JPH11172589A - オゾンと二酸化塩素による紙パルプの漂白方法 - Google Patents
オゾンと二酸化塩素による紙パルプの漂白方法Info
- Publication number
- JPH11172589A JPH11172589A JP10260191A JP26019198A JPH11172589A JP H11172589 A JPH11172589 A JP H11172589A JP 10260191 A JP10260191 A JP 10260191A JP 26019198 A JP26019198 A JP 26019198A JP H11172589 A JPH11172589 A JP H11172589A
- Authority
- JP
- Japan
- Prior art keywords
- pulp
- ozone
- bleaching
- oxygen
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 42
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 238000004061 bleaching Methods 0.000 title claims abstract description 30
- 229920001131 Pulp (paper) Polymers 0.000 title claims abstract description 26
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 19
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 34
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 230000002093 peripheral effect Effects 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 6
- 238000004076 pulp bleaching Methods 0.000 claims description 3
- 230000000295 complement effect Effects 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 239000000523 sample Substances 0.000 description 12
- 238000011282 treatment Methods 0.000 description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 10
- 229910052801 chlorine Inorganic materials 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 8
- 239000000123 paper Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000000605 extraction Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000002655 kraft paper Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000004045 organic chlorine compounds Chemical class 0.000 description 3
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 241000202567 Fatsia japonica Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
- D21C9/144—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites with ClO2/Cl2 and other bleaching agents in a multistage process
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1015—Bleaching ; Apparatus therefor with use of means other than pressure, temperature
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/16—Bleaching ; Apparatus therefor with per compounds
- D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9711446A FR2768442B1 (fr) | 1997-09-15 | 1997-09-15 | Procede de blanchiment d'une pate a papier avec de l'ozone et du dioxyde de chlore |
| FR9711446 | 1997-09-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11172589A true JPH11172589A (ja) | 1999-06-29 |
Family
ID=9511079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10260191A Pending JPH11172589A (ja) | 1997-09-15 | 1998-09-14 | オゾンと二酸化塩素による紙パルプの漂白方法 |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0902120A1 (fr) |
| JP (1) | JPH11172589A (fr) |
| KR (1) | KR19990029786A (fr) |
| CN (1) | CN1212310A (fr) |
| AU (1) | AU732875B2 (fr) |
| BR (1) | BR9803938A (fr) |
| CA (1) | CA2247532A1 (fr) |
| FR (1) | FR2768442B1 (fr) |
| NZ (1) | NZ331806A (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002069879A (ja) * | 2000-09-04 | 2002-03-08 | Nippon Paper Industries Co Ltd | セルロース質繊維材料のパルプの漂白方法 |
| JP2002523641A (ja) * | 1998-08-24 | 2002-07-30 | シーアールエス リアクター エンジニアリング(ユーケイ)リミテッド | 高剪断混合なしの、中程度のコンシステンシーのパルプのオゾンによる漂白 |
| JP2016093777A (ja) * | 2014-11-13 | 2016-05-26 | 大王製紙株式会社 | 汚泥の脱水助剤 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE532470C2 (sv) * | 2008-05-13 | 2010-02-02 | Metso Paper Inc | Slutblekning av oxygendelignifierad massa med ozon, klordioxid och peroxid |
| CN110656527A (zh) * | 2019-09-12 | 2020-01-07 | 华南理工大学 | 一种臭氧和二氧化氯协同高效漂白中浓纸浆的方法及装置 |
| CN111040049A (zh) * | 2019-12-02 | 2020-04-21 | 广西大学 | 一种分离提纯甘蔗渣中半纤维素的方法 |
| CN111979818A (zh) * | 2020-08-07 | 2020-11-24 | 齐鲁工业大学 | 一种硫酸盐木浆短程序ecf漂白工艺x/z/d-eop-d或x/d/z-eop-d |
| SE545758C2 (en) * | 2022-06-20 | 2024-01-02 | Valmet Oy | Method for bleaching pulp from recycled textile material |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4216054A (en) * | 1977-09-26 | 1980-08-05 | Weyerhaeuser Company | Low-consistency ozone delignification |
| CA2186176C (fr) * | 1995-09-28 | 2002-11-26 | Derek Hornsey | Methode de blanchiment a l'ozone de la pate cellulosique de faible consistance, et appareil connexe |
| FR2743094B1 (fr) * | 1995-12-27 | 1998-02-13 | Centre Tech Ind Papier | Procede de blanchiment des pates a papier chimiques |
-
1997
- 1997-09-15 FR FR9711446A patent/FR2768442B1/fr not_active Expired - Fee Related
-
1998
- 1998-09-08 NZ NZ331806A patent/NZ331806A/xx unknown
- 1998-09-11 CA CA002247532A patent/CA2247532A1/fr not_active Abandoned
- 1998-09-14 EP EP98402261A patent/EP0902120A1/fr not_active Withdrawn
- 1998-09-14 AU AU84212/98A patent/AU732875B2/en not_active Ceased
- 1998-09-14 BR BR9803938-5A patent/BR9803938A/pt not_active IP Right Cessation
- 1998-09-14 JP JP10260191A patent/JPH11172589A/ja active Pending
- 1998-09-15 CN CN98120618A patent/CN1212310A/zh active Pending
- 1998-09-15 KR KR1019980037906A patent/KR19990029786A/ko not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002523641A (ja) * | 1998-08-24 | 2002-07-30 | シーアールエス リアクター エンジニアリング(ユーケイ)リミテッド | 高剪断混合なしの、中程度のコンシステンシーのパルプのオゾンによる漂白 |
| JP2002069879A (ja) * | 2000-09-04 | 2002-03-08 | Nippon Paper Industries Co Ltd | セルロース質繊維材料のパルプの漂白方法 |
| JP2016093777A (ja) * | 2014-11-13 | 2016-05-26 | 大王製紙株式会社 | 汚泥の脱水助剤 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU732875B2 (en) | 2001-05-03 |
| EP0902120A1 (fr) | 1999-03-17 |
| FR2768442A1 (fr) | 1999-03-19 |
| KR19990029786A (ko) | 1999-04-26 |
| BR9803938A (pt) | 1999-12-07 |
| NZ331806A (en) | 2000-01-28 |
| AU8421298A (en) | 1999-03-25 |
| FR2768442B1 (fr) | 1999-10-15 |
| CN1212310A (zh) | 1999-03-31 |
| CA2247532A1 (fr) | 1999-03-15 |
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