JPS557552A - Preparation of phosphagen oligomer - Google Patents
Preparation of phosphagen oligomerInfo
- Publication number
- JPS557552A JPS557552A JP8012878A JP8012878A JPS557552A JP S557552 A JPS557552 A JP S557552A JP 8012878 A JP8012878 A JP 8012878A JP 8012878 A JP8012878 A JP 8012878A JP S557552 A JPS557552 A JP S557552A
- Authority
- JP
- Japan
- Prior art keywords
- phosphagen
- pcl
- oligomer
- mol
- hexane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- DRBBFCLWYRJSJZ-UHFFFAOYSA-N N-phosphocreatine Chemical compound OC(=O)CN(C)C(=N)NP(O)(O)=O DRBBFCLWYRJSJZ-UHFFFAOYSA-N 0.000 title abstract 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000013078 crystal Substances 0.000 abstract 1
- 150000001923 cyclic compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 229910052976 metal sulfide Inorganic materials 0.000 abstract 1
- -1 phosphagen cyclic compound Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 239000013638 trimer Substances 0.000 abstract 1
Landscapes
- Catalysts (AREA)
Abstract
PURPOSE: To carry out the reaction smoothly and to manufacture phosphagen oligoner with a high yield, by directly reacting PCl5 and NH4Cl without using solvent under the existence of catalyst.
CONSTITUTION: PCl5 and NH4Cl are reacted directly without solvent using metal oxides, sulfides or organic salts etc. (for example; MgO, BaS etc.) or phosphagen oligomer (for example; cyclic and/or linear phosphagen oligomer) as ctalyst. On this occasion, PCl and NH4Cl are reacted under stirring at 1:0.8W10 of mol ratio, especially 1:4W10 and 100W200°C of reaction temperature. Also, adding quantity of catalyst is made 0.01W10 mol% against 1 mol of PCl5. Next, n- hexane is added to the reaction mixture and phosphagen cyclic compound is separated as n-soluble component and then, trimer and tetramer are filtered and recovered as crystals from oily large cyclic compound after distilling n-hexane.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8012878A JPS557552A (en) | 1978-07-01 | 1978-07-01 | Preparation of phosphagen oligomer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8012878A JPS557552A (en) | 1978-07-01 | 1978-07-01 | Preparation of phosphagen oligomer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS557552A true JPS557552A (en) | 1980-01-19 |
| JPS62843B2 JPS62843B2 (en) | 1987-01-09 |
Family
ID=13709572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8012878A Granted JPS557552A (en) | 1978-07-01 | 1978-07-01 | Preparation of phosphagen oligomer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS557552A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5033033A (en) * | 1973-07-27 | 1975-03-31 | ||
| JPS50137892A (en) * | 1974-04-05 | 1975-11-01 | ||
| JPS611363A (en) * | 1985-04-20 | 1986-01-07 | Takeshi Ishizaka | Method for removing tomentum of osmund by rubbing |
-
1978
- 1978-07-01 JP JP8012878A patent/JPS557552A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5033033A (en) * | 1973-07-27 | 1975-03-31 | ||
| JPS50137892A (en) * | 1974-04-05 | 1975-11-01 | ||
| JPS611363A (en) * | 1985-04-20 | 1986-01-07 | Takeshi Ishizaka | Method for removing tomentum of osmund by rubbing |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62843B2 (en) | 1987-01-09 |
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