JPH1116618A - Method for connecting superconductive wire - Google Patents
Method for connecting superconductive wireInfo
- Publication number
- JPH1116618A JPH1116618A JP9168453A JP16845397A JPH1116618A JP H1116618 A JPH1116618 A JP H1116618A JP 9168453 A JP9168453 A JP 9168453A JP 16845397 A JP16845397 A JP 16845397A JP H1116618 A JPH1116618 A JP H1116618A
- Authority
- JP
- Japan
- Prior art keywords
- stabilizing metal
- connection
- joining
- stabilizing
- superconductive wire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title description 13
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 claims abstract description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 238000003825 pressing Methods 0.000 claims abstract description 6
- 238000005304 joining Methods 0.000 claims description 27
- 239000012535 impurity Substances 0.000 claims description 11
- 238000005554 pickling Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 abstract description 19
- 239000002887 superconductor Substances 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 230000006866 deterioration Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 238000005406 washing Methods 0.000 abstract 1
- 239000010949 copper Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011810 insulating material Substances 0.000 description 3
- 238000005476 soldering Methods 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 229910020012 Nb—Ti Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E40/00—Technologies for an efficient electrical power generation, transmission or distribution
- Y02E40/60—Superconducting electric elements or equipment; Power systems integrating superconducting elements or equipment
Landscapes
- Pressure Welding/Diffusion-Bonding (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は超伝導マグネット等
の超伝導線材の接続方法に関する。The present invention relates to a method for connecting a superconducting wire such as a superconducting magnet.
【０００２】[0002]
【従来の技術】従来、超伝導線材の接合方法としては、
はんだ付、スポット溶接、かしめ接合などが用いられて
いる。しかしながら、はんだ付は簡便な方法であるが、
接続部の抵抗ははんだ及び接合部の長さに依存し、低い
電気抵抗値を得るのが困難である。また、スポット溶接
のような溶融接合では、接合時の熱影響によって超伝導
線が劣化する場合がある。さらに、また、かしめ接合等
の直接接合法では、インサート材を用いないため接合抵
抗を下げることができるが、安定化材である銅を削除
し、超伝導線同士を接続するため、超伝導状態が破壊さ
れた場合には安定化材が存在しないために電気抵抗が急
激に上昇し、超伝導線材を破損することがある。2. Description of the Related Art Conventionally, as a method of joining a superconducting wire,
Soldering, spot welding, caulking, and the like are used. However, soldering is a simple method,
The resistance of the connection part depends on the length of the solder and the joint part, and it is difficult to obtain a low electric resistance value. In addition, in fusion joining such as spot welding, the superconducting wire may be deteriorated due to the thermal effect at the time of joining. In addition, in the direct joining method such as caulking, the joining resistance can be reduced because an insert material is not used. However, since the stabilizing material, copper, is removed and the superconducting wires are connected to each other, the superconducting state is reduced. In the case where is destroyed, since the stabilizing material does not exist, the electric resistance rises sharply, and the superconducting wire may be damaged.
【０００３】[0003]
【発明が解決しようとする課題】本発明は上記従来の超
伝導線材の接合方法、すなわち、はんだ付、スポット溶
接、かしめ接合などの接合方法におけるような不具合の
ない超伝導線材の接合方法を提供しようとするものであ
る。SUMMARY OF THE INVENTION The present invention provides a method for joining superconducting wires without the disadvantages of the above-mentioned conventional joining methods for superconducting wires, that is, joining methods such as soldering, spot welding, and caulking. What you want to do.
【０００４】[0004]
【課題を解決するための手段】本発明は外部を安定化金
属で被覆した超伝導線材同士を接合するに当り、接合部
の被覆安定化金属表面の不純物を酸洗して除去した後、
接合部を重ね合せ、真空中で１００〜４００℃に加熱し
ながら安定化金属を含む超伝導線材が塑性変形する加圧
力を負荷して加圧接合することを特徴とする超伝導線材
の接合方法である。According to the present invention, in joining superconducting wires whose outer surfaces are coated with a stabilizing metal, impurities on the surface of the stabilizing metal coated at the joint are removed by pickling to remove impurities.
A joining method of superconducting wires, wherein the joining portions are overlapped and pressurized by applying a pressing force for plastically deforming a superconducting wire containing a stabilizing metal while heating to 100 to 400 ° C. in a vacuum. It is.
