JPS555950A - Preparation of methacrylic resin molding material - Google Patents
Preparation of methacrylic resin molding materialInfo
- Publication number
- JPS555950A JPS555950A JP7824078A JP7824078A JPS555950A JP S555950 A JPS555950 A JP S555950A JP 7824078 A JP7824078 A JP 7824078A JP 7824078 A JP7824078 A JP 7824078A JP S555950 A JPS555950 A JP S555950A
- Authority
- JP
- Japan
- Prior art keywords
- tert
- molding material
- resin molding
- methacrylic resin
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000113 methacrylic resin Substances 0.000 title abstract 2
- 239000012778 molding material Substances 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title 1
- -1 tert-butyl peroxy ester Chemical class 0.000 abstract 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000012986 chain transfer agent Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 abstract 1
- 238000005979 thermal decomposition reaction Methods 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Landscapes
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
PURPOSE: To obtain a colorless transparent methacrylic resin molding material having improved resistance to thermal decomposition, by reacting methyl methacrylate with a tert-butyl peroxy ester and a straight chain alkyl mercaptan.
CONSTITUTION: Methyl methacrylate (M) or a mixture comprising 50 wt.% or more of M and a vinyl compound copolymerizable with M is reacted with 0.01W 2 wt.% based on the monomer of a tert-butyl peroxy ester, e.g. tert-butyl peroxyisobutyrate or tert-butyl peroxypivalate as a polymerization initiator, and 0.02W 3 wt.% based on the monomer of a straight chain alkyl mercaptan as a chain transfer agent at 60W120°C.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7824078A JPS555950A (en) | 1978-06-28 | 1978-06-28 | Preparation of methacrylic resin molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7824078A JPS555950A (en) | 1978-06-28 | 1978-06-28 | Preparation of methacrylic resin molding material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS555950A true JPS555950A (en) | 1980-01-17 |
| JPS5751849B2 JPS5751849B2 (en) | 1982-11-04 |
Family
ID=13656496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7824078A Granted JPS555950A (en) | 1978-06-28 | 1978-06-28 | Preparation of methacrylic resin molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS555950A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57153008A (en) * | 1981-03-19 | 1982-09-21 | Asahi Chem Ind Co Ltd | Methacrylic resin having excellent heat resistance |
| JPS62223256A (en) * | 1986-03-26 | 1987-10-01 | Denki Kagaku Kogyo Kk | High-gloss, weather-resistant resin composition |
| JPH04216806A (en) * | 1990-12-18 | 1992-08-06 | Kuraray Co Ltd | Production of methacrylic resin molding material |
| EP0610929A1 (en) * | 1993-02-10 | 1994-08-17 | Unitika Ltd. | Film forming solution, porous film obtained therefrom and coated material with the porous film |
| US7105602B1 (en) | 1999-04-23 | 2006-09-12 | Kaneka Corporation | Processing aid for thermoplastic resin and thermoplastic resin composition containing the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5030986A (en) * | 1973-07-18 | 1975-03-27 | ||
| JPS5034071A (en) * | 1973-07-27 | 1975-04-02 | ||
| JPS51109094A (en) * | 1975-03-20 | 1976-09-27 | Nitto Electric Ind Co | HIDOROKISHIARUKIRUAKURIREETO MATAHA METAKURIREETOOSUCHIRENKOORIGOMAANO SEIZOHOHO |
-
1978
- 1978-06-28 JP JP7824078A patent/JPS555950A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5030986A (en) * | 1973-07-18 | 1975-03-27 | ||
| JPS5034071A (en) * | 1973-07-27 | 1975-04-02 | ||
| JPS51109094A (en) * | 1975-03-20 | 1976-09-27 | Nitto Electric Ind Co | HIDOROKISHIARUKIRUAKURIREETO MATAHA METAKURIREETOOSUCHIRENKOORIGOMAANO SEIZOHOHO |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57153008A (en) * | 1981-03-19 | 1982-09-21 | Asahi Chem Ind Co Ltd | Methacrylic resin having excellent heat resistance |
| JPS62223256A (en) * | 1986-03-26 | 1987-10-01 | Denki Kagaku Kogyo Kk | High-gloss, weather-resistant resin composition |
| JPH04216806A (en) * | 1990-12-18 | 1992-08-06 | Kuraray Co Ltd | Production of methacrylic resin molding material |
| EP0610929A1 (en) * | 1993-02-10 | 1994-08-17 | Unitika Ltd. | Film forming solution, porous film obtained therefrom and coated material with the porous film |
| US7105602B1 (en) | 1999-04-23 | 2006-09-12 | Kaneka Corporation | Processing aid for thermoplastic resin and thermoplastic resin composition containing the same |
| KR100656027B1 (en) * | 1999-04-23 | 2006-12-08 | 가부시키가이샤 가네카 | Processability improving agent for thermoplastic resin and thermoplastic resin composition containing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5751849B2 (en) | 1982-11-04 |
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