JPH11189792A - Sterilizing / deodorizing detergent composition - Google Patents
Sterilizing / deodorizing detergent compositionInfo
- Publication number
- JPH11189792A JPH11189792A JP9360620A JP36062097A JPH11189792A JP H11189792 A JPH11189792 A JP H11189792A JP 9360620 A JP9360620 A JP 9360620A JP 36062097 A JP36062097 A JP 36062097A JP H11189792 A JPH11189792 A JP H11189792A
- Authority
- JP
- Japan
- Prior art keywords
- detergent composition
- deodorizing
- present
- ethanol
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Apparatus For Disinfection Or Sterilisation (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Detergent Compositions (AREA)
Abstract
(57)【要約】
【課題】 キッチン、トイレ、風呂場、洗面所等で優れ
た殺菌及び消臭効果を有し、更に、通常の手洗い後の除
菌及び殺菌も手軽にできる殺菌・消臭清浄剤組成物を提
供する。
【解決手段】 エタノールとカンゾウ抽出物とを含有す
ることを特徴とする殺菌・消臭清浄剤組成物。(57) [Summary] [PROBLEMS] Disinfection and deodorization that has excellent disinfection and deodorization effects in kitchens, toilets, bathrooms, lavatories, etc., and also facilitates disinfection and disinfection after ordinary hand washing. A detergent composition is provided. SOLUTION: A sterilizing / deodorizing detergent composition containing ethanol and liquorice extract.
Description
【0001】[0001]
【発明の属する技術分野】本発明は、キッチン、トイ
レ、風呂場、洗面所等で優れた殺菌及び消臭効果を有す
る殺菌・消臭清浄剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a disinfecting and deodorizing detergent composition having an excellent disinfecting and deodorizing effect in kitchens, toilets, bathrooms, washrooms and the like.
【0002】[0002]
【従来の技術】一般に、キッチン、トイレ、風呂場、洗
面所等の水まわりは、雑菌が繁殖しやすく、悪臭も発生
しやすい環境である。特に、キッチンは食品を扱うた
め、雑菌の繁殖には充分注意すべきであり、調理器具や
食器類、またそれらを扱う手の洗浄には極めて衛生的で
なければならない。また、生ゴミから発生する悪臭も不
快であり消臭すべきものである。2. Description of the Related Art Generally, the environment around kitchens, toilets, bathrooms, lavatories, etc. is susceptible to propagation of germs and offensive odor. In particular, kitchens handle food, so care must be taken to the propagation of various germs, and kitchen utensils, tableware, and the hands that handle them must be extremely sanitary. Further, the bad odor generated from the garbage is also unpleasant and should be deodorized.
【0003】従来において、殺菌剤は種々知られている
が、これらは肌荒れを起こしたり、臭いが強いなど使い
にくい場合が多い。更に、キッチン、トイレ、風呂場、
洗面所など一般家庭内で使用するには必要以上に効果が
強すぎ、霧状に散布するとかえって人体に害を及ぼすも
のもある。Conventionally, various fungicides have been known, but they are often difficult to use because they cause rough skin or have a strong odor. In addition, kitchens, toilets, bathrooms,
The effect is too strong for use in general households such as washrooms, and some may harm the human body when sprayed.
【0004】一方、従来において、消臭剤の成分も多種
多様であり、キッチンで使用した場合、食品や調理器
具、食器類にかかると安全性に不安を抱くものもある。
また、マスキング効果により消臭するものもあるが、こ
の方法は臭いが強く、キッチンでの使用には不適切であ
った。更に、殺菌効果と消臭効果とを同時に満足するも
のはなく、殺菌及び消臭には、殺菌剤、消臭剤を夫々個
別に用意する必要があり、使用、保管ともに繁雑のもの
となっていた。[0004] On the other hand, in the past, the components of deodorants have also been diverse, and when used in a kitchen, there is a concern about the safety of food, cooking utensils, and tableware.
In addition, there are some which deodorize due to the masking effect, but this method has a strong smell and is unsuitable for use in a kitchen. Furthermore, there is nothing satisfying both the bactericidal effect and the deodorant effect at the same time, and it is necessary to prepare a bactericide and a deodorant separately for sterilization and deodorization, and both use and storage are complicated. Was.
