JPH1086276A - Composite decorative material and its production - Google Patents
Composite decorative material and its productionInfo
- Publication number
- JPH1086276A JPH1086276A JP26258196A JP26258196A JPH1086276A JP H1086276 A JPH1086276 A JP H1086276A JP 26258196 A JP26258196 A JP 26258196A JP 26258196 A JP26258196 A JP 26258196A JP H1086276 A JPH1086276 A JP H1086276A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- paper
- vinyl chloride
- impregnated
- decorative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 32
- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title description 4
- 229920005989 resin Polymers 0.000 claims abstract description 40
- 239000011347 resin Substances 0.000 claims abstract description 40
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052751 metal Inorganic materials 0.000 claims abstract description 25
- 239000002184 metal Substances 0.000 claims abstract description 25
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 17
- 239000000853 adhesive Substances 0.000 claims abstract description 17
- 230000001070 adhesive effect Effects 0.000 claims abstract description 17
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 15
- 239000005011 phenolic resin Substances 0.000 claims abstract description 13
- 239000004640 Melamine resin Substances 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002344 surface layer Substances 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 5
- 239000002537 cosmetic Substances 0.000 claims description 2
- 238000003475 lamination Methods 0.000 claims description 2
- 235000019504 cigarettes Nutrition 0.000 abstract description 11
- 229920001577 copolymer Polymers 0.000 abstract description 3
- 238000010030 laminating Methods 0.000 abstract description 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000123 paper Substances 0.000 description 35
- 238000005299 abrasion Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000004641 Diallyl-phthalate Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- CBECDWUDYQOTSW-UHFFFAOYSA-N 2-ethylbut-3-enal Chemical compound CCC(C=C)C=O CBECDWUDYQOTSW-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- JTHNLKXLWOXOQK-UHFFFAOYSA-N n-propyl vinyl ketone Natural products CCCC(=O)C=C JTHNLKXLWOXOQK-UHFFFAOYSA-N 0.000 description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 229920003987 resole Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- VJFPVACZAZLCCM-UAIGNFCESA-N (z)-but-2-enedioic acid;chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C.OC(=O)\C=C/C(O)=O VJFPVACZAZLCCM-UAIGNFCESA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101000663183 Homo sapiens Scavenger receptor class F member 1 Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 102100037081 Scavenger receptor class F member 1 Human genes 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
Landscapes
- Phenolic Resins Or Amino Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、耐シガレット性及び耐
摩耗性に優れた複合化粧材とその製法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composite decorative material excellent in cigarette resistance and abrasion resistance and a method for producing the same.
【０００２】[0002]
【従来の技術】従来、化粧材としては塩化ビニル樹脂製
タイルや壁装材などの様に、熱可塑性樹脂からなる押出
成形品やフィルム状基材に印刷した化粧シートがあっ
た。2. Description of the Related Art Heretofore, as a decorative material, there has been an extruded product made of a thermoplastic resin, such as a vinyl chloride resin tile or a wall covering material, or a decorative sheet printed on a film-like base material.
【０００３】また、メラミン化粧板やダップ化粧板の如
く、熱硬化性樹脂をコア紙、化粧紙、オーバレイ紙など
の多孔質基材に含浸したプリプレグを加熱圧着積層した
熱硬化性樹脂化粧板も知られている。[0003] Further, such as a melamine decorative board or a dup decorative board, a thermosetting resin decorative board in which a prepreg in which a thermosetting resin is impregnated into a porous base material such as core paper, decorative paper, overlay paper or the like is heat-pressed and laminated. Are known.
【０００４】近年、主に床材として、塩化ビニル樹脂タ
イルの耐シガレット性、耐摩耗性を向上させるために、
塩化ビニル樹脂タイルの表面にメラミン樹脂、ジアリル
フタレート樹脂、紫外線硬化樹脂などの熱硬化性樹脂を
含浸あるいはコーティングした化粧紙を接着剤を介して
表面に接合した複合床材も検討されている。In recent years, mainly as a floor material, in order to improve the cigarette resistance and abrasion resistance of a vinyl chloride resin tile,
A composite floor material in which decorative paper in which the surface of a vinyl chloride resin tile is impregnated or coated with a thermosetting resin such as a melamine resin, a diallyl phthalate resin, and an ultraviolet curable resin is bonded to the surface via an adhesive is also being studied.
