JPH1088193A - Skin cleaning agent - Google Patents
Skin cleaning agentInfo
- Publication number
- JPH1088193A JPH1088193A JP8265366A JP26536696A JPH1088193A JP H1088193 A JPH1088193 A JP H1088193A JP 8265366 A JP8265366 A JP 8265366A JP 26536696 A JP26536696 A JP 26536696A JP H1088193 A JPH1088193 A JP H1088193A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- skin
- acid salt
- feeling
- extract
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title abstract 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 25
- 229930195729 fatty acid Natural products 0.000 claims abstract description 25
- 239000000194 fatty acid Substances 0.000 claims abstract description 25
- -1 fatty acid salt Chemical class 0.000 claims abstract description 22
- 235000014837 Malpighia glabra Nutrition 0.000 claims abstract description 15
- WVXRAFOPTSTNLL-NKWVEPMBSA-N 2',3'-dideoxyadenosine Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@H]1CC[C@@H](CO)O1 WVXRAFOPTSTNLL-NKWVEPMBSA-N 0.000 claims abstract description 14
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 10
- 241001640002 Malpighia emarginata Species 0.000 claims abstract 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract description 12
- 239000000203 mixture Substances 0.000 abstract description 9
- 239000003599 detergent Substances 0.000 abstract description 8
- 239000007864 aqueous solution Substances 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract description 3
- 239000003906 humectant Substances 0.000 abstract description 3
- 239000002738 chelating agent Substances 0.000 abstract description 2
- 239000000706 filtrate Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 229920003169 water-soluble polymer Polymers 0.000 abstract description 2
- 238000001914 filtration Methods 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 1
- 235000015203 fruit juice Nutrition 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 abstract 1
- 229940082004 sodium laurate Drugs 0.000 abstract 1
- 238000005187 foaming Methods 0.000 description 13
- 240000003394 Malpighia glabra Species 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
- 238000005406 washing Methods 0.000 description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000001953 sensory effect Effects 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 235000019482 Palm oil Nutrition 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- TYTGWHZODQKWEF-UHFFFAOYSA-N 1-o-dodecyl 4-o-sulfo butanedioate Chemical compound CCCCCCCCCCCCOC(=O)CCC(=O)OS(O)(=O)=O TYTGWHZODQKWEF-UHFFFAOYSA-N 0.000 description 1
- MFMNADOFNGXVAW-UHFFFAOYSA-N 2-[carboxymethyl(dodecyl)amino]acetic acid Chemical compound CCCCCCCCCCCCN(CC(O)=O)CC(O)=O MFMNADOFNGXVAW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- FRPAVHFNOFSNDR-UHFFFAOYSA-N 3-(2,4-dioxo-1,3-thiazolidin-3-yl)propanoic acid Chemical compound OC(=O)CCN1C(=O)CSC1=O FRPAVHFNOFSNDR-UHFFFAOYSA-N 0.000 description 1
- QKACYUNWMGTCNR-UHFFFAOYSA-N 3-(2-oxotridecylamino)propanoic acid Chemical class CCCCCCCCCCCC(=O)CNCCC(O)=O QKACYUNWMGTCNR-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 241000093727 Berzelia alopecuroides Species 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- OVBJJZOQPCKUOR-UHFFFAOYSA-L EDTA disodium salt dihydrate Chemical compound O.O.[Na+].[Na+].[O-]C(=O)C[NH+](CC([O-])=O)CC[NH+](CC([O-])=O)CC([O-])=O OVBJJZOQPCKUOR-UHFFFAOYSA-L 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- 235000011552 Rhamnus crocea Nutrition 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- ZJDCURJWFBQZMS-UHFFFAOYSA-L disodium;2-[carboxylatomethyl(dodecyl)amino]acetate Chemical compound [Na+].[Na+].CCCCCCCCCCCCN(CC([O-])=O)CC([O-])=O ZJDCURJWFBQZMS-UHFFFAOYSA-L 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 229960004585 etidronic acid Drugs 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- WYVGZXIHGGQSQN-UHFFFAOYSA-N hexadecanoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCCCCC(O)=O WYVGZXIHGGQSQN-UHFFFAOYSA-N 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 229940071180 lauryl sulfosuccinate Drugs 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- HAHAETDVDDDHEZ-UHFFFAOYSA-M sodium 2-(dimethylamino)tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCC(N(C)C)C([O-])=O HAHAETDVDDDHEZ-UHFFFAOYSA-M 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、泡立ちに優れ、す