【0005】他方、エタノールは以前から殺菌力を有す
ることが知られており、殺菌剤として多々用いられてき
たが、エタノール単独では、その消臭力は知られていな
かった。また、カンゾウ抽出物は、抗菌作用等が知られ
ており、例えばカンゾウ又はその同属植物の油溶性エキ
スからなる口腔用組成物が報告されている(特開平4-16
4021号公報等)。しかしながら、カンゾウ抽出物を用い
たものに着色や沈殿等が生じるため、カンゾウ抽出物を
使用し難い等の課題を有していた。[0005] On the other hand, ethanol has been known for a long time as having a bactericidal activity, and has been widely used as a bactericide. However, the deodorizing effect of ethanol alone has not been known. In addition, the licorice extract is known to have an antibacterial action and the like, and for example, an oral composition comprising an oil-soluble extract of licorice or a plant belonging to the same genus has been reported (Japanese Patent Application Laid-Open No. 4-16).
No. 4021). However, since coloring or precipitation occurs in a product using a licorice extract, there is a problem that it is difficult to use the licorice extract.
【0006】[0006]
【発明が解決しようとする課題】本発明は、上記従来の
課題に鑑み、キッチン、トイレ、風呂場、洗面所等で優
れた殺菌及び消臭効果を有し、更に、通常の手洗い後の
除菌及び殺菌も手軽にできる殺菌・消臭清浄剤組成物を
提供することを目的とする。SUMMARY OF THE INVENTION In view of the above-mentioned problems, the present invention has an excellent sterilizing and deodorizing effect in kitchens, toilets, bathrooms, washrooms, etc. It is an object of the present invention to provide a disinfecting and deodorizing detergent composition that can easily perform bacteria and disinfection.
【0007】[0007]
【課題を解決するための手段】本発明者らは、上記課題
を解決するために鋭意研究を重ねた結果、エタノールと
カンゾウ抽出物とを組み合わせて用いることにより、殺
菌力と消臭力とが相乗的に効果を発揮し得るこれまでに
ない優れた殺菌・消臭性能を有し、また、上記課題のな
い一般家庭等どこでも安心して使用可能な殺菌・消臭清
浄剤組成物を見い出し、本発明を完成するに至ったので
ある。Means for Solving the Problems The inventors of the present invention have conducted intensive studies to solve the above-mentioned problems, and as a result, by using ethanol and licorice extract in combination, the bactericidal and deodorizing powers have been improved. It has an unprecedented sterilization and deodorization performance that can exert synergistic effects, and also finds a sterilization and deodorization detergent composition that can be used safely in general households without the above-mentioned problems and can be used safely. The invention was completed.
【0008】即ち、本発明の殺菌・消臭清浄剤組成物
は、エタノールとカンゾウ抽出物とを含有することを特
徴とする。[0008] That is, the disinfecting and deodorizing detergent composition of the present invention is characterized by containing ethanol and licorice extract.
【0009】[0009]
【発明の実施の形態】以下、本発明の実施の形態を詳細
に説明する。本発明は、エタノールとカンゾウ抽出物と
を含有することを特徴とする殺菌・消臭清浄剤組成物、
である。Embodiments of the present invention will be described below in detail. The present invention is a disinfecting and deodorizing detergent composition characterized by containing ethanol and liquorice extract,
It is.
【0010】本発明の殺菌・消臭清浄剤組成物(以下、
単に、「本発明の組成物」ということもある。)で用い
られるエタノールとしては、例えば発酵エタノール、合
成エタノール等が挙げられ、キッチンで使用する場合に
は発酵エタノールが好ましい。尚、該エタノールには変
性剤が添加されていても良い。The germicidal and deodorant detergent composition of the present invention (hereinafter referred to as “the deodorant / deodorant detergent composition”
It may simply be referred to as “the composition of the present invention”. Examples of the ethanol used in ()) include fermented ethanol and synthetic ethanol. When used in a kitchen, fermented ethanol is preferred. Incidentally, a denaturant may be added to the ethanol.
【0011】変性剤としては、例えばメタノール、アセ
トアルデヒド、プロピオン酸エチル、食品用フレーバー
等が挙げられ、中でもキッチンで使用する場合には食品
用フレーバーが好ましく用いられ、食品用フレーバーの
なかでもフレーバーH−No.13がより好ましく用い
られる。Examples of the denaturing agent include methanol, acetaldehyde, ethyl propionate, food flavors and the like. Among them, when used in a kitchen, food flavors are preferably used, and among food flavors, flavor H- is preferred. No. 13 is more preferably used.
