JPS5444668A - Novel pyrrole derivative - Google Patents
Novel pyrrole derivativeInfo
- Publication number
- JPS5444668A JPS5444668A JP10920977A JP10920977A JPS5444668A JP S5444668 A JPS5444668 A JP S5444668A JP 10920977 A JP10920977 A JP 10920977A JP 10920977 A JP10920977 A JP 10920977A JP S5444668 A JPS5444668 A JP S5444668A
- Authority
- JP
- Japan
- Prior art keywords
- pyrrole derivative
- pyrrole
- formulai
- hydrocarbyl
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000003233 pyrroles Chemical class 0.000 title abstract 5
- -1 alkocarbonyl Chemical group 0.000 abstract 2
- 125000000623 heterocyclic group Chemical group 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007868 Raney catalyst Substances 0.000 abstract 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 abstract 1
- 229910000564 Raney nickel Inorganic materials 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
Landscapes
- Pyrrole Compounds (AREA)
Abstract
NEW MATERIAL:Pyrrole derivatives of formulaI(R1, R2 are hydrocarbyl or heterocyclic residue that may be substituted; R4 is aryl, alkocarbonyl, cyano).
EXAMPLE: 2,3-Di-t-butylthio-5-phenylpyrrole.
USE: Starting material for synthesizing agricultural chemicals, medicines, and various kinds of chemicals, especially intermediate for known pyrrole derivatives.
PREPARATION: Tricyclopropenium salt of formula II (R3 is hydrocarbyl or heterocyclic residue that may be substituted; X⊖ is anion) is reacted with a primary amine of formula III to form the objective pyrrole derivative of formulaI. When the resulting compound is treated with hydrogen in the presence of a metal catalyst such as Raney nickel, -SR1 and -SR2 are eliminated to afford a inown pyrrole derivative.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10920977A JPS5444668A (en) | 1977-09-10 | 1977-09-10 | Novel pyrrole derivative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10920977A JPS5444668A (en) | 1977-09-10 | 1977-09-10 | Novel pyrrole derivative |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5444668A true JPS5444668A (en) | 1979-04-09 |
| JPS5439379B2 JPS5439379B2 (en) | 1979-11-27 |
Family
ID=14504354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10920977A Granted JPS5444668A (en) | 1977-09-10 | 1977-09-10 | Novel pyrrole derivative |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5444668A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0708090A1 (en) | 1994-10-07 | 1996-04-24 | Rhone-Poulenc Agrochimie | Intermediates useful for the synthesis of pesticides |
-
1977
- 1977-09-10 JP JP10920977A patent/JPS5444668A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0708090A1 (en) | 1994-10-07 | 1996-04-24 | Rhone-Poulenc Agrochimie | Intermediates useful for the synthesis of pesticides |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5439379B2 (en) | 1979-11-27 |
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