【０００５】[0005]
【発明の実施の形態】本発明の対象とする超伝導線材の
超伝導体としてはＮｂＴｉ（Ｎｂ−５０ａｔ％Ｔｉ）を
初め、Ｎｂ3 Ｇｅ（Ｎｂ−２５ａｔ％Ｇｅ），Ｎｂ3 Ｓ
ｎ（Ｎｂ−２５ａｔ％Ｓｎ），Ｖ3 Ｇａ（Ｖ−２５ａｔ
％Ｇａ），Ｎｂ3 Ａｌ（Ｎｂ−２５ａｔ％Ａｌ）などが
あげられ、超伝導線材を被覆する安定化材としてはＣｕ
を初め、Ａｌ，Ａｇなどがあげられる。安定化金属で被
覆した超伝導線材を接合する前に、接合部の安定化金属
の表面の不純物を除去するのは不純物が十分な複合を阻
害するからであって、安定化金属の種類如何によって生
成している不純物も様々であるので、不純物の除去に適
する酸を使用して除去する。なお、一般的に安定化金属
で被覆した超伝導線材の表面には、エナメルなどの絶縁
材が塗布されているので、安定化金属の酸洗の前に接合
部の絶縁材を機械的に除去しておくのがよい。DESCRIPTION OF THE PREFERRED EMBODIMENTS The superconductors of the superconducting wires to which the present invention is applied include NbTi (Nb-50 at% Ti), Nb 3 Ge (Nb-25 at% Ge), and Nb 3 S.
n (Nb-25at% Sn) , V 3 Ga (V-25at
% Ga), Nb 3 Al (Nb-25 at% Al) and the like. As a stabilizing material for covering the superconducting wire, Cu is used.
And Al, Ag and the like. Before joining the superconducting wire coated with the stabilizing metal, the impurities on the surface of the stabilizing metal at the joint are removed because the impurities impede sufficient compounding, and depending on the type of the stabilizing metal. Since various impurities are generated, the impurities are removed by using an acid suitable for removing the impurities. Generally, the surface of the superconducting wire coated with the stabilizing metal is coated with an insulating material such as enamel, so the insulating material at the joint is mechanically removed before the pickling of the stabilizing metal. It is good to keep.
【０００６】接合に当っては、不純物を除去した部分の
安定化金属被覆超伝導線材同士を真空中（５×１０-4Ｔ
ｏｒｒ以下）で、１００〜４００℃に加熱しながら、安
定化金属を含む超伝導線材が塑性変形する加圧力を負荷
して加圧接合する。真空中で加圧するのは安定化金属表
面の酸化を防するためであり、加熱温度を上記のように
設定したのは１００℃未満では接合ができず、４００℃
を超える温度では超伝導線材の状態が劣化するからであ
る。[0006] In joining, the stabilizing metal-coated superconducting wires in the portion from which impurities have been removed are placed in a vacuum (5 × 10 -4 T).
(orr or less), while applying a pressure of 100 to 400 ° C. and applying a pressing force at which the superconducting wire containing the stabilizing metal undergoes plastic deformation, to perform pressure joining. Pressing in a vacuum is for preventing oxidation of the surface of the stabilized metal, and the heating temperature is set as described above.
If the temperature exceeds the above, the state of the superconducting wire is deteriorated.
【０００７】[0007]
【実施例】以下、本発明の具体的な実施例を、図１、図
２を参照しながら説明し、本発明の効果を明らかにす
る。図１は本発明の一実施例に係る接合方法の説明図、
図２は本発明の一実施例により接合した超伝導線材の接
合抵抗の測定効果を示す図表である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, specific embodiments of the present invention will be described with reference to FIGS. 1 and 2 to clarify the effects of the present invention. FIG. 1 is an explanatory diagram of a joining method according to one embodiment of the present invention,
FIG. 2 is a table showing the effect of measuring the joining resistance of the superconducting wires joined according to one embodiment of the present invention.