【0012】エタノールの配合量としては、通常30〜60
重量%、好ましくは40〜60重量%の範囲から適宜選択さ
れる。エタノールの配合量が30重量%未満では、殺菌効
果が低下し、60重量%を越えると、エタノール臭が強
く、気分が悪くなる等官能的に好ましくなく、また、手
荒れ等の問題が生じ、更に、引火性の恐れもある。The mixing amount of ethanol is usually 30 to 60.
% By weight, preferably in the range of 40 to 60% by weight. If the blending amount of ethanol is less than 30% by weight, the bactericidal effect is reduced, and if it exceeds 60% by weight, ethanol odor is strong, the feeling is bad and it is not organoleptically desirable, and there is a problem such as rough hands. May be flammable.
【0013】本発明で用いられるカンゾウ抽出物は、マ
メ科カンゾウ属(Glycyrrhiza sp.)の植物(例えばGly
cyrrhiza glabra L.,G.glabra L.var.glandulifera Re
g. et Herd.,G.echinata L.,G.uralensis Fisch. et D
C.等)の根及び/又は根茎等を原料として用い、これを
水及び/又は有機溶媒で抽出することにより得られるも
のを用いれば良い。これらの原料は、生のものや乾燥し
たものをそのままの状態或いは粉末等にしたものを用い
れば良い。The licorice extract used in the present invention is a plant of the genus Glycyrrhiza sp.
cyrrhiza glabra L., G.glabra L.var.glandulifera Re
g. et Herd., G. echinata L., G. uralensis Fisch. et D
C. etc.) may be used as a raw material, and a material obtained by extracting it with water and / or an organic solvent may be used. As these raw materials, raw or dried raw materials or powdered materials may be used.
【0014】カンゾウ抽出物としては、水で抽出される
ものが好ましく用いられ、水で抽出され且つ食品添加物
として使用可能なものがより好ましく用いられる。水抽
出物は、有機溶媒抽出物より人体への安全性や、製剤化
したときの安定性等に優れている。As the licorice extract, those extracted with water are preferably used, and those extracted with water and usable as food additives are more preferably used. The water extract is superior to the organic solvent extract in terms of safety to the human body and stability when formulated.
【0015】抽出に用いられる有機溶媒としては、例え
ばメタノール,エタノール,プロパノール,イソプロパ
ノール,ブタノール等の低級アルコール類、例えば酢酸
エチル,酢酸ブチル,プロピオン酸エチル等のエステル
類、例えばジクロロメタン,クロロホルム,1,2-ジクロ
ロエタン等のハロゲン化炭化水素類、例えばアセトン,
メチルエチルケトン,イソブチルメチルケトン等のケト
ン類等が挙げられる。これらは夫々単独で用いても2種
以上適宜組み合わせて用いても良い。Examples of the organic solvent used for extraction include lower alcohols such as methanol, ethanol, propanol, isopropanol and butanol, and esters such as ethyl acetate, butyl acetate and ethyl propionate, for example, dichloromethane, chloroform, 1,1, and the like. Halogenated hydrocarbons such as 2-dichloroethane, for example, acetone,
And ketones such as methyl ethyl ketone and isobutyl methyl ketone. These may be used alone or in combination of two or more.
【0016】カンゾウ抽出物の配合量としては、通常0.
0001〜0.1重量%、好ましくは0.001〜0.01重量%の範囲
から適宜選択される。カンゾウ抽出物の配合量が0.0001
重量%未満では殺菌効果並びに消臭効果が低下し、0.1
重量%を越えると、着色、沈殿が生じる等の問題があ
り、製剤化し難くなり、また、コスト的にも不経済であ
る。The amount of the licorice extract is usually 0.1
It is appropriately selected from the range of 0001 to 0.1% by weight, preferably 0.001 to 0.01% by weight. 0.0001 of licorice extract
If it is less than 0.1% by weight, the bactericidal effect and the deodorizing effect decrease, and
If the amount is more than 10% by weight, problems such as coloration and precipitation occur, making it difficult to formulate the preparation, and it is uneconomical in terms of cost.
