JPS5599902A - Polymerization of alpha-olefin - Google Patents
Polymerization of alpha-olefinInfo
- Publication number
- JPS5599902A JPS5599902A JP655279A JP655279A JPS5599902A JP S5599902 A JPS5599902 A JP S5599902A JP 655279 A JP655279 A JP 655279A JP 655279 A JP655279 A JP 655279A JP S5599902 A JPS5599902 A JP S5599902A
- Authority
- JP
- Japan
- Prior art keywords
- acid ester
- organic acid
- compound
- olefin
- pulverizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE: To prepare an α-olefin polymer having remarkably improved crystallinity and bulk density, by using a catalyst comprising an aluminum compound, an electron donor, and a composition provided by pulverizing a magnesium compound together with an organic acid ester, an unsaturated monomer, etc., and treating the mixture with titanium tetrachloride.
CONSTITUTION: An α-olefin (e.g. propylene, etc.) is polymerized to give the desired polymer by using a polymerization catalyst comprising (A) a composition provided by pulverizing (a) a magnesium halide together with (b) an organic acid ester (e.g. ethyl bensoate, etc.), (c) an aromatic hydrocarbon having an unsaturated substituent (e.g. α-methylstyrene, etc.) and (d) a liquid propylene oligomer, and thermally treating the mixture with (e) titanium tetrachloride, (B) an organoaluminum compound (e.g. triisobutylaluminum, etc.) and (C) an electron-donative compound, e.g. an organic acid ester or its complex with an aluminum halide, etc.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP655279A JPS5599902A (en) | 1979-01-25 | 1979-01-25 | Polymerization of alpha-olefin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP655279A JPS5599902A (en) | 1979-01-25 | 1979-01-25 | Polymerization of alpha-olefin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5599902A true JPS5599902A (en) | 1980-07-30 |
| JPS6351162B2 JPS6351162B2 (en) | 1988-10-13 |
Family
ID=11641487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP655279A Granted JPS5599902A (en) | 1979-01-25 | 1979-01-25 | Polymerization of alpha-olefin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5599902A (en) |
-
1979
- 1979-01-25 JP JP655279A patent/JPS5599902A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6351162B2 (en) | 1988-10-13 |
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