JPH1176797A - Silane aqueous emulsion - Google Patents
Silane aqueous emulsionInfo
- Publication number
- JPH1176797A JPH1176797A JP25434197A JP25434197A JPH1176797A JP H1176797 A JPH1176797 A JP H1176797A JP 25434197 A JP25434197 A JP 25434197A JP 25434197 A JP25434197 A JP 25434197A JP H1176797 A JPH1176797 A JP H1176797A
- Authority
- JP
- Japan
- Prior art keywords
- aqueous emulsion
- silane
- acid
- group
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000077 silane Inorganic materials 0.000 title claims abstract description 80
- 239000000839 emulsion Substances 0.000 title claims abstract description 75
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 38
- 239000000194 fatty acid Substances 0.000 claims abstract description 38
- 229930195729 fatty acid Natural products 0.000 claims abstract description 38
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 36
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 18
- 150000003839 salts Chemical class 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 8
- 125000003118 aryl group Chemical group 0.000 claims abstract description 8
- 125000005843 halogen group Chemical group 0.000 claims abstract description 5
- 125000003277 amino group Chemical group 0.000 claims abstract description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- -1 silane compound Chemical class 0.000 claims description 52
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 8
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 22
- 230000003405 preventing effect Effects 0.000 abstract description 21
- 229910052799 carbon Inorganic materials 0.000 abstract description 18
- 239000004567 concrete Substances 0.000 abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 16
- 230000002087 whitening effect Effects 0.000 abstract description 10
- 238000013329 compounding Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 24
- 239000002253 acid Substances 0.000 description 21
- 239000004568 cement Substances 0.000 description 20
- 239000000463 material Substances 0.000 description 14
- 238000011156 evaluation Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 10
- 238000006253 efflorescence Methods 0.000 description 10
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 10
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 10
- 230000002265 prevention Effects 0.000 description 10
- 206010037844 rash Diseases 0.000 description 10
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 9
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 9
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 9
- 239000005642 Oleic acid Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 150000004756 silanes Chemical class 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000012875 nonionic emulsifier Substances 0.000 description 5
- 150000004671 saturated fatty acids Chemical class 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 239000004570 mortar (masonry) Substances 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 4
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- KHAVLLBUVKBTBG-UHFFFAOYSA-N dec-9-enoic acid Chemical compound OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 description 2
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 2
- 239000005695 Ammonium acetate Substances 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- 239000004280 Sodium formate Substances 0.000 description 2
- 241000519995 Stachys sylvatica Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 235000019257 ammonium acetate Nutrition 0.000 description 2
- 229940043376 ammonium acetate Drugs 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 239000012874 anionic emulsifier Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000006172 buffering agent Substances 0.000 description 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 2
- 239000001639 calcium acetate Substances 0.000 description 2
- 235000011092 calcium acetate Nutrition 0.000 description 2
- 229960005147 calcium acetate Drugs 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- CUXQLKLUPGTTKL-UHFFFAOYSA-M microcosmic salt Chemical compound [NH4+].[Na+].OP([O-])([O-])=O CUXQLKLUPGTTKL-UHFFFAOYSA-M 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 description 2
- 235000011009 potassium phosphates Nutrition 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 2
- 235000019254 sodium formate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- WUMSTCDLAYQDNO-UHFFFAOYSA-N triethoxy(hexyl)silane Chemical compound CCCCCC[Si](OCC)(OCC)OCC WUMSTCDLAYQDNO-UHFFFAOYSA-N 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- UYSIAYNEXMRMET-UHFFFAOYSA-N (4-bromophenyl)methyl-tripropoxysilane Chemical compound CCCO[Si](OCCC)(OCCC)CC1=CC=C(Br)C=C1 UYSIAYNEXMRMET-UHFFFAOYSA-N 0.000 description 1
- RKRKRHCXBBLINE-UHFFFAOYSA-N (4-chlorophenyl)methyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CC1=CC=C(Cl)C=C1 RKRKRHCXBBLINE-UHFFFAOYSA-N 0.000 description 1
- RCERCQQPFQFWSM-UHFFFAOYSA-N (4-chlorophenyl)methyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CC1=CC=C(Cl)C=C1 RCERCQQPFQFWSM-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- PBQAYLNBRDAQQX-UHFFFAOYSA-N 2-ethylhexyl(trimethoxy)silane Chemical compound CCCCC(CC)C[Si](OC)(OC)OC PBQAYLNBRDAQQX-UHFFFAOYSA-N 0.000 description 1
- 125000006281 4-bromobenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1Br)C([H])([H])* 0.000 description 1
- 125000006283 4-chlorobenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1Cl)C([H])([H])* 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- RFCIRPRPWWLXQT-UHFFFAOYSA-N 6-chlorohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCCCCl RFCIRPRPWWLXQT-UHFFFAOYSA-N 0.000 description 1
- YWWVWXASSLXJHU-UHFFFAOYSA-N 9E-tetradecenoic acid Natural products CCCCC=CCCCCCCCC(O)=O YWWVWXASSLXJHU-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 235000021322 Vaccenic acid Nutrition 0.000 description 1
- UWHZIFQPPBDJPM-FPLPWBNLSA-M Vaccenic acid Natural products CCCCCC\C=C/CCCCCCCCCC([O-])=O UWHZIFQPPBDJPM-FPLPWBNLSA-M 0.000 description 1
- VENIIVIRETXKSV-BQYQJAHWSA-N Ximenynic acid Chemical compound CCCCCC\C=C\C#CCCCCCCCC(O)=O VENIIVIRETXKSV-BQYQJAHWSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- GQVVQDJHRQBZNG-UHFFFAOYSA-N benzyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CC1=CC=CC=C1 GQVVQDJHRQBZNG-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XGZGKDQVCBHSGI-UHFFFAOYSA-N butyl(triethoxy)silane Chemical compound CCCC[Si](OCC)(OCC)OCC XGZGKDQVCBHSGI-UHFFFAOYSA-N 0.000 description 1
- SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KQAHMVLQCSALSX-UHFFFAOYSA-N decyl(trimethoxy)silane Chemical compound CCCCCCCCCC[Si](OC)(OC)OC KQAHMVLQCSALSX-UHFFFAOYSA-N 0.000 description 1
- YPENMAABQGWRBR-UHFFFAOYSA-N dibutyl(dimethoxy)silane Chemical compound CCCC[Si](OC)(OC)CCCC YPENMAABQGWRBR-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 1
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SCPWMSBAGXEGPW-UHFFFAOYSA-N dodecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OC)(OC)OC SCPWMSBAGXEGPW-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- KUCGHDUQOVVQED-UHFFFAOYSA-N ethyl(tripropoxy)silane Chemical compound CCCO[Si](CC)(OCCC)OCCC KUCGHDUQOVVQED-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- CZWLNMOIEMTDJY-UHFFFAOYSA-N hexyl(trimethoxy)silane Chemical compound CCCCCC[Si](OC)(OC)OC CZWLNMOIEMTDJY-UHFFFAOYSA-N 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- RJMRIDVWCWSWFR-UHFFFAOYSA-N methyl(tripropoxy)silane Chemical compound CCCO[Si](C)(OCCC)OCCC RJMRIDVWCWSWFR-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- UWHZIFQPPBDJPM-BQYQJAHWSA-N trans-vaccenic acid Chemical compound CCCCCC\C=C\CCCCCCCCCC(O)=O UWHZIFQPPBDJPM-BQYQJAHWSA-N 0.000 description 1
- VLYHVNSXCTXWQS-UHFFFAOYSA-N tribromo(dodecyl)silane Chemical compound CCCCCCCCCCCC[Si](Br)(Br)Br VLYHVNSXCTXWQS-UHFFFAOYSA-N 0.000 description 1
- BNCXNUWGWUZTCN-UHFFFAOYSA-N trichloro(dodecyl)silane Chemical compound CCCCCCCCCCCC[Si](Cl)(Cl)Cl BNCXNUWGWUZTCN-UHFFFAOYSA-N 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- OYGYKEULCAINCL-UHFFFAOYSA-N triethoxy(hexadecyl)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC OYGYKEULCAINCL-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- FZMJEGJVKFTGMU-UHFFFAOYSA-N triethoxy(octadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC FZMJEGJVKFTGMU-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- SVKDNKCAGJVMMY-UHFFFAOYSA-N triethoxy(tetradecyl)silane Chemical compound CCCCCCCCCCCCCC[Si](OCC)(OCC)OCC SVKDNKCAGJVMMY-UHFFFAOYSA-N 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- CERVGQPARMTDQC-UHFFFAOYSA-N trimethoxy(6,6,6-trifluorohexyl)silane Chemical compound CO[Si](OC)(OC)CCCCCC(F)(F)F CERVGQPARMTDQC-UHFFFAOYSA-N 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- VUWVDNLZJXLQPT-UHFFFAOYSA-N tripropoxy(propyl)silane Chemical compound CCCO[Si](CCC)(OCCC)OCCC VUWVDNLZJXLQPT-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/4922—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/40—Surface-active agents, dispersants
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/21—Efflorescence resistance
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Colloid Chemistry (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、コンクリート等の
躯体に対して吸水防止性と白華（エフロレッセンス）防
止性を付与することにより、その美観と耐久性を向上さ
せる、シラン系水性エマルションに関するものであり、
土木・建築構造物の内外装に広く使用することができ、
これらの技術分野で賞用され得るものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silane-based water-based emulsion which improves the aesthetic appearance and durability by imparting water absorption preventing property and efflorescence preventing property to a body such as concrete. Things,
Can be widely used for interior and exterior of civil engineering and building structures,
It can be awarded in these technical fields.
