JPS58110540A - 7−メチル−3−メチレン−7−オクテン−1−イルプロパノエ−トの製造方法 - Google Patents
7−メチル−3−メチレン−7−オクテン−1−イルプロパノエ−トの製造方法Info
- Publication number
- JPS58110540A JPS58110540A JP57221745A JP22174582A JPS58110540A JP S58110540 A JPS58110540 A JP S58110540A JP 57221745 A JP57221745 A JP 57221745A JP 22174582 A JP22174582 A JP 22174582A JP S58110540 A JPS58110540 A JP S58110540A
- Authority
- JP
- Japan
- Prior art keywords
- methyl
- formula
- methylene
- compound
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- KRONWWNTASLWRC-UHFFFAOYSA-N (7-methyl-3-methylideneoct-7-enyl) propanoate Chemical compound CCC(=O)OCCC(=C)CCCC(C)=C KRONWWNTASLWRC-UHFFFAOYSA-N 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- -1 alkyl lithium Chemical compound 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000000010 aprotic solvent Substances 0.000 claims description 10
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 10
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- 235000019260 propionic acid Nutrition 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 claims description 7
- 239000011541 reaction mixture Substances 0.000 claims description 7
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 5
- 230000010933 acylation Effects 0.000 claims description 4
- 238000005917 acylation reaction Methods 0.000 claims description 4
- 150000003973 alkyl amines Chemical class 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 239000012024 dehydrating agents Substances 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- RZWZRACFZGVKFM-UHFFFAOYSA-N propanoyl chloride Chemical compound CCC(Cl)=O RZWZRACFZGVKFM-UHFFFAOYSA-N 0.000 claims description 2
- KNBNDCBHTQFHMF-UHFFFAOYSA-N 7-methyl-3-methylideneoct-7-en-1-ol Chemical compound CC(=C)CCCC(=C)CCO KNBNDCBHTQFHMF-UHFFFAOYSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 125000001475 halogen functional group Chemical group 0.000 claims 1
- MDVPRIBCAFEROC-UHFFFAOYSA-N oct-1-en-1-ol Chemical compound CCCCCCC=CO MDVPRIBCAFEROC-UHFFFAOYSA-N 0.000 claims 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 claims 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical compound [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 description 4
- CPJRRXSHAYUTGL-UHFFFAOYSA-N isopentenyl alcohol Chemical compound CC(=C)CCO CPJRRXSHAYUTGL-UHFFFAOYSA-N 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 238000004440 column chromatography Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 125000006058 4-methyl-4-pentenyl group Chemical group 0.000 description 2
- LOFHPLKGPULNQP-UHFFFAOYSA-N 4-methylpent-4-en-1-ol Chemical compound CC(=C)CCCO LOFHPLKGPULNQP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910021590 Copper(II) bromide Inorganic materials 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000012280 lithium aluminium hydride Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 230000001568 sexual effect Effects 0.000 description 2
- 238000001308 synthesis method Methods 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- NDQXKKFRNOPRDW-UHFFFAOYSA-N 1,1,1-triethoxyethane Chemical compound CCOC(C)(OCC)OCC NDQXKKFRNOPRDW-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- HAYSUYZJKHDVNB-UHFFFAOYSA-N C(CC)(=O)OCCC(CCCC=C)=C Chemical compound C(CC)(=O)OCCC(CCCC=C)=C HAYSUYZJKHDVNB-UHFFFAOYSA-N 0.000 description 1
- 229910021589 Copper(I) bromide Inorganic materials 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- 241000586568 Diaspidiotus perniciosus Species 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- 125000005278 alkyl sulfonyloxy group Chemical group 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000005279 aryl sulfonyloxy group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- NKNDPYCGAZPOFS-UHFFFAOYSA-M copper(i) bromide Chemical compound Br[Cu] NKNDPYCGAZPOFS-UHFFFAOYSA-M 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- DEQYTNZJHKPYEZ-UHFFFAOYSA-N ethyl acetate;heptane Chemical compound CCOC(C)=O.CCCCCCC DEQYTNZJHKPYEZ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000002964 excitative effect Effects 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- WXPWPYISTQCNDP-UHFFFAOYSA-N oct-7-en-1-ol Chemical compound OCCCCCCC=C WXPWPYISTQCNDP-UHFFFAOYSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- ROJSQZUHNAFOPE-UHFFFAOYSA-N pent-4-enyl propanoate Chemical compound CCC(=O)OCCCC=C ROJSQZUHNAFOPE-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000003586 protic polar solvent Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/44—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon double or triple bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU2251/3843/81 | 1981-12-18 | ||
