JPS5533423A - Production of carboxylic derivative - Google Patents
Production of carboxylic derivativeInfo
- Publication number
- JPS5533423A JPS5533423A JP10599778A JP10599778A JPS5533423A JP S5533423 A JPS5533423 A JP S5533423A JP 10599778 A JP10599778 A JP 10599778A JP 10599778 A JP10599778 A JP 10599778A JP S5533423 A JPS5533423 A JP S5533423A
- Authority
- JP
- Japan
- Prior art keywords
- imidazolidinone
- alkyl
- compound
- alkali
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Pyridine Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE:In the oxidation of an aromatic or heterocyclic methyl compound in the presence of an alkali catalyst to the corresponding carboxylic acid, an alkyl-2-imidazolidinone is used as the solvent, thus producing the objective compound in high yield. CONSTITUTION:In the oxidation of a compound of formula I (ring A is pyridine or benzene or naphthalene ring) under oxygen atmosphere in the presence of an alkali catalyst to a compound of formula II (X is H, alkali metal atom), an alkyl- 2-imidazolidinone of formula III (R1, R2 are 1-3C alkyl; R3 is H, methyl) as 1, 3- dimethyl-2-imidazolidinone is used as the solvent. The alkali catalyst is, e.g., 1-10 molar equivalents, based the starting material, of sodium methoxide and the reaction temperature is 0-220 deg.C. EFFECT:The alkyl-2-imidazolidinone is so stable against alkali that it can be reacily recovered after the reaction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10599778A JPS6052743B2 (en) | 1978-08-30 | 1978-08-30 | Method for producing carboxylic acid derivatives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10599778A JPS6052743B2 (en) | 1978-08-30 | 1978-08-30 | Method for producing carboxylic acid derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5533423A true JPS5533423A (en) | 1980-03-08 |
| JPS6052743B2 JPS6052743B2 (en) | 1985-11-21 |
Family
ID=14422342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10599778A Expired JPS6052743B2 (en) | 1978-08-30 | 1978-08-30 | Method for producing carboxylic acid derivatives |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6052743B2 (en) |
-
1978
- 1978-08-30 JP JP10599778A patent/JPS6052743B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6052743B2 (en) | 1985-11-21 |
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