すぎ時に皮膚のぬるつきがなく、洗浄後の皮膚のつっぱ
り感もない皮膚洗浄剤に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a skin cleansing agent which is excellent in foaming, does not lose skin when rinsing, and does not have a firm feeling on the skin after washing.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】高級脂
肪酸塩である石鹸は、泡立ちが良く、洗浄後さっぱりと
した感触が得られる為、皮膚洗浄剤として多用されてい
る。しかし、石鹸の強い脱脂力によって皮膚のうるおい
成分が過度に取り除かれる為、洗浄後に皮膚のつっぱり
感等の障害を引き起こすことがある。このため、石鹸に
保湿剤としてプロピレングリコールやグリセリン等の多
価アルコールを配合することや、他の界面活性剤を添加
したりすることが知られている(特開平7−30974
2号公報)。しかし、これら成分の配合は、泡立ちの低
下やすすぎ時の皮膚のぬるつき感を生じさせる等の欠点
をもたらす。BACKGROUND OF THE INVENTION Soap, which is a higher fatty acid salt, is frequently used as a skin cleansing agent because it has good foaming and gives a refreshing feel after washing. However, the strong degreasing power of the soap excessively removes the moisture component of the skin, which may cause an obstacle such as a feeling of tightness of the skin after washing. For this reason, it is known to mix a soap with a polyhydric alcohol such as propylene glycol or glycerin as a humectant, or to add another surfactant (Japanese Patent Laid-Open No. 7-30974).
No. 2). However, the incorporation of these components brings about disadvantages such as a reduction in foaming and a feeling of slimy skin upon rinsing.
【0003】そこで、本発明は泡立ちに優れ、すすぎ時
に皮膚のぬるつきがなく、洗浄後の皮膚のつっぱり感も
ない皮膚洗浄剤を提供することを目的とする。[0003] Therefore, an object of the present invention is to provide a skin cleansing agent which is excellent in foaming, does not lose skin lubricity during rinsing, and has no feeling of tightness of the skin after washing.
【0004】[0004]
【課題を解決するための手段】上記目的を達成するた
め、本発明者は、鋭意研究した結果、高級脂肪酸塩とア
セロラの果実より抽出したエキスとを含有する皮膚洗浄
剤が、泡立ちに優れ、すすぎ時の皮膚のぬるつきがな
く、洗浄後の皮膚のつっぱり感もない優れた効果を有し
ていることを見出し、本発明に至った。Means for Solving the Problems In order to achieve the above object, the present inventors have conducted intensive studies, and as a result, a skin cleansing agent containing a higher fatty acid salt and an extract extracted from the fruit of acerola is excellent in foaming, The present inventors have found that the present invention has an excellent effect that there is no sliminess of the skin at the time of rinsing and there is no feeling of tightness of the skin after washing, and the present invention has been achieved.
【0005】すなわち、本発明の請求項1の発明は、高
級脂肪酸塩とアセロラの果実より抽出したエキスとを含
有することを特徴とする皮膚洗浄剤である。[0005] That is, the invention of claim 1 of the present invention is a skin cleanser comprising a higher fatty acid salt and an extract extracted from the fruit of acerola.
【0006】[0006]
【発明の実施の形態】以下、本発明の実施の形態を詳述
する。本発明に用いられるアセロラ(Malpighia glabra
Linne)は、西インド諸島原産の高さ3〜5メートルの
常緑の灌木で、開花後、直径1〜3センチメートルの小
さなサクランボに似た赤い実をつける。このアセロラの
果実は多量のアスコルビン酸を含むことから、加工され
て食品素材として利用されている。一方、この抽出エキ
スを化粧品に配合することはよく知られている(特開平
2−第200610号公報)。しかし、皮膚洗浄剤にお
ける効果については現在のところ知られていない。Embodiments of the present invention will be described below in detail. Acerola (Malpighia glabra) used in the present invention
Linne) is a 3-5 meter tall evergreen shrub native to the West Indies that, after flowering, bears red berries similar to small cherries 1-3 cm in diameter. Since the fruit of this acerola contains a large amount of ascorbic acid, it is processed and used as a food material. On the other hand, it is well known that this extracted extract is incorporated into cosmetics (Japanese Patent Application Laid-Open No. 2-200610). However, its effect on skin cleansers is currently unknown.
