JPH111680A - Gasket material - Google Patents
Gasket materialInfo
- Publication number
- JPH111680A JPH111680A JP17312097A JP17312097A JPH111680A JP H111680 A JPH111680 A JP H111680A JP 17312097 A JP17312097 A JP 17312097A JP 17312097 A JP17312097 A JP 17312097A JP H111680 A JPH111680 A JP H111680A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- layer
- cork
- gasket material
- nonwoven fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
(57)【要約】
【課題】 開口部の密封をなすガスケット材に関してお
り、層状に形成して高いシール性及び防音性さらに防振
性等を発揮することのできるガスケット材を提供する目
的を持つ。
【解決手段】 ガスケット材(A)であって、合成ゴム
(1)とコルク粒(2)を練り込んでゴムシート(3)
を形成せしめ、該ゴムシート(3)の両側へ不織布
(2)を接着剤を介して配置せしめてこれを加硫せし
め、中層にコルク層(5)を、その両側面に不織布層
(6)を、両外表面にゴム層(7)を形成一体化せしめ
る。これにより、十分な硬度と強度のガスケット材が得
られしかも良好な圧縮性をも発揮するものとなる。
(57) [Summary] [Problem] To provide a gasket material that forms an opening and that can exhibit high sealing performance, soundproofing, vibration-proofing, etc., in a layered manner. . SOLUTION: The gasket material (A) is a rubber sheet (3) in which synthetic rubber (1) and cork particles (2) are kneaded.
Is formed, and a nonwoven fabric (2) is arranged on both sides of the rubber sheet (3) via an adhesive, and then vulcanized, and a cork layer (5) is provided as an intermediate layer, and a nonwoven fabric layer (6) is provided on both sides thereof. To form a rubber layer (7) on both outer surfaces. As a result, a gasket material having sufficient hardness and strength can be obtained and also exhibit good compressibility.
Description
【0001】[0001]
【発明の属する技術分野】本発明は、開口部を有する二
部材間に介在せしめてその部材間の密封をなすガスケッ
ト材に関しており、具体的には、シール性、防音性、及
び防振性等に優れるガスケット材に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gasket material which is interposed between two members having an opening and seals the members, and more specifically, has a sealing property, a soundproofing property, a vibrationproofing property and the like. It relates to a gasket material which is excellent.
【0002】[0002]
【従来の技術】従来、密封必要部材間に装着してその密
封をなさしめるガスケット材にあっては、圧縮性及び成
形性に優れる合成ゴム材料、あるいはこの合成ゴム材料
に適度の粒度に粉砕形成されたコルク粒を混練して形成
したコルク粒入り合成ゴム材料などが採用されている
が、昨今のエンジンの軽量化、高熱化、高回転化に伴
い、高い圧縮性、高強度性、耐熱性などが求められてお
り、これに対応するためには価格的及び成型的には不利
となるが材料特性に優れるアクリルゴムが多く採用され
るようになり現在ではガスケット材の主流となってい
る。2. Description of the Related Art Conventionally, a gasket material which is mounted between members which need to be hermetically sealed to achieve sealing is made of a synthetic rubber material excellent in compressibility and moldability, or formed by pulverizing the synthetic rubber material to an appropriate particle size. Synthetic rubber material containing cork particles formed by kneading the cork particles is used, but with recent engine weight reduction, high heat and high speed, high compressibility, high strength, heat resistance In order to respond to this demand, acrylic rubber, which is disadvantageous in terms of cost and molding but is excellent in material properties, has been widely used, and is currently the mainstream of gasket materials.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、エンジ
ンのコンパクト化、高出力化に伴いさらに高い圧縮性と
か高強度性の向上が望まれており、高性能な材料による
ガスケットが検討されている。このような状況にあっ
て、要求される性能を満たし価格的に優位なガスケット
材料としてはシリコーンゴム、フロロシリコーンゴム、
あるいはフッ素ゴムなどが知られているが、シリコーン
ゴム系は耐エンジン油性に劣り、フッ素ゴムは極端なコ
ストアップにつながるなどのマイナス面を有している。However, with the downsizing and higher output of the engine, further improvement in compressibility and strength is desired, and gaskets made of high-performance materials are being studied. Under these circumstances, gasket materials that meet the required performance and are superior in price include silicone rubber, fluorosilicone rubber,
Alternatively, fluorine rubber and the like are known, but silicone rubbers have poor engine oil resistance, and fluorine rubbers have disadvantages such as an extreme increase in cost.
