JPH11130918A - 未硬化ゴムコンパウンドへの予備硬化ゴムコンパウンドの硬化接着性を改善する方法 - Google Patents
未硬化ゴムコンパウンドへの予備硬化ゴムコンパウンドの硬化接着性を改善する方法Info
- Publication number
- JPH11130918A JPH11130918A JP10231317A JP23131798A JPH11130918A JP H11130918 A JPH11130918 A JP H11130918A JP 10231317 A JP10231317 A JP 10231317A JP 23131798 A JP23131798 A JP 23131798A JP H11130918 A JPH11130918 A JP H11130918A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- phr
- compound
- cured
- tire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 148
- 239000005060 rubber Substances 0.000 title claims abstract description 148
- 150000001875 compounds Chemical class 0.000 title claims abstract description 70
- 230000006872 improvement Effects 0.000 title description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 87
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 41
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 29
- 239000000194 fatty acid Substances 0.000 claims abstract description 29
- 229930195729 fatty acid Natural products 0.000 claims abstract description 29
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 29
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 24
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 24
- 229920001194 natural rubber Polymers 0.000 claims abstract description 24
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 23
- 239000011593 sulfur Substances 0.000 claims abstract description 23
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 22
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 20
- 239000000839 emulsion Substances 0.000 claims description 8
- 230000001133 acceleration Effects 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 2
- 238000001723 curing Methods 0.000 description 20
- 238000002156 mixing Methods 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 239000000523 sample Substances 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 7
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- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- -1 thiuram compound Chemical class 0.000 description 4
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000013068 control sample Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 238000010058 rubber compounding Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229920003261 Durez Polymers 0.000 description 2
- 239000005041 Mylar™ Substances 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 239000012990 dithiocarbamate Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N guanidine group Chemical group NC(=N)N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000010077 mastication Methods 0.000 description 2
- 230000018984 mastication Effects 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 239000010734 process oil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- YOSRRIGSGJDAJR-UHFFFAOYSA-N 1-(2-dimethoxysilylpropyltrisulfanyl)propan-2-yl-dimethoxysilane Chemical compound CC(CSSSCC(C)[SiH](OC)OC)[SiH](OC)OC YOSRRIGSGJDAJR-UHFFFAOYSA-N 0.000 description 1
- LYPJSBQIFJESQY-UHFFFAOYSA-N 1-(3-diethoxysilylhexyldisulfanyl)hexan-3-yl-diethoxysilane Chemical compound C(CC)C(CCSSCCC(CCC)[SiH](OCC)OCC)[SiH](OCC)OCC LYPJSBQIFJESQY-UHFFFAOYSA-N 0.000 description 1
- BULPGPDAJKQNHS-UHFFFAOYSA-N 1-(3-dimethoxysilylheptyltrisulfanyl)heptan-3-yl-dimethoxysilane Chemical compound C(CCC)C(CCSSSCCC(CCCC)[SiH](OC)OC)[SiH](OC)OC BULPGPDAJKQNHS-UHFFFAOYSA-N 0.000 description 1