【0007】アセロラの果実よりエキスを抽出する製造
例を示す。すなわち、アセロラの果実(10キログラ
ム)を圧搾し、圧搾汁を得る。これを濃縮し、オリをろ
過し、ろ液(約2キログラム)を得る。これにプロピレ
ングリコール30重量%水溶液(18キログラム)を加
え、冷所に7〜10日間放置して熟成させ、ろ過してエ
キス(約20キログラム)を得る。このようにして得た
エキスには、アスコルビン酸、酒石酸、リンゴ酸などの
有機酸やグルコース、フルクトースの糖類及びタンパク
質などが含まれている。アセロラの果実より抽出したエ
キスは皮膚洗浄剤の全組成中に0.01〜5重量%が好
ましい。0.01重量%未満では充分な官能特性が発現
しない場合が、5重量%を超えても配合量に相当する充
分な官能特性が発現しない場合がそれぞれある。A production example of extracting an extract from the fruit of acerola will be described. That is, the acerola fruit (10 kg) is pressed to obtain a pressed juice. This is concentrated, and the oil is filtered to obtain a filtrate (about 2 kg). To this is added a 30% by weight aqueous solution of propylene glycol (18 kg), left to stand in a cool place for 7 to 10 days, aged, and filtered to obtain an extract (about 20 kg). The extract thus obtained contains organic acids such as ascorbic acid, tartaric acid, malic acid, glucose, fructose saccharides and proteins. The extract extracted from the fruit of acerola is preferably 0.01 to 5% by weight in the total composition of the skin cleanser. If the amount is less than 0.01% by weight, sufficient sensory characteristics may not be exhibited. If the amount exceeds 5% by weight, sufficient sensory characteristics corresponding to the compounding amount may not be exhibited.
【0008】本発明で用いられる高級脂肪酸塩として
は、飽和又は不飽和のいずれであってもよく、炭素数8
〜22の高級脂肪酸塩が好ましい。具体例としては、ラ
ウリン酸、ミリスチン酸、パルミチン酸、パルミトレイ
ン酸、ステアリン酸、イソステアリン酸、オレイン酸、
ヤシ油脂肪酸、パーム核脂肪酸などがある。また、塩を
構成する対イオンには、ナトリウム、カリウムなどのア
ルカリ金属塩、アンモニウム塩、モノエタノールアミン
塩、トリエタノールアミン塩、2−アミノ−2−メチル
プロパノールなどのアルカノールアミン塩、リジン、ア
ルギニンなどの塩基性アミノ酸塩などが挙げられる。ま
た、高級脂肪酸塩は、必ずしも脂肪酸塩として配合する
必要はなく、遊離の高級脂肪酸を含んでもよい。The higher fatty acid salt used in the present invention may be either saturated or unsaturated and has 8 carbon atoms.
~ 22 higher fatty acid salts are preferred. Specific examples include lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid,
Palm oil fatty acids, palm kernel fatty acids and the like. Examples of the counter ion constituting the salt include alkali metal salts such as sodium and potassium, ammonium salts, alkanolamine salts such as monoethanolamine salt, triethanolamine salt and 2-amino-2-methylpropanol, lysine and arginine. And other basic amino acid salts. Further, the higher fatty acid salt does not necessarily need to be blended as a fatty acid salt, and may contain a free higher fatty acid.
【0009】これらの高級脂肪酸塩は、1種又は2種以
上を組合せて用いることができ、全組成中に5〜30重
量%が好ましい。5重量%未満では充分な泡立ち、洗浄
力が得られず、30重量%を越えると系の安定性が悪く
なり好ましくない場合がある。These higher fatty acid salts can be used alone or in combination of two or more, and preferably 5 to 30% by weight in the whole composition. If the amount is less than 5% by weight, sufficient foaming and detergency cannot be obtained. If the amount exceeds 30% by weight, the stability of the system becomes poor, which is not preferable.
