is deposited. In this way, the suspended matter in the washing drainage is accumulated as flocs in the sludge storage zone 88, and the sludge water pipe 9
Discharged by 0.
【0021】以下に、膜濾過装置10と凝集沈澱装置4
0とからなる本実施例の水処理装置の運転方法について
説明する。先ず、膜濾過装置10を運転し、従来の膜濾
過装置と同様にして膜濾過工程を実施し、濾過膜の通水
差圧が所定圧力に上昇した時点で洗浄工程に移行する。
洗浄工程で流出した洗浄排水を洗浄排水タンク42に一
旦収容する。次いで、洗浄排水ポンプ44により洗浄排
水タンク42から薬品混和槽50に洗浄排水を送水しつ
つ凝集剤注入ポンプ48により凝集剤溶液を薬品混和槽
50に所定の添加率で注入する。洗浄排水は、薬品混和
槽50内で、所定時間、攪拌混和され、次いで流入管6
2を経て凝集沈澱槽52に流入する。凝集沈澱槽52で
は、凝集により集塊化した懸濁物を含めて洗浄排水中の
懸濁物が分離され、洗浄排水は、比較的微細な、例えば
100μm 以下の懸濁物のみを少量含有する処理水とな
って流出管82を経て原水タンク12に返る。一方、汚
泥水管90により排出された汚泥水は、一旦、汚泥水タ
ンク54に収容され、汚泥水ポンプ58によりプレス式
脱水機56に送られて脱水される。脱水の後に、含水率
の低い汚泥が得られる。プレス式脱水機56等の機械的
脱水機に代えて、汚泥水を天日乾燥処理しても良い。Hereinafter, the membrane filtration device 10 and the coagulation / sedimentation device 4
An operation method of the water treatment apparatus according to the present embodiment, which is 0, will be described. First, the membrane filtration device 10 is operated, the membrane filtration process is performed in the same manner as in the conventional membrane filtration device, and the process shifts to the washing process when the pressure difference in water passing through the filtration membrane rises to a predetermined pressure.
The washing wastewater that has flowed out in the washing process is temporarily stored in the washing wastewater tank 42. Next, the coagulant solution is injected into the chemical mixing tank 50 at a predetermined addition rate by the coagulant injection pump 48 while the cleaning drainage is supplied from the cleaning drain tank 42 to the chemical mixing tank 50 by the cleaning drain pump 44. The washing wastewater is stirred and mixed for a predetermined time in the chemical mixing tank 50, and then the inflow pipe 6
After that, it flows into the coagulation sedimentation tank 52. In the coagulation sedimentation tank 52, the suspension in the washing wastewater including the suspension agglomerated by aggregation is separated, and the washing wastewater contains only a relatively fine suspension, for example, a small amount of only a suspension of 100 μm or less. It returns to the raw water tank 12 through the outflow pipe 82 as treated water. On the other hand, the sludge water discharged from the sludge water pipe 90 is once stored in the sludge water tank 54 and sent to the press type dehydrator 56 by the sludge water pump 58 to be dewatered. After dewatering, sludge with a low moisture content is obtained. Instead of the mechanical dehydrator such as the press dehydrator 56, the sludge water may be subjected to solar drying.
【0022】長期間にわたり運転すると、凝集沈澱槽5
2の接触材74に懸濁物が堆積して、凝集沈澱機能が低
下するので、凝集沈澱槽52の洗浄が必要になる。凝集
沈澱槽52を洗浄するには、凝集沈澱槽52への洗浄排
水の送水を中止し、先ず、空気ブロワー94を起動し、
所定時間、空気供給管92のノズルから空気を噴出さ
せ、接触材集積層76の接触材を攪拌し、流動させる。
これにより、接触材に付着した懸濁物及び接触材の間に
捕捉されていた懸濁物は、接触材から分離する。次い
で、空気の噴射を停止し、放置すると、懸濁物は沈降し
て汚泥貯留ゾーン88に堆積する。次いで、汚泥水管9
0を開放して、堆積した汚泥を凝集沈澱槽52内の水と
一緒に排出する。排出水が懸濁物を高濃度で含むときに
は、通常の汚泥水と同様に処理し、排出水の懸濁物濃度
が低いときには、汚泥水管90から分岐した排出水管9
6により原水タンク12に送る。When operated for a long time, the coagulation settling tank 5
Since the suspended matter accumulates on the second contact material 74 and the coagulation sedimentation function is reduced, the coagulation sedimentation tank 52 needs to be washed. In order to wash the coagulation sedimentation tank 52, the supply of the washing wastewater to the coagulation sedimentation tank 52 is stopped, and first, the air blower 94 is activated,
For a predetermined time, air is jetted from the nozzle of the air supply pipe 92 to stir and flow the contact material of the contact material accumulation layer 76.
