JPS5486594A - Preparation of unsaturated polyester resin - Google Patents
Preparation of unsaturated polyester resinInfo
- Publication number
- JPS5486594A JPS5486594A JP15432977A JP15432977A JPS5486594A JP S5486594 A JPS5486594 A JP S5486594A JP 15432977 A JP15432977 A JP 15432977A JP 15432977 A JP15432977 A JP 15432977A JP S5486594 A JPS5486594 A JP S5486594A
- Authority
- JP
- Japan
- Prior art keywords
- mole
- give
- mixture
- inert gas
- reaction product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006337 unsaturated polyester resin Polymers 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract 4
- 239000007795 chemical reaction product Substances 0.000 abstract 3
- 239000011261 inert gas Substances 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 238000006482 condensation reaction Methods 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
PURPOSE: To prepare an almost colorless unsaturated polyester resin having excellent curing characteristics, in a short time, by reacting an unsaturated dicarboxylic acid anhydride with a dihydric alcohol under specific conditions, and subjecting the reaction product to a special reaction and dehydrative condensation reaction.
CONSTITUTION: 1 mole of a dicarboxylic acid anhydride component containing ≥ 20 mole % of an α,β-unsaturated dicarboxylic acid anhydride is reacted with 0.25 W 0.4 mole of a dihydric alcohol at 90 W 150°C in an inert gas to give a reaction product mixture (A) containing 0.33 W 0.65 equivalent/100 g of carboxyl group. The mixture (A) is reacted with an alkylene oxide at 110 W 190°C in an inert gas to give a reaction product mixture (B) having an acid value of 70 W 160, the difference between the cid value and the hydroxyl value of ≤ 30, and a molecular weight of 400 W 800. Dehydrative condensation of the mixture (B) is carried out at 180 W 240°C in an inert gas to give the desired resin having an acid value of 15 W 60.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15432977A JPS6019771B2 (en) | 1977-12-23 | 1977-12-23 | Method for producing unsaturated polyester resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15432977A JPS6019771B2 (en) | 1977-12-23 | 1977-12-23 | Method for producing unsaturated polyester resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5486594A true JPS5486594A (en) | 1979-07-10 |
| JPS6019771B2 JPS6019771B2 (en) | 1985-05-17 |
Family
ID=15581756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15432977A Expired JPS6019771B2 (en) | 1977-12-23 | 1977-12-23 | Method for producing unsaturated polyester resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6019771B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001002461A3 (en) * | 1999-07-02 | 2001-03-29 | Buna Sow Leuna Olefinverb Gmbh | Method for producing polyethylene terephthahlate modified with o-phthalic acid units |
-
1977
- 1977-12-23 JP JP15432977A patent/JPS6019771B2/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001002461A3 (en) * | 1999-07-02 | 2001-03-29 | Buna Sow Leuna Olefinverb Gmbh | Method for producing polyethylene terephthahlate modified with o-phthalic acid units |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6019771B2 (en) | 1985-05-17 |
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