【0010】本発明の皮膚洗浄剤には、前記高級脂肪酸
塩以外に、通常洗浄剤に用いられる、その他のアニオン
性、両性、ノニオン性界面活性剤を、本発明の効果を損
なわない範囲で配合してもよい。例えば、ポリオキシエ
チレンラウリルエーテル硫酸塩、ポリオキシエチレン脂
肪酸アミドエーテル硫酸塩、ヤシ油脂肪酸メチルタウリ
ンナトリウム、ポリオキシエチレンラウリルエーテル酢
酸ナトリウム、ポリオキシエチレンラウリン酸モノエタ
ノールアミド酢酸ナトリウム、ヤシ油脂肪酸エチルエス
テルスルホン酸塩、モノアルキルリン酸塩、ラウリルス
ルホコハク酸塩、ラウリルイミノジ酢酸塩、ラウロイル
メチル−β−アラニン塩、ラウロイル−L−グルタミン
酸塩、ラウロイル−L−アスパラギン酸塩などのアニオ
ン性界面活性剤。両性活性剤としては、ラウリルジメチ
ルアミノ酢酸ナトリウム、ラウリン酸アミドプロピルベ
タイン、2−アルキル−N−ヒドロキシエチル−N−カ
ルボキシメチルイミダゾリニウムベタイン、ラウリルヒ
ドロキシスルホベタインなどがある。また、ノニオン性
活性剤は脂肪酸ジエタノールアミド、脂肪酸モノエタノ
ールアミド、脂肪酸イソプロパノールアミド、ラウリル
ジメチルアミンオキシド、ポリオキシエチレンアルキル
エーテル、アルキルグルコシドなどがある。[0010] In addition to the higher fatty acid salts, other anionic, amphoteric, or nonionic surfactants commonly used in detergents are incorporated into the skin detergent of the present invention within a range that does not impair the effects of the present invention. May be. For example, polyoxyethylene lauryl ether sulfate, polyoxyethylene fatty acid amide ether sulfate, coconut oil fatty acid methyl taurine sodium, polyoxyethylene lauryl ether sodium acetate, polyoxyethylene lauric acid monoethanolamide sodium acetate, coconut oil fatty acid ethyl ester Anionic surfactants such as sulfonate, monoalkyl phosphate, lauryl sulfosuccinate, lauryliminodiacetate, lauroylmethyl-β-alanine salt, lauroyl-L-glutamate, lauroyl-L-aspartate and the like . Examples of the amphoteric activator include sodium lauryldimethylaminoacetate, amidopropylbetaine laurate, 2-alkyl-N-hydroxyethyl-N-carboxymethylimidazolinium betaine, laurylhydroxysulfobetaine and the like. The nonionic activator includes fatty acid diethanolamide, fatty acid monoethanolamide, fatty acid isopropanolamide, lauryl dimethylamine oxide, polyoxyethylene alkyl ether, alkyl glucoside and the like.
【0011】また、本発明の皮膚洗浄剤には、通常皮膚
洗浄剤に配合される他の成分、例えば保湿剤、油分、水
溶性高分子、色素、キレート剤、殺菌剤、紫外線吸収
剤、香料などが配合できる。The skin cleansing composition of the present invention also contains other components that are usually blended with the skin cleansing composition, such as humectants, oils, water-soluble polymers, pigments, chelating agents, bactericides, ultraviolet absorbers, and fragrances. Can be blended.
【0012】[0012]
【実施例】次に実施例によって本発明を具体的に説明す
る。なお、効果の測定は以下の評価法によった。Next, the present invention will be described in detail with reference to examples. The effect was measured according to the following evaluation method.
【0013】泡立ち ロスマイルス試験法に準じて泡立ちを測定した。ただ
し、試料は2重量%水溶液(CaCO3 、50ppm人
工硬水使用)、温度は40℃である。 ◎… 泡立ちが極めて良好、泡立ち250mm以上 ○… 泡立ちが良好、泡立ち200mm以上、250m
m未満 △… 泡立ちが普通、泡立ち150mm以上、200m
m未満 ×… 泡立ちが不良、泡立ち150mm未満Lathering Lathering was measured according to the Ross Miles test method. However, the sample was a 2% by weight aqueous solution (using CaCO3, 50 ppm artificial hard water), and the temperature was 40C. …: Very good bubbling, 250 mm or more 250: Good bubbling, 200 mm or more, 250 m
Less than m △: Foaming is normal, foaming is 150mm or more, 200m
Less than × × Foaming is poor, foaming is less than 150 mm
【0014】ぬるつき感、つっぱり感 官能試験による評価法である。試料約1gを手のひらに
採って35〜40℃の温水による洗顔試験を行い、すす
ぎ時のぬるつき感を官能評価した。また、洗顔後タオル
ドライし、5分後のつっぱり感を評価した。試験対象者
として女性パネラー20名を選んだ。 ぬるつき感の評点 ◎… ぬるつき感がなく良いと答えた人が16名以上の
場合 ○… ぬるつき感がなく良いと答えた人が12〜15名
の場合 △… ぬるつき感がなく良いと答えた人が7〜11名の
場合 ×… ぬるつき感がなく良いと答えた人が6名以下の場
合 つっぱり感の評点 ◎… つっぱり感がなく良いと答えた人が16名以上の
場合 ○… つっぱり感がなく良いと答えた人が12〜15名
の場合 △… つっぱり感がなく良いと答えた人が7〜11名の
場合 ×… つっぱり感がなく良いと答えた人が6名以下の場
