JPS562941A - Purification of xylylenediamine - Google Patents
Purification of xylylenediamineInfo
- Publication number
- JPS562941A JPS562941A JP7896979A JP7896979A JPS562941A JP S562941 A JPS562941 A JP S562941A JP 7896979 A JP7896979 A JP 7896979A JP 7896979 A JP7896979 A JP 7896979A JP S562941 A JPS562941 A JP S562941A
- Authority
- JP
- Japan
- Prior art keywords
- iron
- xylylenediamine
- chromium
- catalyst
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000746 purification Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 10
- 229910052742 iron Inorganic materials 0.000 abstract 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 2
- XQZYPMVTSDWCCE-UHFFFAOYSA-N phthalonitrile Chemical compound N#CC1=CC=CC=C1C#N XQZYPMVTSDWCCE-UHFFFAOYSA-N 0.000 abstract 2
- 229920006391 phthalonitrile polymer Polymers 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the highly pure xylylenediamine having high color stability, by the contact of xylylenediamine obtained by the catalytic hydrogenation of phthalonitrile, with a catalyst containing an iron oxide or iron and a chromium oxide, in the presence of water.
CONSTITUTION: Xylylenediamine is prepared by the catalytic hydrogenation of phthalonitrile, and purified by the contact with a catalyst comprising an iron oxide or iron and a chromium oxide, in the presence of water. The catalyst is prepared by calcining the precipitated carbonates or hydroxides of iron and chromium, and may be carried on a carrier. A catalyst containing oxides of iron and chromium is excellent in durability compared with the one containing only iron. The amount of water added is suitably 0.5W20wt% based on xylylenediamine, and treatment conditions are 80W200°C, 1W30kg/cm2G of ressure and 30minW3hr. The reduction is preferably carried out after removal of the solvent from the reaction solution.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7896979A JPS562941A (en) | 1979-06-22 | 1979-06-22 | Purification of xylylenediamine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7896979A JPS562941A (en) | 1979-06-22 | 1979-06-22 | Purification of xylylenediamine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS562941A true JPS562941A (en) | 1981-01-13 |
| JPS5727098B2 JPS5727098B2 (en) | 1982-06-08 |
Family
ID=13676720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7896979A Granted JPS562941A (en) | 1979-06-22 | 1979-06-22 | Purification of xylylenediamine |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS562941A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973746A (en) * | 1988-10-24 | 1990-11-27 | General Electric Company | Process for converting pet scrap to diamine monomers |
| JP2002161076A (en) * | 2000-09-12 | 2002-06-04 | Mitsubishi Gas Chem Co Inc | Amino compound and method for producing the same |
| JP2003026797A (en) * | 2001-07-19 | 2003-01-29 | Mitsubishi Gas Chem Co Inc | Xylylene group-containing polyamide resin |
| JP2005154426A (en) * | 2003-11-06 | 2005-06-16 | Mitsubishi Gas Chem Co Inc | Solid xylylenediamine in containers, method for producing the same, and method for storing xylylenediamine |
| US7626057B2 (en) | 2006-06-29 | 2009-12-01 | Mitsubishi Gas Chemical Company, Inc. | Production of xylylenediamines |
| KR101155776B1 (en) * | 2003-11-06 | 2012-06-12 | 미츠비시 가스 가가쿠 가부시키가이샤 | Solid xylylenediamine in container, production method thereof, and method for storing xylylenediamine |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113365975B (en) | 2019-03-20 | 2024-10-25 | 三菱瓦斯化学株式会社 | Method for producing xylylenediamine |
-
1979
- 1979-06-22 JP JP7896979A patent/JPS562941A/en active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973746A (en) * | 1988-10-24 | 1990-11-27 | General Electric Company | Process for converting pet scrap to diamine monomers |
| JP2002161076A (en) * | 2000-09-12 | 2002-06-04 | Mitsubishi Gas Chem Co Inc | Amino compound and method for producing the same |
| JP2003026797A (en) * | 2001-07-19 | 2003-01-29 | Mitsubishi Gas Chem Co Inc | Xylylene group-containing polyamide resin |
| JP2005154426A (en) * | 2003-11-06 | 2005-06-16 | Mitsubishi Gas Chem Co Inc | Solid xylylenediamine in containers, method for producing the same, and method for storing xylylenediamine |
| KR101155776B1 (en) * | 2003-11-06 | 2012-06-12 | 미츠비시 가스 가가쿠 가부시키가이샤 | Solid xylylenediamine in container, production method thereof, and method for storing xylylenediamine |
| US7626057B2 (en) | 2006-06-29 | 2009-12-01 | Mitsubishi Gas Chemical Company, Inc. | Production of xylylenediamines |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5727098B2 (en) | 1982-06-08 |
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