【０００２】[0002]
【従来の技術】従来からアルコキシシランに代表される
加水分解性シラン化合物は、石造物やコンクリート等の
建築土木材料の撥水材及び吸水防止材として有用である
ことが広く知られている。一般的に、これら加水分解性
シラン化合物は、種々の溶剤で希釈して使用されていた
が、このような溶剤系のものは、溶剤の毒性、引火性及
び揮発性により使用範囲に制限がある他、低分子量アル
コールであるイソプロパノールを溶剤とする吸水防止材
は、蒸発速度が急速であるため、躯体への浸透性が充分
でない等の問題があり、逆に揮発しにくい溶剤を使用し
たものは、塗工面の湿潤状態が長くなるため、空気中の
ゴミが付着する機会が増えたり、又硬化に長時間を要す
るという問題がある。さらに、溶剤系のものは、濡れた
コンクリート表面には塗工できない問題点も有するもの
であった。2. Description of the Related Art It has been widely known that a hydrolyzable silane compound represented by an alkoxysilane is useful as a water repellent and a water absorption preventive for building civil engineering materials such as masonry and concrete. In general, these hydrolyzable silane compounds have been used after being diluted with various solvents. However, such a solvent-based compound has a limited use range due to the toxicity, flammability and volatility of the solvent. In addition, the water absorption preventing material using isopropanol, which is a low molecular weight alcohol, as a solvent, has a problem that the evaporation rate is rapid, such that the permeability into the frame is not sufficient. In addition, since the wet state of the coated surface is prolonged, there is a problem that dusts in the air are more likely to adhere and that curing takes a long time. Further, the solvent-based one has a problem that it cannot be applied to a wet concrete surface.
【０００３】これらの問題を解決するためには、加水分
解性シラン化合物を水溶液又は水性分散体としたものが
好ましいが、加水分解性シラン化合物は化学的な性質
上、水と接触すると文字どおり加水分解反応を引き起こ
し、更にこれに続く縮合反応が起こり易いため、水中で
安定に存在させることは極めて難しいことされていた。
この問題を解決するシラン系水性エマルションとして、
ＨＬＢが４〜１５の乳化剤を用いたシラン系水性エマル
ション（特開昭６２−１９７３６９）や非イオン性乳化
剤とアニオン性乳化剤を組み合わせたシラン系水性エマ
ルション（特開平３−２３２５２７）が報告されており
更にシラン系水性エマルションをセメントモルタル用組
成物としてセメントスラリーに混和させて使用すること
で耐久性を向上させる例（特開平６−３０５８００）が
報告されている。In order to solve these problems, it is preferable to use an aqueous solution or an aqueous dispersion of the hydrolyzable silane compound. However, the hydrolyzable silane compound is hydrolyzed when it comes into contact with water due to its chemical properties. It has been considered that it is extremely difficult to stably exist in water because it causes a reaction and a subsequent condensation reaction easily occurs.
As a silane-based aqueous emulsion that solves this problem,
A silane-based aqueous emulsion using an emulsifier having an HLB of 4 to 15 (JP-A-62-197369) and a silane-based aqueous emulsion combining a nonionic emulsifier and an anionic emulsifier (JP-A-3-232527) have been reported. Further, there has been reported an example in which durability is improved by mixing a silane-based aqueous emulsion as a composition for cement mortar with a cement slurry for use (JP-A-6-305800).
【０００４】ところで、モルタルやコンクリート等の建
設・土木用の材料又は構造物においては、環境条件によ
っては、これら材料又は構造物に白華が発生してしまう
という問題があり、白華防止のための種々の試みがなさ
れている。白華防止の方法としては、コンクリート等の
躯体を製造する際に、キレート化合物を原料混合物中に
配合し、白華の原因であるセメント水和物中のＣａイオ
ンを捕捉する方法や、エマルション系塗料等の防水材を
躯体表面に塗布して、セメント水和物中のＣａイオンが
当該水和物中の水分と共に躯体表面に移行すること抑制
する方法等が知られている。又、コンクリート等の躯体
の表面にフミン酸塩を塗布する方法や（特開平５−１７
０５７３号）、コンクリート等を製造する際に、フミン
酸塩を原料混合物中に配合する方法も知られている（特
開平５−１７０４９９号）。[0004] In construction and civil engineering materials and structures such as mortar and concrete, there is a problem that, depending on the environmental conditions, the materials or structures may generate white spots. Various attempts have been made. As a method of preventing efflorescence, a method of mixing a chelate compound in a raw material mixture to capture Ca ions in cement hydrate, which is the cause of efflorescence, when manufacturing a frame such as concrete, or an emulsion-based method There is known a method in which a waterproof material such as paint is applied to the surface of a skeleton to suppress Ca ions in cement hydrate from migrating to the surface of the skeleton together with moisture in the hydrate. Further, a method of applying a humate to the surface of a body such as concrete or the like (Japanese Patent Laid-Open No.
No. 0573), and a method of incorporating a humate into a raw material mixture when producing concrete or the like is also known (Japanese Patent Laid-Open No. 5-170499).
【０００５】[0005]
【本発明が解決しようとする課題】しかしながら、躯体
製造時にキレート化合物を配合する方法では、セメント
水和物中の水分移行を抑制できず、又セメント水和物中
の水の移行と共に表面へ移行するＣａイオンを完全に捕
捉することは不可能であることを原因として、白華防止
効果が不充分な上、キレート化合物の配合量によっては
躯体の物理特性を阻害する場合もあった。又、防水材を
躯体表面に塗布する方法も、白華発生を充分抑制できる
ものではない上、防水材の塗膜とコンクリート等の躯体
の表面との密着性が不足することが多く、又塗膜形成に
よる外観変化は避けられない為、建造物等に使用した場
合にはコンクリート表面の持つ独特の風合いをそのまま
表現する事は不可能であった。又、躯体表面にフミン酸
塩を塗布する方法や躯体製造時にフミン酸塩を原料混合
物中に配合する方法でも、実用的に充分な白華防止効果
が発揮されていないのが現状である。一方、躯体に吸水
防止性等を付与することを目的として、上記した様なシ
ラン系水性エマルションを躯体に塗布する場合やコンク
リート等の躯体の製造時に混合して使用する場合のいず
れにおいても、環境条件によっては、同様に白華が発生
してしまう問題があり、吸水防止性能を有すると共に白
華防止性も兼ね備えた材料が望まれている。本発明者ら
は、コンクリート等の躯体に対して、吸水防止性及び白
華防止性を付与し得る組成物を見い出すため鋭意検討を
行ったのである。However, in the method in which a chelate compound is blended at the time of manufacturing a skeleton, water transfer in cement hydrate cannot be suppressed, and water transfer in cement hydrate transfers to the surface. Due to the fact that it is impossible to completely capture Ca ions, the effect of preventing the bleaching is insufficient and the physical properties of the skeleton may be inhibited depending on the compounding amount of the chelate compound. Also, the method of applying a waterproofing material to the surface of the skeleton does not sufficiently suppress the occurrence of efflorescence, and in many cases, the adhesion between the coating film of the waterproofing material and the surface of the skeleton such as concrete is insufficient. Since the appearance change due to film formation is inevitable, it is impossible to directly express the unique texture of the concrete surface when used in a building or the like. Further, at present, even a method of applying a humate to the surface of a skeleton or a method of incorporating a humate into a raw material mixture at the time of manufacturing a skeleton does not exhibit a practically sufficient effect of preventing efflorescence. On the other hand, for the purpose of imparting water absorption prevention properties to the skeleton, the silane-based aqueous emulsion as described above is applied to the skeleton or used when mixed at the time of manufacturing a skeleton such as concrete. Depending on the conditions, there is also a problem that whitening occurs, and a material having water absorption preventing performance and also having whitening preventing properties is desired. The present inventors have conducted intensive studies in order to find a composition capable of imparting water absorption preventing properties and whitening preventing properties to a body such as concrete.
