JPS5441815A - Preparation of acrylate or methacrylate - Google Patents
Preparation of acrylate or methacrylateInfo
- Publication number
- JPS5441815A JPS5441815A JP10500077A JP10500077A JPS5441815A JP S5441815 A JPS5441815 A JP S5441815A JP 10500077 A JP10500077 A JP 10500077A JP 10500077 A JP10500077 A JP 10500077A JP S5441815 A JPS5441815 A JP S5441815A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- alcohol
- meth
- lithium
- acrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the titled high quality compound, a starting material for treatments and additives, in high yield through simplified operations by the ester exchange of an alcohol ester of (meth)acrylic acid with an alcohol, using a catalyst of Li or a specific Li compound free from deterioration of the activity.
CONSTITUTION: A lower alcohol ester of (meth)acrylic acid is subjected to the ester exchange with a higher (polyhydric)alcohol using Li, a compound of LiR (R=H, 1-4C clkyl, or phenyl) (e.g. lithium hydride, butyllithium), a compound of LiAl (R')4 (R'=H, 1-4 alkoxy) (e.g. lithiumaluminum hydride), an inorganic acid salt of Li (e.g. lithium halide, lithium carbonate), an organic acid salt of Li (e.g. Li laurate, Li stearate), lithium acetylacetonate, or a Li oxide as a catalyst to afford a higher (polyhydric) alcohol ester of (meth)acrylic acid.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10500077A JPS5441815A (en) | 1977-09-02 | 1977-09-02 | Preparation of acrylate or methacrylate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10500077A JPS5441815A (en) | 1977-09-02 | 1977-09-02 | Preparation of acrylate or methacrylate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5441815A true JPS5441815A (en) | 1979-04-03 |
| JPS5742061B2 JPS5742061B2 (en) | 1982-09-07 |
Family
ID=14395811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10500077A Granted JPS5441815A (en) | 1977-09-02 | 1977-09-02 | Preparation of acrylate or methacrylate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5441815A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5793930A (en) * | 1980-12-03 | 1982-06-11 | Mitsui Toatsu Chem Inc | Preparation of methacrylic ester |
| FR2566394A1 (en) * | 1984-06-26 | 1985-12-27 | Roehm Gmbh | PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION |
| JPS6150940A (en) * | 1984-06-26 | 1986-03-13 | レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | Manufacture of acrylic acid- or methacrylic acid ester from alcohol by esterification |
| FR2924114A1 (en) * | 2007-11-27 | 2009-05-29 | Arkema France | PROCESS FOR THE SYNTHESIS OF ALCOXYPOLYALKYLENE GLYCOLS (METH) ACRYLATES BY TRANSESTERIFICATION |
| WO2023199756A1 (en) * | 2022-04-15 | 2023-10-19 | 東ソー株式会社 | Compound, method for producing same, composition, urethane resin, aqueous urethane resin dispersion, and coating agent |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5225714A (en) * | 1975-08-21 | 1977-02-25 | Mitsubishi Rayon Co Ltd | Process for preparation of acrylic acid esters or methacrylic acid est ers |
-
1977
- 1977-09-02 JP JP10500077A patent/JPS5441815A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5225714A (en) * | 1975-08-21 | 1977-02-25 | Mitsubishi Rayon Co Ltd | Process for preparation of acrylic acid esters or methacrylic acid est ers |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5793930A (en) * | 1980-12-03 | 1982-06-11 | Mitsui Toatsu Chem Inc | Preparation of methacrylic ester |
| FR2566394A1 (en) * | 1984-06-26 | 1985-12-27 | Roehm Gmbh | PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION |
| JPS6150940A (en) * | 1984-06-26 | 1986-03-13 | レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | Manufacture of acrylic acid- or methacrylic acid ester from alcohol by esterification |
| JPS6156155A (en) * | 1984-06-26 | 1986-03-20 | レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | Manufacture of polyhydric alcohol of acrylic acid- and methacrylic acid ester by esterification |
| FR2924114A1 (en) * | 2007-11-27 | 2009-05-29 | Arkema France | PROCESS FOR THE SYNTHESIS OF ALCOXYPOLYALKYLENE GLYCOLS (METH) ACRYLATES BY TRANSESTERIFICATION |
| WO2009071786A1 (en) * | 2007-11-27 | 2009-06-11 | Arkema France | Method for synthesizing alkoxypolyalkylene glycol (meth)acrylates by transesterification |
| WO2023199756A1 (en) * | 2022-04-15 | 2023-10-19 | 東ソー株式会社 | Compound, method for producing same, composition, urethane resin, aqueous urethane resin dispersion, and coating agent |
| JPWO2023199756A1 (en) * | 2022-04-15 | 2023-10-19 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5742061B2 (en) | 1982-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5459211A (en) | Preparation of carboxylic acid and/or its ester | |
| JPS5441814A (en) | Preparation of acrylate or methacrylate | |
| JPS55143935A (en) | Ester exchange | |
| JPS5436233A (en) | Obtainment of optically active isomers of threo-3-(3, 4-benzyloxy-phenyl)-n- carbobenzyloxy-cerin | |
| JPS5424827A (en) | Preparation of carbonate ester | |
| JPS5334714A (en) | Preparation of dialkylaminoalkyl acrylate and dialkylaminoalkyl methacrylate | |
| JPS5793930A (en) | Preparation of methacrylic ester | |
| JPS5419911A (en) | Preparation of dialkylaminoethyl ester of acrylic acid or methacrylic acid | |
| JPS5742643A (en) | 6,10,14,18-tetramethyl-5,9,13,17-nonadecatetraene-2-ol | |
| JPS53124221A (en) | Preparation of phosphoroamidate having hydroxyalkyl group | |
| JPS5283524A (en) | Novel dicarbonyl compounds | |
| JPS5439042A (en) | Preparation of 2-(4-iso butylphenyl)-propionic acid | |
| JPS5513253A (en) | Cis-3-aralkyl substituted-8-benzoylthio-6,11-dimethyl-2,6- methano-1,2,3,4,5,6-hexahydro-3-benzazocine or its acid addition salt | |
| JPS5469162A (en) | Stabilized urethane polymer | |
| JPS54157519A (en) | Preparation of dimethylformamide | |
| JPS5420285A (en) | Fast breeder | |
| JPS5289603A (en) | Preparation of perfluorovinyl compounds | |
| JPS5399712A (en) | Confirmation system for facsimile information communication | |
| JPS5626845A (en) | Ester of carboxylic acid and insecticidal and acaricidal agent | |
| JPS52153910A (en) | Preparation of dimethylaminoethylmethacrylate | |
| JPS53104095A (en) | Channel box for water-cooled reactor | |
| JPS5665844A (en) | Preparation of ethylidene diacetate | |
| JPS5481249A (en) | Preparation of 1-methyl-adamantane | |
| JPS5331649A (en) | Cholesteric compounds | |
| JPS5438647A (en) | Face lattice concurrently used as eaves |