JPS5524152A - Recovery of high purity adipic acid - Google Patents
Recovery of high purity adipic acidInfo
- Publication number
- JPS5524152A JPS5524152A JP9773878A JP9773878A JPS5524152A JP S5524152 A JPS5524152 A JP S5524152A JP 9773878 A JP9773878 A JP 9773878A JP 9773878 A JP9773878 A JP 9773878A JP S5524152 A JPS5524152 A JP S5524152A
- Authority
- JP
- Japan
- Prior art keywords
- adipic acid
- washing
- waste water
- high purity
- crude
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare high purity adipic acid useful for the synthesis of plasticizers, nylons, etc., economically, by washing crude adipic acid obtained from acidic waste water produced by the liquid phase oxidation of cyclohexane, with said waste water, and purifying the adipic acid by nitric acid oxidation, etc.
CONSTITUTION: An acidic waste water (containing 5W20% of adipic acid) produced from the process for the production of cyclohexanone and cyclohexanol by the liquid-phase oxidation of cyclohexane, is concentrated, cooled and crystallized to obtain crude adipic acid, which is washed with said waste water at 0W70°C to remove the impurities such as condensates having high condensation degree. High purity adipic acid is obtained from the crude acid by oxidizing with nitric acid, washing with water, treating with activated charcoal and recrystallizing. The washing is pref. carried out using a multi-stage washing column to enable the reuse of the washing liquid. The used washing liquid is recycled to the crude adipic acid recovering step.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9773878A JPS5524152A (en) | 1978-08-09 | 1978-08-09 | Recovery of high purity adipic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9773878A JPS5524152A (en) | 1978-08-09 | 1978-08-09 | Recovery of high purity adipic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5524152A true JPS5524152A (en) | 1980-02-21 |
Family
ID=14200228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9773878A Pending JPS5524152A (en) | 1978-08-09 | 1978-08-09 | Recovery of high purity adipic acid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5524152A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1313431C (en) * | 2004-11-26 | 2007-05-02 | 天津大学 | Method of preparing metal ion less adipic acid by nitric acid oxidation of cyclohexane oxidation liquid pickling water |
-
1978
- 1978-08-09 JP JP9773878A patent/JPS5524152A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1313431C (en) * | 2004-11-26 | 2007-05-02 | 天津大学 | Method of preparing metal ion less adipic acid by nitric acid oxidation of cyclohexane oxidation liquid pickling water |
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