【0017】本発明の組成物のpHとしては、通常4〜
8、好ましくは4.5〜7.5の範囲から適宜選択される。
尚、pHが4未満または8を越えると、トイレ、風呂
場、洗面所等の配管部分、キッチンで使用する包丁や調
理器具等の、被洗物になる金属等の材質に、サビや変色
等が生じることが懸念される。The pH of the composition of the present invention is usually from 4 to
8, preferably selected from the range of 4.5 to 7.5.
If the pH is less than 4 or more than 8, rusting, discoloration, etc. may occur on materials such as metals to be washed, such as plumbing parts in toilets, bathrooms, washrooms, kitchen knives and cooking utensils used in kitchens. Is likely to occur.
【0018】本発明の組成物には精製水等の水の他に必
要に応じてその性質を損なわない範囲で他の成分を添加
しても良い。添加可能な成分としては、防腐剤、酸化防
止剤、紫外線吸収剤、pH調整剤、界面活性剤、色素、
香料等が挙げられる。[0018] In addition to water such as purified water, other components may be added to the composition of the present invention, if necessary, as long as the properties are not impaired. Components that can be added include preservatives, antioxidants, ultraviolet absorbers, pH adjusters, surfactants, pigments,
Fragrance and the like.
【0019】本発明の組成物で殺菌・消臭可能なもの及
び場所としては特に限定されないが、例えば包丁等の調
理器具、例えば流し台、三角コーナー、生ゴミ、冷蔵
庫、食卓等のキッチンまわり、例えば手等の皮膚、例え
ばコップ、皿等の食器類、トイレ、風呂場、洗面所、医
療器具等が挙げられる。The composition and the place where the composition of the present invention can be sterilized and deodorized are not particularly limited. For example, cooking utensils such as kitchen knives, for example, around kitchens such as sinks, triangle corners, garbage, refrigerators, dining tables, etc. Skins such as hands, for example, tableware such as cups and dishes, toilets, bathrooms, washrooms, medical instruments, and the like.
【0020】本発明の組成物を用いて上記殺菌・消臭可
能なものを殺菌・消臭するには例えば下記の如くして行
えば良い。即ち、本発明の組成物で上記殺菌・消臭可能
なものを浸漬,噴霧(例えばトリガースプレー、ディス
ペンサースプレー、エアゾール等の形態が挙げられ
る。),塗布等の方法によって処理すれば良い。処理後
の後処理等は、風乾、拭きとり等適宜の手段によって行
えば良い。In order to sterilize and deodorize the above-mentioned sterilizable and deodorizable substances using the composition of the present invention, for example, the following may be performed. That is, the composition of the present invention that can be sterilized and deodorized may be treated by dipping, spraying (for example, trigger spray, dispenser spray, aerosol, and the like), coating, and the like. Post-treatment after the treatment may be performed by an appropriate means such as air drying and wiping.
【0021】本発明の殺菌・消臭清浄剤組成物は、エタ
ノールとカンゾウ抽出物とを組み合わせることが特徴で
ある。これにより、従来有していたエタノール及びカン
ゾウ抽出物を用いる場合の課題を解決したばかりでな
く、両者を組み合わせたことにより、殺菌及び消臭力が
同時に得られる、という相乗的な効果を奏するものであ
る(これらの点については、後述する実施例等で更に詳
述する)。The germicidal and deodorant detergent composition of the present invention is characterized by combining ethanol and licorice extract. This not only solves the problem of using the conventional ethanol and licorice extract, but also has a synergistic effect that by combining the two, sterilization and deodorizing power can be obtained simultaneously. (These points will be described in more detail in Examples and the like described later).
【0022】[0022]
【実施例】以下に、実施例及び比較例等を挙げて本発明
を更に詳細に説明するが、本発明は実施例によって何ら
限定されるものではない。EXAMPLES The present invention will be described in more detail with reference to examples and comparative examples, but the present invention is not limited to the examples.
【0023】[実施例1〜2及び比較例1〜3.(組成
物の調製)]下記表1に示した割合の組成物を夫々調製
した。[Examples 1-2 and Comparative Examples 1-3. (Preparation of Compositions)] Compositions having the ratios shown in Table 1 below were prepared.