【０００６】[0006]
【課題を解決するための手段】本発明者らは、前記課題
を解決する為には、加水分解性シラン化合物と炭素数１
０〜３０の脂肪酸又はその塩とからなる水性エマルショ
ンが、優れた白華防止効果を有することを見い出し、本
発明を完成した。以下、本発明を詳細に説明する。Means for Solving the Problems In order to solve the above-mentioned problems, the present inventors have proposed a method of preparing a hydrolyzable silane compound having 1 carbon atom.
It has been found that an aqueous emulsion comprising 0 to 30 fatty acids or salts thereof has an excellent bleaching prevention effect, and the present invention has been completed. Hereinafter, the present invention will be described in detail.
【０００７】[0007]
◎加水分解性シラン化合物 本発明のシラン系水性エマルションで使用する加水分解
性シラン化合物は、躯体に対して吸水防止性及び撥水性
を付与することができるものであれば種々のものが使用
でき、モノマーでもオリゴマーでも使用可能である。オ
リゴマーは、加水分解性シラン化合物の２量体以上の縮
合物であり、好ましいオリゴマーは、２〜１０量体であ
る。１０量体を超えるオリゴマーを使用する場合は、得
られる水性エマルションの吸水防止性能が低下すること
があり、又当該水性エマルションを躯体に塗布して使用
するときには、得られる被膜にムラができることがあ
る。本発明では、加水分解性シラン化合物として、下記
一般式（１）で表される加水分解性シラン化合物又はそ
のオリゴマーが好ましく使用できる。◎ Hydrolyzable silane compound The hydrolyzable silane compound used in the silane-based aqueous emulsion of the present invention may be any of various types as long as it can impart water absorption prevention and water repellency to the main body. Both monomers and oligomers can be used. The oligomer is a condensate of a dimer or more of a hydrolyzable silane compound, and a preferable oligomer is a dimer to a dimer. When an oligomer having more than 10-mers is used, the water-absorbing prevention performance of the obtained aqueous emulsion may be reduced, and when the aqueous emulsion is applied to a skeleton, the resulting coating may have unevenness. . In the present invention, as the hydrolyzable silane compound, a hydrolyzable silane compound represented by the following general formula (1) or an oligomer thereof can be preferably used.
【０００８】[0008]
【化２】Ｒn Ｓｉ（Ｒ1 ）4-n ・・・・（１）Embedded image R n Si (R 1 ) 4-n (1)
【０００９】ここで、式（１）において、Ｒは加水分解
を起こし難く、安定な疎水基であり、炭素数１〜３０の
アルキル基、置換アルキル基又はアリール基である。ア
ルキル基の具体例としては、メチル基、エチル基、プロ
ピル基、ブチル基、ヘキシル基、シクロヘキシル基、オ
クチル基、デシル基、ドデシル基、テトラデシル基、ヘ
キサデシル基、オクタデシル基及びエイコシル基等を挙
げることができる。置換アルキル基としては、ハロゲン
化アルキル基、芳香族置換アルキル基等が挙げられる。
ハロゲン化アルキル基としては、上記アルキル基のフッ
素化物、塩素化物及び臭素化物等があり、具体的には３
−クロロプロピル基、６−クロロヘキシル基及び６，
６，６−トリフルオロヘキシル基等を挙げることができ
る。芳香族置換アルキル基としては、ベンジル基、並び
に４−クロロベンジル基及び４−ブロモベンジル基等の
ハロゲン置換ベンジル基等を挙げることができる。アリ
ール基としては、フェニル基、トリル基、メシチル基及
びナフチル基等が挙げられる。Ｒ1 は、加水分解性の官
能基であり、炭素数１〜６のアルコキシ基、ハロゲン原
子、アミノ基、ヒドロシキル基及びカルボキシル基であ
る。アルコキシ基の例としては、メトキシ基、エトキシ
基及びプロポキシ基等が挙げられる。ハロゲン原子とし
ては、塩素原子又は臭素原子が好ましい。シラン化合物
が複数個のＲ又はＲ1 を持つ場合は、それぞれは同一で
あっても異なっていても良い。ｎは１又は２である。ｎ
が０のものは、得られるエマルションによる吸水防止性
が十分でないという問題がある。Here, in the formula (1), R is a stable hydrophobic group that hardly causes hydrolysis and is an alkyl group having 1 to 30 carbon atoms, a substituted alkyl group or an aryl group. Specific examples of the alkyl group include methyl, ethyl, propyl, butyl, hexyl, cyclohexyl, octyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, eicosyl and the like. Can be. Examples of the substituted alkyl group include a halogenated alkyl group and an aromatic substituted alkyl group.
Examples of the halogenated alkyl group include a fluorinated product, a chlorinated product and a brominated product of the above alkyl group.
-Chloropropyl group, 6-chlorohexyl group and 6,
6,6-trifluorohexyl group and the like can be mentioned. Examples of the aromatic-substituted alkyl group include a benzyl group and a halogen-substituted benzyl group such as a 4-chlorobenzyl group and a 4-bromobenzyl group. Examples of the aryl group include a phenyl group, a tolyl group, a mesityl group, and a naphthyl group. R 1 is a hydrolyzable functional group, which is an alkoxy group having 1 to 6 carbon atoms, a halogen atom, an amino group, a hydroxy group or a carboxyl group. Examples of the alkoxy group include a methoxy group, an ethoxy group and a propoxy group. As the halogen atom, a chlorine atom or a bromine atom is preferable. Silane compound If with a plurality of R or R 1, may be the same or different, each. n is 1 or 2. n
Is 0, there is a problem that the obtained emulsion has insufficient water absorption preventing properties.
【００１０】加水分解性シラン化合物の具体例として
は、下記に示すシラン化合物又はこれらのオリゴマーが
好適なものとして挙げることができる。 ○一般式（１）において、Ｒがアルキル基、ハロゲン化
アルキル基又は芳香族置換アルキル基で、Ｒ1 がアルコ
キシ基で、ｎが１のシラン化合物の例Ｒがアルキル基の
例としては、メチルトリメトキシシラン、メチルトリエ
トキシシラン、メチル−トリ−ｎ−プロポキシシラン、
エチルトリメトキシシラン、エチルトリエトキシシラ
ン、エチル−トリ−ｎ−プロポキシシラン、プロピルト
リエトキシシラン、プロピル−トリ−ｎ−プロポキシシ
ラン、ブチルトリメトキシシラン、ブチルトリエトキシ
シラン、イソブチルトリメトキシシラン、イソブチルト
リエトキシシラン、ｎ−ヘキシルトリメトキシシラン、
ｎ−ヘキシルトリエトキシシラン、シクロヘキシルトリ
メトキシシラン、オクチルトリメトキシシラン、オクチ
ルトリエトキシシラン、オクチルトリイソプロポキシシ
ラン、２−エチルヘキシルトリメトキシシラン、デシル
トリメトキシシラン、ドデシルトリメトキシシラン、テ
トラデシルトリエトキシシラン、ヘキサデシルトリエト
キシシラン、オクタデシルトリエトキシシラン及びエイ
コシルトリメトキシシラン等が挙げられる。Ｒがハロゲ
ン化アルキル基の例としては、６−クロロヘキシルトリ
メトキシシラン及び６，６，６−トリフルオロヘキシル
トリメトキシシラン等が挙げられる。Ｒが芳香族置換ア
ルキル基の例としては、ベンジルトリメトキシシラン、
４−クロロベンジルトリメトキシシラン、４−クロロベ
ンジルトリエトキシシラン及び４−ブロモベンジルトリ
−ｎ−プロポキシシラン等が挙げられる。As specific examples of the hydrolyzable silane compound, the following silane compounds or oligomers thereof are preferred. In the general formula (1), R is an alkyl group, a halogenated alkyl group or an aromatic substituted alkyl group, R 1 is an alkoxy group, and n is 1. Examples of the silane compound R is an alkyl group. Trimethoxysilane, methyltriethoxysilane, methyl-tri-n-propoxysilane,
Ethyltrimethoxysilane, ethyltriethoxysilane, ethyl-tri-n-propoxysilane, propyltriethoxysilane, propyl-tri-n-propoxysilane, butyltrimethoxysilane, butyltriethoxysilane, isobutyltrimethoxysilane, isobutyltriethoxysilane Ethoxysilane, n-hexyltrimethoxysilane,
n-hexyltriethoxysilane, cyclohexyltrimethoxysilane, octyltrimethoxysilane, octyltriethoxysilane, octyltriisopropoxysilane, 2-ethylhexyltrimethoxysilane, decyltrimethoxysilane, dodecyltrimethoxysilane, tetradecyltriethoxysilane , Hexadecyltriethoxysilane, octadecyltriethoxysilane, eicosyltrimethoxysilane and the like. Examples of the case where R is a halogenated alkyl group include 6-chlorohexyltrimethoxysilane and 6,6,6-trifluorohexyltrimethoxysilane. Examples of R is an aromatic substituted alkyl group include benzyltrimethoxysilane,
4-chlorobenzyltrimethoxysilane, 4-chlorobenzyltriethoxysilane and 4-bromobenzyltri-n-propoxysilane.