Thereby, the suspension adhered to the contact material and the suspension trapped between the contact materials are separated from the contact material. Then, the injection of air is stopped, and the suspension is settled and left to accumulate in the sludge storage zone 88. Next, the sludge water pipe 9
0 is released, and the accumulated sludge is discharged together with the water in the coagulation sedimentation tank 52. When the effluent contains suspended matter at a high concentration, it is treated in the same manner as ordinary sludge water. When the effluent has a low suspended matter concentration, the discharged water pipe 9 branched from the sludge water pipe 90 is used.
It is sent to the raw water tank 12 by 6.
【0023】実験例 膜濾過装置10と凝集沈澱装置40とからなる本実施例
の水処理装置と基本的に同じ構成の実験装置を以下の仕
様に従って作製し、原水の濾過処理、濾過膜の洗浄処理
及び洗浄排水の濃縮処理を以下の条件で行った。膜濾過装置10 モジュール:中空糸膜モジュール モジュールの本数:1本 モジュール1本当たりの有効濾過膜面積:50m2 濾過膜:分画分子量が150,000で膜材質が酢酸セ
ルロースのUF膜 通水流束:1.2m3 /m2 /日 EXPERIMENTAL EXAMPLE An experimental apparatus basically having the same configuration as the water treatment apparatus of the present embodiment, comprising the membrane filtration apparatus 10 and the coagulation / sedimentation apparatus 40, was manufactured according to the following specifications. The treatment and concentration treatment of the washing wastewater were performed under the following conditions. Membrane filtration device 10 modules: Hollow fiber membrane module Number of modules: 1 Effective filtration membrane area per module: 50 m 2 Filtration membrane: UF membrane with a cut-off molecular weight of 150,000 and membrane material of cellulose acetate Water flow : 1.2 m 3 / m 2 / day
【0024】凝集沈澱装置40 洗浄排水タンク42 材質:ポリエチレンタンク 有効容積:1.5m3 洗浄排水の滞留時間:6時間 急速混和槽50 材質:ポリエチレンタンク 有効容積:0.1m3 洗浄排水と凝集剤溶液の滞留時間:7.2分 凝集沈澱槽52 直径:150mm 断面積:0.0177m2 充填材集積層の層高:1.0m 通水速度:14.1m/h 通水流量:0.25m3 /h 汚泥水タンク54 材質:ポリエチレンタンク 有効容積:0.1m3 脱水機56 型式:片面ダイヤフラム式加圧脱水機 濾布面積:0.0209m2 圧入圧力:0.7Mpa 圧入時間:60分 圧搾圧力:1.5Mpa 圧搾時間:40分 Coagulating sedimentation device 40 Washing drainage tank 42 Material: polyethylene tank Effective volume: 1.5 m 3 Residence time of washing drainage: 6 hours Rapid mixing tank 50 Material: polyethylene tank Effective volume: 0.1 m 3 Washing drainage and flocculant Residence time of the solution: 7.2 minutes Coagulation sedimentation tank 52 Diameter: 150 mm Cross-sectional area: 0.0177 m 2 Layer height of the filler accumulation layer: 1.0 m Water flow rate: 14.1 m / h Water flow: 0.25 m 3 / h Sludge water tank 54 Material: Polyethylene tank Effective volume: 0.1 m 3 Dehydrator 56 Model: Single-sided diaphragm type pressure dehydrator Filter cloth area: 0.0209 m 2 Press-in pressure: 0.7 Mpa Press-in time: 60 minutes Pressing Pressure: 1.5Mpa Pressing time: 40 minutes
【0025】原水 水源:河川水 平均SS:カオリンを添加して22mg/lのSSに調
整 膜濾過装置10の運転条件 濾過方式:クロスフロー 水回収率:90%、従って洗浄水の水量は、原水の水量
の10%に相当凝集沈澱装置40で使用した凝集剤 種類:PAC(ポリ塩化アルミニウム) 添加率:18mgのPAC/リットル−洗浄排水(但
し、Al2 O3 濃度10%のPAC溶液として)Raw water Water source: river water Average SS: adjusted to 22 mg / l SS by adding kaolin Operating conditions of membrane filtration device 10 Filtration method: cross flow Water recovery: 90%, therefore, the amount of washing water is of 10% corresponds coagulating sedimentation apparatus 40 coagulant type was used in the water: PAC (polyaluminum chloride) addition rate: 18 mg of PAC / liter - detergent drain (however, the concentration of Al 2 O 3 of 10% PAC solution)