【０００５】[0005]
【発明が解決しようとする課題】塩化ビニル樹脂タイル
の表面に、ダップ樹脂を含浸した化粧紙、あるいは紫外
線硬化樹脂をコーティングした化粧層を積層成形した化
粧材は、メラミン系樹脂含浸化粧紙を積層成形した化粧
材に比べて、耐摩耗性、耐シガレット性に劣るものであ
った。The decorative material obtained by laminating a decorative paper impregnated with a DAP resin or a decorative layer coated with an ultraviolet curable resin on the surface of a vinyl chloride resin tile is laminated with a melamine resin impregnated decorative paper. The abrasion resistance and the cigarette resistance were inferior to the molded decorative material.
【０００６】一方、塩化ビニル樹脂タイルの表面に、透
明性と耐熱性の優れているメラミン樹脂含浸化粧紙を熱
圧積層した化粧材は、耐シガレット性、耐摩耗性、耐汚
染性などの表面物性が、ダップ樹脂含浸化粧積層板や紫
外線硬化樹脂コーティング化粧材よりは優れているが、
床材などに使用して経時後で、表面が摩耗した状態で、
火の付いたタバコを表面に放置したりすると、表面が焼
けて黒くなり、取り除くことができず、表面外観を著し
く損ねた。On the other hand, a decorative material obtained by hot-press laminating a melamine resin impregnated decorative paper having excellent transparency and heat resistance on the surface of a vinyl chloride resin tile has a surface having cigarette resistance, abrasion resistance, stain resistance and the like. Physical properties are better than DAP resin impregnated decorative laminate and UV curable resin coating decorative material,
After a long time using the floor material, etc., with the surface worn out,
When a lit cigarette was left on the surface, the surface was burnt and blackened, and could not be removed, significantly impairing the surface appearance.
【０００７】また、塩化ビニル樹脂基材と熱硬化性樹脂
プリプレグとの密着性が悪く、耐シガレット性試験後や
荷重試験後に接合界面で剥離してふくれが生じたりし
た。Further, the adhesion between the vinyl chloride resin base material and the thermosetting resin prepreg was poor, and peeling occurred at the joining interface after a cigarette resistance test or a load test, causing blistering.
【０００８】本発明の目的は、塩化ビニル樹脂基材と表
面層の熱硬化性樹脂含浸化粧紙との密着性の改良と、メ
ラミン系樹脂含浸化粧紙層の表面摩耗後の耐シガレット
性を改良する複合化粧材とその製法を提供することにあ
る。It is an object of the present invention to improve the adhesion between a vinyl chloride resin substrate and a thermosetting resin-impregnated paper having a surface layer, and to improve the cigarette resistance of a melamine resin-impregnated decorative paper layer after surface wear. And a method of manufacturing the same.
【０００９】[0009]
【課題を解決するための手段】本発明は、塩化ビニル樹
脂基材と表面層の熱硬化性樹脂含浸紙との間に金属シー
トを介在積層したことを特徴とする複合化粧材である。The present invention is a composite decorative material characterized in that a metal sheet is interposed and laminated between a vinyl chloride resin substrate and a thermosetting resin-impregnated paper as a surface layer.
【００１０】また、表面層がメラミン樹脂含浸紙である
上記の複合化粧材である。[0010] The composite decorative material according to the above, wherein the surface layer is a melamine resin-impregnated paper.
【００１１】また、塩化ビニル樹脂基材と表面層の熱硬
化性樹脂含浸紙との間に金属シートを介在させるのにブ
チラール−フェノール樹脂系接着剤を使用して熱圧積層
することを特徴とする複合化粧材の製法である。[0011] The present invention is characterized in that a butyral-phenol resin-based adhesive is used for hot-press lamination for interposing a metal sheet between a vinyl chloride resin base material and a thermosetting resin-impregnated paper as a surface layer. This is a method of producing a composite cosmetic material.
【００１２】本発明での塩化ビニル樹脂基材とは、硬
質、半硬質、軟質いずれでもよく、また再生塩化ビニル
でもよく、シート状で厚さ０．５〜３．０mmのものが適
当である。また、補強材として、ガラス繊維、増量剤と
して炭酸カルシウム、クレー、タルクなどを使用した通
常の塩化ビニルタイルのことをいう。The vinyl chloride resin substrate in the present invention may be any of hard, semi-hard and soft, and may be recycled vinyl chloride, and a sheet-like one having a thickness of 0.5 to 3.0 mm is suitable. . Also, it refers to a normal vinyl chloride tile using glass fiber as a reinforcing material and calcium carbonate, clay, talc or the like as a filler.