| HU813843A HU186455B (en) | 1981-12-18 | 1981-12-18 | Process for producing 7-methyl-3-methylen-7-okten-1-y1-propionate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58110540A true JPS58110540A (ja) | 1983-07-01 |
Family
ID=10965739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57221745A Pending JPS58110540A (ja) | 1981-12-18 | 1982-12-17 | 7−メチル−3−メチレン−7−オクテン−1−イルプロパノエ−トの製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS58110540A (it) |
| AU (1) | AU9170682A (it) |
| ES (1) | ES518341A0 (it) |
| FR (1) | FR2518535A1 (it) |
| GB (1) | GB2111501A (it) |
| HU (1) | HU186455B (it) |
| IT (1) | IT1155431B (it) |
| PT (1) | PT75999B (it) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016121105A (ja) * | 2014-12-25 | 2016-07-07 | 信越化学工業株式会社 | 7−メチル−3−メチレン−7−オクテニル=ハライド及びその製造方法並びに7−メチル−3−メチレン−7−オクテニル=プロピオネートの製造方法 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6249938B2 (ja) | 2014-12-25 | 2017-12-20 | 信越化学工業株式会社 | 4−アルキル−3−メチレンブチル=カルボキシレートの製造方法 |
| JP6249937B2 (ja) | 2014-12-25 | 2017-12-20 | 信越化学工業株式会社 | 1−(2−アシロキシエチル)シクロプロピル=スルホネート化合物及び4−アルキル−3−メチレンブチル=カルボキシレートの製造方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4264518A (en) * | 1978-10-30 | 1981-04-28 | Zoecon Corporation | Unsaturated carboxylic acids and esters |
-
1981
- 1981-12-18 HU HU813843A patent/HU186455B/hu not_active IP Right Cessation
-
1982
- 1982-12-12 AU AU91706/82A patent/AU9170682A/en not_active Abandoned
- 1982-12-17 FR FR8221193A patent/FR2518535A1/fr active Pending
- 1982-12-17 JP JP57221745A patent/JPS58110540A/ja active Pending
- 1982-12-17 GB GB08235947A patent/GB2111501A/en not_active Withdrawn
- 1982-12-17 IT IT24818/82A patent/IT1155431B/it active
- 1982-12-17 ES ES518341A patent/ES518341A0/es active Granted
- 1982-12-17 PT PT75999A patent/PT75999B/pt unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016121105A (ja) * | 2014-12-25 | 2016-07-07 | 信越化学工業株式会社 | 7−メチル−3−メチレン−7−オクテニル=ハライド及びその製造方法並びに7−メチル−3−メチレン−7−オクテニル=プロピオネートの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| IT8224818A1 (it) | 1984-06-17 |
| AU9170682A (en) | 1983-06-23 |
| IT8224818A0 (it) | 1982-12-17 |
| IT1155431B (it) | 1987-01-28 |
| HU186455B (en) | 1985-08-28 |
| PT75999B (en) | 1985-10-04 |
| GB2111501A (en) | 1983-07-06 |
| FR2518535A1 (fr) | 1983-06-24 |
| ES8405754A1 (es) | 1984-06-16 |
| ES518341A0 (es) | 1984-06-16 |
| PT75999A (en) | 1983-01-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4156687A (en) | Tetrahydrofuran polycarboxylates | |
| CN1168718C (zh) | 2-(6-取代吡啶-2-基氧甲基)苯乙酸酯的制备方法 | |
| US3919329A (en) | Synthesis of the pink bollworm sex pheromone | |
| JP3976784B2 (ja) | 農薬中間体としての2−(ピリジ−2−イルオキシメチル)フェニルアセテート類の製造方法 | |
| US4007217A (en) | Process for producing 2-hydroxy-3-butenoic acid derivatives | |
| EP0220025B1 (en) | 3-perfluoroalkyl-5-hydroxyisoxazoles | |
| US3953532A (en) | 4,8-Tridecadien-1-ol,4 cis,8 cis,trans | |
| US5750778A (en) | Fungicide intermediates | |
| US5077439A (en) | Process for the preparation of halo-aliphatic aldehydes | |
| GB2111501A (en) | Process for the preparation of 7-methyl-3-methylene-7-octen-1-yl propanoate | |
| US4203907A (en) | Process for preparing a furanic compound | |
| JP3856241B2 (ja) | 1(2h)−キノリンカルボン酸の新規な誘導体、その合成方法及び抗生剤作用を有する化合物を合成するためのその使用方法 | |
| JPS6334127B2 (it) | ||
| US4927945A (en) | Process for preparing diphenyl ethers | |
| US4276218A (en) | Preparation of dihalogenovinyl-γ-butyrolactones | |
| US4500733A (en) | Process for preparing dihalovinylcyclopropanecarboxylic acids | |
| US3987073A (en) | Synthesis of tridecadienoic esters | |
| US3989729A (en) | Synthesis of 8-oxo-4-cis-octenoic acid ester | |
| JPS621941B2 (it) | ||
| JPS59163345A (ja) | α−アリ−ルアルカン酸エステル類の製造法 | |
| JPH07145098A (ja) | アルコキシル基含有化合物 | |
| JPH0244459B2 (it) | ||
| US5264630A (en) | Halo-substituted thiobutanals | |
| Fröhlich et al. | Synthesis of novel 3-heterospiro [5.5] undecanes | |
| JPS59196842A (ja) | (e)−3,7−ジメチル−2,7−オクタジエン−1−イルプロパノエ−トの製造方法 |