JPS5452014A - Isomerization of dichlorobutene - Google Patents

Isomerization of dichlorobutene

Info

Publication number
JPS5452014A
JPS5452014A JP11688077A JP11688077A JPS5452014A JP S5452014 A JPS5452014 A JP S5452014A JP 11688077 A JP11688077 A JP 11688077A JP 11688077 A JP11688077 A JP 11688077A JP S5452014 A JPS5452014 A JP S5452014A
Authority
JP
Japan
Prior art keywords
dichlorobutene
copper
catalyst
isomerization
chlorophenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11688077A
Other languages
Japanese (ja)
Other versions
JPS5546372B2 (en
Inventor
Azuma Ito
Seiichi Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denka Co Ltd
Original Assignee
Denki Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denki Kagaku Kogyo KK filed Critical Denki Kagaku Kogyo KK
Priority to JP11688077A priority Critical patent/JPS5452014A/en
Priority to GB7838010A priority patent/GB2004880B/en
Priority to IT28260/78A priority patent/IT1099667B/en
Priority to DE2842610A priority patent/DE2842610C3/en
Priority to FR7827975A priority patent/FR2404613A1/en
Publication of JPS5452014A publication Critical patent/JPS5452014A/en
Priority to US06/063,257 priority patent/US4237074A/en
Priority to US06/120,826 priority patent/US4461920A/en
Publication of JPS5546372B2 publication Critical patent/JPS5546372B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To isomerize dichlorobutene in high yield with preventing obstruction of an apparatus by suppressing the formation of tarry high-boiling by-products, by using a highly active caralyst comprising a copper compound and piperidine hydrochloride, glycine ethyl ester hydrochloride or 2-amino-4-chlorophenol.
CONSTITUTION: Isomerization between 3, 4-dichlorobutene-1 and 1, 4-dichlorobutene -2 is carried out at a relatively low temperature of 80-120°C, preferably 85-95°C, using as an isomerization catalyst, a copper compound, e.g. suprous chloride, copper naphthenate, copper acetate, etc., and piperidine hydrochloride, glycine ethyl ester hydrochloride or Z-amino-4-chlorophenol. Concentration of the catalyst is 0.05-2, especially 0.1-1, wt.% of a copper compound and 0.05-4, especially 0.15- 2, wt.% of the other compound based on dichlorobutene.
EFFECT: Said catalyst is highly active even in low concentration and is not corrosive to the apparatus
COPYRIGHT: (C)1979,JPO&Japio
JP11688077A 1977-09-30 1977-09-30 Isomerization of dichlorobutene Granted JPS5452014A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP11688077A JPS5452014A (en) 1977-09-30 1977-09-30 Isomerization of dichlorobutene
GB7838010A GB2004880B (en) 1977-09-30 1978-09-25 Isomerization of dichlorobutenes
IT28260/78A IT1099667B (en) 1977-09-30 1978-09-29 ISOMERIZATION OF DICHLOROBUTENI
DE2842610A DE2842610C3 (en) 1977-09-30 1978-09-29 Process for isomerization between 3,4-dichlorobutene - (1) and 1,4-dichlorobutene - (2)
FR7827975A FR2404613A1 (en) 1977-09-30 1978-09-29 PROCESS FOR ISOMERIZING DICHLOROBUTENES IN THE PRESENCE OF A CATALYST BASED ON A COPPER COMPOUND
US06/063,257 US4237074A (en) 1977-09-30 1979-08-02 Isomerization of dichlorobutenes
US06/120,826 US4461920A (en) 1977-09-30 1980-02-12 Isomerization of dichlorobutenes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11688077A JPS5452014A (en) 1977-09-30 1977-09-30 Isomerization of dichlorobutene

Publications (2)

Publication Number Publication Date
JPS5452014A true JPS5452014A (en) 1979-04-24
JPS5546372B2 JPS5546372B2 (en) 1980-11-22

Family

ID=14697914

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11688077A Granted JPS5452014A (en) 1977-09-30 1977-09-30 Isomerization of dichlorobutene

Country Status (1)

Country Link
JP (1) JPS5452014A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6041625A (en) * 1983-07-20 1985-03-05 ユニオン・キヤンプ・コ−ポレイシヨン Arylhalide isomerization by organic amine
WO2020054568A1 (en) * 2018-09-10 2020-03-19 昭和電工株式会社 Method for producing 3,4-dichloro-1-butene

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6041625A (en) * 1983-07-20 1985-03-05 ユニオン・キヤンプ・コ−ポレイシヨン Arylhalide isomerization by organic amine
WO2020054568A1 (en) * 2018-09-10 2020-03-19 昭和電工株式会社 Method for producing 3,4-dichloro-1-butene
JPWO2020054568A1 (en) * 2018-09-10 2021-08-30 昭和電工株式会社 Method for producing 3,4-dichloro-1-butene

Also Published As

Publication number Publication date
JPS5546372B2 (en) 1980-11-22

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