【００１３】また、熱硬化性樹脂含浸紙とは、メラミン
樹脂、フェノール樹脂、ジアリルフタレート樹脂、不飽
和ポリエステル樹脂など熱硬化性樹脂を、セルロース
紙、印刷チタン紙、クラフト紙などに含浸してオーバレ
イ含浸紙、パターン含浸紙、コア含浸紙などとして使用
される通常の熱硬化性樹脂化粧積層板に使用されるプリ
プレグのことをいう。[0013] Thermosetting resin impregnated paper refers to an overlay obtained by impregnating a thermosetting resin such as a melamine resin, a phenol resin, a diallyl phthalate resin, and an unsaturated polyester resin into cellulose paper, printed titanium paper, kraft paper, or the like. It refers to a prepreg used for an ordinary thermosetting resin decorative laminate used as an impregnated paper, a pattern impregnated paper, a core impregnated paper, and the like.
【００１４】次に、金属シートとしては、アルミニウム
シートが放熱性、腐食性、密着性の点で望ましいが、ス
テンレス、銅、アルミ合金、鉛等の金属シート、あるい
は、金属微粉末をバインダー樹脂によりシート化したも
のを用いてもよい。厚さとしては５μm以上であればよ
く、通常は１０μm〜２００μm程度が望ましい。Next, as the metal sheet, an aluminum sheet is preferable in terms of heat dissipation, corrosion, and adhesion. However, a metal sheet of stainless steel, copper, aluminum alloy, lead, or the like, or a metal fine powder is mixed with a binder resin. A sheet may be used. The thickness may be 5 μm or more, and usually about 10 μm to 200 μm is desirable.
【００１５】また、樹脂含浸紙と金属シートとの密着性
向上剤（プライマー）として使用するブチラール−フェ
ノール樹脂系接着剤（シート）とは、市販のビニルブチ
ラール樹脂とレゾールタイプのフェノール樹脂との混合
物で、アルファ−セルロースを主体とする紙類などに含
浸乾燥したプリプレグを接着シートとして使用されるこ
ともある。A butyral-phenol resin-based adhesive (sheet) used as an adhesion improver (primer) between a resin-impregnated paper and a metal sheet is a mixture of a commercially available vinyl butyral resin and a resol type phenol resin. In some cases, a prepreg obtained by impregnating and drying papers mainly containing alpha-cellulose is used as an adhesive sheet.
【００１６】また、塩化ビニル樹脂と金属シートとの密
着性向上剤（プライマー）として使用する塩化ビニル用
プライマーとしては、塩化ビニル共重合体で、例えば、
塩化ビニル−酢酸ビニル共重合体、塩化ビニル−酢酸ビ
ニル−ビニルアルコール三元重合体、塩化ビニル−酢酸
ビニル−マレイン酸三元重合体などの樹脂をＭＥＫやト
ルエンなどの有機溶剤で溶解して使用される。また、欠
膠防止のために、微粉末シリカ、炭カル、クレーなどの
フィラーを添加することもある。The primer for vinyl chloride used as an adhesion improver (primer) between the vinyl chloride resin and the metal sheet is a vinyl chloride copolymer.
Resins such as vinyl chloride-vinyl acetate copolymer, vinyl chloride-vinyl acetate-vinyl alcohol terpolymer, and vinyl chloride-vinyl acetate-maleic acid terpolymer are dissolved and used in an organic solvent such as MEK or toluene. Is done. In addition, a filler such as finely divided silica, charcoal, clay or the like may be added in order to prevent deficiency.
【００１７】本発明の複合化粧材の製法としては、上記
の塩化ビニル樹脂基材、金属シート、熱硬化性樹脂含浸
紙を必須構成分として、表面層はメラミン樹脂含浸紙、
必要に応じて、塩化ビニル用接着プライマー、金属シー
ト用接着プライマー、金属シート用接着シートなどを使
用して、表１または図１に示す如き構成に積層して、加
熱加圧して一体化する。加熱加圧は、周知のホットプレ
スなどの加熱、加圧手段を用いて、圧力が１０〜１００
Kg/cm2、温度が１００〜１５０℃、時間が１０〜３０分
程度の条件で行われる。As a method for producing the composite decorative material of the present invention, the above-mentioned vinyl chloride resin base material, metal sheet and thermosetting resin impregnated paper are essential components, and the surface layer is a melamine resin impregnated paper.
