JPS5441815A - Preparation of acrylate or methacrylate - Google Patents

Preparation of acrylate or methacrylate

Info

Publication number
JPS5441815A
JPS5441815A JP10500077A JP10500077A JPS5441815A JP S5441815 A JPS5441815 A JP S5441815A JP 10500077 A JP10500077 A JP 10500077A JP 10500077 A JP10500077 A JP 10500077A JP S5441815 A JPS5441815 A JP S5441815A
Authority
JP
Japan
Prior art keywords
compound
alcohol
meth
lithium
acrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10500077A
Other languages
Japanese (ja)
Other versions
JPS5742061B2 (en
Inventor
Masaya Kametani
Yasuo Iioi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Nitto Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Chemical Industry Co Ltd filed Critical Nitto Chemical Industry Co Ltd
Priority to JP10500077A priority Critical patent/JPS5441815A/en
Publication of JPS5441815A publication Critical patent/JPS5441815A/en
Publication of JPS5742061B2 publication Critical patent/JPS5742061B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain the titled high quality compound, a starting material for treatments and additives, in high yield through simplified operations by the ester exchange of an alcohol ester of (meth)acrylic acid with an alcohol, using a catalyst of Li or a specific Li compound free from deterioration of the activity.
CONSTITUTION: A lower alcohol ester of (meth)acrylic acid is subjected to the ester exchange with a higher (polyhydric)alcohol using Li, a compound of LiR (R=H, 1-4C clkyl, or phenyl) (e.g. lithium hydride, butyllithium), a compound of LiAl (R')4 (R'=H, 1-4 alkoxy) (e.g. lithiumaluminum hydride), an inorganic acid salt of Li (e.g. lithium halide, lithium carbonate), an organic acid salt of Li (e.g. Li laurate, Li stearate), lithium acetylacetonate, or a Li oxide as a catalyst to afford a higher (polyhydric) alcohol ester of (meth)acrylic acid.
COPYRIGHT: (C)1979,JPO&Japio
JP10500077A 1977-09-02 1977-09-02 Preparation of acrylate or methacrylate Granted JPS5441815A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10500077A JPS5441815A (en) 1977-09-02 1977-09-02 Preparation of acrylate or methacrylate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10500077A JPS5441815A (en) 1977-09-02 1977-09-02 Preparation of acrylate or methacrylate

Publications (2)

Publication Number Publication Date
JPS5441815A true JPS5441815A (en) 1979-04-03
JPS5742061B2 JPS5742061B2 (en) 1982-09-07

Family

ID=14395811

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10500077A Granted JPS5441815A (en) 1977-09-02 1977-09-02 Preparation of acrylate or methacrylate

Country Status (1)

Country Link
JP (1) JPS5441815A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5793930A (en) * 1980-12-03 1982-06-11 Mitsui Toatsu Chem Inc Preparation of methacrylic ester
FR2566394A1 (en) * 1984-06-26 1985-12-27 Roehm Gmbh PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION
JPS6150940A (en) * 1984-06-26 1986-03-13 レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Manufacture of acrylic acid- or methacrylic acid ester from alcohol by esterification
FR2924114A1 (en) * 2007-11-27 2009-05-29 Arkema France PROCESS FOR THE SYNTHESIS OF ALCOXYPOLYALKYLENE GLYCOLS (METH) ACRYLATES BY TRANSESTERIFICATION
WO2023199756A1 (en) * 2022-04-15 2023-10-19 東ソー株式会社 Compound, method for producing same, composition, urethane resin, aqueous urethane resin dispersion, and coating agent

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5225714A (en) * 1975-08-21 1977-02-25 Mitsubishi Rayon Co Ltd Process for preparation of acrylic acid esters or methacrylic acid est ers

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5225714A (en) * 1975-08-21 1977-02-25 Mitsubishi Rayon Co Ltd Process for preparation of acrylic acid esters or methacrylic acid est ers

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5793930A (en) * 1980-12-03 1982-06-11 Mitsui Toatsu Chem Inc Preparation of methacrylic ester
FR2566394A1 (en) * 1984-06-26 1985-12-27 Roehm Gmbh PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION
JPS6150940A (en) * 1984-06-26 1986-03-13 レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Manufacture of acrylic acid- or methacrylic acid ester from alcohol by esterification
JPS6156155A (en) * 1984-06-26 1986-03-20 レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Manufacture of polyhydric alcohol of acrylic acid- and methacrylic acid ester by esterification
FR2924114A1 (en) * 2007-11-27 2009-05-29 Arkema France PROCESS FOR THE SYNTHESIS OF ALCOXYPOLYALKYLENE GLYCOLS (METH) ACRYLATES BY TRANSESTERIFICATION
WO2009071786A1 (en) * 2007-11-27 2009-06-11 Arkema France Method for synthesizing alkoxypolyalkylene glycol (meth)acrylates by transesterification
WO2023199756A1 (en) * 2022-04-15 2023-10-19 東ソー株式会社 Compound, method for producing same, composition, urethane resin, aqueous urethane resin dispersion, and coating agent
JPWO2023199756A1 (en) * 2022-04-15 2023-10-19

Also Published As

Publication number Publication date
JPS5742061B2 (en) 1982-09-07

Similar Documents

Publication Publication Date Title
JPS5459211A (en) Preparation of carboxylic acid and/or its ester
JPS5441814A (en) Preparation of acrylate or methacrylate
JPS55143935A (en) Ester exchange
JPS5436233A (en) Obtainment of optically active isomers of threo-3-(3, 4-benzyloxy-phenyl)-n- carbobenzyloxy-cerin
JPS5424827A (en) Preparation of carbonate ester
JPS5334714A (en) Preparation of dialkylaminoalkyl acrylate and dialkylaminoalkyl methacrylate
JPS5793930A (en) Preparation of methacrylic ester
JPS5419911A (en) Preparation of dialkylaminoethyl ester of acrylic acid or methacrylic acid
JPS5742643A (en) 6,10,14,18-tetramethyl-5,9,13,17-nonadecatetraene-2-ol
JPS53124221A (en) Preparation of phosphoroamidate having hydroxyalkyl group
JPS5283524A (en) Novel dicarbonyl compounds
JPS5439042A (en) Preparation of 2-(4-iso butylphenyl)-propionic acid
JPS5513253A (en) Cis-3-aralkyl substituted-8-benzoylthio-6,11-dimethyl-2,6- methano-1,2,3,4,5,6-hexahydro-3-benzazocine or its acid addition salt
JPS5469162A (en) Stabilized urethane polymer
JPS54157519A (en) Preparation of dimethylformamide
JPS5420285A (en) Fast breeder
JPS5289603A (en) Preparation of perfluorovinyl compounds
JPS5399712A (en) Confirmation system for facsimile information communication
JPS5626845A (en) Ester of carboxylic acid and insecticidal and acaricidal agent
JPS52153910A (en) Preparation of dimethylaminoethylmethacrylate
JPS53104095A (en) Channel box for water-cooled reactor
JPS5665844A (en) Preparation of ethylidene diacetate
JPS5481249A (en) Preparation of 1-methyl-adamantane
JPS5331649A (en) Cholesteric compounds
JPS5438647A (en) Face lattice concurrently used as eaves