- LLMLGZUZTFMXSA-UHFFFAOYSA-N 2,3,4,5,6-pentachlorobenzenethiol Chemical compound SC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LLMLGZUZTFMXSA-UHFFFAOYSA-N 0.000 description 1
- CSIPGRDAPMEMLW-UHFFFAOYSA-N 3-ethoxypropoxy-[1-[2-(3-ethoxypropoxysilyl)propyltetrasulfanyl]propan-2-yl]silane Chemical compound CC(CSSSSCC(C)[SiH2]OCCCOCC)[SiH2]OCCCOCC CSIPGRDAPMEMLW-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- SDFBDFHBGFUNGG-UHFFFAOYSA-N C(C)(C)O[Si](OC(C)C)(OC(C)C)CCCCCCCCCCSSCCCCCCCCCC[Si](OC(C)C)(OC(C)C)OC(C)C Chemical compound C(C)(C)O[Si](OC(C)C)(OC(C)C)CCCCCCCCCCSSCCCCCCCCCC[Si](OC(C)C)(OC(C)C)OC(C)C SDFBDFHBGFUNGG-UHFFFAOYSA-N 0.000 description 1
- QSCMLRSSRJJJKX-UHFFFAOYSA-N CC=1C(=C(C(OC1)SSSSC1OC=C(C(=C1[SiH2]OCC)CCCC)C)[SiH2]OCC)CCCC Chemical compound CC=1C(=C(C(OC1)SSSSC1OC=C(C(=C1[SiH2]OCC)CCCC)C)[SiH2]OCC)CCCC QSCMLRSSRJJJKX-UHFFFAOYSA-N 0.000 description 1
- JXWBEOBROLXBGC-UHFFFAOYSA-N CO[SiH2]C(C)(C)CSSCC(C)(C)[SiH2]OC Chemical compound CO[SiH2]C(C)(C)CSSCC(C)(C)[SiH2]OC JXWBEOBROLXBGC-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- NVHLTUPSVCBIJJ-UHFFFAOYSA-N [1-[(1,2-dimethoxy-2-methyl-1-phenylsilylpropyl)disulfanyl]-1,2-dimethoxy-2-methylpropyl]-phenylsilane Chemical compound COC(C([SiH2]C1=CC=CC=C1)(OC)SSC(C(C)(OC)C)(OC)[SiH2]C1=CC=CC=C1)(C)C NVHLTUPSVCBIJJ-UHFFFAOYSA-N 0.000 description 1
- SKFWHOBZYWUYMC-UHFFFAOYSA-N [2-[(2-diethoxysilyl-2-methoxyethyl)tetrasulfanyl]-1-methoxyethyl]-diethoxysilane Chemical compound CCO[SiH](OCC)C(OC)CSSSSCC(OC)[SiH](OCC)OCC SKFWHOBZYWUYMC-UHFFFAOYSA-N 0.000 description 1
- PWRCPTKSXMCQLS-UHFFFAOYSA-N [3-[(3,3-diphenyl-3-propan-2-yloxysilylpropyl)tetrasulfanyl]-1,1-diphenylpropyl]-propan-2-yloxysilane Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)([SiH2]OC(C)C)CCSSSSCCC([SiH2]OC(C)C)(C=1C=CC=CC=1)C1=CC=CC=C1 PWRCPTKSXMCQLS-UHFFFAOYSA-N 0.000 description 1
- AIQUYWRDQFFHKH-UHFFFAOYSA-N [3-[(3-dimethoxysilyl-3-phenylpropyl)tetrasulfanyl]-1-phenylpropyl]-dimethoxysilane Chemical compound C1(=CC=CC=C1)C(CCSSSSCCC(C1=CC=CC=C1)[SiH](OC)OC)[SiH](OC)OC AIQUYWRDQFFHKH-UHFFFAOYSA-N 0.000 description 1
- UHBSMIYRAQANCI-UHFFFAOYSA-N [3-ethyl-1-[(3-ethyl-3-methoxysilylpentyl)tetrasulfanyl]pentan-3-yl]-methoxysilane Chemical compound C(C)C(CCSSSSCCC(CC)(CC)[SiH2]OC)([SiH2]OC)CC UHBSMIYRAQANCI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- RTACIUYXLGWTAE-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene;styrene Chemical compound C=CC=C.CC(=C)C=C.C=CC1=CC=CC=C1 RTACIUYXLGWTAE-UHFFFAOYSA-N 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- GITLYQNXZPGJRU-UHFFFAOYSA-N butan-2-yloxy-[1-[(2-butan-2-yloxysilyl-2-methylpropyl)trisulfanyl]-2-methylpropan-2-yl]silane Chemical compound CC(CSSSCC([SiH2]OC(C)CC)(C)C)([SiH2]OC(C)CC)C GITLYQNXZPGJRU-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- GPRMZRVUGCUUCQ-UHFFFAOYSA-N cyclohexyloxy-[3-[(3-cyclohexyloxysilyl-3,3-diphenylpropyl)disulfanyl]-1,1-diphenylpropyl]silane Chemical compound C1(=CC=CC=C1)C(CCSSCCC(C1=CC=CC=C1)(C1=CC=CC=C1)[SiH2]OC1CCCCC1)([SiH2]OC1CCCCC1)C1=CC=CC=C1 GPRMZRVUGCUUCQ-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- CVTGXJYPLFSIDQ-UHFFFAOYSA-N di(butan-2-yloxy)-[1-[3-di(butan-2-yloxy)silylpentyldisulfanyl]pentan-3-yl]silane Chemical compound C(C)C(CCSSCCC([SiH](OC(C)CC)OC(C)CC)CC)[SiH](OC(C)CC)OC(C)CC CVTGXJYPLFSIDQ-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- LAQYGVFTFKGFLA-UHFFFAOYSA-N dimethoxymethyl-[5-[5-(dimethoxymethylsilyl)pentyltrisulfanyl]pentyl]silane