JPS5917852U - クロマトグラフ - Google Patents
クロマトグラフInfo
- Publication number
- JPS5917852U JPS5917852U JP1983062817U JP6281783U JPS5917852U JP S5917852 U JPS5917852 U JP S5917852U JP 1983062817 U JP1983062817 U JP 1983062817U JP 6281783 U JP6281783 U JP 6281783U JP S5917852 U JPS5917852 U JP S5917852U
- Authority
- JP
- Japan
- Prior art keywords
- column
- carrier medium
- detector
- filament
- medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012530 fluid Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/26—Conditioning of the fluid carrier; Flow patterns
- G01N30/38—Flow patterns
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/62—Detectors specially adapted therefor
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/62—Detectors specially adapted therefor
- G01N30/64—Electrical detectors
- G01N30/66—Thermal conductivity detectors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N2030/022—Column chromatography characterised by the kind of separation mechanism
- G01N2030/025—Gas chromatography
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/26—Conditioning of the fluid carrier; Flow patterns
- G01N30/38—Flow patterns
- G01N2030/382—Flow patterns flow switching in a single column
- G01N2030/383—Flow patterns flow switching in a single column by using auxiliary fluid
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/62—Detectors specially adapted therefor
- G01N2030/621—Detectors specially adapted therefor signal-to-noise ratio
- G01N2030/625—Detectors specially adapted therefor signal-to-noise ratio by measuring reference material, e.g. carrier without sample
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Investigating Or Analyzing Materials Using Thermal Means (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
め要約のデータは記録されません。
Description
第1図は本考案に係るシングル・カラム流路を備えたガ
ス・クロマトグラフ全体のブロック図、第2図は本考案
に係るダブル・カラム流路を備えたガス・クロマトグラ
フ全体のブロック図、第3A図〜第3D図は第2図に示
された検出器85及び他の付属パイプの構造を説明した
図、第4図は本考案に係るガス・クロマトグラフを応用
した流体モニタ装置全体のブロック図である。 2:ストレージ・タンク、4:流量調節器、6:カラム
、8:試料導入部、30:検出器、34. 36:圧力
調節器、42,44,111.192:バルブ、46,
130:バルブ駆動回路、58゜132:記録計及び積
分器、82:カラム、84:キャリア・ガス・ボンベ、
85:検出器、94:試料導入部、97:カラム、10
4ニスイツチング・ガス・ボンベ、116:フィラメン
ト駆動回路及び検出回路、178:パイプ・ライン、1
81:熱伝導セル、186:基準ガス・タンク。
ス・クロマトグラフ全体のブロック図、第2図は本考案
に係るダブル・カラム流路を備えたガス・クロマトグラ
フ全体のブロック図、第3A図〜第3D図は第2図に示
された検出器85及び他の付属パイプの構造を説明した
図、第4図は本考案に係るガス・クロマトグラフを応用
した流体モニタ装置全体のブロック図である。 2:ストレージ・タンク、4:流量調節器、6:カラム
、8:試料導入部、30:検出器、34. 36:圧力
調節器、42,44,111.192:バルブ、46,
130:バルブ駆動回路、58゜132:記録計及び積
分器、82:カラム、84:キャリア・ガス・ボンベ、
85:検出器、94:試料導入部、97:カラム、10
4ニスイツチング・ガス・ボンベ、116:フィラメン
ト駆動回路及び検出回路、178:パイプ・ライン、1
81:熱伝導セル、186:基準ガス・タンク。
Claims (1)
- 分析すべき試料物質を含むキャリア媒体が導入されるカ
ラムと、フィラメントを通過する媒体の熱伝導率の変化
に対応した電気信号を発生する単一の熱伝導形検出器と
、前記カラムの出力媒体とキャリア媒体のみとを交互に
且つ周期的に前記フィラメントに送出する流体切換え手
段とより成り、前記切換え手段の切換えに応動して前記
検出器から送り出される電気信号の差信号をとりだすよ
うにしたことを特徴とするクロマトグラフ。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/730,559 US4254654A (en) | 1976-10-07 | 1976-10-07 | Modulated fluid detector |
| US730559 | 1991-07-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5917852U true JPS5917852U (ja) | 1984-02-03 |
| JPS6132369Y2 JPS6132369Y2 (ja) | 1986-09-20 |
Family
ID=24935847
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12084177A Pending JPS5346091A (en) | 1976-10-07 | 1977-10-07 | Chromatograph |