【0024】上記実施例1〜2及び比較例1〜3で得ら
れた殺菌・消臭清浄剤組成物を用いて下記試験方法によ
り殺菌力試験及び消臭力試験を行った。これらの評価結
果を下記表1に併せて示す。Using the disinfecting and deodorizing detergent compositions obtained in Examples 1 and 2 and Comparative Examples 1 to 3, a disinfecting test and a deodorizing test were carried out by the following test methods. The evaluation results are shown in Table 1 below.
【0025】(1)殺菌力試験 試験菌 試験菌として黄色ブドウ球菌(S.aureusFDA209P)を用
いた。 菌液の調製 SCDLP培地で37℃、18〜24時間培養した試験菌をS
CDLP培地に再度接種し、37℃で18〜24時間培養し
た。培養後、培養した菌体を生理食塩水に均一に分散さ
せ、1ml当たりの菌数が約108となるように調製した。 試験方法 実施例1〜2及び比較例1〜3で得られた組成物 5ml
を夫々とり、これにで得られた菌液 50μlを撹拌しな
がら添加した。15秒後、これをSCDLPブイヨンで100倍に
希釈して殺菌反応を停止させた後、生存している菌数を
SCDLP寒天培地を用いた混釈平板培養法(35℃で48
時間)により、生菌数を測定した。(1) Test of bactericidal activity Test bacterium Staphylococcus aureus (S. aureus FDA209P) was used as a test bacterium. Preparation of bacterial solution Test bacteria cultured in SCDLP medium at 37 ° C for 18 to 24 hours
The CDLP medium was inoculated again and cultured at 37 ° C. for 18 to 24 hours. After the cultivation, the cultured cells were uniformly dispersed in physiological saline, and the number of cells per ml was adjusted to about 10 8 . Test method 5 ml of the composition obtained in Examples 1-2 and Comparative Examples 1-3
Was taken, and 50 μl of the obtained bacterial solution was added thereto with stirring. After 15 seconds, this was diluted 100-fold with SCDLP broth to stop the bactericidal reaction, and the number of surviving bacteria was counted by a pour plate culture method using SCDLP agar medium (48 ° C at 35 ° C).
Time), the number of viable bacteria was measured.
【0026】(2)消臭力試験(トリメチルアミンの消
臭力試験) 200mlのガラス瓶に実施例1〜2及び比較例1〜3で得
られた組成物 10gを夫々取り、これにトリメチルアミ
ンのエタノール溶液(5μg/μl) 5μlを添加し、水
浴中、25℃で10分間振とうさせた後、ヘッドスペースの
トリメチルアミン濃度を検知管で測定し、試験液1g当
たりのトリメチルアミン捕捉量を消臭力として算出し
た。(2) Deodorizing Power Test (Deodorizing Power Test of Trimethylamine) 10 g of each of the compositions obtained in Examples 1 and 2 and Comparative Examples 1 to 3 was placed in a 200-ml glass bottle. (5 μg / μl) After adding 5 μl and shaking at 25 ° C. for 10 minutes in a water bath, the concentration of trimethylamine in the head space was measured with a detector tube, and the trapped amount of trimethylamine per 1 g of the test solution was calculated as the deodorizing power. did.
【0027】[0027]
【表1】 [Table 1]
【0028】(殺菌力試験の考察)表1の結果から、比
較例1〜3で得られた組成物に比べ実施例1及び2で得
られた本発明の殺菌・消臭清浄剤組成物は、15秒で菌を
すべて死滅させることから、本発明の殺菌・消臭清浄剤
組成物は、優れた殺菌力を有していることが判る。(Consideration of the germicidal activity test) From the results shown in Table 1, the germicidal and deodorant detergent compositions of the present invention obtained in Examples 1 and 2 are more excellent than the compositions obtained in Comparative Examples 1 to 3. Since all the bacteria were killed in 15 seconds, it can be seen that the disinfecting and deodorizing detergent composition of the present invention has excellent disinfecting power.
【0030】(消臭力試験の考察)表1の結果から、実
施例1及び2で得られた本発明の殺菌・消臭清浄剤組成
物は、比較例1〜3で得られた殺菌・消臭清浄剤組成物
に比べ、25000倍のトリメチルアミンを捕捉したことか
ら、本発明の殺菌・消臭清浄剤組成物は、優れた消臭力
を有することが判る。(Consideration of Deodorizing Power Test) From the results shown in Table 1, the disinfecting and deodorizing detergent compositions of the present invention obtained in Examples 1 and 2 are the same as those of Comparative Examples 1 to 3. Since 25,000 times more trimethylamine was trapped than the deodorant detergent composition, it can be seen that the disinfectant / deodorant detergent composition of the present invention has excellent deodorizing power.
