JPS5587767A - Recovery of epsilon-caprolactam - Google Patents

Recovery of epsilon-caprolactam

Info

Publication number
JPS5587767A
JPS5587767A JP16010878A JP16010878A JPS5587767A JP S5587767 A JPS5587767 A JP S5587767A JP 16010878 A JP16010878 A JP 16010878A JP 16010878 A JP16010878 A JP 16010878A JP S5587767 A JPS5587767 A JP S5587767A
Authority
JP
Japan
Prior art keywords
layer
water
product
caprolactam
peroxydicyclohexylamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16010878A
Other languages
Japanese (ja)
Other versions
JPS6149305B2 (en
Inventor
Kazuhiko Hirozawa
Kiyoshi Kumakawa
Haruhiko Miyazaki
Kenji Kuniyasu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ube Corp
Original Assignee
Ube Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ube Industries Ltd filed Critical Ube Industries Ltd
Priority to JP16010878A priority Critical patent/JPS5587767A/en
Publication of JPS5587767A publication Critical patent/JPS5587767A/en
Publication of JPS6149305B2 publication Critical patent/JPS6149305B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To recover the title compound, an intermediate for nylon 6, in high purity, by saparation of the oily layer (Ol) from the thermal decomposition product of 1,1'-peroxydicyclohexylamine, and by mixing of the aqueous layer with a water extract of Ol, followed by concentration distillation, crystallization of the mixture.
CONSTITUTION: 1,1'-Peroxydicyclohexylamine (PXA) is thermally decomposed with steam at 300W1000°C, and ε-caprolactam (LC) is recovered from the product. The process comprises the following steps: (A) separation of product 1 into the aqueous layer 2 consisting mainly of 11-cyanoundecanoic acid, and the oily layer 3, (B) mixing of the extract of the layer 3 with water 4, (C) removal of water and low-boiling substances 6 from the mixture 5 to give the concentrate LC7 and distillation of the LC cut 9, and (D) crystallization and separation of the LC cut 9 from the toluene 10 to give the LC crystals 12.
COPYRIGHT: (C)1980,JPO&Japio
JP16010878A 1978-12-27 1978-12-27 Recovery of epsilon-caprolactam Granted JPS5587767A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16010878A JPS5587767A (en) 1978-12-27 1978-12-27 Recovery of epsilon-caprolactam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16010878A JPS5587767A (en) 1978-12-27 1978-12-27 Recovery of epsilon-caprolactam

Publications (2)

Publication Number Publication Date
JPS5587767A true JPS5587767A (en) 1980-07-02
JPS6149305B2 JPS6149305B2 (en) 1986-10-29

Family

ID=15708016

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16010878A Granted JPS5587767A (en) 1978-12-27 1978-12-27 Recovery of epsilon-caprolactam

Country Status (1)

Country Link
JP (1) JPS5587767A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109678754A (en) * 2017-10-19 2019-04-26 万华化学集团股份有限公司 A kind of preparation method of 11- cyano undecanoic acid

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01227608A (en) * 1988-03-07 1989-09-11 Nippon Telegr & Teleph Corp <Ntt> Cable connecting double box

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109678754A (en) * 2017-10-19 2019-04-26 万华化学集团股份有限公司 A kind of preparation method of 11- cyano undecanoic acid
CN109678754B (en) * 2017-10-19 2021-09-07 万华化学集团股份有限公司 A kind of preparation method of 11-cyanoundecanoic acid

Also Published As

Publication number Publication date
JPS6149305B2 (en) 1986-10-29

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