JPS5762231A - Preparation of oxygen-containing 2c compound from synthesis gas - Google Patents
Preparation of oxygen-containing 2c compound from synthesis gasInfo
- Publication number
- JPS5762231A JPS5762231A JP55137776A JP13777680A JPS5762231A JP S5762231 A JPS5762231 A JP S5762231A JP 55137776 A JP55137776 A JP 55137776A JP 13777680 A JP13777680 A JP 13777680A JP S5762231 A JPS5762231 A JP S5762231A
- Authority
- JP
- Japan
- Prior art keywords
- rhodium
- compound
- catalyst
- calcium
- cocatalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 229910052760 oxygen Inorganic materials 0.000 title abstract 2
- 239000001301 oxygen Substances 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 239000007789 gas Substances 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 4
- 229910052703 rhodium Inorganic materials 0.000 abstract 4
- 239000010948 rhodium Substances 0.000 abstract 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 229940043430 calcium compound Drugs 0.000 abstract 1
- 150000001674 calcium compounds Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To obtain the titled compound, e.g., acetic acid, acetaldehyde, ethanol, etc., by reacting carbon monoxide with hydrogen using a highly active catalyst obtained by blending rhodium with lithium or calcium as a cocatalyst.
CONSTITUTION: In reacting carbon monoxide with hydrogen in the presence of a rhodium catalyst to give an oxygen-containing hydrocarbon compound having two carbon atoms, e.g., acetic acid, acetaldehyde, and (or) ethanol, lighium or calcium is used together as a cocatalyst. This catalyst is obtained by dissolving rhodium and lithium or calcium compound in water or an organic solvent, e.g., n-hexane, alcohol, etc., adding a porous inorganic carrier substance to the solution, supporting these substances on the carrier conventionally, followed by reduction or heat treatment. Preferably the rhodium content in the supported catalyst is 0.1W10wt%, and the content of cocatalyst metal is 0.2W15wt%.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55137776A JPS5762231A (en) | 1980-10-03 | 1980-10-03 | Preparation of oxygen-containing 2c compound from synthesis gas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55137776A JPS5762231A (en) | 1980-10-03 | 1980-10-03 | Preparation of oxygen-containing 2c compound from synthesis gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5762231A true JPS5762231A (en) | 1982-04-15 |
Family
ID=15206565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55137776A Pending JPS5762231A (en) | 1980-10-03 | 1980-10-03 | Preparation of oxygen-containing 2c compound from synthesis gas |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5762231A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4568699A (en) * | 1983-04-11 | 1986-02-04 | Agency Of Industrial Science And Technology | Process for producing oxygen-containing hydrocarbon compounds |
| JPH01294643A (en) * | 1988-05-20 | 1989-11-28 | Daicel Chem Ind Ltd | Production of oxygen-containing compound |
-
1980
- 1980-10-03 JP JP55137776A patent/JPS5762231A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4568699A (en) * | 1983-04-11 | 1986-02-04 | Agency Of Industrial Science And Technology | Process for producing oxygen-containing hydrocarbon compounds |
| JPH01294643A (en) * | 1988-05-20 | 1989-11-28 | Daicel Chem Ind Ltd | Production of oxygen-containing compound |
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