JPS59111920A - タリウム（１）のタリウム（３）への酸化方法 - Google Patents

タリウム（１）のタリウム（３）への酸化方法

Info

Publication number: JPS59111920A
Authority: JP; Japan
Prior art keywords: thallium; oxidation; hydrogen peroxide; iii; oxygen
Prior art date: 1982-12-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP22925383A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6241174B2 (2

Inventor

リチヤ−ド・アレキサンダ−・ブロ−ン

ランス・ロ−リンズ・バイア−ズ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

FMC Corp

Original Assignee

FMC Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-12-06

Filing date

1983-12-06

Publication date

1984-06-28

1983-12-06 Application filed by FMC Corp filed Critical FMC Corp

1984-06-28 Publication of JPS59111920A publication Critical patent/JPS59111920A/ja

1987-09-01 Publication of JPS6241174B2 publication Critical patent/JPS6241174B2/ja

Status Granted legal-status Critical Current

Links

238000007254 oxidation reaction Methods 0.000 title claims description 15
230000003647 oxidation Effects 0.000 title claims description 14
ZLUSCZLCHQSJRU-UHFFFAOYSA-N thallium(1+) Chemical compound [Tl+] ZLUSCZLCHQSJRU-UHFFFAOYSA-N 0.000 title description 5
XWVKTOHUMPLABF-UHFFFAOYSA-N thallium(3+) Chemical compound [Tl+3] XWVKTOHUMPLABF-UHFFFAOYSA-N 0.000 title description 5
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 28
229910052716 thallium Inorganic materials 0.000 claims description 24
238000000034 method Methods 0.000 claims description 10
239000007864 aqueous solution Substances 0.000 claims description 4
150000001875 compounds Chemical class 0.000 claims description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 24
238000006243 chemical reaction Methods 0.000 description 15
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
239000001301 oxygen Substances 0.000 description 7
229910052760 oxygen Inorganic materials 0.000 description 7
-1 thallium carboxylates Chemical class 0.000 description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 5
239000003054 catalyst Substances 0.000 description 5
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
229910001882 dioxygen Inorganic materials 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
239000003929 acidic solution Substances 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000007789 gas Substances 0.000 description 3
150000002432 hydroperoxides Chemical class 0.000 description 3
229910001870 ammonium persulfate Inorganic materials 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
229910000510 noble metal Inorganic materials 0.000 description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 description 2
239000000047 product Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000003476 thallium compounds Chemical class 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
241001432959 Chernes Species 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
LVAMVZXECCXUGI-UHFFFAOYSA-N acetic acid;thallium Chemical compound [Tl].CC(O)=O LVAMVZXECCXUGI-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
150000001805 chlorine compounds Chemical group 0.000 description 1
235000019219 chocolate Nutrition 0.000 description 1
150000002118 epoxides Chemical class 0.000 description 1
125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000004967 organic peroxy acids Chemical class 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
WKMKTIVRRLOHAJ-UHFFFAOYSA-N oxygen(2-);thallium(1+) Chemical compound [O-2].[Tl+].[Tl+] WKMKTIVRRLOHAJ-UHFFFAOYSA-N 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
229910003438 thallium oxide Inorganic materials 0.000 description 1
229910021517 thallium(III) hydroxide Inorganic materials 0.000 description 1
GEPJDKDOADVEKE-UHFFFAOYSA-K thallium(iii) hydroxide Chemical compound O[Tl](O)O GEPJDKDOADVEKE-UHFFFAOYSA-K 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1

Landscapes

Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Steroid Compounds (AREA)

JP22925383A 1982-12-06 1983-12-06 タリウム（１）のタリウム（３）への酸化方法 Granted JPS59111920A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US44736982A	1982-12-06	1982-12-06
US447369		1982-12-06

Publications (2)

Publication Number	Publication Date
JPS59111920A true JPS59111920A (ja)	1984-06-28
JPS6241174B2 JPS6241174B2 (2)	1987-09-01

Family

ID=23776100

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP22925383A Granted JPS59111920A (ja)	1982-12-06	1983-12-06	タリウム（１）のタリウム（３）への酸化方法

Country Status (1)

Country	Link
JP (1)	JPS59111920A (2)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0633172U (ja) *	1991-06-28	1994-04-28	有限会社シンクドリーム	ラベル
WO2020090913A1 (ja) *	2018-10-30	2020-05-07	浜松ホトニクス株式会社	レーザ加工装置及びレーザ加工方法

1983
- 1983-12-06 JP JP22925383A patent/JPS59111920A/ja active Granted

Also Published As

Publication number	Publication date
JPS6241174B2 (2)	1987-09-01

Publication	Publication Date	Title
TWI255811B (en)	2006-06-01	Process for the production of acrylic acid
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AU2002331372A1 (en)	2003-02-24	Catalyst and its use in the synthesis of hydrogen peroxide
CA2421363A1 (en)	2003-09-18	Method for preparing iron oxides
Ohshiro et al.	1983	Micelle enhanced oxidation of amines by coenzyme PQQ
FR2408573A1 (fr)	1979-06-08	Procede de preparation de l'acide terephtalique
CA2082976A1 (en)	1993-05-19	Catalytic production of aryl alkyl hydroperoxides by manganese complexes
Thiel	1999	New Routes to Hydrogen Peroxide: Alternatives for Established Processes?
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