If necessary, an adhesive primer for vinyl chloride, an adhesive primer for a metal sheet, an adhesive sheet for a metal sheet, or the like is used and laminated in a configuration as shown in Table 1 or FIG. 1, and integrated by heating and pressing. The heating and pressurizing is performed by using a heating and pressurizing means such as a known hot press, and the pressure is 10 to 100.
Kg / cm 2 , temperature is 100 to 150 ° C., and time is about 10 to 30 minutes.
【００１８】[0018]
【実施例】以下、表１及び図面に示す実施例により説明
する。 実施例１、２及び比較例１、２、３ 本発明に係る複合化粧材の構成を表１に○は使用、×は
不使用として示し、実施例１の構成断面図を図１に示
す。また、各符号はそれぞれ次のものを示す。The present invention will be described below with reference to examples shown in Table 1 and the drawings. Examples 1 and 2 and Comparative Examples 1, 2, and 3 The composition of the composite decorative material according to the present invention is shown in Table 1 as "O" used and "X" not used, and a cross-sectional view of the composition of Example 1 is shown in FIG. Further, each symbol indicates the following.
【００１９】１．塩化ビニル樹脂基材（塩ビ基材）。 塩化ビニル樹脂基材としては、厚さ２．０mm軟質塩化ビ
ニル樹脂シートを使用する。そして、上面（金属シート
載置面）に下記２．に記載の塩化ビニル用接着プライマ
ー（塩ビ用プライマー）を約２０g/m2（固形分換算値）
塗布して乾燥させた。1. Vinyl chloride resin base material (PVC base material). As the vinyl chloride resin base material, a soft vinyl chloride resin sheet having a thickness of 2.0 mm is used. Then, on the upper surface (metal sheet placement surface), About 20 g / m 2 (solid content equivalent) of the vinyl chloride adhesive primer (PVC primer)
Coated and dried.
【００２０】２．塩化ビニル用接着プライマー（塩ビ用
プライマー）。 塩化ビニル−酢酸ビニル−ビニルアルコール共重合体と
微粉末シリカとの混合物を溶剤に分散したもの。2. Adhesive primer for vinyl chloride (primer for PVC). A mixture of a vinyl chloride-vinyl acetate-vinyl alcohol copolymer and finely divided silica dispersed in a solvent.
【００２１】３．金属シート用接着プライマー（金属用
プライマー）。 ビニルブチラール樹脂（例、エスレックＢ、積水化学社
製）とフェノール樹脂（レゾールタイプ）との混合物。3. Adhesive primer for metal sheet (primer for metal). A mixture of a vinyl butyral resin (eg, SREC B, manufactured by Sekisui Chemical Co., Ltd.) and a phenol resin (resole type).
【００２２】４．金属シート（例、厚さ５０μmの軟質
アルミニウムシート）。 金属シートとしては、厚さ５０μmの軟質アルミニウム
シートを使用する。そして、裏面（塩ビシート面）に、
上記３．に記載の金属シート用接着プライマー（金属用
プライマー）を約５０g/m2（固形分換算値）塗布して乾
燥させた。4. Metal sheet (eg, a soft aluminum sheet having a thickness of 50 μm). As the metal sheet, a soft aluminum sheet having a thickness of 50 μm is used. And on the back side (PVC sheet side)
3 above. About 50 g / m 2 (in terms of solid content) and dried.
【００２３】５．金属シート用接着シート（接着シー
ト）。 米坪約２０g/m2の表面紙（オーバーレイ紙）に、上記
３．のビニルブチラール樹脂とフェノール樹脂の混合物
を固形分換算値で約４０g/m2含浸乾燥したプレプレグ。5. Adhesive sheet for metal sheet (adhesive sheet). A basis weight of about 20 g / m 2 of the surface sheet (overlay paper), the three. A prepreg obtained by impregnating and drying a mixture of a vinyl butyral resin and a phenol resin of about 40 g / m 2 in terms of solid content.