| JP1983062817U Granted JPS5917852U (ja) | 1976-10-07 | 1983-04-26 | クロマトグラフ |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12084177A Pending JPS5346091A (en) | 1976-10-07 | 1977-10-07 | Chromatograph |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US4254654A (ja) |
| JP (2) | JPS5346091A (ja) |
| DE (1) | DE2743519C2 (ja) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61172141U (ja) * | 1985-04-11 | 1986-10-25 | ||
| JPH0338393U (ja) * | 1989-08-28 | 1991-04-12 | ||
| JP2011169778A (ja) * | 2010-02-19 | 2011-09-01 | Yokogawa Electric Corp | 熱伝導度検出器 |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4185490A (en) * | 1978-10-06 | 1980-01-29 | Hewlett-Packard Company | Phase discrimination in modulated thermal conductivity detector |
| JPS5647883U (ja) * | 1979-09-17 | 1981-04-28 | ||
| US4316381A (en) * | 1980-07-14 | 1982-02-23 | Hewlett-Packard Company | Modulated detector |
| US4316382A (en) * | 1980-07-21 | 1982-02-23 | Hewlett-Packard Company | Detector with intermittent flow |
| US4464925A (en) * | 1982-05-17 | 1984-08-14 | Hewlett-Packard Company | Hydrogen, deuterium thermal conductivity detector |
| JPS60102558A (ja) * | 1983-11-04 | 1985-06-06 | バリアン・アソシエイツ・インコーポレイテツド | ガスクロマトグラフイーのための試料変調セル |
| US4670220A (en) * | 1984-03-07 | 1987-06-02 | Varian Associates, Inc. | Sample valve for solute modulated synchronous detection |
| US4735082A (en) * | 1986-07-14 | 1988-04-05 | Hewlett-Packard Company | Pulse modulated thermal conductivity detector |
| AT391211B (de) * | 1988-02-22 | 1990-09-10 | Voest Alpine Stahl | Einrichtung zum analysieren von gasen |
| US5038304A (en) * | 1988-06-24 | 1991-08-06 | Honeywell Inc. | Calibration of thermal conductivity and specific heat devices |
| US4956793A (en) * | 1988-06-24 | 1990-09-11 | Honeywell Inc. | Method and apparatus for measuring the density of fluids |
| US4944035A (en) * | 1988-06-24 | 1990-07-24 | Honeywell Inc. | Measurement of thermal conductivity and specific heat |
| US4970891A (en) * | 1989-12-26 | 1990-11-20 | Ethyl Corporation | Apparatus for measuring gaseous impurity in solids |
| US5187674A (en) * | 1989-12-28 | 1993-02-16 | Honeywell Inc. | Versatile, overpressure proof, absolute pressure sensor |
| US5177696A (en) * | 1989-12-28 | 1993-01-05 | Honeywell Inc. | Method of determination of gas properties at reference conditions |
| US5281256A (en) * | 1990-09-28 | 1994-01-25 | Regents Of The University Of Michigan | Gas chromatography system with column bifurcation and tunable selectivity |
| US5583282A (en) * | 1990-12-14 | 1996-12-10 | Millipore Investment Holdings Limited | Differential gas sensing in-line monitoring system |
| US5265459A (en) * | 1991-08-22 | 1993-11-30 | The Perkin Elmer Corporation | Single-element thermal conductivity detector |
| US5587520A (en) * | 1995-09-29 | 1996-12-24 | Hewlett-Packard Company | Thermal conductivity detector |
| DE10119788C2 (de) * | 2001-04-23 | 2003-08-07 | Siemens Ag | Wärmeleitfähigkeitsdetektor |
| CN100437111C (zh) * | 2005-04-21 | 2008-11-26 | 安捷伦科技有限公司 | 热导检测器热丝的保护 |
| US20080291966A1 (en) * | 2007-05-24 | 2008-11-27 | Engel Steven J | Thermal conductivity detector (TCD) having compensated constant temperature element |
| US7670046B2 (en) * | 2007-06-18 | 2010-03-02 | Iliya Mitov | Filled hotwire elements and sensors for thermal conductivity detectors |
