JPS59216634A - 低スチ−ム操業に耐えるエチルベンゼン脱水素用触媒 - Google Patents

低スチ−ム操業に耐えるエチルベンゼン脱水素用触媒

Info

Publication number: JPS59216634A
Authority: JP; Japan
Prior art keywords: metal carbonate; catalyst; alkaline earth; alkali metal; earth metal
Prior art date: 1983-05-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP58091965A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0446182B2 (fr

Inventor

Taketoku Hirano

竹徳平野

Hidemi Unei

運永　秀美

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sued Chemie Catalysts Japan Inc

Original Assignee

Nissan Girdler Catalysts Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-05-25

Filing date

1983-05-25

Publication date

1984-12-06

1983-05-25 Application filed by Nissan Girdler Catalysts Co Ltd filed Critical Nissan Girdler Catalysts Co Ltd

1983-05-25 Priority to JP58091965A priority Critical patent/JPS59216634A/ja

1984-12-06 Publication of JPS59216634A publication Critical patent/JPS59216634A/ja

1992-07-29 Publication of JPH0446182B2 publication Critical patent/JPH0446182B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 64
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 title claims description 30
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 19
-1 alkaline earth metal carbonate Chemical class 0.000 claims abstract description 18
229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 15
229910000288 alkali metal carbonate Inorganic materials 0.000 claims abstract description 11
150000008041 alkali metal carbonates Chemical class 0.000 claims abstract description 11
238000006356 dehydrogenation reaction Methods 0.000 claims abstract description 9
239000012752 auxiliary agent Substances 0.000 claims abstract 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 34
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 20
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract description 18
239000001095 magnesium carbonate Substances 0.000 abstract description 18
229910000021 magnesium carbonate Inorganic materials 0.000 abstract description 18
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical group [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 14
229910000019 calcium carbonate Inorganic materials 0.000 abstract description 10
229910000027 potassium carbonate Inorganic materials 0.000 abstract description 7
235000014380 magnesium carbonate Nutrition 0.000 abstract 3
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
235000010216 calcium carbonate Nutrition 0.000 abstract 1
230000003197 catalytic effect Effects 0.000 abstract 1
229910000421 cerium(III) oxide Inorganic materials 0.000 abstract 1
235000015320 potassium carbonate Nutrition 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 28
229910052700 potassium Inorganic materials 0.000 description 17
239000000203 mixture Substances 0.000 description 14
230000000694 effects Effects 0.000 description 11
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 10
239000011591 potassium Substances 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
QXQZBDRCFKSYAA-UHFFFAOYSA-N [Cr].[K].[Fe] Chemical compound [Cr].[K].[Fe] QXQZBDRCFKSYAA-UHFFFAOYSA-N 0.000 description 9
DIGZKZLYDYJFHH-UHFFFAOYSA-N [K].[Mo].[Ce].[Fe] Chemical compound [K].[Mo].[Ce].[Fe] DIGZKZLYDYJFHH-UHFFFAOYSA-N 0.000 description 7
230000000052 comparative effect Effects 0.000 description 6
230000007423 decrease Effects 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
239000011148 porous material Substances 0.000 description 5
238000000034 method Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
229910000420 cerium oxide Inorganic materials 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
229910000476 molybdenum oxide Inorganic materials 0.000 description 3
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
229910000423 chromium oxide Inorganic materials 0.000 description 2
230000006866 deterioration Effects 0.000 description 2
238000010304 firing Methods 0.000 description 2
239000008188 pellet Substances 0.000 description 2
229910052596 spinel Inorganic materials 0.000 description 2
239000011029 spinel Substances 0.000 description 2
VMSLCPKYRPDHLN-UHFFFAOYSA-N (R)-Humulone Chemical compound CC(C)CC(=O)C1=C(O)C(CC=C(C)C)=C(O)C(O)(CC=C(C)C)C1=O VMSLCPKYRPDHLN-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
WKNIDMJWLWUOMZ-UHFFFAOYSA-N [K].[Cr] Chemical compound [K].[Cr] WKNIDMJWLWUOMZ-UHFFFAOYSA-N 0.000 description 1
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
229910000272 alkali metal oxide Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
239000003575 carbonaceous material Substances 0.000 description 1
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910000018 strontium carbonate Inorganic materials 0.000 description 1
238000010998 test method Methods 0.000 description 1
229910001935 vanadium oxide Inorganic materials 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP58091965A 1983-05-25 1983-05-25 低スチ−ム操業に耐えるエチルベンゼン脱水素用触媒 Granted JPS59216634A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP58091965A JPS59216634A (ja)	1983-05-25	1983-05-25	低スチ−ム操業に耐えるエチルベンゼン脱水素用触媒