【0031】以上の結果からも明らかなように、エタノ
ールとカンゾウ抽出物とを組み合わせた本発明の殺菌・
消臭清浄剤組成物は、殺菌効果と消臭効果という両方の
効果を同時に有するものであることが判る。As is evident from the above results, the sterilization / treatment of the present invention combining ethanol and licorice extract was performed.
It can be seen that the deodorant detergent composition has both a bactericidal effect and a deodorant effect at the same time.
【0032】[0032]
【発明の効果】本発明の殺菌・消臭清浄剤組成物は、キ
ッチン、トイレ、風呂場、洗面所等で優れた殺菌及び消
臭効果を有し、更に、通常の手洗い後の除菌及び殺菌も
手軽にできる、という点に顕著な効果を奏するものであ
る。The disinfecting and deodorizing detergent composition of the present invention has excellent disinfecting and deodorizing effects in kitchens, toilets, bathrooms, lavatories, etc., and furthermore, has the ability to remove bacteria after ordinary hand washing. This has a remarkable effect in that sterilization can be easily performed.
Claims (1)
ることを特徴とする殺菌・消臭清浄剤組成物。1. A sterilizing / deodorizing detergent composition comprising ethanol and a liquorice extract.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36062097A JP3597688B2 (en) | 1997-12-26 | 1997-12-26 | Sterilizing / deodorizing detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36062097A JP3597688B2 (en) | 1997-12-26 | 1997-12-26 | Sterilizing / deodorizing detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11189792A true JPH11189792A (en) | 1999-07-13 |
| JP3597688B2 JP3597688B2 (en) | 2004-12-08 |
Family
ID=18470197
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP36062097A Expired - Fee Related JP3597688B2 (en) | 1997-12-26 | 1997-12-26 | Sterilizing / deodorizing detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3597688B2 (en) |
-
1997
- 1997-12-26 JP JP36062097A patent/JP3597688B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP3597688B2 (en) | 2004-12-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104873432B (en) | Handguard type Washing free gel for disinfection and preparation method thereof | |
| CN100518505C (en) | Composition with storage effect for controlling microbe | |
| US8741271B2 (en) | Antimicrobial compositions containing essential oils | |
| KR20150036426A (en) | Topical sanitizing formulations and uses thereof | |
| CN102018981A (en) | Spray disinfectant-deodorant agent comprising hinokitiol | |
| KR20230004975A (en) | Antibacterial and Preservative Compositions | |
| KR20030070487A (en) | The preparation of antimicrobial cleansing deodorant | |
| CN101766186A (en) | Composition capable of slowly-releasing chlorine dioxide and application thereof | |
| US11691036B2 (en) | Macrocyclic ketone as malodor counteracting ingredient | |
| CN115209731B (en) | Cleaning composition | |
| KR102699190B1 (en) | Antibacterial and Preservative Compositions | |
| JP5456659B2 (en) | Phenylpropanoid compounds | |
| JP2025527220A (en) | biocidal composition | |
| JPH11113779A (en) | Sanitizing wet tissue | |
| JP5806716B2 (en) | β-glucuronidase inhibitor | |
| KR102699189B1 (en) | Antibacterial and Preservative Compositions | |
| JP5674283B2 (en) | β-glucuronidase inhibitor | |
| JP2001139993A (en) | Skin disinfectant cleaner | |
| JP3597688B2 (en) | Sterilizing / deodorizing detergent composition | |
| JP4660088B2 (en) | Deodorant and deodorant composition, cosmetic composition and cleaning composition containing the deodorant | |
| Makin et al. | Deodorant ingredients | |
| KR100321411B1 (en) | Disinfectant sanitary tissue | |
| JP2000355506A (en) | Degerming agent | |
| JPH11302121A (en) | Antibacterial agent using green tea catechin | |
| EP3648763B1 (en) | 2,4-disubstituted pyridines as malodor counteracting ingredients |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20040907 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20040909 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080917 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080917 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090917 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090917 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100917 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100917 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110917 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110917 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120917 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130917 Year of fee payment: 9 |
|
| LAPS | Cancellation because of no payment of annual fees |