Chemical compound COC(OC)[SiH2]CCCCCSSSCCCCC[SiH2]C(OC)OC LAQYGVFTFKGFLA-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- AWJOGEUUYZRGOU-UHFFFAOYSA-N ethylsulfanyl-[4-[(3-ethylsulfanylsilyl-3-methylbutyl)tetrasulfanyl]-2-methylbutan-2-yl]silane Chemical compound CC(CCSSSSCCC(C)(C)[SiH2]SCC)([SiH2]SCC)C AWJOGEUUYZRGOU-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- GZOUCNGRFRMHIZ-UHFFFAOYSA-N methoxy-[1-[(2-methoxysilyl-3-phenylpropyl)trisulfanyl]-3-phenylpropan-2-yl]silane Chemical compound C=1C=CC=CC=1CC([SiH2]OC)CSSSCC([SiH2]OC)CC1=CC=CC=C1 GZOUCNGRFRMHIZ-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
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- 150000001282 organosilanes Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
- 239000006235 reinforcing carbon black Substances 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical group [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- ATYIZISYPACGCO-UHFFFAOYSA-N tributoxy-[3-(3-tributoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCCSSCCC[Si](OCCCC)(OCCCC)OCCCC ATYIZISYPACGCO-UHFFFAOYSA-N 0.000 description 1
- NMPPNPIZYXDMMY-UHFFFAOYSA-N tricyclohexyloxy-[3-(3-tricyclohexyloxysilylpropyltetrasulfanyl)propyl]silane Chemical compound C1CCCCC1O[Si](OC1CCCCC1)(OC1CCCCC1)CCCSSSSCCC[Si](OC1CCCCC1)(OC1CCCCC1)OC1CCCCC1 NMPPNPIZYXDMMY-UHFFFAOYSA-N 0.000 description 1
- RLQRJIRGQDCNKY-UHFFFAOYSA-N tricyclopentyloxy-[3-(3-tricyclopentyloxysilylpropyltrisulfanyl)propyl]silane Chemical compound C1CCCC1O[Si](OC1CCCC1)(OC1CCCC1)CCCSSSCCC[Si](OC1CCCC1)(OC1CCCC1)OC1CCCC1 RLQRJIRGQDCNKY-UHFFFAOYSA-N 0.000 description 1
- ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 description 1
- KORAJTACFWEGPU-UHFFFAOYSA-N triethoxy-[6-(6-triethoxysilylhexyltetrasulfanyl)hexyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCCCCSSSSCCCCCC[Si](OCC)(OCC)OCC KORAJTACFWEGPU-UHFFFAOYSA-N 0.000 description 1
- XGVRSFOOQXXSDO-UHFFFAOYSA-N trihexoxy-[3-(3-trihexoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCCCCCO[Si](OCCCCCC)(OCCCCCC)CCCSSCCC[Si](OCCCCCC)(OCCCCCC)OCCCCCC XGVRSFOOQXXSDO-UHFFFAOYSA-N 0.000 description 1
- XQCNPXMIHJAHGO-UHFFFAOYSA-N trimethoxy-[(trimethoxysilylmethyltetrasulfanyl)methyl]silane Chemical compound CO[Si](OC)(OC)CSSSSC[Si](OC)(OC)OC XQCNPXMIHJAHGO-UHFFFAOYSA-N 0.000 description 1
- SVNJQEIWNMNTBW-UHFFFAOYSA-N trimethoxy-[18-(18-trimethoxysilyloctadecyltetrasulfanyl)octadecyl]silane Chemical compound CO[Si](OC)(OC)CCCCCCCCCCCCCCCCCCSSSSCCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SVNJQEIWNMNTBW-UHFFFAOYSA-N 0.000 description 1
- IPBOZRUUILDBBF-UHFFFAOYSA-N trimethoxy-[2-methyl-1-[(2-methyl-1-trimethoxysilylpropyl)tetrasulfanyl]propyl]silane Chemical compound CO[Si](OC)(OC)C(C(C)C)SSSSC(C(C)C)[Si](OC)(OC)OC IPBOZRUUILDBBF-UHFFFAOYSA-N 0.000 description 1
- NQRACKNXKKOCJY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSCCC[Si](OC)(OC)OC NQRACKNXKKOCJY-UHFFFAOYSA-N 0.000 description 1
- YGLOWFUKVQMIQC-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropylhexasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSSSCCC[Si](OC)(OC)OC YGLOWFUKVQMIQC-UHFFFAOYSA-N 0.000 description 1
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 description 1
- BPBNXPYFZUPVRY-UHFFFAOYSA-N trimethoxy-[3-(4-trimethoxysilylbut-1-en-2-yltetrasulfanyl)but-3-enyl]silane Chemical compound CO[Si](OC)(OC)CCC(=C)SSSSC(=C)CC[Si](OC)(OC)OC BPBNXPYFZUPVRY-UHFFFAOYSA-N 0.000 description 1