【０００８】超伝導線として直径０．７ｍｍのＮｂ−Ｔ
ｉ（Ｎｂ−５０ａｔ％Ｔｉ）多芯線を用いて接合試験を
行った。あらかじめ、超伝導線表面のエナメル絶縁材を
機械的に除去した後、１０％硫酸水溶液中に先端部分２
０〜３０ｍｍを約１分間浸漬し、Ｃｕ安定化材表面の酸
化物及び不純物を除去し、接合用の超伝導線材１とし
た。これを図１に示すように、接合部を約２０ｍｍ重ね
合せて軟鋼ボックス製治具２中にセットし、真空雰囲気
（５×１０-4Ｔｏｒｒ以下）で、加熱温度：３００℃、
保持時間：６０ｍｉｎ、加圧力：１０ｋｇｆ／ｍｍ2 で
接合した。Nb-T having a diameter of 0.7 mm as a superconducting wire
A bonding test was performed using i (Nb-50at% Ti) multifilamentary wire. After mechanically removing the enamel insulating material from the surface of the superconducting wire in advance, the tip 2 is placed in a 10% sulfuric acid aqueous solution.
0 to 30 mm was immersed for about 1 minute to remove oxides and impurities on the surface of the Cu stabilizing material to obtain a superconducting wire 1 for bonding. As shown in FIG. 1, as shown in FIG. 1, the joining portion was overlapped by about 20 mm, and set in a mild steel box jig 2. In a vacuum atmosphere (5 × 10 −4 Torr or less), a heating temperature: 300 ° C.
The bonding was performed at a holding time of 60 min and a pressure of 10 kgf / mm 2 .
【０００９】上記条件で接合を行った超伝導線材の接続
抵抗の測定結果を図２に示す。図２から明らかなよう
に、本発明接合方法によれば、はんだ接合に比べて３〜
４桁低い抵抗値となっており、その効果が極めて優れて
いることが判る。FIG. 2 shows the measurement results of the connection resistance of the superconducting wires joined under the above conditions. As is clear from FIG. 2, according to the joining method of the present invention, three to three times as compared with solder joining.
The resistance value is four orders of magnitude lower, indicating that the effect is extremely excellent.
【００１０】以上、超伝導体としてＮｂ−Ｔｉを、安定
化金属としてＣｕを被覆した超伝導線材を接合する場合
について説明したが、他の安定化金属、超伝導体よりな
る超伝導線材を本発明方法により接合しても、ほぼ同様
の結果が得られた。The case of joining a superconducting wire coated with Nb-Ti as a superconductor and Cu as a stabilizing metal has been described above, but a superconducting wire made of another stabilizing metal and a superconductor is used. Almost the same results were obtained even when bonding was performed by the method of the present invention.
【００１１】[0011]
【発明の効果】本発明によれば、表面に被覆された超伝
導線材の接合部の安定化金属の表面を酸洗することによ
り、表面の酸化物や油脂等の不純物を完全に除去し、接
合に適した活性な表面を得ることができ、そのため、接
合時の加熱温度を低く抑えることが可能となり、超伝導
線材の性能劣化を防止することができる。According to the present invention, impurities such as oxides and fats and oils on the surface are completely removed by pickling the surface of the stabilizing metal at the joint of the superconducting wire rod coated on the surface, An active surface suitable for joining can be obtained, so that the heating temperature at the time of joining can be kept low, and performance deterioration of the superconducting wire can be prevented.
【図１】本発明の一実施例に係る接合方法の説明図。FIG. 1 is an explanatory diagram of a joining method according to one embodiment of the present invention.
