JPH10508318A - モルホリンの選択的な分離方法 - Google Patents

モルホリンの選択的な分離方法

Info

Publication number: JPH10508318A
Authority: JP; Japan
Prior art keywords: morpholine; methylmorpholine; nmmo; cation exchanger; aqueous solution
Prior art date: 1995-08-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

JP9508733A

Other languages

English (en)

Japanese (ja)

Inventor

マンゲング、ブルノ

メンナー、ヨハン

フィルゴ、ハインリッヒ

Original Assignee

レンツィングアクチェンゲゼルシャフト

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-08-18

Filing date

1996-08-16

Publication date

1998-08-18

1996-08-16 Application filed by レンツィングアクチェンゲゼルシャフト filed Critical レンツィングアクチェンゲゼルシャフト

1998-08-18 Publication of JPH10508318A publication Critical patent/JPH10508318A/ja

Status Ceased legal-status Critical Current

Links

YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 title claims abstract description 84
238000000034 method Methods 0.000 title claims abstract description 54
238000000926 separation method Methods 0.000 title description 7
SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims abstract description 96
150000001768 cations Chemical class 0.000 claims abstract description 30
239000007864 aqueous solution Substances 0.000 claims abstract description 19
LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 claims abstract description 6
150000001412 amines Chemical class 0.000 claims description 34
239000000243 solution Substances 0.000 claims description 25
238000007254 oxidation reaction Methods 0.000 claims description 16
230000003647 oxidation Effects 0.000 claims description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
230000001590 oxidative effect Effects 0.000 claims description 6
150000002978 peroxides Chemical class 0.000 claims description 6
229910052698 phosphorus Inorganic materials 0.000 claims description 6
239000011574 phosphorus Substances 0.000 claims description 6
230000005855 radiation Effects 0.000 claims description 6
239000007800 oxidant agent Substances 0.000 claims description 5
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
238000010521 absorption reaction Methods 0.000 claims description 2
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 2
229910052753 mercury Inorganic materials 0.000 claims description 2
125000000542 sulfonic acid group Chemical group 0.000 claims description 2
238000005341 cation exchange Methods 0.000 abstract description 3
ZKXDGKXYMTYWTB-UHFFFAOYSA-N N-nitrosomorpholine Chemical compound O=NN1CCOCC1 ZKXDGKXYMTYWTB-UHFFFAOYSA-N 0.000 description 20
229920002678 cellulose Polymers 0.000 description 11
239000001913 cellulose Substances 0.000 description 11
238000012545 processing Methods 0.000 description 11
238000004519 manufacturing process Methods 0.000 description 9
238000001556 precipitation Methods 0.000 description 9
239000000126 substance Substances 0.000 description 9
239000002253 acid Substances 0.000 description 8
150000003512 tertiary amines Chemical class 0.000 description 7
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000002351 wastewater Substances 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000007788 liquid Substances 0.000 description 4
238000000354 decomposition reaction Methods 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
239000000203 mixture Substances 0.000 description 3
150000004005 nitrosamines Chemical class 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
239000000047 product Substances 0.000 description 3
230000001172 regenerating effect Effects 0.000 description 3
230000000717 retained effect Effects 0.000 description 3
238000001223 reverse osmosis Methods 0.000 description 3
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
101700012268 Holin Proteins 0.000 description 2
241000907681 Morpho Species 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
230000008033 biological extinction Effects 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000003480 eluent Substances 0.000 description 2
239000000835 fiber Substances 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
238000004128 high performance liquid chromatography Methods 0.000 description 2
BQJCRHHNABKAKU-KBQPJGBKSA-N morphine Chemical compound O([C@H]1[C@H](C=C[C@H]23)O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4O BQJCRHHNABKAKU-KBQPJGBKSA-N 0.000 description 2
238000000465 moulding Methods 0.000 description 2
XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
QEVHRUUCFGRFIF-MDEJGZGSSA-N reserpine Chemical compound O([C@H]1[C@@H]([C@H]([C@H]2C[C@@H]3C4=C(C5=CC=C(OC)C=C5N4)CCN3C[C@H]2C1)C(=O)OC)OC)C(=O)C1=CC(OC)=C(OC)C(OC)=C1 QEVHRUUCFGRFIF-MDEJGZGSSA-N 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
230000008961 swelling Effects 0.000 description 2
239000010409 thin film Substances 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
OURXRFYZEOUCRM-UHFFFAOYSA-N 4-hydroxymorpholine Chemical compound ON1CCOCC1 OURXRFYZEOUCRM-UHFFFAOYSA-N 0.000 description 1
206010073306 Exposure to radiation Diseases 0.000 description 1
229920000433 Lyocell Polymers 0.000 description 1
150000001204 N-oxides Chemical class 0.000 description 1
IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
229960005070 ascorbic acid Drugs 0.000 description 1
235000010323 ascorbic acid Nutrition 0.000 description 1
239000011668 ascorbic acid Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000008380 degradant Substances 0.000 description 1
239000007857 degradation product Substances 0.000 description 1
238000013461 design Methods 0.000 description 1
230000008034 disappearance Effects 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000010828 elution Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000010408 film Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000007429 general method Methods 0.000 description 1
239000004519 grease Substances 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
RLZZZVKAURTHCP-UHFFFAOYSA-N phenanthrene-3,4-diol Chemical compound C1=CC=C2C3=C(O)C(O)=CC=C3C=CC2=C1 RLZZZVKAURTHCP-UHFFFAOYSA-N 0.000 description 1
229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000004445 quantitative analysis Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000012465 retentate Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
230000002000 scavenging effect Effects 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
- C07D295/28—Nitrogen atoms