- WUMASLCNJBRHDA-UHFFFAOYSA-N trimethoxy-[4-(4-trimethoxysilylbutyltetrasulfanyl)butyl]silane Chemical compound CO[Si](OC)(OC)CCCCSSSSCCCC[Si](OC)(OC)OC WUMASLCNJBRHDA-UHFFFAOYSA-N 0.000 description 1
- ORMMMPDHLQZPEB-UHFFFAOYSA-N trioctoxy-[3-(3-trioctoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCCCCCCCO[Si](OCCCCCCCC)(OCCCCCCCC)CCCSSSSCCC[Si](OCCCCCCCC)(OCCCCCCCC)OCCCCCCCC ORMMMPDHLQZPEB-UHFFFAOYSA-N 0.000 description 1
- VKJFZCCNSAEGRS-UHFFFAOYSA-N tripropoxy-[18-(18-tripropoxysilyloctadec-1-enyltetrasulfanyl)octadec-17-enyl]silane Chemical compound CCCO[Si](OCCC)(OCCC)CCCCCCCCCCCCCCCCC=CSSSSC=CCCCCCCCCCCCCCCCC[Si](OCCC)(OCCC)OCCC VKJFZCCNSAEGRS-UHFFFAOYSA-N 0.000 description 1
- HRAOIWWIABULSC-UHFFFAOYSA-N tripropoxy-[2-(2-tripropoxysilylethylpentasulfanyl)ethyl]silane Chemical compound CCCO[Si](OCCC)(OCCC)CCSSSSSCC[Si](OCCC)(OCCC)OCCC HRAOIWWIABULSC-UHFFFAOYSA-N 0.000 description 1
- IRNPVNAUHNTHDI-UHFFFAOYSA-N tris(6-methylheptoxy)-[3-[3-[tris(6-methylheptoxy)silyl]propyltetrasulfanyl]propyl]silane Chemical compound CC(C)CCCCCO[Si](OCCCCCC(C)C)(OCCCCCC(C)C)CCCSSSSCCC[Si](OCCCCCC(C)C)(OCCCCCC(C)C)OCCCCCC(C)C IRNPVNAUHNTHDI-UHFFFAOYSA-N 0.000 description 1
- CONCKWGHNZAEBO-UHFFFAOYSA-N tris[(2-methylpropan-2-yl)oxy]-[3-[3-[tris[(2-methylpropan-2-yl)oxy]silyl]propyldisulfanyl]propyl]silane Chemical compound CC(C)(C)O[Si](OC(C)(C)C)(OC(C)(C)C)CCCSSCCC[Si](OC(C)(C)C)(OC(C)(C)C)OC(C)(C)C CONCKWGHNZAEBO-UHFFFAOYSA-N 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US91541397A | 1997-08-20 | 1997-08-20 | |
| US915413 | 1997-08-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11130918A true JPH11130918A (ja) | 1999-05-18 |
Family
ID=25435684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10231317A Pending JPH11130918A (ja) | 1997-08-20 | 1998-08-18 | 未硬化ゴムコンパウンドへの予備硬化ゴムコンパウンドの硬化接着性を改善する方法 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0897946A3 (fr) |
| JP (1) | JPH11130918A (fr) |
| BR (1) | BR9803153A (fr) |
| CA (1) | CA2244355A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011102081A1 (fr) * | 2010-02-18 | 2011-08-25 | 株式会社ブリヂストン | Procédé et appareil pour produire un produit en caoutchouc |
| JP2015178631A (ja) * | 2010-10-01 | 2015-10-08 | 株式会社ブリヂストン | ゴム組成物の製造方法 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017091319A1 (fr) * | 2015-11-23 | 2017-06-01 | Bridgestone Americas Tire Operations, Llc | Bandages pneumatiques à composants de composition similaire |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2996420A (en) * | 1956-10-01 | 1961-08-15 | Firestone Tire & Rubber Co | Laminated article |
| JPS54155283A (en) * | 1978-05-30 | 1979-12-07 | Bridgestone Corp | Bond of unvulcanized rubber to vulcanized rubber by cure |
-
1998
- 1998-07-30 CA CA002244355A patent/CA2244355A1/fr not_active Abandoned
- 1998-08-13 BR BR9803153-8A patent/BR9803153A/pt not_active Application Discontinuation
- 1998-08-18 JP JP10231317A patent/JPH11130918A/ja active Pending
- 1998-08-20 EP EP98115655A patent/EP0897946A3/fr not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011102081A1 (fr) * | 2010-02-18 | 2011-08-25 | 株式会社ブリヂストン | Procédé et appareil pour produire un produit en caoutchouc |
| JP2015178631A (ja) * | 2010-10-01 | 2015-10-08 | 株式会社ブリヂストン | ゴム組成物の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR9803153A (pt) | 1999-12-14 |
| CA2244355A1 (fr) | 1999-02-20 |
| EP0897946A3 (fr) | 2000-04-19 |
| EP0897946A2 (fr) | 1999-02-24 |
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