JPS5736103A - Preparation of porous, phosphoric acid-type ion exchange resin - Google Patents
Preparation of porous, phosphoric acid-type ion exchange resinInfo
- Publication number
- JPS5736103A JPS5736103A JP11078380A JP11078380A JPS5736103A JP S5736103 A JPS5736103 A JP S5736103A JP 11078380 A JP11078380 A JP 11078380A JP 11078380 A JP11078380 A JP 11078380A JP S5736103 A JPS5736103 A JP S5736103A
- Authority
- JP
- Japan
- Prior art keywords
- phosphoric acid
- ion exchange
- monomer
- porous
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 title 1
- 239000003456 ion exchange resin Substances 0.000 title 1
- 229920003303 ion-exchange polymer Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 2
- -1 glycidyl ester Chemical class 0.000 abstract 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 229920002554 vinyl polymer Polymers 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 abstract 1
- 150000001253 acrylic acids Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 abstract 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 231100000167 toxic agent Toxicity 0.000 abstract 1
- 239000003440 toxic substance Substances 0.000 abstract 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To prepare the titled resin having high ion exchange capacity, without using toxic substance, by radically polymerizing glycidyl ester of acrylic acids and a specific amount of a polyvinyl monomer in an organic solvent, reacting the product with phosphoric acid, etc., and hydrolyzing the reaction product.
CONSTITUTION: A monovinyl monomer containing the glycidyl ester of acrylic acid which may have an alkyl group at the α-carbon atom (e.g. glycidyl methacrylate) is mixed with ≤5mol%, pref. 0.5W4mol%, based on the monomer, of a polyvinyl monomer (e.g. divinylbenzene), and subjected to the radical polymerization in the presence of an organic compound (e.g. isooctane) which acts as a solvent to the monomers. The produced polymer is made to react with phosphoric acid or phosphorus oxychloride, and hydrolyzed to obtain the objective resin.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11078380A JPS5736103A (en) | 1980-08-12 | 1980-08-12 | Preparation of porous, phosphoric acid-type ion exchange resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11078380A JPS5736103A (en) | 1980-08-12 | 1980-08-12 | Preparation of porous, phosphoric acid-type ion exchange resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5736103A true JPS5736103A (en) | 1982-02-26 |
Family
ID=14544499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11078380A Pending JPS5736103A (en) | 1980-08-12 | 1980-08-12 | Preparation of porous, phosphoric acid-type ion exchange resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5736103A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5075994A (en) * | 1973-08-29 | 1975-06-21 | Ceskoslovenska Akademie Ved |
-
1980
- 1980-08-12 JP JP11078380A patent/JPS5736103A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5075994A (en) * | 1973-08-29 | 1975-06-21 | Ceskoslovenska Akademie Ved |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2101088A (en) | Improved process for preparing water-absorbing resins | |
| JPS55106211A (en) | Porous crosslinked copolymer of chloromethylstyrene and its iminodiacetic acid derivative, and preparation thereof | |
| JPS57105418A (en) | Aqueous dispersion composition | |
| JPS5736103A (en) | Preparation of porous, phosphoric acid-type ion exchange resin | |
| JPS54138432A (en) | Photographic elements for color diffusion transfer process | |
| JPS5620169A (en) | Scale inhibitor | |
| JPS5552338A (en) | Oxymethylene copolymer composition | |
| JPS56103159A (en) | Preparation of novel peroxy ester | |
| JPS5411988A (en) | Preparation of vinyl chloride polymer | |
| JPS56127671A (en) | Coating resin composition | |
| JPS56163105A (en) | Porduction of fluorine-containing polymer | |
| JPS56161414A (en) | Production of self-crosslinking water-absorbing resin | |
| JPS5575407A (en) | Preparation of high molecular organotin compound | |
| JPS5363492A (en) | Preparation of modified polyolefin | |
| JPS5538863A (en) | Preparation of highly water-absorbing polymeric material | |
| JPS56133329A (en) | Preparation of polymer polyol and polyurethane | |
| JPS5653115A (en) | Preparation of low molecular weight acrylic copolymer | |
| JPS57185306A (en) | Preparation of curable resin | |
| JPS57174307A (en) | Production of nonaqueous resin dispersion | |
| JPS572309A (en) | Methyl methacrylate polymer | |
| JPS57121009A (en) | Preparation of water-soluble high-molecular weight polymer | |
| JPS57159804A (en) | Radiation-sensitive organic high-molecular material | |
| JPS57212143A (en) | Methacrylic acid ester compound | |
| JPS57212282A (en) | Adhesive curable with electron rays | |
| JPS55102602A (en) | Preparation of cation exchanger |