JPS5594338A - Preparation of oxalate - Google Patents
Preparation of oxalateInfo
- Publication number
- JPS5594338A JPS5594338A JP169279A JP169279A JPS5594338A JP S5594338 A JPS5594338 A JP S5594338A JP 169279 A JP169279 A JP 169279A JP 169279 A JP169279 A JP 169279A JP S5594338 A JPS5594338 A JP S5594338A
- Authority
- JP
- Japan
- Prior art keywords
- palladium nitrate
- quinone
- catalysts
- oxalate
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 title abstract 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 abstract 5
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229930192627 Naphthoquinone Natural products 0.000 abstract 1
- -1 aliphatic alcohols Chemical class 0.000 abstract 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 abstract 1
- 150000004056 anthraquinones Chemical class 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 150000002791 naphthoquinones Chemical class 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 235000006408 oxalic acid Nutrition 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To obtain the title compound in high selectivity, useful as a raw material for oxalic acid, analytical reagents, solvents for perfumes, intermediates for organic compounds, etc., by the reaction of aliphatic alcohols, carbon monoxide, and O2, under pressure, in the presence of palladium nitrate and a quinone as catalysts.
CONSTITUTION: An aliphatic alcohol, preferably a 1W6C straight chain aliphatic alcohol, carbon monoxide and molecular oxygen are reacted under pressure, in the presence of palladium nitrate in an amount of 0.5W10mmol based on 100ml of a raw material alcohol, and a quinone in a molar amount of 0.5W40 times that of the palladium nitrate, e.g. benzoquinone, naphthoquinone, or anthraquinone, as catalysts, to obtain an oxalate.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP169279A JPS5594338A (en) | 1979-01-10 | 1979-01-10 | Preparation of oxalate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP169279A JPS5594338A (en) | 1979-01-10 | 1979-01-10 | Preparation of oxalate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5594338A true JPS5594338A (en) | 1980-07-17 |
Family
ID=11508570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP169279A Pending JPS5594338A (en) | 1979-01-10 | 1979-01-10 | Preparation of oxalate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5594338A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5283351A (en) * | 1991-04-11 | 1994-02-01 | Idemitsu Kosan Co., Ltd. | Process for producing an organic carbonate from an organic hydroxy compound and carbon monoxide in the presence of a palladium catalyst |
| US5336803A (en) * | 1991-03-14 | 1994-08-09 | Idemitsu Kosan Co., Ltd. | Process for producing an organic carbonate |
| RU2493238C1 (en) * | 2012-09-26 | 2013-09-20 | Государственное унитарное предприятие "Институт нефтехимпереработки Республики Башкортостан" (ГУП "ИНХП РБ") | Method for obtaining ether additive to deep-hydrocleaned diesel fuel |
-
1979
- 1979-01-10 JP JP169279A patent/JPS5594338A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5336803A (en) * | 1991-03-14 | 1994-08-09 | Idemitsu Kosan Co., Ltd. | Process for producing an organic carbonate |
| US5283351A (en) * | 1991-04-11 | 1994-02-01 | Idemitsu Kosan Co., Ltd. | Process for producing an organic carbonate from an organic hydroxy compound and carbon monoxide in the presence of a palladium catalyst |
| RU2493238C1 (en) * | 2012-09-26 | 2013-09-20 | Государственное унитарное предприятие "Институт нефтехимпереработки Республики Башкортостан" (ГУП "ИНХП РБ") | Method for obtaining ether additive to deep-hydrocleaned diesel fuel |
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