【００１１】○一般式（１）において、Ｒがアルキル基
で、Ｒ1 がハロゲン原子で、ｎが１のシラン化合物の例
ドデシルトリクロロシラン及びドデシルトリブロモシラ
ン等が挙げられる。In the general formula (1), examples of silane compounds in which R is an alkyl group, R 1 is a halogen atom, and n is 1 include dodecyltrichlorosilane and dodecyltribromosilane.
【００１２】○一般式（１）において、Ｒがアリール基
で、Ｒ1 がアルコキシ基で、ｎが１のシラン化合物の例
フェニルトリメトキシシラン及びフェニルトリエトキシ
シラン等が挙げられる。In the general formula (1), examples of silane compounds in which R is an aryl group, R 1 is an alkoxy group and n is 1 include phenyltrimethoxysilane and phenyltriethoxysilane.
【００１３】○一般式（１）において、Ｒがアルキル基
で、Ｒ1 がアルコキシ基で、ｎが２のシラン化合物の例
ジメチルジメトキシシラン、ジメチルジエトキシシラ
ン、ジブチルジメトキシシラン及びジイソブチルジメト
キシシラン等が挙げられる。In the general formula (1), examples of silane compounds in which R is an alkyl group, R 1 is an alkoxy group and n is 2 include dimethyldimethoxysilane, dimethyldiethoxysilane, dibutyldimethoxysilane and diisobutyldimethoxysilane. No.
【００１４】本発明では、一般式（１）において、Ｒが
アルキル基、Ｒ1 がアルコキシ基で、ｎが１のシラン化
合物、即ちアルキルトリアルコシキシランを使用するこ
とが、保存安定性に優れ、粒子径の小さいエマルション
が得られるためより好ましい。In the present invention, the use of a silane compound of the general formula (1) wherein R is an alkyl group, R 1 is an alkoxy group and n is 1, ie, alkyltrialkoxysilane, is excellent in storage stability, It is more preferable because an emulsion having a small particle size can be obtained.
【００１５】これら加水分解性シラン化合物又はそのオ
リゴマーは、２種以上を併用することもできる。[0015] Two or more of these hydrolyzable silane compounds or oligomers thereof may be used in combination.
【００１６】本発明で使用される加水分解性シラン化合
物又はそのオリゴマーは、製造時の不純物であるシラノ
ール基を持つ化合物や残留触媒等を含んでいるものであ
っても良い。The hydrolyzable silane compound or its oligomer used in the present invention may contain a compound having a silanol group, which is an impurity at the time of production, or a residual catalyst.
【００１７】シラン系水性エマルション中の加水分解性
シラン化合物の割合は、１〜６５重量％であることが好
ましく、より好ましくは５〜５０重量％である。この割
合が１重量％に満たない場合には、得られる水性エマル
ションが躯体に対して吸水防止性及び撥水性等の所望の
性能を発現し難くなることがあり、他方６５重量％を越
える場合には、加水分解性シラン化合物の乳化が困難に
なったり、得られた水性エマルションが不安定で分離し
易くなることがある。The proportion of the hydrolyzable silane compound in the silane-based aqueous emulsion is preferably 1 to 65% by weight, more preferably 5 to 50% by weight. If this proportion is less than 1% by weight, the resulting aqueous emulsion may not be able to exhibit desired properties such as water absorption prevention and water repellency with respect to the skeleton, whereas if it exceeds 65% by weight. In some cases, emulsification of the hydrolyzable silane compound becomes difficult, or the obtained aqueous emulsion is unstable and may be easily separated.
【００１８】シラン系水性エマルション中の加水分解性
シラン化合物の平均粒子径としては、１０μ以下が好ま
しく、より好ましくは１μ以下である。The average particle diameter of the hydrolyzable silane compound in the silane-based aqueous emulsion is preferably 10 μm or less, more preferably 1 μm or less.
【００１９】◎炭素数１０〜３０の脂肪酸又はその塩 本発明では炭素数１０〜３０の脂肪酸又はその塩を使用
する。炭素数が１０に満たないものは、得られる水性エ
マルションに刺激臭があり、他方炭素数３０を超える場
合は、エマルションに対する溶解性又は分散性が不充分
となる。C10-30 fatty acids or salts thereof In the present invention, C10-30 fatty acids or salts thereof are used. Those having less than 10 carbon atoms have a pungent odor in the obtained aqueous emulsion, while those having more than 30 carbon atoms have insufficient solubility or dispersibility in the emulsion.
【００２０】当該脂肪酸としては、飽和脂肪酸及び不飽
和脂肪酸のいずれも使用可能である。飽和脂肪酸として
は、直鎖状飽和脂肪酸及び分岐状飽和脂肪酸のいずれも
使用可能である。直鎖状飽和脂肪酸の具体例としては、
カプリン酸（炭素数１０）、ウンデカン酸（炭素数１
１）、ラウリン酸（炭素数１２）、ミリスチン酸（炭素
数１４）、パルミチン酸（炭素数１６）、ステアリン酸
（炭素数１８）、アラキン酸（炭素数２０）、ベヘン酸
（炭素数２２）、リグノセリン酸（炭素数２４）、セロ
チン酸（炭素数２６）、モンタン酸（炭素数２８）及び
メリシン酸（炭素数３０）等が挙げられる。不飽和脂肪
酸としては、モノエン不飽和脂肪酸及びポリエン不飽和
脂肪酸のいずれも使用可能である。モノエン不飽和脂肪
酸の具体例としては、オブツシル酸（炭素数１０）、カ
プロレイン酸（炭素数１０）、ウンデシレン酸（炭素数
１１）、リンデル酸（炭素数１２）、ツズ酸（炭素数１
４）、フィゼテリン酸（炭素数１４）、ミリストレイン
酸（炭素数１４）、パルメトレイン酸（炭素数１６）、
ペトロセリン酸（炭素数１８）、オレイン酸（炭素数１
８）、エライジン酸（炭素数１８）、アスクレピン酸
（炭素数１８）、バクセン酸（炭素数１８）、ガドレイ
ン酸（炭素数２０）、ゴンドイン酸（炭素数２０）、セ
トレイン酸（炭素数２２）、セルカ酸（炭素数２２）、
ブラシジン酸（炭素数２２）、セラコレイン酸（炭素数
２４）、キシメン酸（炭素数２６）及びルメクエン酸
（炭素数３０）等のが挙げられる。これらの中でも、炭
素数１４〜２２の脂肪酸が、常温で油状であり取扱い易
いため好ましく、より好ましくは、白華防止効果に優れ
ていることから炭素数１４〜２２の不飽和脂肪酸であ
る。脂肪酸は、２種以上を併用することもできる。As the fatty acid, either a saturated fatty acid or an unsaturated fatty acid can be used. As the saturated fatty acid, any of a linear saturated fatty acid and a branched saturated fatty acid can be used. Specific examples of the linear saturated fatty acids include:
Capric acid (C10), undecanoic acid (C1)
1), lauric acid (carbon number 12), myristic acid (carbon number 14), palmitic acid (carbon number 16), stearic acid (carbon number 18), arachiic acid (carbon number 20), behenic acid (carbon number 22) Lignoceric acid (carbon number 24), cellotinic acid (carbon number 26), montanic acid (carbon number 28), melisic acid (carbon number 30) and the like. As the unsaturated fatty acid, any of a monoene unsaturated fatty acid and a polyene unsaturated fatty acid can be used. Specific examples of the monoene unsaturated fatty acid include ovtusylic acid (carbon number 10), caproleic acid (carbon number 10), undecylenic acid (carbon number 11), lindelic acid (carbon number 12), and tuzunic acid (carbon number 1).
4), fisthenic acid (14 carbon atoms), myristoleic acid (14 carbon atoms), palmetreic acid (16 carbon atoms),
Petroseric acid (C18), oleic acid (C1)
8), elaidic acid (18 carbon atoms), ascrepic acid (18 carbon atoms), vaccenic acid (18 carbon atoms), gadolinic acid (20 carbon atoms), gondoyic acid (20 carbon atoms), setreic acid (22 carbon atoms) , Cercaic acid (22 carbon atoms),
Examples include brassic acid (C22), serracoleic acid (C24), xymenic acid (C26), and lumecitric acid (C30). Among them, fatty acids having 14 to 22 carbon atoms are preferable because they are oily at room temperature and easy to handle, and more preferably are unsaturated fatty acids having 14 to 22 carbon atoms because of their excellent anti-whitening effect. Two or more fatty acids can be used in combination.
【００２１】脂肪酸の塩は、上記した脂肪酸を下記に示
すようなアルカリ性化合物により中和されたものであ
る。脂肪酸の塩は、２種以上を併用することもでき、又
脂肪酸と併用することもできる。The fatty acid salt is obtained by neutralizing the above-mentioned fatty acid with an alkaline compound as shown below. Two or more fatty acid salts can be used in combination, or can be used in combination with a fatty acid.
