JPS5937653A - Nonaqueous solvent battery - Google Patents

Nonaqueous solvent battery

Info

Publication number
JPS5937653A
JPS5937653A JP57148893A JP14889382A JPS5937653A JP S5937653 A JPS5937653 A JP S5937653A JP 57148893 A JP57148893 A JP 57148893A JP 14889382 A JP14889382 A JP 14889382A JP S5937653 A JPS5937653 A JP S5937653A
Authority
JP
Japan
Prior art keywords
battery
lead terminal
positive electrode
negative electrode
pin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57148893A
Other languages
Japanese (ja)
Inventor
Koichi Tanaka
浩一 田中
Shintaro Suzuki
信太郎 鈴木
Koji Fujita
宏次 藤田
Fumiko Honma
本間 富美子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FDK Twicell Co Ltd
Original Assignee
Toshiba Battery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Battery Co Ltd filed Critical Toshiba Battery Co Ltd
Priority to JP57148893A priority Critical patent/JPS5937653A/en
Publication of JPS5937653A publication Critical patent/JPS5937653A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/534Electrode connections inside a battery casing characterised by the material of the leads or tabs
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Abstract

PURPOSE:To simplify the assembly process, enhance the high-volume production capability and increase the battery characteristic of a nonaqueuous solvent battery by bringing a pin-like lead terminal and a current collecting member into connection with each other. CONSTITUTION:A negative lead terminal 17 and a current colecting member 15 can be unified by only connecting the end part of the lead terminal 17 to the current collecting member 15. Therefore, in practically assembling a battery, a first positive electrode 12a, a non-woven fabric 13a, a negative electrode 14 having the current collecting member 15, a non-woven fabric 13c and a second positive electrode 12b are stacked in that order in a case body 11a before the opening of the case body 11a is closed with a lid body 11b having a pin-like lead terminal 17. Thus, the process of the assembly can be greatly simplified.

Description

【発明の詳細な説明】 この発明は内部構造を改良した非水溶媒電池に関するも
のである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a non-aqueous solvent battery with an improved internal structure.

リチウム、ナトリウムなどの軽金属を負極とした非水溶
媒電池は周知の酸化銀電池、アルカリ・マンガン電池な
どと比べてエネルギー密度が高く。
Nonaqueous solvent batteries with light metals such as lithium and sodium as negative electrodes have a higher energy density than well-known silver oxide batteries, alkaline manganese batteries, etc.

しかも高信頼性を有するなどの理由から近時小形のiL
子(幾器などに多く用いられる傾向にある。
Moreover, due to its high reliability, small iL
It tends to be used a lot for ko (Ikuware).

ところで、このような非水溶媒電池は所謂細形と呼ばれ
電池容器の両面が夫々正負極のリード端子を兼ねた形状
ものがほとんどであったが、最近重負荷放電特性の向上
や大容量化を月相したり。
By the way, most of these non-aqueous solvent batteries are so-called narrow type, with both sides of the battery container serving as lead terminals for the positive and negative electrodes, respectively, but recently they have improved heavy load discharge characteristics and increased capacity. The moon phase.

あるいは利用者の様々な電池形状の要求に答えるべく正
負極のいずれか一方のリードを電池容器に兼ねさせ、他
の極のリードとして金属性のピン状端子を′4池容器よ
り絶縁体を介在させて突設するようにしたものが考えら
れている。
Alternatively, in order to meet the demands of users for various battery shapes, one of the positive and negative electrode leads can also be used as a battery container, and a metal pin-shaped terminal can be used as the lead for the other electrode with an insulator interposed from the battery container. It is being considered that the structure is installed protrudingly.

しかして、従来この種構造の電池として第1図に示すよ
うに正極リード端子を兼ねた電池容器1a。
As shown in FIG. 1, a conventional battery having this type of structure has a battery container 1a which also serves as a positive electrode lead terminal.