【0004】また、アクリルゴム、シリコーンゴム、あ
るいはフッ素ゴムなどを種々ブレンドしたブレンドゴム
や、新規なゴム材料で前記の耐熱性あるいは低価格性等
の諸要求を満足させるものは未だ開発されていない。一
方、コルク材料においては、圧縮性材料として横流れの
少ないガスケット材として使用されているが、ヘタリを
発生させるため大きな荷重を加えることができず、さら
に強度が弱いため薄板状の製品を造形することができな
い。本発明はこのような欠点を解消し、密封性に優れか
つ防音、防振性に富むガスケット材を提供しようとする
ものである。[0004] Further, a blend rubber obtained by blending various kinds of acrylic rubber, silicone rubber, fluorine rubber and the like, and a novel rubber material satisfying the above-mentioned requirements such as heat resistance and low price have not yet been developed. . On the other hand, cork material is used as a gasket material with little lateral flow as a compressible material, but it cannot be applied with a large load because it generates settling, and its strength is weak, so it is necessary to mold a thin plate product Can not. An object of the present invention is to eliminate such disadvantages and to provide a gasket material which is excellent in sealing performance and has excellent soundproofing and vibration-proofing properties.
【0005】[0005]
【課題を解決しようとする手段】本発明は図面によって
詳述すると、図1に示すように、内燃機関用のガスケッ
トあるいは冷凍機用ガスケット等に使用されるガスケッ
ト材(A)であって、図2に示すように未加硫の合成ゴ
ム(1)と粒度5〜30メッシュ程度に粉砕精製したコ
ルク粒(2)とを混練してゴムシート(3)を形成し、
形成したゴムシート(3)の両面へ接着剤を塗布した天
然繊維あるいは合成繊維からなる不織布(4)を配置し
てこれを加圧・加熱条件下で加硫成型せしめ、中層部に
コルクリッチとなるコルク層(5)を形成し、その両側
にゴム材と小粒のコルク粒(2)を内絡する不織布層
(6)を形成し、その両外表面に合成ゴム(1)を滲出
させてゴム層(7)を形成したことを特徴としている。The present invention will be described in detail with reference to the drawings. As shown in FIG. 1, the present invention relates to a gasket material (A) used for a gasket for an internal combustion engine or a gasket for a refrigerator. As shown in 2, a rubber sheet (3) is formed by kneading an unvulcanized synthetic rubber (1) and a cork particle (2) pulverized and refined to a particle size of about 5 to 30 mesh.
A nonwoven fabric (4) made of a natural fiber or a synthetic fiber coated with an adhesive is placed on both sides of the formed rubber sheet (3) and vulcanized under pressure and heating conditions. A cork layer (5) is formed, and a nonwoven fabric layer (6) enclosing a rubber material and small cork particles (2) is formed on both sides thereof, and synthetic rubber (1) is exuded on both outer surfaces thereof. It is characterized in that a rubber layer (7) is formed.