【００２２】本発明では、脂肪酸を使用する場合、シラ
ン系水性エマルションへの溶解又は分散性に優れたもの
となることから、アルカリ性化合物により一部又は全部
が中和された脂肪酸の水溶液又は分散液を用いることが
好ましい。この場合、脂肪酸は、酸及び／又はその塩と
して水中に存在する。アルカリ性化合物としては、一般
に有機酸の溶解又は分散性のために用いられているもの
で良く、例えば水酸化ナトリウム及び水酸化カリウム等
の金属水酸化物、炭酸水素ナトリウム、炭酸ナトリウ
ム、炭酸アンモニウム、ホウ酸ナトリウム、燐酸１、２
又は３ナトリウム、燐酸１、２又は３カリウム、燐酸ア
ンモニウムナトリウム、硫酸１又は２ナトリウム、珪酸
ナトリウム、酢酸ナトリウム、酢酸カリウム、酢酸アン
モニウム、酢酸カルシウム、ぎ酸ナトリウム、硫化１又
は２ナトリウム、アンモニア、モノ、ジ又はトリエチル
アミン、モノ、ジ又はトリエタノールアミン、（エチレ
ンジニトリロ）４酢酸ナトリウム塩（Ｅ．Ｄ．Ｔ．Ａ．
ナトリウム）、ピリジン、並びにアニリン等が挙げられ
る。これらの中でも、ｐＨ調製が容易であることから、
弱アルカリ性のものを使用することが好ましい。これら
は２種以上を併用することもできる。脂肪酸の水溶液又
は分散液の製造方法としては、アルカリ性化合物を含む
水溶液中に、脂肪酸を添加する方法等が挙げられる。こ
の場合のアルカリ性化合物の割合としては、得られる脂
肪酸の水溶液又は水分散液のｐＨが６〜９となる割合で
ある。当該ｐＨに満たない場合、又は超える場合は、得
られるシラン系水性エマルション中の加水分解性シラン
化合物の加水分解が発生してしまうことがある。In the present invention, when a fatty acid is used, it is excellent in dissolution or dispersibility in a silane-based aqueous emulsion. Therefore, an aqueous solution or dispersion of a fatty acid partially or wholly neutralized with an alkaline compound. It is preferable to use In this case, the fatty acids are present in the water as acids and / or salts thereof. As the alkaline compound, those generally used for dissolving or dispersing an organic acid may be used. For example, metal hydroxides such as sodium hydroxide and potassium hydroxide, sodium hydrogen carbonate, sodium carbonate, ammonium carbonate, borane Sodium acid, phosphoric acid 1,2
Or trisodium, 1, 2 or 3 potassium phosphate, sodium ammonium phosphate, 1 or 2 sodium sulfate, sodium silicate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, sodium formate, 1 or 2 sodium sulfide, ammonia, mono , Di- or triethylamine, mono-, di- or triethanolamine, (ethylenedinitrilo) tetraacetic acid sodium salt (EDTA).
Sodium), pyridine, and aniline. Among them, pH adjustment is easy,
It is preferable to use a weak alkaline one. These may be used in combination of two or more. Examples of a method for producing an aqueous solution or dispersion of a fatty acid include a method of adding a fatty acid to an aqueous solution containing an alkaline compound. The ratio of the alkaline compound in this case is a ratio at which the pH of the obtained aqueous solution or aqueous dispersion of the fatty acid is 6 to 9. If the pH is less than or exceeds the pH, hydrolysis of the hydrolyzable silane compound in the obtained silane-based aqueous emulsion may occur.
【００２３】本発明における脂肪酸又はその塩の配合割
合は、特に制限はないが、得られる水性エマルションの
被膜の仕上がり感に影響を及ぼさない程度に配合するこ
とが好ましい。具体的には、本発明の水性エマルション
を躯体表面に塗布して使用する場合は、水性エマルショ
ン１００重量部に対して、脂肪酸又はその塩を脂肪酸基
準で０．１〜０．５重量部、より好ましくは０．２〜
０．３部の割合である。この割合が０．１重量部に満た
ないと充分な白華防止性能が得られないことがあり、他
方０．５重量部を越えると、表面が暗変する等の仕上が
り感に影響を及ぼすことがある。又、本発明の水性エマ
ルションをモルタルやコンクリート等の躯体中に配合す
る場合は、躯体原料の混練時に添加して用いることがで
き、この場合は水性エマルション１００重量部に対して
脂肪酸又はその塩を脂肪酸基準で５〜１５重量部配合す
ることが好ましく、より好ましくは７〜１２重量部であ
る。この割合が５重量部に満たない場合は、白華防止効
果が不充分なことがあり、他方１５重量部を超えると、
得られる躯体の強度が低下することがある。脂肪酸を水
溶液又は分散液として配合する場合における、水溶液又
は分散液中の脂肪酸又はその塩の濃度は、脂肪酸基準で
５〜２０重量％が好ましく、より好ましくは８〜１２重
量％である。The mixing ratio of the fatty acid or salt thereof in the present invention is not particularly limited, but it is preferable to mix the fatty acid or the salt thereof to such an extent that the finished feeling of the film of the obtained aqueous emulsion is not affected. Specifically, when the aqueous emulsion of the present invention is applied to the surface of a skeleton and used, 100 to 100 parts by weight of the aqueous emulsion, 0.1 to 0.5 parts by weight of a fatty acid or a salt thereof on a fatty acid basis, more Preferably 0.2 to
The ratio is 0.3 parts. If this ratio is less than 0.1 part by weight, sufficient anti-whitening performance may not be obtained, while if it exceeds 0.5 part by weight, it may affect the finished feeling such as darkening of the surface. There is. Further, when the aqueous emulsion of the present invention is blended into a skeleton such as mortar or concrete, it can be used by adding at the time of kneading the raw material of the skeleton. In this case, the fatty acid or a salt thereof is added to 100 parts by weight of the aqueous emulsion. It is preferable to mix 5 to 15 parts by weight, more preferably 7 to 12 parts by weight, based on the fatty acid. If this proportion is less than 5 parts by weight, the effect of preventing whitening may be insufficient, while if it exceeds 15 parts by weight,
The strength of the obtained skeleton may be reduced. When the fatty acid is blended as an aqueous solution or dispersion, the concentration of the fatty acid or its salt in the aqueous solution or dispersion is preferably 5 to 20% by weight, more preferably 8 to 12% by weight, based on the fatty acid.
【００２４】◎乳化剤 本発明で使用される乳化剤は、前記加水分解性シラン化
合物を水性エマルションないしはそれに近い状態にする
目的で配合されるものであり、ノニオン性、アニオン性
及びカチオン性の何れのタイプのものも使用可能であ
る。これらの中でもノニオン性乳化剤を使用した加水分
解性シラン化合物の水性エマルションは乳化安定性が優
れており好ましい。ノニオン性及びアニオン性乳化剤を
使用する場合には、加水分解縮合反応が比較的早く発生
し効力が低下してしまうので、調製後速やかに使用する
ことが好ましい。ノニオン性乳化剤としては、ＨＬＢ＝
４〜２２のタイプのもの、又はそれらの混合物が好適に
使用される。具体例としては、ポリオキシエチレンラウ
リルエーテル、ポリオキシエチレンオクチルフェニルエ
ーテル、ポリオキシエチレンノニルフェニルエーテル、
ポリオキシエチレン誘導体、ソルビタンモノラウレー
ト、ソルビタンモノステアレート、ポリオキシエチレン
ソルビタンモノラウレート及びポリオキシエチレンソル
ビタンモノステアレート等が挙げられる。その他の乳化
剤のＨＬＢとしては１．５〜２２のものが好ましく、よ
り好ましくは４〜１５である。乳化剤は、加水分解性シ
ラン化合物に対して０．１〜５０重量％に範囲で使用す
ることが好ましく、より好ましくは１〜２０重量％であ
る。乳化剤の種類及び濃度は、使用する加水分解性シラ
ン化合物により変化するため、乳化剤を使用するに当た
っては、実験的に検討し決定することが好ましい。これ
ら乳化剤は、２種以上を併用することもできる。◎ Emulsifier The emulsifier used in the present invention is blended for the purpose of converting the hydrolyzable silane compound into an aqueous emulsion or a state close to an aqueous emulsion, and may be any of nonionic, anionic and cationic types. Can also be used. Among these, an aqueous emulsion of a hydrolyzable silane compound using a nonionic emulsifier is preferred because of its excellent emulsion stability. When a nonionic or anionic emulsifier is used, the hydrolysis-condensation reaction occurs relatively quickly and the efficacy is reduced. Therefore, it is preferable to use the nonionic and anionic emulsifiers immediately after preparation. As a nonionic emulsifier, HLB =
4 to 22 types or mixtures thereof are preferably used. Specific examples include polyoxyethylene lauryl ether, polyoxyethylene octyl phenyl ether, polyoxyethylene nonyl phenyl ether,
Examples thereof include polyoxyethylene derivatives, sorbitan monolaurate, sorbitan monostearate, polyoxyethylene sorbitan monolaurate, and polyoxyethylene sorbitan monostearate. The HLB of the other emulsifiers is preferably from 1.5 to 22, more preferably from 4 to 15. The emulsifier is preferably used in the range of 0.1 to 50% by weight, more preferably 1 to 20% by weight, based on the hydrolyzable silane compound. Since the type and concentration of the emulsifier vary depending on the hydrolyzable silane compound used, it is preferable to experimentally study and determine the emulsifier when using the emulsifier. These emulsifiers can be used in combination of two or more kinds.