lb内に円板状に成形された第1の正極2aと中空円板
状に成形された第2の正極2bとの間にポリプロピレン
製などの不織布3a、3bを介して片面にニッケル製金
網などの集電体4を圧着した金属リチウムの中空円板状
負極5を介在させてなる内容物を収容するとともに負極
5のリードとして一端部を覗池容i?B]bの中心部に
合成樹脂などのシール6を介して支持される吉ともに他
端を第2の正極2bの中空部を介して集電体4にスポッ
ト溶接したピン状のリード端子7を設けたものがある。
A wire mesh made of nickel or the like is placed on one side of the first positive electrode 2a formed in the shape of a disk and a second positive electrode 2b formed in the shape of a hollow disk through nonwoven fabrics 3a and 3b made of polypropylene or the like. A hollow disc-shaped negative electrode 5 made of metal lithium is interposed with a current collector 4 crimped to accommodate the contents, and one end is used as a lead of the negative electrode 5 to serve as a peephole. B] A pin-shaped lead terminal 7 is supported through a seal 6 made of synthetic resin or the like in the center of b, and the other end is spot-welded to the current collector 4 through the hollow part of the second positive electrode 2b. There is something set up.

ところが、このものは負匝リードたるピン状のリード端
子7を集(体4にスポットa接する構造をなしているた
め実際に電池を組立てるにあたって次の手順をとらなけ
ればならなかった。まず。
However, since this product has a structure in which the pin-shaped lead terminal 7, which is a negative lead, is brought into contact with the body 4 at a spot a, the following steps had to be taken when actually assembling the battery.

シール6を介して負tilA IJ−ド端子7を支持し
た電池容器1bを裏返しにして用意し、これに中空円板
状の正極2bおよび不織布3bを載せて電解液を注液し
、ざらに集電体4を圧着した負極5を載せる。この場合
負極5は中空円板状をなすためこの中空部を介して集電
体4が露出するので、この中空部を介して喚電体4と負
極リード端子7とのスポット溶接を行なう。一方電池容
器la中に円板状の正極2aを挿入し、この上に不織布
3aを載せて電解液を注液する。この状態で上記正極2
b。
A battery container 1b supporting a negative terminal 7 through a seal 6 is prepared by turning it upside down, and a hollow disc-shaped positive electrode 2b and a nonwoven fabric 3b are placed thereon, and an electrolyte is poured into the container to collect it roughly. Place the negative electrode 5 on which the electric body 4 is crimped. In this case, since the negative electrode 5 has a hollow disc shape, the current collector 4 is exposed through this hollow part, and therefore the current collector 4 and the negative electrode lead terminal 7 are spot welded through this hollow part. On the other hand, a disk-shaped positive electrode 2a is inserted into the battery container la, a nonwoven fabric 3a is placed on top of the positive electrode 2a, and an electrolyte is poured into the positive electrode 2a. In this state, the positive electrode 2
b.

不織布3a、負極5を積み重ねた電池容器1bを反転し
て電池容器la上にかぶせ周縁をレーザ等で溶接し、も
って電池を完成している。
The battery container 1b in which the nonwoven fabric 3a and the negative electrode 5 are stacked is inverted, placed over the battery container la, and the peripheral edges are welded using a laser or the like, thereby completing the battery.

したがって、このような従来の構成の電池にあっては集
電体き負極リード端子とのスポット溶接の作業が複雑で
あるだけでなく、電池容器の反転工程を有するなど組立
て手順そのものも混み入ったものとなり量産性に乏しい
欠点があった。また。
Therefore, in batteries with such conventional configurations, not only is the spot welding work between the current collector and the negative electrode lead terminal complicated, but the assembly procedure itself is also complicated, including the process of reversing the battery container. The drawback was that it was not suitable for mass production. Also.

電池容器の反転工程を有することは特に負極+J −ド
端子周辺の空隙を電解液で充分溝すことが難しく、シか
も組立て工程全体に手数と時間がかかるのでこの間に多
量の電解液が揮散されてしまいこの結果電池内の電解液
が不足し、これが原因で電池特性の劣化を招く欠点があ
った。
Having the process of reversing the battery container makes it difficult to fully fill the voids around the negative electrode + J - terminal with electrolyte, and the entire assembly process also takes time and effort, so a large amount of electrolyte is volatilized during this process. As a result, there is a shortage of electrolyte in the battery, which has the disadvantage of causing deterioration of battery characteristics.

この発明は上記欠点を除去するためなされたものでピン
状リード端子と集電体を係着させる構成とすることによ
り組立工程を簡単化し得、量産性の向上を図ることがで
き、しかも電池特性の向上をも図り得る非水溶媒電池を
提供するこ吉を目的とする。
This invention was made in order to eliminate the above-mentioned drawbacks, and by adopting a structure in which the pin-shaped lead terminal and the current collector are connected, the assembly process can be simplified, mass productivity can be improved, and battery characteristics can be improved. The purpose of Kokichi is to provide a non-aqueous solvent battery that can also improve performance.