合This is an evaluation method based on a sensory test of a slimy feeling and a feeling of tightness. Approximately 1 g of the sample was taken on the palm and subjected to a face washing test with warm water at 35 to 40 ° C., and the sensory evaluation of the sliminess upon rinsing was performed. After washing the face, the towel was dried, and the feeling of tightness after 5 minutes was evaluated. Twenty female panelists were selected as test subjects. Score of slimy feeling ◎: 16 or more people answered that there was no sliminess ○: 12 to 15 people who answered that there was no sliminess △: Good without sliminess When 7 or 11 people answered "No", ... 6 or less answered that there was no slimy feeling. Rating of feeling of tightness ◎ ... When 16 or more people answered that there was no feeling of being tight and good. ○: 12 to 15 respondents who answered that there was no feeling of tightness △: 7 to 11 persons who answered that there was no feeling of tightness × 6 people who answered that there was no feeling of tightness When
【0015】実施例1,2、比較例1〜3 表1に示す配合組成の皮膚洗浄剤を通常の方法で調製
し、各必須成分の効果を調べ、その結果を表1に示す。
なお、配合量は重量%である。Examples 1 and 2 and Comparative Examples 1 to 3 A skin cleanser having the composition shown in Table 1 was prepared by an ordinary method, and the effect of each essential component was examined. The results are shown in Table 1.
In addition, the compounding amount is weight%.
【0016】[0016]
【表1】 [Table 1]
【0017】この結果から明らかなように本発明の成分
を用いた皮膚洗浄剤(実施例1,2)は泡立ち、ぬるつ
き感及びつっぱり感のいずれも優れた性能を示した。一
方、必須成分のどちらかを欠いた場合(比較例1,2,
3)はいずれも充分な性能を示さなかった。As is apparent from the results, the skin cleansing compositions (Examples 1 and 2) using the components of the present invention foamed and showed excellent performances in both a slimy feeling and a firm feeling. On the other hand, when one of the essential components was missing (Comparative Examples 1, 2,
None of 3) showed sufficient performance.
【0018】実施例3 次に示す洗顔剤を調製し、前記の方法にて評価した。い
ずれの項目も優れた評価であった。 (重量%) 1.ミリスチン酸カリウム 12.0 2.ミリスチン酸リジン 4.0 3.ラウリン酸アミドプロピルベタイン 3.0 4.ラウリン酸ジエタノールアミド 3.0 5.ジステアリン酸エチレングリコール 2.0 6.ソルビトール液 5.0 7.ヒドロキシプロピルメチルセルロース 0.3 8.アセロラ抽出エキス 3.0 9.エデト酸四ナトリウム 0.1 10. 香料 適量 11. 精製水 残余Example 3 The following facial cleanser was prepared and evaluated by the above method. All items were excellent evaluations. (% By weight) Potassium myristate 12.0 2. 2. Lysine myristate 4.0 Amidopropyl betaine laurate 3.0 4.0 Lauric acid diethanolamide 3.0 5. 5. Ethylene glycol distearate 2.0 Sorbitol solution 5.0 7. 7. Hydroxypropyl methylcellulose 0.3 Acerola extract 3.0 3.0 Tetrasodium edetate 0.1 10. Appropriate amount of fragrance 11. Purified water residue
【0019】実施例4 次に示すボディシャンプーを調製し、前記の方法にて評
価した。泡立ちが良く、ぬるつき感がなく、つっぱり感
のない感触を示した。 (重量%) 1.ラウリン酸トリエタノールアミン 18.0 2.パルミチン酸トリエタノールアミン 2.0 3.ラウリルヒドロキシスルホベタイン 2.0 4.ラウリルイミノジ酢酸ナトリウム 3.0 5.ジステアリン酸エチレングリコール 2.5 6.パーム核油脂肪酸ジエタノールアミド 4.0 7.ヒドロキシエタンジホスホン酸 0.1 8.アセロラ抽出エキス 4.0 9.香料 適量 10. 精製水 残余Example 4 The following body shampoo was prepared and evaluated by the above method. The foaming was good, there was no slimy feeling, and there was no feeling of tightness. (% By weight) Triethanolamine laurate 18.0 2. 2. Triethanolamine palmitate 2.0 Lauryl hydroxysulfobetaine 2.0 4. Sodium lauryliminodiacetate 3.0 5. 5. ethylene glycol distearate 2.5 Palm kernel oil fatty acid diethanolamide 4.0 7. 7. Hydroxyethane diphosphonic acid 0.1 Acerola extract 4.0 4.0 9. Appropriate amount of fragrance 10. Purified water residue