【００２５】◎その他の成分 本発明の水性エマルションには、上記必須成分の他、必
要に応じて、シリコーン系マクロモノマーからなる乳化
剤等の前記したもの以外の乳化剤、保護コロイド剤及び
緩衝剤等を通常の割合含有しても良い。この他にも、防
黴剤、殺菌剤、フレグランス、着色剤、シックナー、発
泡剤及び消泡剤等をシラン系水性エマルションの性能を
損わない程度添加することもできる。本発明では、エマ
ルション中の加水分解性シラン化合物の加水分解反応を
抑制する目的で、緩衝剤を配合することが好ましい。緩
衝剤としては、有機酸、無機酸、塩基及びこれらの塩等
が挙げられる。無機酸としては、炭酸、燐酸、硫酸及び
ヒドロ硫酸等が挙げられる。有機酸としては、炭素数１
〜６のオルガノ−、モノ又はポリカルボン酸、有機酸の
塩としては、炭素数２〜３０のアルキレンイミノポリカ
ルボン酸のモノ又はポリアルカリ金属塩、アルカリ土類
金属塩又はアミン塩等が挙げられる。塩基としては、ア
ンモニア、炭素数１〜３０の有機塩基等が挙げられる。
本発明では、無機酸の塩を使用することが好ましく、具
体的には、炭酸水素ナトリウム、炭酸ナトリウム、炭酸
アンモニウム、ホウ酸ナトリウム、燐酸１、２又は３ナ
トリウム、燐酸１、２又は３カリウム、燐酸アンモニウ
ムナトリウム、硫酸１又は２ナトリウム、酢酸ナトリウ
ム、酢酸カリウム、酢酸アンモニウム、酢酸カルシウ
ム、ぎ酸ナトリウム、硫化１又は２ナトリウム、アンモ
ニア、モノ、ジ又はトリエチルアミン、モノ、ジ又はト
リエタノールアミン、（エチレンジニトリロ）４酢酸ナ
トリウム塩（Ｅ．Ｄ．Ｔ．Ａ．ナトリウム）、ピリジ
ン、アニリン及び珪酸ナトリウム等が挙げられる。これ
らは２種以上を併用することもできる。緩衝剤の配合割
合は、通常シラン系水性エマルションに添加されている
割合で良く、具体的には水性エマルション中に０．０１
〜５重量％が好ましい。◎ Other components In addition to the above essential components, the aqueous emulsion of the present invention may further contain, if necessary, an emulsifier other than those described above, such as an emulsifier comprising a silicone macromonomer, a protective colloid agent and a buffering agent. Ordinary proportions may be contained. In addition, an antifungal agent, a bactericide, a fragrance, a coloring agent, a thickener, a foaming agent, an antifoaming agent, and the like can be added to the extent that the performance of the silane-based aqueous emulsion is not impaired. In the present invention, it is preferable to add a buffer for the purpose of suppressing the hydrolysis reaction of the hydrolyzable silane compound in the emulsion. Examples of the buffer include organic acids, inorganic acids, bases, and salts thereof. Examples of the inorganic acid include carbonic acid, phosphoric acid, sulfuric acid and hydrosulfuric acid. Organic acids include those having 1 carbon atom
Examples of the salt of an organo-, mono- or polycarboxylic acid and an organic acid having from 6 to 6 include a mono- or poly-alkali metal salt, an alkaline earth metal salt or an amine salt of an alkylene imino polycarboxylic acid having 2 to 30 carbon atoms. . Examples of the base include ammonia, an organic base having 1 to 30 carbon atoms, and the like.
In the present invention, it is preferable to use a salt of an inorganic acid, and specifically, sodium hydrogen carbonate, sodium carbonate, ammonium carbonate, sodium borate, 1, 2 or 3 sodium phosphate, 1, 2 or 3 potassium phosphate, Sodium ammonium phosphate, 1 or 2 sodium sulfate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, sodium formate, 1 or 2 sodium sulfide, ammonia, mono, di or triethylamine, mono, di or triethanolamine, (ethylene Dinitrile) tetraacetic acid sodium salt (EDTA sodium), pyridine, aniline, sodium silicate and the like. These may be used in combination of two or more. The mixing ratio of the buffering agent may be the ratio usually added to the silane-based aqueous emulsion, and specifically, 0.01% in the aqueous emulsion.
~ 5% by weight is preferred.
【００２６】◎水 本発明における水は、加水分解性シラン化合物を分散さ
せるための分散媒であり、その好ましい使用割合は、シ
ラン系水性エマルション中に３５〜９９重量％であり、
より好ましくは５０〜９５重量％である。エマルション
中の水の割合が３５重量％に満たないと、シラン化合物
の乳化が困難になったり、得られたエマルションが不安
定で分離し易くなる場合があり、他方９９重量％を超え
ると、シラン化合物の割合が少ないため、得られる被膜
又は硬化物が、撥水性及び吸水防止性を発現し難くなる
場合がある。Water Water in the present invention is a dispersion medium for dispersing the hydrolyzable silane compound, and its preferred proportion is 35 to 99% by weight in the silane-based aqueous emulsion.
More preferably, it is 50 to 95% by weight. When the proportion of water in the emulsion is less than 35% by weight, emulsification of the silane compound may be difficult, and the obtained emulsion may be unstable and easy to separate. Since the proportion of the compound is small, the resulting coating or cured product may be difficult to exhibit water repellency and water absorption prevention properties.
【００２７】◎製造方法 本発明のシラン系水性エマルションは、極めて容易に製
造することができる。例えば、加水分解性シラン化合
物、脂肪酸又はその塩、乳化剤及び水を撹拌混合して加
水分解性シラン化合物をエマルション化する方法、並び
に加水分解性シラン化合物、乳化剤及び水を撹拌混合し
て加水分解性シラン化合物をエマルション化したもの
と、脂肪酸又はその塩を撹拌下混合する方法等が挙げら
れる。この場合、脂肪酸の添加方法としては、そのまま
配合することも可能であるが、アルカリ性化合物により
一部又は全部が中和された脂肪酸の水溶液又は分散液と
して使用することが、脂肪酸のシラン系水性エマルショ
ンへの溶解又は分散性に優れるためため好ましい。得ら
れた水性エマルションに更に水を加えて任意に希釈する
こともできるが、前記した各必須成分の好ましい割合の
下限値を下回らない様注意する必要がある。又、前記し
たその他の成分は、各成分に配合しておいても、各成分
の配合時に配合することも又は各成分の配合後に配合す
ることもできる。Production Method The silane-based aqueous emulsion of the present invention can be produced very easily. For example, a method of emulsifying a hydrolyzable silane compound by stirring and mixing a hydrolyzable silane compound, a fatty acid or a salt thereof, an emulsifier and water, and a method of stirring and mixing a hydrolyzable silane compound, an emulsifier and water to form a hydrolyzable compound. A method in which a silane compound is emulsified and a fatty acid or a salt thereof are mixed with stirring is exemplified. In this case, as a method of adding the fatty acid, it is possible to mix the fatty acid as it is, but it is possible to use a silane-based aqueous emulsion of the fatty acid as an aqueous solution or dispersion of a fatty acid partially or wholly neutralized with an alkaline compound. It is preferable because it has excellent dissolution or dispersibility in water. The obtained aqueous emulsion may be further diluted by adding water, but care must be taken so as not to fall below the lower limit of the above-mentioned preferred ratio of each essential component. The other components described above may be added to each component, may be added when each component is added, or may be added after each component is added.
