JPS5479210A - Preparation of polyhydric alcohols - Google Patents

Preparation of polyhydric alcohols

Info

Publication number
JPS5479210A
JPS5479210A JP14542177A JP14542177A JPS5479210A JP S5479210 A JPS5479210 A JP S5479210A JP 14542177 A JP14542177 A JP 14542177A JP 14542177 A JP14542177 A JP 14542177A JP S5479210 A JPS5479210 A JP S5479210A
Authority
JP
Japan
Prior art keywords
preparation
residol
dioxane
isobutene
dimethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP14542177A
Other languages
Japanese (ja)
Other versions
JPS6137269B2 (en
Inventor
Sunao Kyo
Kenichi Hino
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Priority to JP14542177A priority Critical patent/JPS5479210A/en
Publication of JPS5479210A publication Critical patent/JPS5479210A/en
Publication of JPS6137269B2 publication Critical patent/JPS6137269B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain a polyhydric alcohol without removing formaldehyde by distillation in high yield, by heating a high b.p. compound, formed as a by-product in the preparation of 4,4-dimethyl-1,3-dioxane, with a tertiary butanol.
CONSTITUTION: A compound (Residol) having a higher b.p. than dioxane, which is formed as a by-product in the preparation of 4,4-dimethyl-1,3-dioxane from isobutene and formaldehyde, is heated at 120-180°C with a tertiary butanol and/or isobutene in the presence of boric acid or a boron compound containing oxygen to give 3-methylbutane-1,3-diol together with triols of formulas I and II. The reaction scheme is shown for a component of the Residol. Water added is less than the equivalent amount of the water needed for the hydrolysis of the Residol. USE;E.g. strarting meterial for the preparation or an additive of polymers, plasticizer, wetting agent, etc.
COPYRIGHT: (C)1979,JPO&Japio
JP14542177A 1977-12-02 1977-12-02 Preparation of polyhydric alcohols Granted JPS5479210A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14542177A JPS5479210A (en) 1977-12-02 1977-12-02 Preparation of polyhydric alcohols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14542177A JPS5479210A (en) 1977-12-02 1977-12-02 Preparation of polyhydric alcohols

Publications (2)

Publication Number Publication Date
JPS5479210A true JPS5479210A (en) 1979-06-25
JPS6137269B2 JPS6137269B2 (en) 1986-08-22

Family

ID=15384852

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14542177A Granted JPS5479210A (en) 1977-12-02 1977-12-02 Preparation of polyhydric alcohols

Country Status (1)

Country Link
JP (1) JPS5479210A (en)

Also Published As

Publication number Publication date
JPS6137269B2 (en) 1986-08-22

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