【００２４】６．フェノール樹脂含浸コア紙（コア含浸
紙）。 米坪約１６０g/m2のクラフト紙にフェノール樹脂（積層
板用樹脂）を固形分換算値で約８０g/m2含浸乾燥したプ
レプレグ。6. Phenolic resin impregnated core paper (core impregnated paper). Basis weight of about 160 g / m 2 kraft paper phenol resin (laminate resin) prepregs were about 80 g / m 2 impregnated dried in terms of solid content.
【００２５】７．メラミン樹脂含浸化粧紙（化粧含浸
紙） 米坪約８０g/m2の印刷チタン紙に、化粧板用メラミン−
ホルムアルデヒド樹脂（硬化剤としてパラトルエンスル
ホン酸使用）を固形分換算値で約８０g/m2含浸乾燥した
プレプレグ。[7] Melamine resin impregnated decorative paper (decorative impregnated paper) basis weight of about 80 g / m 2 Printing titanium paper, veneer melamine -
A prepreg obtained by impregnating and drying formaldehyde resin (using paratoluenesulfonic acid as a curing agent) in an amount of about 80 g / m 2 in terms of solid content.
【００２６】８．メラミン樹脂含浸表面紙（表面含浸
紙） 米坪約３０g/m2のアルミナ入オーバーレイ紙（表面紙）
に化粧板用メラミン−ホルムアルデヒド樹脂（硬化剤と
してパラトルエンスルホン酸使用、離型剤入）を固形分
換算値で約６０g/m2含浸乾燥したプレプレグ。8. Melamine resin impregnated surface sheet (surface-impregnated paper) basis weight about 30 g / m 2 of alumina input overlay paper (surface sheet)
A prepreg impregnated with a melamine-formaldehyde resin for decorative board (using paratoluenesulfonic acid as a curing agent and containing a release agent) at a solid content of about 60 g / m 2 and dried.
【００２７】なお、熱圧成形条件はいずれも次の通りで
ある。 圧力 ７０Kg/cm2、温度 １２０℃、時間 ３０分間The hot pressing conditions are as follows. Pressure 70Kg / cm 2 , temperature 120 ° C, time 30 minutes
【００２８】次に、製品の耐シガレット試験として、化
粧板の表面をＡ．摩耗前、及びＢ．サンドペーパーNO．
８０により摩耗後、のそれぞれの状態で、たばこ「マイ
ルドセブン」の火が消えるまで約５分間放置し、その
後、中性洗剤で拭き取り後の外観をこげ跡の有無、ふく
れの有無を測定し、その結果を表１に示す。Next, as a cigarette resistance test of the product, the surface of the decorative plate was subjected to A.I. Before abrasion, and B. Sandpaper NO.
After abrasion by 80, in each state, the cigarette "Mild Seven" was left for about 5 minutes until the fire was extinguished, then the appearance after wiping with a neutral detergent was measured for the presence of burn marks and blisters. Table 1 shows the results.
【００２９】[0029]
【表１】 [Table 1]
【００３０】[0030]
【発明の効果】表１より明らかな如く、塩化ビニル樹脂
基材と熱硬化性樹脂含浸コア紙、又は含浸化粧紙との間
に金属シートを介在積層した本発明の複合化粧材は、表
面摩耗後の耐シガレット試験でもこげ跡を取り除くこと
ができ、ふくれも生じないが、金属シートを介在させな
いものはこげ跡を取り除くことができず、ふくれも発生
した。As is clear from Table 1, the composite decorative material of the present invention, in which a metal sheet is interposed and laminated between a vinyl chloride resin substrate and a thermosetting resin-impregnated core paper or an impregnated decorative paper, has a high surface wear. In the subsequent cigarette resistance test, the burn marks could be removed and no blistering occurred, but those without a metal sheet could not remove the burn marks and blisters occurred.
【図１】本発明の一実施例の構成断面図。FIG. 1 is a sectional view showing the configuration of an embodiment of the present invention.
