JPS5548204A - Resinous water-absorbing and -retentive agent - Google Patents
Resinous water-absorbing and -retentive agentInfo
- Publication number
- JPS5548204A JPS5548204A JP11969179A JP11969179A JPS5548204A JP S5548204 A JPS5548204 A JP S5548204A JP 11969179 A JP11969179 A JP 11969179A JP 11969179 A JP11969179 A JP 11969179A JP S5548204 A JPS5548204 A JP S5548204A
- Authority
- JP
- Japan
- Prior art keywords
- water
- hydrolyzed
- cellulose
- crosslinking agent
- starch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- 229920002472 Starch Polymers 0.000 abstract 2
- 229920002678 cellulose Polymers 0.000 abstract 2
- 239000001913 cellulose Substances 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 230000005855 radiation Effects 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000008107 starch Substances 0.000 abstract 2
- 235000019698 starch Nutrition 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- GCGQYJSQINRKQL-UHFFFAOYSA-N n-hexylprop-2-enamide Chemical compound CCCCCCNC(=O)C=C GCGQYJSQINRKQL-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Biological Depolymerization Polymers (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Graft Or Block Polymers (AREA)
Abstract
PURPOSE: To prepare a water-insoluble resin having high water absorption and biodegradability, by polymerizing starch or cellulose, a specific monomer and a small amount of a crosslinking agent, and thereafter hydrolyzing the polymer.
CONSTITUTION: (A) Starch and/or cellulose, (B) a monomer having an polymerizable double bond and soluble in water when hydrolyzed (e.g. methyl acrylate, acrylonitrile, N-hexylacryl-amide, etc.), and (C) a crosslinking agent (e.g. di- or triacrylic ester) are polymerized by radiation, electron radiation or a ceric salt and hydrogen peroxide, and hydrolyzed. The preferable weight ratio (A):(B):(C) are 100:10W1000:0.0001W10, respectively.
EFFECT: The resin is storable for long period, comparably inexpensive and easily disposed, and therefore useful as paper diapers, sanitary napkins, etc.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54119691A JPS5910725B2 (en) | 1979-09-17 | 1979-09-17 | Resin water absorption and water retention agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54119691A JPS5910725B2 (en) | 1979-09-17 | 1979-09-17 | Resin water absorption and water retention agent |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50037669A Division JPS51125468A (en) | 1975-03-27 | 1975-03-27 | Method of preparing resins of high water absorbency |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5548204A true JPS5548204A (en) | 1980-04-05 |
| JPS5910725B2 JPS5910725B2 (en) | 1984-03-10 |
Family
ID=14767664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54119691A Expired JPS5910725B2 (en) | 1979-09-17 | 1979-09-17 | Resin water absorption and water retention agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5910725B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61126101A (en) * | 1984-11-22 | 1986-06-13 | Yasuhiko Onishi | Starch derivative and its copolymer |
| KR100400943B1 (en) * | 2000-10-23 | 2003-10-08 | 재단법인서울대학교산학협력재단 | Starch-based Superabsorbent with Good Biodegradability and Method of Preparing the Same |
| JP2007112827A (en) * | 2005-10-18 | 2007-05-10 | Japan Atomic Energy Agency | Method for recovering biodegradable polymer after loss of biodegradability |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60244826A (en) * | 1984-05-21 | 1985-12-04 | Matsushita Electric Ind Co Ltd | temperature sensor |
| JPH03109031U (en) * | 1990-02-13 | 1991-11-08 |
-
1979
- 1979-09-17 JP JP54119691A patent/JPS5910725B2/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61126101A (en) * | 1984-11-22 | 1986-06-13 | Yasuhiko Onishi | Starch derivative and its copolymer |
| KR100400943B1 (en) * | 2000-10-23 | 2003-10-08 | 재단법인서울대학교산학협력재단 | Starch-based Superabsorbent with Good Biodegradability and Method of Preparing the Same |
| JP2007112827A (en) * | 2005-10-18 | 2007-05-10 | Japan Atomic Energy Agency | Method for recovering biodegradable polymer after loss of biodegradability |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5910725B2 (en) | 1984-03-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4124748A (en) | Cross-linked saponified absorbent polymer | |
| JP3940103B2 (en) | Water absorbent resin composition | |
| CA1331691C (en) | Sugar-containing water-absorbing composition which facilitates fiber formation | |
| GB1589975A (en) | Water absorbent polymers | |
| JPS5773007A (en) | Preparation of water-absorbig resin | |
| KR890008243A (en) | Polymer composition having high water absorption and manufacturing process thereof | |
| CA2095077A1 (en) | Freeze-dried pad | |
| JPS5554301A (en) | Preparation of aqueous dispersion of synthetic resin solubilized with cellulose acetate alkylate | |
| JPS5614504A (en) | New water-soluble copolymer, production thereof and paper-strengthening agent consisting mainly of same | |
| JPS60149609A (en) | Production of water-absorptive composite material | |
| JPS57202364A (en) | Adhesive | |
| JPS5259690A (en) | Preparation of water absorbing resin | |
| JPS5579303A (en) | Stable aqueous suspension control agent | |
| JPS5227455A (en) | Process for preparing a high polymer material having water absorption properties | |
| WO1990008806A1 (en) | Superabsorbing copolymers of vinyl alcohol | |
| JPS5437188A (en) | Preparation of water-absorbing resin | |
| ATE194147T1 (en) | AQUEOUS POLYMERIZATION PROCESS | |
| JPS53130789A (en) | Preparation of water absorbing resin | |
| JPS5516053A (en) | Resin usable for processing e.g. paper conversion | |
| JPS5225886A (en) | Process for preparing water absorbing resins | |
| JPS5765328A (en) | Water absorbing composition having shape imparting property | |
| JPS53118489A (en) | Production of vinyl ester polymer | |
| JPS53130788A (en) | Preparation of water absorbing resin | |
| JPS56136808A (en) | Water absorbing resin | |
| JPS545096A (en) | Method of immobilizing enzyme or mold using betain polymer |