JPS5647406A - Production of immobilized crown compound - Google Patents
Production of immobilized crown compoundInfo
- Publication number
- JPS5647406A JPS5647406A JP12502779A JP12502779A JPS5647406A JP S5647406 A JPS5647406 A JP S5647406A JP 12502779 A JP12502779 A JP 12502779A JP 12502779 A JP12502779 A JP 12502779A JP S5647406 A JPS5647406 A JP S5647406A
- Authority
- JP
- Japan
- Prior art keywords
- chloromethylated
- integer
- amino group
- formula
- produce
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE:A specific crown ether bearing an amino group is made to react with a chloromethylated and crosslinked polystyrene to produce the titled compound that is used as an interphase transferring catalyst, metal capturing agent or separator because of its readily recoverably properties and no toxicity in high efficiency. CONSTITUTION:The reaction of (A) a crown ether bearing an amino group of formula I (l is integer of 1-7) or formula II (m, n are 0 or integer of 1-6) such as aminobenzo-15-crown-5, with (B) a chloromethylated and crosslinked polystyrene is conducted in a solvent such as dimethylformamide in a nitrogen atmosphere at room temperature to 150 deg.C to produce the objective compound. The preferred amount of component A is 1-10 times equivalents of the chlorine atoms in component B. By using this resin, both of sodium and potassium salts are separated from a mixed aqueous solution containing them.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12502779A JPS5647406A (en) | 1979-09-28 | 1979-09-28 | Production of immobilized crown compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12502779A JPS5647406A (en) | 1979-09-28 | 1979-09-28 | Production of immobilized crown compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5647406A true JPS5647406A (en) | 1981-04-30 |
Family
ID=14900027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12502779A Pending JPS5647406A (en) | 1979-09-28 | 1979-09-28 | Production of immobilized crown compound |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5647406A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0320489A (en) * | 1989-06-19 | 1991-01-29 | Chlorine Eng Corp Ltd | Production of tetraalkylammonium hydroxide |
| WO2014019501A1 (en) * | 2012-08-03 | 2014-02-06 | 天津工业大学 | Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereof |
| JP2017520667A (en) * | 2014-04-03 | 2017-07-27 | ユニヴェルシテ パリ−スュッドＵｎｉｖｅｒｓｉｔｅ Ｐａｒｉｓ−Ｓｕｄ | A novel complex for the separation of cations. |
| JP2021529265A (en) * | 2018-07-06 | 2021-10-28 | モーゼル テクノロジーズ, リミテッド ライアビリティー カンパニーMoselle Technologies, Llc | Methods and Compositions for Recovering Lithium from Solution Using Nanoparticles |
| JP2023033707A (en) * | 2021-08-30 | 2023-03-13 | 国立大学法人北海道大学 | Ion extraction compound, method for manufacturing the same, ion substitute, method for manufacturing the same, intercalation compound, method for manufacturing the same, and high pressure solid electrochemical pressure cell |
| CN117225476A (en) * | 2023-11-15 | 2023-12-15 | 山东华夏神舟新材料有限公司 | Supported metal catalyst and preparation and regeneration methods and application thereof |
-
1979
- 1979-09-28 JP JP12502779A patent/JPS5647406A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0320489A (en) * | 1989-06-19 | 1991-01-29 | Chlorine Eng Corp Ltd | Production of tetraalkylammonium hydroxide |
| WO2014019501A1 (en) * | 2012-08-03 | 2014-02-06 | 天津工业大学 | Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereof |
| KR20150058153A (en) * | 2012-08-03 | 2015-05-28 | 티엔진 폴리테크닉 유니버시티 | Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereof |
| US9988466B2 (en) | 2012-08-03 | 2018-06-05 | Tianjin Polytechnic University | Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereof |
| JP2017520667A (en) * | 2014-04-03 | 2017-07-27 | ユニヴェルシテ パリ−スュッドＵｎｉｖｅｒｓｉｔｅ Ｐａｒｉｓ−Ｓｕｄ | A novel complex for the separation of cations. |
| JP2021529265A (en) * | 2018-07-06 | 2021-10-28 | モーゼル テクノロジーズ, リミテッド ライアビリティー カンパニーMoselle Technologies, Llc | Methods and Compositions for Recovering Lithium from Solution Using Nanoparticles |
| US11993827B2 (en) | 2018-07-06 | 2024-05-28 | Moselle Technologies, Llc | Methods and compositions for recovery of lithium from liquid solutions with nanoparticles |
| JP2025084764A (en) * | 2018-07-06 | 2025-06-03 | モーゼル テクノロジーズ，リミテッド ライアビリティー カンパニー | Methods and compositions for recovering lithium from solution using nanoparticles - Patent Application 20070229633 |
| US12545975B2 (en) | 2018-07-06 | 2026-02-10 | Moselle Technologies, Llc | Methods and compositions for recovery of lithium from liquid solutions with nanoparticles |
| JP2023033707A (en) * | 2021-08-30 | 2023-03-13 | 国立大学法人北海道大学 | Ion extraction compound, method for manufacturing the same, ion substitute, method for manufacturing the same, intercalation compound, method for manufacturing the same, and high pressure solid electrochemical pressure cell |
| CN117225476A (en) * | 2023-11-15 | 2023-12-15 | 山东华夏神舟新材料有限公司 | Supported metal catalyst and preparation and regeneration methods and application thereof |
| CN117225476B (en) * | 2023-11-15 | 2024-02-20 | 山东华夏神舟新材料有限公司 | Supported metal catalyst and preparation and regeneration methods and application thereof |
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