【0006】[0006]
【発明の実施の形態】本発明のガスケット材(A)は、
図2に示すように合成ゴム(1)にコルク粒(2)を混
練したゴムシート(3)とそのゴムシート(3)に適合
できる接着剤を塗布した不織布(4)とを両側面に重ね
合せ、これをプレス機等で加硫接着せしめてガスケット
材(A)を形成する。この加硫接着時に、ゴムシート
(3)は不織布(4)と共に圧縮されると密度の低い不
織布(4)の側へ流れ込もうとするが、内含するコルク
粒(2)は不織布(4)の複雑に絡み合う繊維のフィル
ター作用によってその移動流出が阻止されてそのまま残
り、反対に浸透・透過力に優れる合成ゴム(1)の一部
は不織布(4)を透過し表面側まで滲み出て加硫硬化さ
れる。ここで中部にコルクリッチのコルク層(5)が形
成され、これを両側から不織布層(6)で挟んでゴム層
(7)が形成される。この加硫成型の際、合成ゴム
(1)の加硫反応が進むと同時に不織布(4)に塗布し
た接着剤と化学結合を形成させ強固に一体化されたガス
ケット材(A)が得られる。このような作用によってよ
り強固な結合が形成される。BEST MODE FOR CARRYING OUT THE INVENTION The gasket material (A) of the present invention comprises:
As shown in FIG. 2, a rubber sheet (3) obtained by kneading cork particles (2) into a synthetic rubber (1) and a nonwoven fabric (4) coated with an adhesive compatible with the rubber sheet (3) are overlaid on both sides. Then, they are vulcanized and bonded by a press or the like to form a gasket material (A). During this vulcanization bonding, when the rubber sheet (3) is compressed together with the nonwoven fabric (4), the rubber sheet (3) tends to flow into the side of the low density nonwoven fabric (4). Due to the filter action of the complexly intertwined fibers, the movement and outflow are prevented and remain as it is. On the other hand, a part of the synthetic rubber (1) having excellent permeation / permeation power permeates the nonwoven fabric (4) and exudes to the surface side. Vulcanized and cured. Here, a cork-rich cork layer (5) is formed in the center, and a rubber layer (7) is formed by sandwiching the cork layer from both sides with a nonwoven fabric layer (6). In this vulcanization molding, the vulcanization reaction of the synthetic rubber (1) proceeds, and at the same time, a chemical bond is formed with the adhesive applied to the nonwoven fabric (4) to obtain a strongly integrated gasket material (A). By such an action, a stronger bond is formed.
【0007】[0007]
【実施例】本発明のガスケット材(A)の合成ゴム
(1)としては、ニトリルゴム、アクリルゴム、スチレ
ンブタジエンゴム、クロロブタジエンゴム、ブチルゴ
ム、シリコーンゴム、あるいはフッ素ゴム等を挙げるこ
とができる。次に、コルク粒(2)としては、天然のコ
ルク樹皮を粉砕機に投入しこれを細かく粉砕した後、5
〜30メッシュ程度の粒度に精製せしめて用いるもの
で、その特性は、軽量で強い弾力性と高い圧縮回復力を
有して熱絶縁性及び振動吸収性さらには遮音性などに優
れる特徴を持っている。また、不織布(4)としては、
ポリエステル繊維、ポリアミド繊維、ポリプロピレン繊
維、アクリル繊維、アラミド繊維、などの合成繊維、ま
たはガラス繊維、セラミックス繊維、炭素繊維などが挙
げられ、その厚みは約10〜200μm、秤量が約20
〜100g/m2、引っ張り強さが約1〜10kg/c
m2のものが用いられる。Examples of the synthetic rubber (1) of the gasket material (A) of the present invention include nitrile rubber, acrylic rubber, styrene butadiene rubber, chlorobutadiene rubber, butyl rubber, silicone rubber, and fluorine rubber. Next, as the cork grain (2), natural cork bark was put into a crusher and crushed finely.
It is used after being refined to a particle size of about 30 mesh, and has the characteristics that it is lightweight, has strong elasticity and high compression recovery force, and is excellent in heat insulation, vibration absorption, and sound insulation. I have. In addition, as the nonwoven fabric (4),
Examples thereof include synthetic fibers such as polyester fiber, polyamide fiber, polypropylene fiber, acrylic fiber, and aramid fiber, and glass fiber, ceramic fiber, and carbon fiber. The thickness is about 10 to 200 μm, and the weight is about 20.
100100 g / m 2 , tensile strength about 1-10 kg / c
m 2 is used.