１ 塩化ビニル樹脂基材 ２ 塩化ビニル用接着プライマー ３ 金属シート用接着プライマー ４ 金属シート ５ 金属シート用接着シート ６ フェノール樹脂含浸コア紙 ７ メラミン樹脂含浸化粧紙 ８ メラミン樹脂含浸表面紙 DESCRIPTION OF SYMBOLS 1 Vinyl chloride resin base material 2 Adhesive primer for vinyl chloride 3 Adhesive primer for metal sheets 4 Metal sheet 5 Adhesive sheet for metal sheets 6 Phenolic resin impregnated core paper 7 Melamine resin impregnated decorative paper 8 Melamine resin impregnated surface paper
フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｂ３２Ｂ 27/42 １０２ Ｂ３２Ｂ 27/42 １０２ 33/00 33/00 Ｃ０９Ｊ 161/08 ＪＥＱ Ｃ０９Ｊ 161/08 ＪＥＱ // Ｃ０８Ｇ 12/32 ＮＣＷ Ｃ０８Ｇ 12/32 ＮＣＷ 14/10 ＮＤＥ 14/10 ＮＤＥ Continuation of the front page (51) Int.Cl. 6 Identification code FI B32B 27/42 102 B32B 27/42 102 33/00 33/00 C09J 161/08 JEQ C09J 161/08 JEQ // C08G 12/32 NCW C08G 12 / 32 NCW 14/10 NDE 14/10 NDE
Claims (3)
樹脂含浸紙との間に金属シートを介在積層したことを特
徴とする複合化粧材。A composite decorative material comprising a metal sheet interposed and laminated between a vinyl chloride resin substrate and a thermosetting resin-impregnated paper as a surface layer.
項１に記載の複合化粧材。2. The composite decorative material according to claim 1, wherein the surface layer is melamine resin impregnated paper.
樹脂含浸紙との間にアルミシートを介在させるのにブチ
ラール−フェノール樹脂系接着剤を使用して熱圧積層す
ることを特徴とする複合化粧材の製法。3. A hot-press lamination using a butyral-phenol resin adhesive to interpose an aluminum sheet between the vinyl chloride resin base material and the thermosetting resin-impregnated paper of the surface layer. To make composite cosmetics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26258196A JPH1086276A (en) | 1996-09-10 | 1996-09-10 | Composite decorative material and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26258196A JPH1086276A (en) | 1996-09-10 | 1996-09-10 | Composite decorative material and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1086276A true JPH1086276A (en) | 1998-04-07 |
Family
ID=17377805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26258196A Pending JPH1086276A (en) | 1996-09-10 | 1996-09-10 | Composite decorative material and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH1086276A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100579841B1 (en) * | 1998-12-08 | 2006-05-12 | 주식회사 엘지화학 | Melamine sheet laminated floor decoration material and manufacturing method thereof |
| KR100612663B1 (en) * | 2004-09-14 | 2006-08-14 | 유신메라민공업주식회사 | Thermosetting resin decorative plate and its manufacturing method |
| JP2007162011A (en) * | 2005-11-21 | 2007-06-28 | Natl Starch & Chem Investment Holding Corp | Adhesive composition |
| KR100750479B1 (en) * | 2005-04-13 | 2007-08-22 | 주식회사 엘지화학 | Anti-caster wood flooring |
| JP2011149273A (en) * | 1999-11-05 | 2011-08-04 | Industrias Auxilliares Faus Slu | Laminated flooring product |
| CN106273895A (en) * | 2016-08-15 | 2017-01-04 | 苏州扬子江新型材料股份有限公司 | Antitheft door stamping resistance imitation wood stricture of vagina film coated plate |
-
1996
- 1996-09-10 JP JP26258196A patent/JPH1086276A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100579841B1 (en) * | 1998-12-08 | 2006-05-12 | 주식회사 엘지화학 | Melamine sheet laminated floor decoration material and manufacturing method thereof |
| JP2011149273A (en) * | 1999-11-05 | 2011-08-04 | Industrias Auxilliares Faus Slu | Laminated flooring product |
| KR100612663B1 (en) * | 2004-09-14 | 2006-08-14 | 유신메라민공업주식회사 | Thermosetting resin decorative plate and its manufacturing method |
| KR100750479B1 (en) * | 2005-04-13 | 2007-08-22 | 주식회사 엘지화학 | Anti-caster wood flooring |
| JP2007162011A (en) * | 2005-11-21 | 2007-06-28 | Natl Starch & Chem Investment Holding Corp | Adhesive composition |
| CN106273895A (en) * | 2016-08-15 | 2017-01-04 | 苏州扬子江新型材料股份有限公司 | Antitheft door stamping resistance imitation wood stricture of vagina film coated plate |
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