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Physical Water Treatments (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP9508733A 1995-08-18 1996-08-16 モルホリンの選択的な分離方法 Ceased JPH10508318A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
AT1403/95		1995-08-18
AT140395A AT403297B (de)	1995-08-18	1995-08-18	Verfahren zur selektiven abtrennung von morpholin
PCT/AT1996/000146 WO1997007108A1 (de)	1995-08-18	1996-08-16	Verfahren zur selektiven abtrennung von morpholin

Publications (1)

Publication Number	Publication Date
JPH10508318A true JPH10508318A (ja)	1998-08-18

Family

ID=3513141

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP9508733A Ceased JPH10508318A (ja)	1995-08-18	1996-08-16	モルホリンの選択的な分離方法

Country Status (9)

Country	Link
EP (1)	EP0783497A1 (de)
JP (1)	JPH10508318A (de)
CN (1)	CN1071750C (de)
AT (1)	AT403297B (de)
AU (1)	AU700207B2 (de)
BR (1)	BR9606585A (de)
CA (1)	CA2202153A1 (de)
NO (1)	NO310572B1 (de)
WO (1)	WO1997007108A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2024524500A (ja) *	2021-07-02	2024-07-05	ビー－エフシーティーエルカンパニーリミテッド	Ｎｍｍｏの精製方法、システムおよび得られたｎｍｍｏ水和物結晶

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19842556C2 (de) *	1998-09-17	2003-02-06	Alceru Schwarza Gmbh	Verfahren zur Herstellung von cellulosischen Formkörpern
JP2021518334A (ja) *	2018-03-15	2021-08-02	ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆＳｅ	メトキシエタノールとモルホリンとを含有する混合物からのメトキシエタノールの除去方法
CN110563669A (zh) *	2019-10-09	2019-12-13	四川鸿鹏新材料有限公司	一种提高吗啉纯度的方法及装置
CN112480035A (zh) *	2020-10-28	2021-03-12	华茂伟业绿色科技股份有限公司	N-甲基吗啉及其纯化方法、氧化甲基吗啉及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DD254199B5 (de) *	1986-12-04	1994-01-05	Thueringische Faser Ag Schwarz	Verfahren zur reinigung waessriger n-methylmorpholin-n-oxyd-loesungen
DD259863A1 (de) *	1987-04-06	1988-09-07	Schwarza Chemiefaser	Verfahren zur herstellung waessriger, reiner n-methylmorpholin-n-oxid-loesungen
DD274435B5 (de) *	1988-08-02	1996-10-31	Thueringisches Inst Textil	Verfahren zur Rueckgewinnung von N-Methylmorpholin-N-Oxid
AT393114B (de) *	1989-06-08	1991-08-26	Chemiefaser Lenzing Ag	Verfahren zur abtrennung von aminen
AT392915B (de) *	1990-03-28	1991-07-10	Chemiefaser Lenzing Ag	Verfahren zum abtrennen von wasser aus einer verduennten waesserigen loesung von n-methylmorpholin-n-oxid, n-methylmorpholin und/oder morpholin