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP58091965A JPS59216634A (ja)	1983-05-25	1983-05-25	低スチ−ム操業に耐えるエチルベンゼン脱水素用触媒

Publications (2)

Publication Number	Publication Date
JPS59216634A true JPS59216634A (ja)	1984-12-06
JPH0446182B2 JPH0446182B2 (fr)	1992-07-29

Family

ID=14041258

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP58091965A Granted JPS59216634A (ja)	1983-05-25	1983-05-25	低スチ−ム操業に耐えるエチルベンゼン脱水素用触媒

Country Status (1)

Country	Link
JP (1)	JPS59216634A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS62158227A (ja) *	1985-12-27	1987-07-14	シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ	脱水素触媒、それらの製造法並びに非酸化的脱水素法
US5824831A (en) *	1993-11-11	1998-10-20	Idemitsu Petrochemical Co., Ltd.	Catalyst for dehydrogenation of alkyl aromatic hydrocarbon and process for producting vinyl aromatic hydrocarbon using the same

1983
- 1983-05-25 JP JP58091965A patent/JPS59216634A/ja active Granted

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS62158227A (ja) *	1985-12-27	1987-07-14	シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ	脱水素触媒、それらの製造法並びに非酸化的脱水素法
US5824831A (en) *	1993-11-11	1998-10-20	Idemitsu Petrochemical Co., Ltd.	Catalyst for dehydrogenation of alkyl aromatic hydrocarbon and process for producting vinyl aromatic hydrocarbon using the same

Also Published As

Publication number	Publication date
JPH0446182B2 (fr)	1992-07-29

Publication	Publication Date	Title
US4088736A (en)	1978-05-09	Process for purifying a gas containing hydrogen sulfide and contact masses usable therefor
US4220560A (en)	1980-09-02	Spinel dehydrogenation catalyst
CA1208622A (fr)	1986-07-29	Catalyseurs pour la deshydrogenation du para-ethyltoluene
US4176140A (en)	1979-11-27	Dehydrogenation of hydrocarbons with zinc titanate catalyst
CA2101388C (fr)	2000-02-22	Methode et catalyseur pour l'oxychloration de l'ethylene
RU1836141C (ru)	1993-08-23	Катализатор дл дегидрировани этилбензола в стирол
US7435703B2 (en)	2008-10-14	Catalyst comprising iron oxide made by heat decomposition of an iron halide and a lanthanide
US3951869A (en)	1976-04-20	Modified zinc ferrite oxidative dehydrogenation catalysts
US4467046A (en)	1984-08-21	Dehydrogenation catalyst
US4749674A (en)	1988-06-07	Catalyst for the non-oxidative dehydrogenation of alkylbenzene to alkenylbenzene
EP0177832B1 (fr)	1989-04-26	Catalyseur de déshydrogénation
US3901947A (en)	1975-08-26	Production of 2,6-xylenol
US4310442A (en)	1982-01-12	Supported silver catalysts mixed with promoter metal compounds for the production of ethylene oxide
JPS59216634A (ja)	1984-12-06	低スチ−ム操業に耐えるエチルベンゼン脱水素用触媒
US4228040A (en)	1980-10-14	Lithium- or magnesium-promoted zinc titanate catalyst for dehydrogenation of hydrocarbons
JPH08281115A (ja)	1996-10-29	Ｎ−（１−アルキルオキシアルキル）カルバメート類の気相分子内脱アルコール反応用触媒およびｎ−ビニルカルバメート類の製造方法
US5510553A (en)	1996-04-23	Catalytic dehydrogenation of alkylaromatic hydrocarbons
US7262148B2 (en)	2007-08-28	Catalyst for production of unsaturated aldehyde and unsaturated carboxylic acid, and process for its production
US4414135A (en)	1983-11-08	Silver-based catalyst containing bromine and/or fluorine as an anionic component for the production of ethylene oxide
JPS6244536B2 (fr)	1987-09-21
US4370259A (en)	1983-01-25	Oxidative dehydrogenation catalyst
US3005033A (en)	1961-10-17	Polymerization of olefins
US4433186A (en)	1984-02-21	Catalysts for para-ethyltoluene dehydrogenation
US3960773A (en)	1976-06-01	Catalyst compositions and their preparation
US3378591A (en)	1968-04-16	Production of 1-naphthol

JPS59216634A - 低スチ−ム操業に耐えるエチルベンゼン脱水素用触媒 - Google Patents

Info

Links

Classifications

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=14041258

Family Applications (1)

Country Status (1)

Cited By (2)

Cited By (2)

Also Published As

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