JPS5776030A - Polypyrazole and its preparation - Google Patents
Polypyrazole and its preparationInfo
- Publication number
- JPS5776030A JPS5776030A JP15340680A JP15340680A JPS5776030A JP S5776030 A JPS5776030 A JP S5776030A JP 15340680 A JP15340680 A JP 15340680A JP 15340680 A JP15340680 A JP 15340680A JP S5776030 A JPS5776030 A JP S5776030A
- Authority
- JP
- Japan
- Prior art keywords
- expressed
- bis
- polypyrazole
- dihydrazine
- diketone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract 2
- IDHZKLHVZBCCJD-UHFFFAOYSA-N [4-(4-hydrazinylphenyl)sulfonylphenyl]hydrazine Chemical compound C1=CC(NN)=CC=C1S(=O)(=O)C1=CC=C(NN)C=C1 IDHZKLHVZBCCJD-UHFFFAOYSA-N 0.000 abstract 1
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- 229920006015 heat resistant resin Polymers 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- TVDDXVUEWIHEHC-UHFFFAOYSA-N octane-2,4,5,7-tetrone Chemical compound CC(=O)CC(=O)C(=O)CC(C)=O TVDDXVUEWIHEHC-UHFFFAOYSA-N 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 238000006068 polycondensation reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
Landscapes
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
PURPOSE: To obtain a novel polypyrazole, having improved heat resistance and solubility in solvents, and usable as a heat-resistant resin, by reacting a bis-β-diketone with a dihydrazine expressed by specific formulas respectively.
CONSTITUTION: (A) A bis-β-diketone, preferably octane-2,4,5,7-tetraone, expressed by formulaI(R2 and R3 are monofunctional substitutent groups) is subjected to the cylization and polycondensation with (B) a dihydrazine, preferably bis(4-hydrazinophenyl)sulfone, expressed by formula II(R1 is bifunctional organic group) in an organic solvent, e.g. N-methyl-2-pyrrolidone, with stirring under heating to give (C) a polypyrazole expressed by formula III. The amounts of the components (A) and (B) are preferably such that either one is within 5mol% excess.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15340680A JPS5776030A (en) | 1980-10-30 | 1980-10-30 | Polypyrazole and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15340680A JPS5776030A (en) | 1980-10-30 | 1980-10-30 | Polypyrazole and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5776030A true JPS5776030A (en) | 1982-05-12 |
| JPS5738608B2 JPS5738608B2 (en) | 1982-08-17 |
Family
ID=15561787
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15340680A Granted JPS5776030A (en) | 1980-10-30 | 1980-10-30 | Polypyrazole and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5776030A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111808281A (en) * | 2020-07-30 | 2020-10-23 | 福州大学 | A kind of method for one-step synthesis of polypyrazole vesicles |
| JP2021507015A (en) * | 2017-12-14 | 2021-02-22 | アメリカ合衆国 | Conductive poly (pyrazole) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5760686A (en) * | 1980-09-26 | 1982-04-12 | Toshiba Heating Appliances Co | Radiating base for electric heater |
-
1980
- 1980-10-30 JP JP15340680A patent/JPS5776030A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021507015A (en) * | 2017-12-14 | 2021-02-22 | アメリカ合衆国 | Conductive poly (pyrazole) |
| CN111808281A (en) * | 2020-07-30 | 2020-10-23 | 福州大学 | A kind of method for one-step synthesis of polypyrazole vesicles |
| CN111808281B (en) * | 2020-07-30 | 2021-09-28 | 福州大学 | Method for synthesizing polypyrazole vesicles in one step |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5738608B2 (en) | 1982-08-17 |
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