【図２】本発明の一実施例により接合した超伝導線材の
接続抵抗の測定結果を示す図表。FIG. 2 is a table showing measurement results of connection resistance of superconducting wires joined according to one embodiment of the present invention.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｈ０１Ｂ 12/04 ＺＡＡ Ｈ０１Ｂ 12/04 ＺＡＡ ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 6 Identification code FI H01B 12/04 ZAA H01B 12/04 ZAA
Claims (1)
同士を接合するに当り、接合部の被覆安定化金属表面の
不純物を酸洗して除去した後、接合部を重ね合せ、真空
中で１００〜４００℃に加熱しながら安定化金属を含む
超伝導線材が塑性変形する加圧力を負荷して加圧接合す
ることを特徴とする超伝導線材の接合方法。At the time of joining superconducting wires whose outer surfaces are covered with a stabilizing metal, impurities on the surface of the stabilizing metal coated at the joining portion are removed by pickling, and the joining portions are overlapped with each other. A superconducting wire containing a stabilizing metal, while heating to 100 to 400 [deg.] C., and applying a pressing force to plastically deform the superconducting wire, and pressure joining.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16845397A JP3305233B2 (en) | 1997-06-25 | 1997-06-25 | Superconducting wire connection method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16845397A JP3305233B2 (en) | 1997-06-25 | 1997-06-25 | Superconducting wire connection method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH1116618A true JPH1116618A (en) | 1999-01-22 |
| JP3305233B2 JP3305233B2 (en) | 2002-07-22 |
Family
ID=15868396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16845397A Expired - Fee Related JP3305233B2 (en) | 1997-06-25 | 1997-06-25 | Superconducting wire connection method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3305233B2 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002056318A1 (en) * | 2001-01-16 | 2002-07-18 | Nippon Steel Corporation | Low resistance conductor, method of producing the same, and electric component using the same |
| JP2007012582A (en) * | 2005-05-30 | 2007-01-18 | Internatl Superconductivity Technology Center | RE oxide superconducting wire joining method |
| CN100452250C (en) * | 2001-01-16 | 2009-01-14 | 新日本制铁株式会社 | Low-resistance conductor, manufacturing method thereof, and electronic component using same |
| JP2011003382A (en) * | 2009-06-18 | 2011-01-06 | Sumitomo Electric Ind Ltd | Connection method and connection device of superconducting wire rod |
| CN102886615A (en) * | 2012-10-22 | 2013-01-23 | 苏州奔一机电有限公司 | Fusion welding process for metals |
| JP5608842B1 (en) * | 2013-05-28 | 2014-10-15 | 株式会社フジクラ | Wire rod connecting device, wire rod connecting method, and manufacturing method of connection structure |
| CN105636719A (en) * | 2013-08-16 | 2016-06-01 | K.约恩 | ReBCO high temperature superconducting wire bonding device and bonding method using same |
-
1997
- 1997-06-25 JP JP16845397A patent/JP3305233B2/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002056318A1 (en) * | 2001-01-16 | 2002-07-18 | Nippon Steel Corporation | Low resistance conductor, method of producing the same, and electric component using the same |
| US7126060B2 (en) | 2001-01-16 | 2006-10-24 | Nippon Steel Corporation | Low resistance conductors, processes of production thereof, and electrical members using same |
| US7138581B2 (en) | 2001-01-16 | 2006-11-21 | Nippon Steel Corporation | Low resistance conductor, processes of production thereof, and electrical members using same |
| CN100452250C (en) * | 2001-01-16 | 2009-01-14 | 新日本制铁株式会社 | Low-resistance conductor, manufacturing method thereof, and electronic component using same |
| JP2007012582A (en) * | 2005-05-30 | 2007-01-18 | Internatl Superconductivity Technology Center | RE oxide superconducting wire joining method |
| JP2011003382A (en) * | 2009-06-18 | 2011-01-06 | Sumitomo Electric Ind Ltd | Connection method and connection device of superconducting wire rod |
| CN102886615A (en) * | 2012-10-22 | 2013-01-23 | 苏州奔一机电有限公司 | Fusion welding process for metals |
| JP5608842B1 (en) * | 2013-05-28 | 2014-10-15 | 株式会社フジクラ | Wire rod connecting device, wire rod connecting method, and manufacturing method of connection structure |
| WO2014192832A1 (en) * | 2013-05-28 | 2014-12-04 | 株式会社フジクラ | Wire rod connection device, wire rod connection method, and method for manufacturing connection structure |
| US9685769B2 (en) | 2013-05-28 | 2017-06-20 | Fujikura Ltd. | Wire splicing device, wire splicing method, and method for manufacturing splice structure |
| US10014671B2 (en) | 2013-05-28 | 2018-07-03 | Fujikura Ltd. | Wire splicing device, wire splicing method, and method for manufacturing splice structure |
| US10044176B2 (en) | 2013-05-28 | 2018-08-07 | Fujikura Ltd. | Wire splicing device, wire splicing method, and method for manufacturing splice structure |
| CN105636719A (en) * | 2013-08-16 | 2016-06-01 | K.约恩 | ReBCO high temperature superconducting wire bonding device and bonding method using same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3305233B2 (en) | 2002-07-22 |
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