【0020】実施例5 次に示すハンドソープを調製し、前記の方法で評価し
た。泡立ちが良く、めるつき感がなく優れた使用感であ
った。 (重量%) 1.ヤシ油脂肪酸カリウム 15.0 2.ヤシ油脂肪酸ジエタノールアミド 2.0 3.ラウリルジメチルアミノ酢酸ベタイン 4.0 4.プロピレングリコール 8.0 5.トリクロサン 0.3 6.アセロラ抽出エキス 2.0 7.ビタミンEアセテート 0.2 8.エデト酸二ナトリウム 0.05 9.香料 適量 10.精製水 残余Example 5 The following hand soap was prepared and evaluated by the above method. The foaming was good and there was no sticky feeling and the feeling was excellent. (% By weight) Palm oil fatty acid potassium 15.0 2. 2. Palm oil fatty acid diethanolamide 2.0 Betaine lauryl dimethylaminoacetate 4.0 4.0. Propylene glycol 8.0 5. Triclosan 0.3 6. Acerola extract 2.0 2.07. Vitamin E acetate 0.2 8. 8. Disodium edetate 0.05 Appropriate amount of fragrance 10. Purified water residue
【0021】[0021]
【発明の効果】以上記載のように、本発明が泡立ちに優
れ、すすぎ時に皮膚のぬるつきがなく、洗浄後も皮膚の
つっぱり感がない優れた皮膚洗浄剤を提供することは明
らかである。As described above, it is apparent that the present invention provides an excellent skin cleansing agent which is excellent in foaming, has no slimy skin upon rinsing, and does not have a firm skin feeling after washing.
Claims (1)
したエキスとを含有することを特徴とする皮膚洗浄剤。1. A skin cleanser comprising a higher fatty acid salt and an extract extracted from the fruit of acerola.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26536696A JP3375833B2 (en) | 1996-09-12 | 1996-09-12 | Skin cleanser |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26536696A JP3375833B2 (en) | 1996-09-12 | 1996-09-12 | Skin cleanser |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH1088193A true JPH1088193A (en) | 1998-04-07 |
| JP3375833B2 JP3375833B2 (en) | 2003-02-10 |
Family
ID=17416188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26536696A Expired - Fee Related JP3375833B2 (en) | 1996-09-12 | 1996-09-12 | Skin cleanser |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3375833B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000273496A (en) * | 1999-03-26 | 2000-10-03 | Nof Corp | Detergent composition |
| WO2001022924A1 (en) * | 1999-09-30 | 2001-04-05 | The Boots Company Plc | Hair care composition |
| JP2003073695A (en) * | 2001-09-05 | 2003-03-12 | Yamamoto Koryo Kk | Pollen soap |
| JP2009114156A (en) * | 2007-11-09 | 2009-05-28 | Kao Corp | Liquid cleanser composition |
| KR100969323B1 (en) | 2010-01-22 | 2010-07-09 | 화광 교역 주식회사 | Skin cleaning agent having excellent water-soluble |
| JP2012012310A (en) * | 2010-06-29 | 2012-01-19 | Nof Corp | Skin detergent composition |
-
1996
- 1996-09-12 JP JP26536696A patent/JP3375833B2/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000273496A (en) * | 1999-03-26 | 2000-10-03 | Nof Corp | Detergent composition |
| WO2001022924A1 (en) * | 1999-09-30 | 2001-04-05 | The Boots Company Plc | Hair care composition |
| JP2003073695A (en) * | 2001-09-05 | 2003-03-12 | Yamamoto Koryo Kk | Pollen soap |
| JP2009114156A (en) * | 2007-11-09 | 2009-05-28 | Kao Corp | Liquid cleanser composition |
| KR100969323B1 (en) | 2010-01-22 | 2010-07-09 | 화광 교역 주식회사 | Skin cleaning agent having excellent water-soluble |
| JP2012012310A (en) * | 2010-06-29 | 2012-01-19 | Nof Corp | Skin detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3375833B2 (en) | 2003-02-10 |
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