JPS5672007A - Polymerizable composition - Google Patents
Polymerizable compositionInfo
- Publication number
- JPS5672007A JPS5672007A JP14710579A JP14710579A JPS5672007A JP S5672007 A JPS5672007 A JP S5672007A JP 14710579 A JP14710579 A JP 14710579A JP 14710579 A JP14710579 A JP 14710579A JP S5672007 A JPS5672007 A JP S5672007A
- Authority
- JP
- Japan
- Prior art keywords
- spiroorthoester
- formula
- polymerizable composition
- ethylenically unsaturated
- shrinkage during
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000006704 dehydrohalogenation reaction Methods 0.000 abstract 1
- 239000012778 molding material Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
Abstract
PURPOSE: A polymerizable composition which is low in volume shrinkage during polymerization, comprising an ethylenically unsaturated compound and an unsaturated bond-containing spiroorthoester.
CONSTITUTION: A spiroorthoester of formula I, wherein n is 3, 4, or 5, is mixed with an ethylenically unsaturated compound such as acrylic acid, acrylonitrile or styrene. Said composition can be polymerized by use of radical polymerization means such as ultraviolet rays, heat, electron rays or microwaves, shows a low volume shrinkage during polymerization, and is useful for molding materials, adhesives or paints. The compound of formula I is prepared by dehydrohalogenation of a spiroorthoester of formula II, wherein X is Cl, Br or I.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14710579A JPS5672007A (en) | 1979-11-15 | 1979-11-15 | Polymerizable composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14710579A JPS5672007A (en) | 1979-11-15 | 1979-11-15 | Polymerizable composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5672007A true JPS5672007A (en) | 1981-06-16 |
| JPS626569B2 JPS626569B2 (en) | 1987-02-12 |
Family
ID=15422620
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14710579A Granted JPS5672007A (en) | 1979-11-15 | 1979-11-15 | Polymerizable composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5672007A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5815508A (en) * | 1981-07-20 | 1983-01-28 | Sumitomo Chem Co Ltd | Production of ethylene copolymer |
| US4599155A (en) * | 1983-09-22 | 1986-07-08 | Kabushiki Kaisha Toshiba | Resin composition |
-
1979
- 1979-11-15 JP JP14710579A patent/JPS5672007A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5815508A (en) * | 1981-07-20 | 1983-01-28 | Sumitomo Chem Co Ltd | Production of ethylene copolymer |
| US4599155A (en) * | 1983-09-22 | 1986-07-08 | Kabushiki Kaisha Toshiba | Resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS626569B2 (en) | 1987-02-12 |
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