| JP6446985B2 (ja) | 2014-10-10 | 2019-01-09 | 株式会社島津製作所 | 熱伝導度検出器及びガスクロマトグラフ |
| JP6394426B2 (ja) * | 2015-02-04 | 2018-09-26 | 株式会社島津製作所 | ガスクロマトグラフ |
| JP6658862B2 (ja) | 2016-03-07 | 2020-03-04 | 株式会社島津製作所 | 熱伝導度検出器 |
| US10458961B2 (en) | 2017-08-01 | 2019-10-29 | Shimadzu Corporation | Gas chromatograph |
| US11397156B2 (en) * | 2018-09-13 | 2022-07-26 | Shimadzu Corporation | Thermal conductivity detector |
| JP7447774B2 (ja) * | 2020-11-30 | 2024-03-12 | 株式会社島津製作所 | ガス分析装置およびガス分析装置の状態検出方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1954681A (en) * | 1932-09-22 | 1934-04-10 | Charles Engelhard Inc | Mounting block for gas analysis cells |
| US2255551A (en) * | 1938-07-30 | 1941-09-09 | Monocel Inc | Single cell thermal conductivity measurements |
| DE728194C (de) * | 1941-03-21 | 1942-11-21 | Ig Farbenindustrie Ag | Verfahren und Vorrichtung zur Bestimmung des Dichteunterschiedes zweier Gase |
| US3087112A (en) * | 1959-12-30 | 1963-04-23 | Engelhard Ind Inc | Trace gas analyzer |
| US3084536A (en) * | 1960-10-06 | 1963-04-09 | Foxboro Co | Split flow gas analysis detector |
| US3050983A (en) * | 1960-10-17 | 1962-08-28 | Dow Chemical Co | Thermoconductivity cell |
| JPS4919893A (ja) * | 1972-03-25 | 1974-02-21 | ||
| US3924442A (en) * | 1973-10-09 | 1975-12-09 | Kvb Equipment Corp | Pollutant variation correcting system |
| JPS5298594A (en) * | 1976-02-16 | 1977-08-18 | Hitachi Ltd | Simultaneous analyzer for nitrogen compounds and sulfur compounds |
| US4863489A (en) * | 1989-02-03 | 1989-09-05 | Texaco Inc. | Production of demercurized synthesis gas, reducing gas, or fuel gas |
-
1976
- 1976-10-07 US US05/730,559 patent/US4254654A/en not_active Expired - Lifetime
-
1977
- 1977-09-28 DE DE2743519A patent/DE2743519C2/de not_active Expired
- 1977-10-07 JP JP12084177A patent/JPS5346091A/ja active Pending
-
1983
- 1983-04-26 JP JP1983062817U patent/JPS5917852U/ja active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61172141U (ja) * | 1985-04-11 | 1986-10-25 | ||
| JPH0338393U (ja) * | 1989-08-28 | 1991-04-12 | ||
| JP2011169778A (ja) * | 2010-02-19 | 2011-09-01 | Yokogawa Electric Corp | 熱伝導度検出器 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2743519A1 (de) | 1978-04-13 |
| JPS5346091A (en) | 1978-04-25 |
| DE2743519C2 (de) | 1984-08-30 |
| US4254654A (en) | 1981-03-10 |
| JPS6132369Y2 (ja) | 1986-09-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5917852U (ja) | クロマトグラフ | |
| JPS58158357U (ja) | 腐食作用の強い媒体における酸素活性化量を連続的に求めるための電気化学的測定装置 | |
| JPS59153765U (ja) | 油圧シリンダのシ−ル監視装置 | |
| JPS60111247U (ja) | メンブレン式低温タンクのアンモニア試験用配管 | |
| JPS58101168U (ja) | 溶存酸素測定装置 | |
| JPS60107480U (ja) | 吹出安全弁動作検知装置 | |
| JPS5989278U (ja) | 試料液体の採取・希釈装置 | |
| JPS6095536U (ja) | 感温筒取付装置 | |
| JPS5851390U (ja) | 差動分布型熱感知器 | |
| JPS6037862U (ja) | ガスクロマトグラフ | |
| JPS58112944U (ja) | 海水圧測定装置の計測座の保守装置 | |
| JPS5874143U (ja) | 温度検知装置 | |
| JPS6189133U (ja) | ||
| JPS6093942U (ja) | ナトリウム漏洩検出装置 | |
| JPS59185655U (ja) | 熱電対を用いた異常検出機構 | |
| JPS60135651U (ja) | ナトリウム漏洩検出装置 | |
| JPS5842620U (ja) | 流量測定装置 | |
| JPS5982832U (ja) | 漏洩検出装置 | |
| JPS58155810U (ja) | 超電導コイルのクエンチ検出装置 | |
| JPS58107497U (ja) | 熱交換器の汚染検知装置 | |
| JPS5971169U (ja) | ガスクロマトグラフ | |
| JPS5836336U (ja) | ナトリウム漏洩検出装置 | |
| JPS5860246U (ja) | 温度検出器の試験装置 | |
| JPS6351497U (ja) | ||
| JPS5834019U (ja) | 車両用液化ガスの流量測定装置 |