【0026】上記の条件で実験装置を運転し、原水、一
次処理水(凝集沈殿装置の処理水)、洗浄排水等のサン
プルを採取して、pH、水温、SS(mg/ l)、汚泥濃度
(%)を測定したところ、以下に示す結果を得た。 サンプル源 pH 水温(℃) SS(mg/ l) 汚泥濃度(%) 原水 7.7 18 20 − 洗浄排水 7.3 18 200 0.021 一次処理水 7.1 19 6 − 汚泥水 7.1 − 9.1 脱水汚泥 − − − 32.6The experimental apparatus was operated under the above conditions, and samples of raw water, primary treated water (treated water of the coagulation sedimentation apparatus), washing wastewater, etc. were collected, and pH, water temperature, SS (mg / l), sludge concentration were measured. (%), The following results were obtained. Sample source pH Water temperature (° C) SS (mg / l) Sludge concentration (%) Raw water 7.7 18 20-Washing wastewater 7.3 18 200 0.021 Primary treated water 7.1 196-Sludge water 7.1- 9.1 Dewatered sludge---32.6
【0027】本実施例では、洗浄排水を特定の凝集沈澱
装置により濃縮処理することにより、経済的に機械的脱
水処理又は天日乾燥処理できる汚泥濃度まで洗浄排水の
汚泥濃度を高めている。本実施例の凝集沈澱装置40
は、凝集沈澱作用と充填材による再凝集作用とを相互補
完して効率よく行うため、装置を小型化でき、しかも、
動力を必要としないので、従来の方法に比べて、洗浄排
水の濃縮処理を経済的に行うことができる。また、凝集
剤の添加率が低いので、経済的である。In the present embodiment, the concentration of the sludge in the washing wastewater is increased to a concentration that enables economical mechanical dehydration or solar drying by concentrating the washing wastewater with a specific coagulating sedimentation apparatus. The coagulating sedimentation device 40 of the present embodiment
Is effective in complementing the coagulation sedimentation action and the re-agglomeration action due to the filler, so that the apparatus can be miniaturized, and
Since no power is required, the concentration of the washing wastewater can be performed more economically than in the conventional method. In addition, since the addition rate of the coagulant is low, it is economical.
【0028】[0028]
【発明の効果】本発明によれば、沈降分離作用と凝集沈
澱作用とを相互補完的に行う特定の凝集沈澱装置を膜濾
過装置から流出した洗浄排水の濃縮装置として使用する
ことにより、機械的脱水法又は天日乾燥法により経済的
に汚泥を分離できる汚泥濃度にまで洗浄排水を濃縮する
ことができる。また、特定の凝集沈澱装置は、濃縮効率
が高いので、装置が小型化し、設置面積も小さくて済
む。凝集沈澱装置から流出した一次処理水を原水と共に
膜濾過装置に導入することにより、水処理装置の水回収
率を高めることができる。また、凝集剤の使用量が少な
いので、一次処理水を膜濾過装置に導入した場合にも、
膜濾過装置に対する影響を無視できる。According to the present invention, the use of a specific coagulation / sedimentation apparatus, which complementarily performs the sedimentation / separation action and the coagulation / sedimentation action, as a concentrator for the washing wastewater flowing out of the membrane filtration device, enables a mechanically efficient operation. The washing wastewater can be concentrated to a sludge concentration at which sludge can be economically separated by a dehydration method or a solar drying method. Further, the specific coagulation / sedimentation apparatus has a high concentration efficiency, so that the apparatus can be downsized and the installation area can be small. By introducing the primary treated water flowing out of the coagulation and sedimentation device together with the raw water into the membrane filtration device, the water recovery rate of the water treatment device can be increased. In addition, since the amount of the coagulant used is small, even when the primary treated water is introduced into the membrane filtration device,
The effect on the membrane filtration device is negligible.
