JPS5531428A - Production of copper-aluminum oxide catalyst for hydrogenation - Google Patents
Production of copper-aluminum oxide catalyst for hydrogenationInfo
- Publication number
- JPS5531428A JPS5531428A JP10384878A JP10384878A JPS5531428A JP S5531428 A JPS5531428 A JP S5531428A JP 10384878 A JP10384878 A JP 10384878A JP 10384878 A JP10384878 A JP 10384878A JP S5531428 A JPS5531428 A JP S5531428A
- Authority
- JP
- Japan
- Prior art keywords
- copper
- ammonium
- buffer agent
- salt solution
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- UNRNJMFGIMDYKL-UHFFFAOYSA-N aluminum copper oxygen(2-) Chemical compound [O-2].[Al+3].[Cu+2] UNRNJMFGIMDYKL-UHFFFAOYSA-N 0.000 title abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 230000002378 acidificating effect Effects 0.000 abstract 3
- 150000001879 copper Chemical class 0.000 abstract 3
- 239000012266 salt solution Substances 0.000 abstract 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 abstract 2
- 239000001099 ammonium carbonate Substances 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- 229910001388 sodium aluminate Inorganic materials 0.000 abstract 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 abstract 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 abstract 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 abstract 1
- 235000012501 ammonium carbonate Nutrition 0.000 abstract 1
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- NGPGDYLVALNKEG-UHFFFAOYSA-N azanium;azane;2,3,4-trihydroxy-4-oxobutanoate Chemical compound [NH4+].[NH4+].[O-]C(=O)C(O)C(O)C([O-])=O NGPGDYLVALNKEG-UHFFFAOYSA-N 0.000 abstract 1
- 229910001431 copper ion Inorganic materials 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Landscapes
- Fats And Perfumes (AREA)
- Furan Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To produce copper-aluminum oxides catalysts exhibiting an excellent activity by reacting an aqueous solution of sodium aluminate containing sodium hydroxide with an acidic copper salt solution in the presence of a buffer agent.
CONSTITUTION: An ammonium salt, as a buffer agent, capable of forming ammine complex ion with copper ion, preferably ammonium carbonate, ammonium bicarbonate, ammonium nitrate, ammonium tartrate or ammonium oxalate, is added to an aqueous solution of sodium aluminate containing sodium hydroxide. The resulting solution is mixed with an acidic copper salt solution to deposit oxides of copper and aluminum. The deposits are washed and calcined to produce a catalyst. The buffer agent is used preferably in an amount of from 0.05 to 1 mole of the buffer agent per atom of copper. If a nitrate or a sulfate of an alkali metal or an alkaline earth metal is previously dissolved in the acidic copper salt solution, the enhancement of the catalyst activity will be promoted advantageously.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10384878A JPS5531428A (en) | 1978-08-28 | 1978-08-28 | Production of copper-aluminum oxide catalyst for hydrogenation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10384878A JPS5531428A (en) | 1978-08-28 | 1978-08-28 | Production of copper-aluminum oxide catalyst for hydrogenation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5531428A true JPS5531428A (en) | 1980-03-05 |
| JPS5541815B2 JPS5541815B2 (en) | 1980-10-27 |
Family
ID=14364852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10384878A Granted JPS5531428A (en) | 1978-08-28 | 1978-08-28 | Production of copper-aluminum oxide catalyst for hydrogenation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5531428A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5008235A (en) * | 1989-12-21 | 1991-04-16 | Union Carbide Chemicals And Plastics Technology Corporation | Catalysts of Cu-Al-third metal for hydrogenation |
| US5053380A (en) * | 1989-12-21 | 1991-10-01 | Union Carbide Chemicals And Plastics Technology Corporation | Cu-al catalyst for hydrogenation |
| US5142067A (en) * | 1989-12-21 | 1992-08-25 | Union Carbide Chemicals & Plastics Technology Corporation | Hydrogenation with Cu-Al-X catalysts |
| US5191091A (en) * | 1989-12-21 | 1993-03-02 | Union Carbide Chemicals & Plastics Technology Corporation | Hydrogenation with Cu-Al catalysts |
| US5763353A (en) * | 1996-02-15 | 1998-06-09 | Kao Corporation | Hydrogenation catalyst precursor, hydrogenation catalyst and production process for alcohols |
| JP2018513783A (en) * | 2015-03-26 | 2018-05-31 | ビーエーエスエフ コーポレーション | Hydrocracking catalyst with high acid resistance |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60247255A (en) * | 1984-05-22 | 1985-12-06 | Sanyo Electric Co Ltd | Electrophotographic copying machine |
-
1978
- 1978-08-28 JP JP10384878A patent/JPS5531428A/en active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5008235A (en) * | 1989-12-21 | 1991-04-16 | Union Carbide Chemicals And Plastics Technology Corporation | Catalysts of Cu-Al-third metal for hydrogenation |
| US5053380A (en) * | 1989-12-21 | 1991-10-01 | Union Carbide Chemicals And Plastics Technology Corporation | Cu-al catalyst for hydrogenation |
| US5142067A (en) * | 1989-12-21 | 1992-08-25 | Union Carbide Chemicals & Plastics Technology Corporation | Hydrogenation with Cu-Al-X catalysts |
| US5191091A (en) * | 1989-12-21 | 1993-03-02 | Union Carbide Chemicals & Plastics Technology Corporation | Hydrogenation with Cu-Al catalysts |
| US5298472A (en) * | 1989-12-21 | 1994-03-29 | Union Carbide Chemicals & Plastics Technology Corporation | Hydrogenation with Cu-Al catalysts |
| US5763353A (en) * | 1996-02-15 | 1998-06-09 | Kao Corporation | Hydrogenation catalyst precursor, hydrogenation catalyst and production process for alcohols |
| JP2018513783A (en) * | 2015-03-26 | 2018-05-31 | ビーエーエスエフ コーポレーション | Hydrocracking catalyst with high acid resistance |
| US11077428B2 (en) | 2015-03-26 | 2021-08-03 | Basf Corporation | Hydrogenolysis catalysts with high acid tolerance |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5541815B2 (en) | 1980-10-27 |
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