JPS5616430A - Preparation of phenol - Google Patents
Preparation of phenolInfo
- Publication number
- JPS5616430A JPS5616430A JP9181779A JP9181779A JPS5616430A JP S5616430 A JPS5616430 A JP S5616430A JP 9181779 A JP9181779 A JP 9181779A JP 9181779 A JP9181779 A JP 9181779A JP S5616430 A JPS5616430 A JP S5616430A
- Authority
- JP
- Japan
- Prior art keywords
- methyl
- reaction mixture
- substituted aromatic
- hydroperoxide
- concentrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 150000001491 aromatic compounds Chemical class 0.000 abstract 3
- 239000012141 concentrate Substances 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- 239000011541 reaction mixture Substances 0.000 abstract 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 abstract 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 abstract 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical compound CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare the titled compound free from isomers, by oxidizing a methyl- substituted aromatic compound in the presence of an easily and economically available cumene hydroperoxide concentrate, and heat-decomposing the resulting product obtained in high yield without by-products, without separating the product from the reaction mixture.
CONSTITUTION: A primary hydroperoxide is prepared by the liquid phase oxidation of the corresponding methyl-substituted aromatic compound such as toluene, o-, m-, or p-xylene, α-methylnaphthalene, etc., with an O2-containing gas in the presence of cumene hydroperoxide concentrate obtained by concentrating the oxidation reaction mixture of cumene, pref. at 90W140°C and 5W20kg/cm2G, thereby oxidizing one of the methyl groups of the methyl-substituted aromatic compound. The reaction mixture obtained by the above oxidation reaction is concentrated to obtain a liquid containing cumene hydroperoxide and the above primary hydroperoxide, and the concentrate is decomposed in the presence of an acidic catalyst to obtain the corresponding phenols.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54091817A JPS599531B2 (en) | 1979-07-19 | 1979-07-19 | Method for producing phenols |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54091817A JPS599531B2 (en) | 1979-07-19 | 1979-07-19 | Method for producing phenols |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5616430A true JPS5616430A (en) | 1981-02-17 |
| JPS599531B2 JPS599531B2 (en) | 1984-03-03 |
Family
ID=14037179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54091817A Expired JPS599531B2 (en) | 1979-07-19 | 1979-07-19 | Method for producing phenols |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS599531B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6473609A (en) * | 1987-09-14 | 1989-03-17 | Nec Corp | Laminated ceramic capacitor |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2683751A (en) * | 1950-10-31 | 1954-07-13 | Hercules Powder Co Ltd | Phenol production |
-
1979
- 1979-07-19 JP JP54091817A patent/JPS599531B2/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2683751A (en) * | 1950-10-31 | 1954-07-13 | Hercules Powder Co Ltd | Phenol production |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS599531B2 (en) | 1984-03-03 |
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