【0008】本発明は、図1に示す合成ゴム(1)にコ
ルク粒(2)を混練したゴムシート(3)と接着剤を塗
布した複数の不織布(4)とからなるガスケット材
(A)であって、これを加硫成型して一体化せしめると
き、用いられたゴム材の種類に応じて、例えば温度15
0゜C〜250゜C、締め圧0.5〜40kg/cm2、成型
時間1〜60分間の加圧・加熱条件下で加硫成型せしめ
れば、明確に層状に形成されたコルク層(5)と不織布
層(6)とゴム層(7)からなるガスケット材(A)が
得られる。The present invention provides a gasket material (A) comprising a rubber sheet (3) obtained by kneading cork particles (2) into a synthetic rubber (1) shown in FIG. 1 and a plurality of nonwoven fabrics (4) coated with an adhesive. When vulcanizing and integrating them, depending on the type of rubber material used, for example, a temperature of 15
If vulcanization molding is carried out under the conditions of 0 ° C. to 250 ° C., a tightening pressure of 0.5 to 40 kg / cm 2 , and a pressing and heating time of 1 to 60 minutes, a cork layer which is clearly formed into a layer ( 5) A gasket material (A) comprising the nonwoven fabric layer (6) and the rubber layer (7) is obtained.
【0009】本発明では、前記の通りその表面は内側の
合成ゴムの滲出によってゴム層(7)で覆われるが、前
記合成ゴム(1)と不織布(4)の結合によって、比較
的硬度が高く引張り横流れしない強度の大きい層を形成
しており、中部のコルク層(5)の満足できる圧縮性、
及び前記表面側に位置するゴム層の良好な密着性によっ
て苛酷な密封条件に耐え得る高い密封性能を発揮するも
のとなっている。In the present invention, as described above, the surface is covered with the rubber layer (7) due to the exudation of the inner synthetic rubber, but the hardness is relatively high due to the connection between the synthetic rubber (1) and the nonwoven fabric (4). It forms a layer with high strength that does not cause cross-flow, and has satisfactory compressibility of the middle cork layer (5),
And, due to the good adhesion of the rubber layer located on the surface side, high sealing performance capable of withstanding severe sealing conditions is exhibited.
【0010】以下、表1によって本発明のガスケット材
と従来のコルク粒入りゴム材との特性比較を表わす。 The following Table 1 shows a comparison of characteristics between the gasket material of the present invention and a conventional rubber material containing cork particles.
【0011】[0011]
【発明の効果】本発明では、ゴム材にコルク材を混入せ
しめ不織布(4)をもって多層に形成することにより、
コルク材の特性である圧縮時の横流れの少ない特性とゴ
ム材の圧縮荷重を除去すると直ちに基形状に復元する良
好な復元性を引き出し、また不織布(4)と合成ゴム
(1)とを絡ませたことによって引っ張り強度などの機
械的特性を向上させる。この高い機械的強度によって締
付け面圧を高めることができ密封性能を飛躍的に向上さ
せる。また、高い機械的強度は薄板状のガスケット材の
造形が可能となる。According to the present invention, a rubber material is mixed with a cork material to form a multi-layered non-woven fabric (4).
The characteristic of the cork material, which is small in lateral flow at the time of compression, and the good resilience that immediately restores to the basic shape when the compression load of the rubber material is removed, and the nonwoven fabric (4) and the synthetic rubber (1) are entangled. This improves mechanical properties such as tensile strength. With this high mechanical strength, the tightening surface pressure can be increased, and the sealing performance is dramatically improved. In addition, high mechanical strength enables the formation of a thin gasket material.
【図面の簡単な説明】[Brief description of the drawings]
【図1】本発明の一実施例を示す断面図である。FIG. 1 is a sectional view showing an embodiment of the present invention.
【図2】本発明の他の実施例を示す断面図である。FIG. 2 is a sectional view showing another embodiment of the present invention.
