JPS5620182A - Electrodeposition method for lead dioxide on surface of anode plate built in electrolytic bath - Google Patents
Electrodeposition method for lead dioxide on surface of anode plate built in electrolytic bathInfo
- Publication number
- JPS5620182A JPS5620182A JP9635879A JP9635879A JPS5620182A JP S5620182 A JPS5620182 A JP S5620182A JP 9635879 A JP9635879 A JP 9635879A JP 9635879 A JP9635879 A JP 9635879A JP S5620182 A JPS5620182 A JP S5620182A
- Authority
- JP
- Japan
- Prior art keywords
- pbo
- anode
- room
- cathode
- electrolytic bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 title abstract 8
- 238000004070 electrodeposition Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000007747 plating Methods 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 238000005341 cation exchange Methods 0.000 abstract 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 238000004299 exfoliation Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 abstract 1
- 238000011010 flushing procedure Methods 0.000 abstract 1
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 239000010446 mirabilite Substances 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 abstract 1
- 239000010409 thin film Substances 0.000 abstract 1
Landscapes
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
PURPOSE: To obtain PbO2 coat not generating exfoliation or crack, by filling up PbO2 plating solution in the electrolytic bath which can perform power supply operation immediately and turning on an electric current and then, forming PbO2 thin film on the anode plate.
CONSTITUTION: PbO2 plating solution is put in the electrolytic bath regulated and fixed so as to operate immediately and thin PbO2 film is formed on the anode by electrolyzing by the same system direct current in a short time. Then, product on the cathode is dissolved by disscolution solution and is washed by water after discharging and flushing. Hereby, strong PbO2 coat is made on the surface of the anode plate. For example, plating solution containing 10wt% lead nitrate and 1.5wt% copper nitrate, is filled up in the anode room composed of the anode 1, the porous diaphragm 4, the cation exchange membrane 3 and the cathode 2 and middle room and also, cathode room and then, an electric current is turned on at 4A/dm2 current density for two minutes. Inner part is washed by water after discharge. Next, solution containing 3wt% antimony and 0.5wt% ammonium persulfate, is filled up in the cathode room and middle room and is discharged after 4 hours and then, is washed by water. Then, electrolysis of the solution containing Glauber's salt, is immediately performed.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9635879A JPS5620182A (en) | 1979-07-27 | 1979-07-27 | Electrodeposition method for lead dioxide on surface of anode plate built in electrolytic bath |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9635879A JPS5620182A (en) | 1979-07-27 | 1979-07-27 | Electrodeposition method for lead dioxide on surface of anode plate built in electrolytic bath |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5620182A true JPS5620182A (en) | 1981-02-25 |
Family
ID=14162764
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9635879A Pending JPS5620182A (en) | 1979-07-27 | 1979-07-27 | Electrodeposition method for lead dioxide on surface of anode plate built in electrolytic bath |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5620182A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57199639A (en) * | 1981-06-01 | 1982-12-07 | Mitsubishi Heavy Ind Ltd | Method of pre-expansion of green tyre in tyre vulcanizer |
| CN110468279A (en) * | 2019-09-09 | 2019-11-19 | 赵坤 | A method of recycling lead from the lead plaster material of waste lead storage battery |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53135834A (en) * | 1977-04-29 | 1978-11-27 | Olin Corp | Method of lowering overvoltage in electrolyte tank and its device |
| JPS5425275A (en) * | 1977-07-27 | 1979-02-26 | Diamond Shamrock Corp | Method of plating active coat over cathod of halogenation alkali electrolytic cell there |
-
1979
- 1979-07-27 JP JP9635879A patent/JPS5620182A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53135834A (en) * | 1977-04-29 | 1978-11-27 | Olin Corp | Method of lowering overvoltage in electrolyte tank and its device |
| JPS5425275A (en) * | 1977-07-27 | 1979-02-26 | Diamond Shamrock Corp | Method of plating active coat over cathod of halogenation alkali electrolytic cell there |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57199639A (en) * | 1981-06-01 | 1982-12-07 | Mitsubishi Heavy Ind Ltd | Method of pre-expansion of green tyre in tyre vulcanizer |
| CN110468279A (en) * | 2019-09-09 | 2019-11-19 | 赵坤 | A method of recycling lead from the lead plaster material of waste lead storage battery |
| CN110468279B (en) * | 2019-09-09 | 2021-04-06 | 赵坤 | Method for recovering lead from lead plaster material of waste lead storage battery |
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