【００２８】◎使用方法 本発明のシラン系水性エマルションは、種々のコンクリ
ート等の躯体に塗布又は添加することにより、これら躯
体に吸水防止性及び白華防止性を付与することができ
る。躯体としては、種々の材料並びに該材料からなる建
築物及び構造物に適用することができ、例えばモルタ
ル、コンクリート、ＡＬＣ及び気泡コンクリート等のセ
メント系材料、スレート及びサイジングボード等のセメ
ントを結合剤とする材料、タイル、煉瓦及び瓦等のセラ
ミックス、硅酸カルシウム板、並びに石材等の無機質建
築材料が好ましく、その他木材、プラスチック等にも可
能である。本発明の水性エマルションを躯体に塗布して
使用する場合の塗布方法としては、常法に従えばよく、
例えばシラン系水性エマルションを、ハケ塗り法、ロー
ラー塗り法、エアースプレー法、エアレススプレー法、
含浸法又はカーテンロールコーター法等の常法に従い躯
体に塗布し、乾燥させる方法等が挙げられる。本発明の
水性エマルションの使用量は、固形分濃度、躯体の多孔
性及び表面処理方法によって変化するが、概ね０．０５
〜２．０kg/m2 である。躯体製造時において、原料の混
練時に配合する場合も、常法に従えば良く、他の減水防
止剤や消泡剤等の一般の混和剤と同様に添加して練り混
ぜれば良い。この場合、本発明の水性エマルションの使
用量としては、セメント系材料の固形分濃度、躯体の多
孔性によって変化するが、該シラン系水性エマルション
を躯体の他の物性を阻害しない範囲内で配合すれば良
い。具体的には、混練中のセメントスラリー中のセメン
ト分１００重量部に対して、水性エマルションの固形分
が１〜１０重量部であることが好ましく、より好ましく
は１〜５重量部である。この割合が１重量部に満たない
場合は白華防止効果が不充分なことがあり、他方１０重
量部を越えると表面の仕上がり感に影響を及ぼしたり、
強度が低下することがある。Method of Use The silane-based aqueous emulsion of the present invention can impart water absorbing and anti-whitening properties to various skeletons such as concrete by applying or adding them to the skeletons. As the frame, it can be applied to various materials and buildings and structures made of such materials.For example, cement-based materials such as mortar, concrete, ALC and cellular concrete, and cement such as slate and sizing board can be used as a binder. Materials, ceramics such as tiles, bricks and tiles, calcium silicate plates, and inorganic building materials such as stones are preferable, and other materials such as wood and plastic are also possible. As a coating method when the aqueous emulsion of the present invention is used by applying it to a skeleton, a conventional method may be used,
For example, silane-based aqueous emulsion, brush coating method, roller coating method, air spray method, airless spray method,
According to a conventional method such as an impregnation method or a curtain roll coater method, a method in which the composition is applied to a skeleton and dried is used. The amount of the aqueous emulsion of the present invention varies depending on the solid content concentration, the porosity of the skeleton, and the surface treatment method.
２．０2.0 kg / m 2 . When the raw materials are kneaded during the production of the skeleton, the raw materials may be mixed according to a conventional method, and may be added and kneaded in the same manner as other general admixtures such as a water-reducing inhibitor and an antifoaming agent. In this case, the amount of the aqueous emulsion of the present invention varies depending on the solid content concentration of the cement-based material and the porosity of the skeleton, but the silane-based aqueous emulsion is blended within a range that does not inhibit other physical properties of the skeleton. Good. Specifically, the solid content of the aqueous emulsion is preferably 1 to 10 parts by weight, more preferably 1 to 5 parts by weight, based on 100 parts by weight of cement in the cement slurry during kneading. If this proportion is less than 1 part by weight, the effect of preventing whitening may be insufficient, while if it exceeds 10 parts by weight, it may affect the finished feeling of the surface,
The strength may decrease.
【００２９】[0029]
【作用】本発明のシラン系水性エマルションは、分離す
ることなく安定である上、躯体に塗布した場合、撥水性
及び吸水防止性を損なうことなく、躯体に白華防止性を
付与するとができる。又、コンクリート等の躯体製造時
において配合した場合も、脂肪酸を含め従来の様々な市
販の白華防止剤を配合した場合、又はシラン系水性エマ
ルションのみを配合したときと比較して、撥水性及び吸
水防止性を損なうことなく、その表面に白華防止性を付
与することができる。本発明のシラン系水性エマルショ
ンがこの様な優れた性能を発現する理由としては、次の
ことが考えられる。即ち、本発明の水性エマルション
は、シラン化合物の硬化物に起因する撥水性及び吸水防
止性と脂肪酸に起因する遊離イオンの固定効果を併せ持
つため、白華の原因であるセメント水和物中のＣａイオ
ンが当該水和物中の水分と共に躯体表面に移行すること
を阻止し、さらに脂肪酸がＣａイオンを捕捉するとい
う、二重の効果があるためであると考えられる。The silane-based aqueous emulsion of the present invention is stable without being separated and, when applied to a skeleton, can impart an anti-whitening property to the skeleton without impairing water repellency and anti-water absorption properties. Also, when blended at the time of the production of a body such as concrete, when compared with the case where various conventional commercially available whitening inhibitors including fatty acids are blended, or compared with the case where only a silane-based aqueous emulsion is blended, water repellency and The surface can be provided with anti-whitening property without impairing the water absorption preventing property. The reason why the silane-based aqueous emulsion of the present invention exhibits such excellent performance is considered as follows. That is, the aqueous emulsion of the present invention has both water repellency and anti-water absorption properties due to the cured product of the silane compound and the effect of fixing free ions due to the fatty acids, so that Ca in the cement hydrate, which is the cause of efflorescence, This is considered to be because the ion has the dual effect of preventing the ions from migrating to the surface of the body together with the water in the hydrate, and the fatty acid capturing Ca ions.
【００３０】[0030]
【実施例】以下、実施例を挙げて本発明をより具体的に
説明する。なお、各例における「部」は、「重量部」を
意味する。EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. In addition, "part" in each example means "part by weight".
【００３１】○実施例１ ヘキシルトリエトキシシラン４０部に、水５０部、ノニ
オン系乳化剤のオクチルフェノールポリエチレンオキエ
タノール〔７０部のＵＮＩＯＮ ＣＡＲＢＩＤＥ社ＴＲ
ＩＴＯＮ（商標）Ｘ−１００と３０部のＴＲＩＴＯＮ
（商標）Ｘ−３０５からなる乳化剤〕混合物４部及び重
炭酸ナトリウム０．２部を加え高速撹拌して乳化させ、
有効成分４０％のシランエマルションＡを調製した。こ
のシランエマルションＡのｐＨは８．１であった。ｐＨ
１１のアンモニア水９０部に、オレイン酸（商品名ＰＲ
ＩＢＬＯＣＫ、ユニケマ社製）１０部を加えて３０分撹
拌し、オレイン酸の１０％水溶液を調製した。ｐＨは
８．２であった。シランエマルション２５部に、水７
２．５部及び前記オレイン酸水溶液を２．５部を撹拌混
合し、シラン系水性エマルションを得た。得られたシラ
ン系水性エマルションを用いて、材令４ヶ月の７０mm×
７０mm×２０mm下地モルタル（ＪＩＳＲ ５２０１）に
３００ｇ／m2の割合で刷毛にて塗布した後、養生して評
価用の試験体とした。得られた試験体を使用し、下記の
白華評価及び吸水防止性評価を行った。Example 1 In 40 parts of hexyltriethoxysilane, 50 parts of water, octylphenol polyethylene oxyethanol as a nonionic emulsifier [70 parts of TR of UNION CARBIDE, Inc.
ITON ™ X-100 and 30 parts of TRITON
(Trademark) X-305 emulsifier], 4 parts of a mixture and 0.2 parts of sodium bicarbonate are added, and the mixture is emulsified by high-speed stirring.
A silane emulsion A having an active ingredient of 40% was prepared. The pH of this silane emulsion A was 8.1. pH
In 90 parts of ammonia water, oleic acid (trade name: PR
IBLOCK (manufactured by Unichema) (10 parts) was added and stirred for 30 minutes to prepare a 10% aqueous solution of oleic acid. pH was 8.2. 25 parts of silane emulsion and 7 parts of water
2.5 parts and 2.5 parts of the oleic acid aqueous solution were stirred and mixed to obtain a silane-based aqueous emulsion. Using the obtained silane-based aqueous emulsion, a 70 mm ×
After applying to a 70 mm × 20 mm base mortar (JISR 5201) with a brush at a rate of 300 g / m 2 , it was cured and used as a test specimen for evaluation. Using the obtained test body, the following evaluation of efflorescence and evaluation of water absorption prevention were performed.
