JPS5659736A - Preparation of dihydrodicyclopentenyl acrylate and/or dihydrodicyclopentenyl methacrylate - Google Patents
Preparation of dihydrodicyclopentenyl acrylate and/or dihydrodicyclopentenyl methacrylateInfo
- Publication number
- JPS5659736A JPS5659736A JP13479679A JP13479679A JPS5659736A JP S5659736 A JPS5659736 A JP S5659736A JP 13479679 A JP13479679 A JP 13479679A JP 13479679 A JP13479679 A JP 13479679A JP S5659736 A JPS5659736 A JP S5659736A
- Authority
- JP
- Japan
- Prior art keywords
- group
- catalyst
- dihydrodicyclopentenyl
- formula
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 5
- 239000002253 acid Substances 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 125000001153 fluoro group Chemical group F* 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 150000003457 sulfones Chemical class 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To simplify the treatment of a catalyst after the reaction and obtain the titled substance without corrosion of a reactor, by reacting dicyclopentadiene with acrylic acid and/or methacrylic acid in the presence of a high polymer having a specific group as a catalyst.
CONSTITUTION: Dicyclopentadiene is reacted with acrylic acid and/or methacrylic acid in the presence of a high polymer having a group of formula I (Y is acid group; R is F or perfluoroalkyl group) as a catalyst to give the titled compound. Preferably, a compound having the acid group Y in formula I in an amount of about 0.01W5 equivalents, particularly 0.05W2 equivalents, based on 1g of the catalyst is used as the catalyst. An example of the compound is a high polymer of formula II [Y1 is acid group, e.g. carboxyl, sulfone, etc.; R1 is F, etc.; n is 0, 1 or 2; X1 is group of -(CF2)m- (m is an integer 2W10), etc.] which has a number of linked fluorine atoms with ion exchange capacity based on the group of formula I.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13479679A JPS5659736A (en) | 1979-10-18 | 1979-10-18 | Preparation of dihydrodicyclopentenyl acrylate and/or dihydrodicyclopentenyl methacrylate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13479679A JPS5659736A (en) | 1979-10-18 | 1979-10-18 | Preparation of dihydrodicyclopentenyl acrylate and/or dihydrodicyclopentenyl methacrylate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5659736A true JPS5659736A (en) | 1981-05-23 |
Family
ID=15136731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13479679A Pending JPS5659736A (en) | 1979-10-18 | 1979-10-18 | Preparation of dihydrodicyclopentenyl acrylate and/or dihydrodicyclopentenyl methacrylate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5659736A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0870749A3 (en) * | 1997-04-08 | 1999-01-20 | Rohm And Haas Company | Reactive coalescents |
| JP2006137727A (en) * | 2004-11-15 | 2006-06-01 | Mitsubishi Rayon Co Ltd | Method for producing (meth) acrylic acid ester |
-
1979
- 1979-10-18 JP JP13479679A patent/JPS5659736A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0870749A3 (en) * | 1997-04-08 | 1999-01-20 | Rohm And Haas Company | Reactive coalescents |
| JP2006137727A (en) * | 2004-11-15 | 2006-06-01 | Mitsubishi Rayon Co Ltd | Method for producing (meth) acrylic acid ester |
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