JPS5441987A - Curing of vinyl ester resin - Google Patents
Curing of vinyl ester resinInfo
- Publication number
- JPS5441987A JPS5441987A JP10847677A JP10847677A JPS5441987A JP S5441987 A JPS5441987 A JP S5441987A JP 10847677 A JP10847677 A JP 10847677A JP 10847677 A JP10847677 A JP 10847677A JP S5441987 A JPS5441987 A JP S5441987A
- Authority
- JP
- Japan
- Prior art keywords
- curing
- vinyl ester
- ester resin
- mekpo
- cured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005989 resin Polymers 0.000 title abstract 3
- 239000011347 resin Substances 0.000 title abstract 3
- 229920001567 vinyl ester resin Polymers 0.000 title abstract 3
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 abstract 3
- -1 alkyl peroxy ester Chemical class 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005187 foaming Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Polymerization Catalysts (AREA)
Abstract
PURPOSE: To prepare a cured vinyl ester resin useful for the lining of storage tanks, free from foaming and having high curing degree even by the curing at a low temperature in a short time, by using a specific peroxide curing agent and curing accelerator.
CONSTITUTION: (A) Purified methyl ethyl ketone peroxide (MEKPO) is prepared by treating MEKPO with ammonium sulfate, etc., thereby eliminating hydrogen peroxide therefrom. A vinyl ester resin is cured at 0W40°C in the presence of catalysts comprising (A) and (B) a tertiary alkyl peroxy ester (e.g. tert-butyl peroxy neodecanoate, etc.) and curing accelerators comprising (C) an acetoacetic ester (e.g. methyl acetoacetate, etc.) and (D) a metal soap (e.g. cobalt naphthenate, etc.)
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10847677A JPS5441987A (en) | 1977-09-09 | 1977-09-09 | Curing of vinyl ester resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10847677A JPS5441987A (en) | 1977-09-09 | 1977-09-09 | Curing of vinyl ester resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5441987A true JPS5441987A (en) | 1979-04-03 |
| JPS5742085B2 JPS5742085B2 (en) | 1982-09-07 |
Family
ID=14485714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10847677A Granted JPS5441987A (en) | 1977-09-09 | 1977-09-09 | Curing of vinyl ester resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5441987A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62179518A (en) * | 1986-02-03 | 1987-08-06 | Kayaku Nuurii Kk | Curing of vinyl ester resin and curing agent therefore |
| JPS62159951U (en) * | 1986-03-29 | 1987-10-12 | ||
| US4719961A (en) * | 1985-08-09 | 1988-01-19 | Sms Schloemann-Siemag Aktiengesellschaft | Vertical or bow-type continuous casting machine for steel |
| US6329475B1 (en) | 1992-08-12 | 2001-12-11 | The Dow Chemical Company | Curable epoxy vinylester composition having a low peak exotherm during cure |
| WO2010146912A1 (en) | 2009-06-18 | 2010-12-23 | Dic株式会社 | Air-drying polyester (meth)acrylate resin composition, structure and method for providing same |
| JP2018158971A (en) * | 2017-03-22 | 2018-10-11 | 日油株式会社 | Curing agent composition, resin composition, and resin cured product |
-
1977
- 1977-09-09 JP JP10847677A patent/JPS5441987A/en active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4719961A (en) * | 1985-08-09 | 1988-01-19 | Sms Schloemann-Siemag Aktiengesellschaft | Vertical or bow-type continuous casting machine for steel |
| JPS62179518A (en) * | 1986-02-03 | 1987-08-06 | Kayaku Nuurii Kk | Curing of vinyl ester resin and curing agent therefore |
| JPS62159951U (en) * | 1986-03-29 | 1987-10-12 | ||
| US6329475B1 (en) | 1992-08-12 | 2001-12-11 | The Dow Chemical Company | Curable epoxy vinylester composition having a low peak exotherm during cure |
| WO2010146912A1 (en) | 2009-06-18 | 2010-12-23 | Dic株式会社 | Air-drying polyester (meth)acrylate resin composition, structure and method for providing same |
| JP2018158971A (en) * | 2017-03-22 | 2018-10-11 | 日油株式会社 | Curing agent composition, resin composition, and resin cured product |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5742085B2 (en) | 1982-09-07 |
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