【図1】凝集沈澱装置の構成を示すフローシートであ
る。FIG. 1 is a flow sheet showing a configuration of a coagulation / sedimentation apparatus.
【図2】凝集沈澱槽の構成を示す模式図である。FIG. 2 is a schematic diagram showing a configuration of a coagulation sedimentation tank.
【図3】接触材の斜視図である。FIG. 3 is a perspective view of a contact material.
【図4】膜濾過装置の構成を示すフローシートである。FIG. 4 is a flow sheet showing a configuration of a membrane filtration device.
10 膜濾過装置 12 被処理水タンク 14 被処理水ポンプ 16 中空糸膜モジュール 18 処理水タンク 20 洗浄水ポンプ 22 被処理水管 24 処理水管 26 濃縮水管 28 洗浄水管 30 洗浄排水管 40 凝集沈澱装置 42 洗浄排水タンク 44 洗浄排水ポンプ 46 凝集剤溶液タンク 48 凝集剤注入ポンプ 50 薬品混和槽 52 凝集沈澱槽 54 汚泥水タンク 56 プレス式脱水機 58 汚泥水ポンプ 60 攪拌機 62 流入管 64 流入ゾーン 66 接触材集積ゾーン 68 集水ゾーン 70、72 流出防止板 74 接触材 76 接触材集積層 78 集水部 80 集水トラフ 82 流出管 84 変流板 86 アルカリ剤注入管 88 汚泥貯留ゾーン 90 汚泥水管 92 空気供給管 94 空気ブロアー DESCRIPTION OF SYMBOLS 10 Membrane filtration apparatus 12 Treated water tank 14 Treated water pump 16 Hollow fiber membrane module 18 Treated water tank 20 Wash water pump 22 Treated water pipe 24 Treated water pipe 26 Concentrated water pipe 28 Wash water pipe 30 Wash drain pipe 40 Coagulation sedimentation apparatus 42 Cleaning Drain tank 44 Cleaning drain pump 46 Coagulant solution tank 48 Coagulant injection pump 50 Chemical mixing tank 52 Coagulation sedimentation tank 54 Sludge water tank 56 Press dehydrator 58 Sludge water pump 60 Stirrer 62 Inflow pipe 64 Inflow zone 66 Contact material accumulation zone 68 Water collecting zone 70, 72 Outflow prevention plate 74 Contact material 76 Contact material accumulation layer 78 Water collecting part 80 Water collecting trough 82 Outflow pipe 84 Current changing plate 86 Alkaline agent injection pipe 88 Sludge storage zone 90 Sludge water pipe 92 Air supply pipe 94 Air blower
Claims (2)
理水中の異物を濾過膜で捕捉しつつ処理水として透過水
を得る膜濾過工程と、濾過膜を洗浄水で洗浄して濾過膜
から捕捉された異物を剥離し、更に剥離した異物を含む
洗浄排水を排出する洗浄工程とを交互に行う膜濾過装置
を備えた水処理装置において、 膜濾過装置から排出された洗浄排水を送水する送水手段
と、 洗浄排水に凝集剤を添加する添加手段と、 大きな空隙率を有する小片接触材を集積させてなる接触
材集積層を有し、凝集剤の添加された洗浄排水を導入し
て接触材集積層内を上向流で通水し、洗浄排水中の懸濁
物を凝集、分離して、洗浄排水を清浄化し、一次処理水
として流出すると共に分離した懸濁物を含有する汚泥水
を底部から流出させる凝集沈澱槽とを有する凝集沈澱装
置を備えることを特徴とする水処理装置。1. A membrane filtration step in which water to be treated is subjected to membrane filtration by a filtration membrane, and foreign matter in the water to be treated is captured by the filtration membrane to obtain permeated water as treatment water, and the filtration membrane is washed with washing water for filtration. In a water treatment apparatus provided with a membrane filtration device that alternately performs a washing step of alternately performing a washing step of detaching foreign matter trapped from the membrane and further discharging a washing wastewater containing the detached foreign matter, supplying the washing wastewater discharged from the membrane filtration apparatus And a contact material accumulation layer formed by accumulating a small piece of contact material having a large porosity, and introducing the washing wastewater to which the flocculant is added. Sludge that flows through the contact material accumulation layer in an upward flow, agglomerates and separates suspended matter in the washing wastewater, cleans the washing wastewater, flows out as primary treatment water, and contains the separated suspended matter. Coagulation settling tank having coagulation settling tank for discharging water from bottom A water treatment device comprising a sedimentation device.