1995
- 1995-08-18 AT AT140395A patent/AT403297B/de not_active IP Right Cessation
1996
- 1996-08-16 WO PCT/AT1996/000146 patent/WO1997007108A1/de not_active Ceased
- 1996-08-16 CA CA 2202153 patent/CA2202153A1/en not_active Abandoned
- 1996-08-16 CN CN96191128A patent/CN1071750C/zh not_active Expired - Fee Related
- 1996-08-16 JP JP9508733A patent/JPH10508318A/ja not_active Ceased
- 1996-08-16 EP EP96926960A patent/EP0783497A1/de not_active Ceased
- 1996-08-16 BR BR9606585A patent/BR9606585A/pt not_active Application Discontinuation
- 1996-08-16 AU AU66954/96A patent/AU700207B2/en not_active Ceased
1997
- 1997-04-17 NO NO19971753A patent/NO310572B1/no not_active IP Right Cessation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2024524500A (ja) *	2021-07-02	2024-07-05	ビー－エフシーティーエルカンパニーリミテッド	Ｎｍｍｏの精製方法、システムおよび得られたｎｍｍｏ水和物結晶

Also Published As

Publication number	Publication date
CN1071750C (zh)	2001-09-26
WO1997007108A1 (de)	1997-02-27
CN1165514A (zh)	1997-11-19
NO971753L (no)	1997-04-17
CA2202153A1 (en)	1997-02-27
AT403297B (de)	1997-12-29
NO310572B1 (no)	2001-07-23
AU6695496A (en)	1997-03-12
EP0783497A1 (de)	1997-07-16
BR9606585A (pt)	1997-10-28
ATA140395A (de)	1997-05-15
AU700207B2 (en)	1998-12-24
NO971753D0 (no)	1997-04-17

Legal Events

Date	Code	Title	Description
2007-06-05	A131	Notification of reasons for refusal	Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20070605
2007-06-07	A977	Report on retrieval	Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20070522
2007-06-11	A977	Report on retrieval	Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20070529
2007-11-15	A313	Final decision of rejection without a dissenting response from the applicant	Free format text: JAPANESE INTERMEDIATE CODE: A313 Effective date: 20071024
2007-12-11	A02	Decision of refusal	Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20071211

Publication	Publication Date	Title
EP0615556B1 (de)	1998-03-18	Verfahren zur reinigung wässriger lösungenvon amine-n-oxiden
US5602247A (en)	1997-02-11	Process for the purification of aqueous solutions of tertiary amine-oxides
CN115557917A (zh)	2023-01-03	N-甲基吗啉-n-氧化物的纯化方法、系统及得到的n-甲基吗啉-n-氧化物
JPH10508318A (ja)	1998-08-18	モルホリンの選択的な分離方法
CA2202625A1 (en)	1997-02-27	Process for purifying a tertiary aminoxide aqueous solution
US5611932A (en)	1997-03-18	Method for the purification of reclaimed aqueous N-methylmorpholine N-oxide solution
CN1140459C (zh)	2004-03-03	除去n－亚硝基吗啉的方法及其应用
JPS60118704A (ja)	1985-06-26	ゴムの精製法
JP3849724B2 (ja)	2006-11-22	高純度過酸化水素水の製造方法
JPH10507490A (ja)	1998-07-21	アミンオキサイドプロセスからの水性処理液を再利用するためのプロセス
US6113799A (en)	2000-09-05	Process for selective separation of morpholine
US5847129A (en)	1998-12-08	Process for the regeneration of an aqueous process liquid of the amine-oxide process
US5904818A (en)	1999-05-18	Process for the regeneration of an aqueous process liquid of the amine-oxide process
CN1122125C (zh)	2003-09-24	氧化叔胺水溶液的处理或纯化方法
CN1196762A (zh)	1998-10-21	制备n－甲基吗啉－n－氧化物水溶液的方法
KR100214189B1 (ko)	1999-08-02	N-메틸몰포린-n-옥사이드 수용액의 탈색 정제 방법
JPH07126912A (ja)	1995-05-16	Ｎ−メチルモルホリン−ｎ−オキシド水溶液の精製方法
JPS59163366A (ja)	1984-09-14	カプロラクタムの精製方法
JPS6038B2 (ja)	1985-01-05	リフアマイシンｓの製法
JPS632944B2 (de)	1988-01-21

JPH10508318A - モルホリンの選択的な分離方法 - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (3)

Publications (1)

Family

ID=3513141

Family Applications (1)

Country Status (9)

Cited By (1)

Families Citing this family (4)

Family Cites Families (5)

Cited By (1)

Also Published As

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