【００３２】・白華評価 得られた試験体を屋外で３カ月放置した。次いで側面を
エポキシ系樹脂にてシールし、７℃、５０％Ｒ．Ｈ．試
験環境下で供試体上面１ｃｍが水面に出るように半水浸
漬し２８日間放置して上面の白華状況を観察した。尚、
表１において、○及び×は以下の意味を示す。 ○：白華発生せず、×：白華発生Evaluation of Efflorescence The obtained specimen was left outdoors for 3 months. Next, the side surface is sealed with an epoxy resin, and 7 ° C., 50% RH. H. Under the test environment, the specimen was immersed in semi-water so that 1 cm of the upper surface of the specimen was exposed to the surface of the water, and allowed to stand for 28 days to observe the whiteness of the upper surface. still,
In Table 1, ○ and × have the following meanings. ：: No whitening occurred, ×: Whitening occurred
【００３３】・吸水防止性評価 得られた試験体を、ＪＩＳＡ１４０４に準じて７日間水
浸後の吸水比を求めた。尚、吸水比は式により求めた。Evaluation of Water Absorption Prevention The water absorption ratio of the obtained test specimen after immersion in water for 7 days was determined according to JISA1404. Note that the water absorption ratio was determined by the equation.
【００３４】[0034]
【式１】 (Equation 1)
【００３５】[0035]
【表１】 [Table 1]
【００３６】○比較例１ 実施例１のシランエマルションＡの２５部（有効成分４
０％）に、水７５部を撹拌下混合し、シラン系水性エマ
ルションを得た。得られた水性エマルションを使用し、
実施例１と同様に評価した。それらの結果を表１に示
す。Comparative Example 1 25 parts of the silane emulsion A of Example 1 (active ingredient 4
0%) and 75 parts of water were mixed with stirring to obtain a silane-based aqueous emulsion. Using the obtained aqueous emulsion,
Evaluation was performed in the same manner as in Example 1. Table 1 shows the results.
【００３７】○実施例２ 実施例１のシラン系エマルションＡの１部に対し、オレ
イン酸が１部となるよう実施例１のオレイン酸水溶液の
１０部を撹拌下混合し、シラン系水性エマルションを得
た。普通ポルトランドセメント１００部、豊浦標準砂３
００部、水７５部を配合し、これに当該エマルション１
１部（セメントスラリー中のセメント分１００部に対し
てシラン系水性エマルションの固形分１．４部）となる
ように配合して混練し、得られた水和混練物を使用して
セメント板を成形した。この成形物を養生して硬化させ
評価用の試験体とした。得られた試験体を使用し、実施
例１と同様に評価した。それらの結果を表２に示す。Example 2 To 1 part of the silane-based emulsion A of Example 1, 10 parts of the aqueous oleic acid solution of Example 1 were mixed with stirring so that the amount of oleic acid became 1 part, and the aqueous silane-based emulsion was mixed. Obtained. 100 parts of ordinary Portland cement, Toyoura standard sand 3
00 parts and water 75 parts, and the emulsion 1
1 part (the solid content of the silane-based aqueous emulsion is 1.4 parts with respect to 100 parts of the cement content in the cement slurry) and kneaded, and the obtained hydrated kneaded product is used to form a cement board. Molded. This molded product was cured and cured to obtain a test specimen for evaluation. Using the obtained test body, evaluation was made in the same manner as in Example 1. Table 2 shows the results.
【００３８】[0038]
【表２】 [Table 2]
【００３９】○比較例２ 実施例１のシランエマルションＡをそのまま用い、セメ
ントスラリー中のセメント分１００部に対してシランエ
マルションＡの１部を加えた以外は実施例２の場合と同
様にしてセメント板を作製し、評価用の試験体とした。
得られた試験体を用いて、実施例１と同様に評価した。
それらの結果を表２に示す。躯体製造時にシラン化合物
のみを配合した比較例２の試験体では、吸水防止性能に
優れるものの、白華が発生してしまった。Comparative Example 2 Cement was prepared in the same manner as in Example 2 except that silane emulsion A of Example 1 was used as it was, and 1 part of silane emulsion A was added to 100 parts of cement in the cement slurry. A plate was prepared and used as a test body for evaluation.
Using the obtained test body, evaluation was made in the same manner as in Example 1.
Table 2 shows the results. In the test specimen of Comparative Example 2 in which only the silane compound was blended at the time of the production of the skeleton, although the water absorption preventing performance was excellent, white spots were generated.
【００４０】○比較例３ 実施例１のオレイン酸水溶液をそのまま用い、セメント
スラリー中のセメント分１００部に対してオレイン酸水
溶液の１０部を加えた以外は実施例２の場合と同様にし
てセメント板を作製し、評価用の試験体とした。得られ
た試験体を用いて、実施例１と同様に評価した。それら
の結果を表２に示す。躯体製造時にオレイン酸のみを配
合した比較例３の試験体では、吸水防止性能に優れるも
のの、白華が発生してしまった。Comparative Example 3 A cement was prepared in the same manner as in Example 2 except that the oleic acid aqueous solution of Example 1 was used as it was, and 10 parts of the oleic acid aqueous solution was added to 100 parts of cement in the cement slurry. A plate was prepared and used as a test body for evaluation. Using the obtained test body, evaluation was made in the same manner as in Example 1. Table 2 shows the results. In the test specimen of Comparative Example 3 in which only oleic acid was blended at the time of the production of the skeleton, although the water absorption preventing performance was excellent, efflorescence was generated.
【００４１】[0041]
【発明の効果】本発明のシラン系水性エマルションは、
躯体に対して塗布又は躯体製造時に配合することで、躯
体に対して優れた白華防止性及び吸水防止性を付与する
ことができる。The silane-based aqueous emulsion of the present invention is
By applying to the skeleton or blending it at the time of manufacturing the skeleton, it is possible to impart excellent efflorescence prevention and water absorption prevention to the skeleton.
Claims (4)
０の脂肪酸又はその塩、乳化剤及び水からなるシラン系
水性エマルション。1. A hydrolyzable silane compound having 10 to 3 carbon atoms.
A silane-based aqueous emulsion comprising a fatty acid or a salt thereof, an emulsifier, and water.
（１）で表される化合物又はそのオリゴマーであること
を特徴とする請求項１記載のシラン系水性エマルショ
ン。 【化１】Ｒn Ｓｉ（Ｒ1 ）4-n ・・・・（１） （式中、Ｒは炭素数１〜３０のアルキル基、置換アルキ
ル基又はアリール基、Ｒ1 は炭素数１〜６のアルコキシ
基、ハロゲン原子、アミノ基、ヒドロシキル基又はカル
ボキシル基であり、複数個のＲ又はＲ1 を持つ場合、そ
れぞれは同一でも異なっていても良い。ｎは１又は２で
ある）2. The silane-based aqueous emulsion according to claim 1, wherein the hydrolyzable silane compound is a compound represented by the following general formula (1) or an oligomer thereof. Embedded image R n Si (R 1 ) 4-n (1) wherein R is an alkyl group having 1 to 30 carbon atoms, a substituted alkyl group or an aryl group, and R 1 is 1 to 3 carbon atoms. 6 is an alkoxy group, a halogen atom, an amino group, a hydroxy group or a carboxyl group, and when having a plurality of R or R 1 , each may be the same or different; n is 1 or 2)
ルション、及びアルカリ性化合物により一部又は全部が
中和された炭素数１０〜３０の脂肪酸の水溶液又は分散
液を、乳化剤を用い又は用いることなく水に分散させる
ことを特徴とするシラン系水性エマルションの製造方
法。3. An aqueous solution or dispersion of a hydrolyzable silane compound or an aqueous emulsion thereof, and a C10-30 fatty acid partially or wholly neutralized with an alkaline compound, with or without an emulsifier. A method for producing a silane-based aqueous emulsion, characterized by being dispersed in water.
（１）で表される化合物又はそのオリゴマーであること
を特徴とする請求項３記載のシラン系水性エマルション
の製造方法。4. The method for producing a silane-based aqueous emulsion according to claim 3, wherein the hydrolyzable silane compound is a compound represented by the general formula (1) or an oligomer thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25434197A JPH1176797A (en) | 1997-09-03 | 1997-09-03 | Silane aqueous emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25434197A JPH1176797A (en) | 1997-09-03 | 1997-09-03 | Silane aqueous emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1176797A true JPH1176797A (en) | 1999-03-23 |
Family
ID=17263663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25434197A Pending JPH1176797A (en) | 1997-09-03 | 1997-09-03 | Silane aqueous emulsion |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH1176797A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002531642A (en) * | 1998-12-10 | 2002-09-24 | ダウ・コーニング・コーポレーシヨン | Stable, constant particle size, non-polar silane, aqueous emulsion suitable for use in water repellent applications |
| US10829505B2 (en) | 2016-04-20 | 2020-11-10 | Dow Silicones Corporation | Lithium alkylsiliconate composition, coating, and method of making same |
-
1997
- 1997-09-03 JP JP25434197A patent/JPH1176797A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002531642A (en) * | 1998-12-10 | 2002-09-24 | ダウ・コーニング・コーポレーシヨン | Stable, constant particle size, non-polar silane, aqueous emulsion suitable for use in water repellent applications |
| US10829505B2 (en) | 2016-04-20 | 2020-11-10 | Dow Silicones Corporation | Lithium alkylsiliconate composition, coating, and method of making same |
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