被処理水と共に膜濾過装置に導入するようにしたことを
特徴とする請求項1に記載の水処理装置。2. The water treatment apparatus according to claim 1, wherein the primary treatment water flowing out of the coagulation / sedimentation apparatus is introduced into the membrane filtration apparatus together with the water to be treated.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10117097A JPH10286565A (en) | 1997-04-18 | 1997-04-18 | Water treatment plant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10117097A JPH10286565A (en) | 1997-04-18 | 1997-04-18 | Water treatment plant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH10286565A true JPH10286565A (en) | 1998-10-27 |
Family
ID=14293554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10117097A Pending JPH10286565A (en) | 1997-04-18 | 1997-04-18 | Water treatment plant |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH10286565A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013046891A (en) * | 2011-08-29 | 2013-03-07 | Metawater Co Ltd | Outside-tank installation type membrane separation activated sludge method and activated sludge treatment apparatus |
| CN105198106A (en) * | 2015-09-23 | 2015-12-30 | 江苏省科建成套设备有限公司 | Integrated equipment for recycling technological drainage of tap water plant |
| CN108503068A (en) * | 2017-12-04 | 2018-09-07 | 上海昱清环保工程有限公司 | Novel agrochemical wastewater treatment equipment and method |
-
1997
- 1997-04-18 JP JP10117097A patent/JPH10286565A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013046891A (en) * | 2011-08-29 | 2013-03-07 | Metawater Co Ltd | Outside-tank installation type membrane separation activated sludge method and activated sludge treatment apparatus |
| CN105198106A (en) * | 2015-09-23 | 2015-12-30 | 江苏省科建成套设备有限公司 | Integrated equipment for recycling technological drainage of tap water plant |
| CN108503068A (en) * | 2017-12-04 | 2018-09-07 | 上海昱清环保工程有限公司 | Novel agrochemical wastewater treatment equipment and method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104245601B (en) | Method for treating a waste stream using a bioreactor and a membrane filter | |
| JPH11169609A (en) | Flocculating and settling apparatus | |
| CN114890595A (en) | Waste incineration fly ash washing filtrate treatment system and method | |
| JP4253353B1 (en) | Sludge dewatering method and system | |
| JP4408524B2 (en) | Fresh water system | |
| JP3948205B2 (en) | Suspension processing equipment | |
| KR101161327B1 (en) | Water purifying system for improving discharge water quality with membrane | |
| JP3640285B2 (en) | Coagulation sedimentation equipment | |
| CN102633378A (en) | Method and system for recycling catalyst from coal chemical liquid waste | |
| JPH11319414A (en) | Coagulator | |
| JP2911327B2 (en) | Method and apparatus for treating water containing turbid components | |
| CN213266050U (en) | Coal-containing sewage treatment system | |
| KR20140081552A (en) | Submerged membrane apparatus and method for purifying water | |
| KR101064559B1 (en) | Water treatment sludge concentration and dewatering method and apparatus | |
| JPH10202010A (en) | Water treatment device | |
| JP5149133B2 (en) | Apparatus and method for concentrating backwash wastewater from membrane filtration | |
| JP4129479B1 (en) | Sludge treatment method and treatment system | |
| JP3891739B2 (en) | Operation method of membrane filtration device | |
| JP5481654B2 (en) | Sludge treatment method and treatment system | |
| JP2008279339A (en) | Solid-liquid separator | |
| JP3697529B2 (en) | Membrane-based wastewater treatment method and water purification apparatus | |
| JPH1119696A (en) | Sludge drainage treatment method and water purification treatment device | |
| KR20170007629A (en) | System for processing backwashed water of membrance filtration using pressure flotation | |
| JP3872918B2 (en) | Coagulation sedimentation apparatus and operation method thereof | |
| CN211871487U (en) | A filtration and clarification system for supernatant after precipitation treatment of landfill leachate |