JPS5616431A - Preparation of alkylene glycol - Google Patents
Preparation of alkylene glycolInfo
- Publication number
- JPS5616431A JPS5616431A JP9169579A JP9169579A JPS5616431A JP S5616431 A JPS5616431 A JP S5616431A JP 9169579 A JP9169579 A JP 9169579A JP 9169579 A JP9169579 A JP 9169579A JP S5616431 A JPS5616431 A JP S5616431A
- Authority
- JP
- Japan
- Prior art keywords
- molybdenum
- water
- compound
- reacting
- moles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 alkylene glycol Chemical compound 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 6
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 239000001569 carbon dioxide Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 239000005078 molybdenum compound Substances 0.000 abstract 1
- 150000002752 molybdenum compounds Chemical class 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 150000003673 urethanes Chemical class 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare the titled compound useful as a raw material of urethanes, etc., easily, in high selectivity, without using a large excess of water nor producing by-products, by reacting a ≥3C alkylene oxide with water in the presence of carbon dioxide and metallic molybdenum catalyst.
CONSTITUTION: The titled compound is prepared by reacting (A) 1 mole a ≥3C alkylene oxide such as propylene oxide, butylene oxide, etc., with (B) 1W5 moles, pref. 1.01W2.5 moles water, in the presence of (C) 0.0001W1 mole carbon dioxide (CO2 gas or a compound which generates CO2, such as soduim carbonate) and (D) a catalyst comprising molybdenum metal and/or a molybdenum compound (e.g. molybdenum dioxide), at room temp. to 250°C.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9169579A JPS5616431A (en) | 1979-07-20 | 1979-07-20 | Preparation of alkylene glycol |
| CA000335707A CA1120955A (en) | 1979-07-09 | 1979-09-14 | Process for the production of alkylene glycols |
| US06/076,842 US4277632A (en) | 1979-07-09 | 1979-09-19 | Process for the production of alkylene glycols |
| DE19792938115 DE2938115A1 (en) | 1979-07-09 | 1979-09-20 | METHOD FOR PRODUCING ALKYLENE GLYCOLES |
| NL7907002A NL7907002A (en) | 1979-07-09 | 1979-09-20 | PROCESS FOR PREPARING ALKYLENE GLYCOLS. |
| GB7932592A GB2053190B (en) | 1979-07-09 | 1979-09-20 | Production of alkylene glycols |
| BE0/197238A BE878902A (en) | 1979-07-09 | 1979-09-20 | PROCESS FOR PRODUCING ALKYLENE-GLYCOLS |
| FR7923642A FR2460906A1 (en) | 1979-07-09 | 1979-09-21 | PROCESS FOR PRODUCING ALKYLENE GLYCOLS, IN PARTICULAR BY REACTING ALKYLENE OXIDES WITH WATER |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9169579A JPS5616431A (en) | 1979-07-20 | 1979-07-20 | Preparation of alkylene glycol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5616431A true JPS5616431A (en) | 1981-02-17 |
| JPS6118531B2 JPS6118531B2 (en) | 1986-05-13 |
Family
ID=14033642
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9169579A Granted JPS5616431A (en) | 1979-07-09 | 1979-07-20 | Preparation of alkylene glycol |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5616431A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5620529A (en) * | 1979-07-30 | 1981-02-26 | Nippon Shokubai Kagaku Kogyo Co Ltd | Preparation of alkylene glycol |
| JPS59122557U (en) * | 1983-02-07 | 1984-08-17 | 横河電機株式会社 | light voltmeter |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2609543B1 (en) * | 1987-01-13 | 1991-07-19 | Dassault Electronique | DEVICE FOR DETECTING A DIMENSION, PARTICULARLY THE WIDTH OF A RUNNING AREA ON A TRACK |
-
1979
- 1979-07-20 JP JP9169579A patent/JPS5616431A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5620529A (en) * | 1979-07-30 | 1981-02-26 | Nippon Shokubai Kagaku Kogyo Co Ltd | Preparation of alkylene glycol |
| JPS59122557U (en) * | 1983-02-07 | 1984-08-17 | 横河電機株式会社 | light voltmeter |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6118531B2 (en) | 1986-05-13 |
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