A ガスケット材 1 合成ゴム 2 コルク粒 3 ゴムシート 4 不織布 5 コルク層 6 不織布層 7 ゴム層 A gasket material 1 synthetic rubber 2 cork grain 3 rubber sheet 4 nonwoven fabric 5 cork layer 6 nonwoven fabric layer 7 rubber layer
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI C08L 97/00 C08L 97/00 F16J 15/00 F16J 15/00 B // B29K 19:00 105:08 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI C08L 97/00 C08L 97/00 F16J 15/00 F16J 15/00 B // B29K 19:00 105: 08
Claims (1)
ュ程度に精製したコルク粒とを混練してゴムシートを形
成し、 形成したゴムシートの両面へ接着剤を塗布した不織布を
配置してこれを加圧・加熱条件下で加硫成型せしめ、 中層部にコルクリッチのコルク層を、その両側にゴム材
と小粒度のコルク粒を内絡した不織布層を、さらに両外
表面に合成ゴムを滲出させてゴム層を形成したことを特
徴とするガスケット材。1. A rubber sheet is formed by kneading unvulcanized synthetic rubber and cork particles purified to a particle size of about 5 to 30 mesh, and a nonwoven fabric coated with an adhesive is placed on both sides of the formed rubber sheet. Vulcanization molding under pressure and heating conditions, a cork-rich cork layer in the middle layer, a non-woven fabric layer containing rubber material and small-grain cork particles on both sides, and a composite on both outer surfaces A gasket material comprising a rubber layer formed by leaching rubber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17312097A JP3621231B2 (en) | 1997-06-12 | 1997-06-12 | Gasket material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17312097A JP3621231B2 (en) | 1997-06-12 | 1997-06-12 | Gasket material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH111680A true JPH111680A (en) | 1999-01-06 |
| JP3621231B2 JP3621231B2 (en) | 2005-02-16 |
Family
ID=15954518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17312097A Expired - Fee Related JP3621231B2 (en) | 1997-06-12 | 1997-06-12 | Gasket material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3621231B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6871168B1 (en) | 1999-05-12 | 2005-03-22 | Nec Electronics Corporation | Failure analysis system of semiconductor memory device |
| JP2006328167A (en) * | 2005-05-25 | 2006-12-07 | The Eco Kk | Natural vegetable composite molding and method for producing the same |
| WO2019004432A1 (en) * | 2017-06-30 | 2019-01-03 | 三井化学株式会社 | Method for producing sealing member and member-bonding method |
| CN112443660A (en) * | 2020-11-16 | 2021-03-05 | 中国化工株洲橡胶研究设计院有限公司 | Cloth-sandwiched rubber leather cup and manufacturing method thereof |
| CN115214176A (en) * | 2022-07-27 | 2022-10-21 | 上海芯之翼半导体材料有限公司 | Processing technology of silica gel gasket and silica gel gasket |
| CN117769489A (en) * | 2021-07-26 | 2024-03-26 | 德莎欧洲股份公司 | Especially for die-cut parts with permanently closed holes |
-
1997
- 1997-06-12 JP JP17312097A patent/JP3621231B2/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6871168B1 (en) | 1999-05-12 | 2005-03-22 | Nec Electronics Corporation | Failure analysis system of semiconductor memory device |
| JP2006328167A (en) * | 2005-05-25 | 2006-12-07 | The Eco Kk | Natural vegetable composite molding and method for producing the same |
| WO2019004432A1 (en) * | 2017-06-30 | 2019-01-03 | 三井化学株式会社 | Method for producing sealing member and member-bonding method |
| JPWO2019004432A1 (en) * | 2017-06-30 | 2020-04-09 | 三井化学株式会社 | Sealing member manufacturing method and member joining method |
| CN112443660A (en) * | 2020-11-16 | 2021-03-05 | 中国化工株洲橡胶研究设计院有限公司 | Cloth-sandwiched rubber leather cup and manufacturing method thereof |
| CN117769489A (en) * | 2021-07-26 | 2024-03-26 | 德莎欧洲股份公司 | Especially for die-cut parts with permanently closed holes |
| CN115214176A (en) * | 2022-07-27 | 2022-10-21 | 上海芯之翼半导体材料有限公司 | Processing technology of silica gel gasket and silica gel gasket |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3621231B2 (en) | 2005-02-16 |
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