以下、この発明の一実施例を図面に従い説明する。An embodiment of the present invention will be described below with reference to the drawings.

第2図において% 11は正極リード端子を兼ねたステ
ンレスなどからなる偏平形の電池容器で。
In Figure 2, %11 is a flat battery container made of stainless steel that also serves as the positive lead terminal.

この容器11は開口部を有する本体11aとこの本体1
1aの開口部を閉塞する蓋体11bからなっている。容
器本体11a内に円板状に成形した第1の正極12aを
挿入している。ここで、IE極12aは400℃で焼成
した二酸化マンガンに導・4材と結着剤を加えbo圧成
形したものである。この正412a上に炭酸プロピレン
と1.2−ジメトキシエタンとを体積比1:1に混合し
た溶媒に過塩素酸リチウムl mo 1を溶解させてな
る非水溶媒の電解液を含浸させたポリプロピレン製不織
布13aを介して金属リチウムなどの軽金属からなる負
極14を積層している。
This container 11 has a main body 11a having an opening and a main body 1
It consists of a lid 11b that closes the opening of 1a. A first positive electrode 12a shaped like a disk is inserted into the container body 11a. Here, the IE electrode 12a is made of manganese dioxide fired at 400° C., a conductive material and a binder added thereto, and then subjected to Bo pressure molding. Made of polypropylene impregnated with a non-aqueous electrolyte solution made by dissolving 1 mo 1 of lithium perchlorate in a solvent mixed with propylene carbonate and 1,2-dimethoxyethane at a volume ratio of 1:1 on this 412a. A negative electrode 14 made of a light metal such as metallic lithium is laminated via a nonwoven fabric 13a.

この負極14は中心部に切欠部141を有するとともに
片面にニッケル製金網などの集電体15を圧着している
。この場合集電体15は負極14の切欠部141に対応
する部分に後述するリード端子17先端を係着するため
の小孔又は切り込みなどからなる係着手段151を有し
ている。(ここで、上記係着手段151が小孔の場合、
この小孔は上記リード端子17の直径よりわずかに小さ
いものとする必要がある。) 負仮14の集電体15上に上述同様電解液を含浸させた
ポリプロピレン製不織布13bを介して上記第1の正極
12aと同道加圧成形された$2の正極12bを載11
tシている。この場合不織布13bおよび第2の正極1
2bは中心部に切欠孔13bl 、12blを夫々形成
している。
This negative electrode 14 has a notch 141 in the center, and a current collector 15 such as a nickel wire mesh is crimped onto one side. In this case, the current collector 15 has a fastening means 151 in a portion corresponding to the notch 141 of the negative electrode 14, which is a small hole or notch for fastening the tip of a lead terminal 17, which will be described later. (Here, if the above-mentioned fastening means 151 is a small hole,
This small hole needs to be slightly smaller than the diameter of the lead terminal 17. ) On the current collector 15 of the negative temporary 14, a positive electrode 12b of $2, which was pressure-molded in the same way as the first positive electrode 12a, was placed 11 through a polypropylene nonwoven fabric 13b impregnated with an electrolytic solution as described above.
There is a t-shi. In this case, the nonwoven fabric 13b and the second positive electrode 1
2b has cutout holes 13bl and 12bl formed in the center, respectively.

一方、上記容器11の蓋体11bの中心部に合成樹脂な
どの絶縁体シール16を介して負極リードとしてピン状
リード端子17を突設している。
On the other hand, a pin-shaped lead terminal 17 as a negative electrode lead is provided protruding from the center of the lid 11b of the container 11 via an insulating seal 16 made of synthetic resin or the like.

そして、このようにピン状リード端子17を有する蓋体
11bにで本体11aの開口部を閉塞し周縁をレーザに
て溶接し封口している。この場合IJ−ド端子17は上
記第2の正極12bの切欠部12bl。
Then, the opening of the main body 11a is closed with the lid 11b having the pin-shaped lead terminal 17 as described above, and the peripheral edge is welded using a laser to seal the opening. In this case, the IJ-do terminal 17 is the notch 12bl of the second positive electrode 12b.

不織布13bの切欠部13b1を通って容器11aの中
心部に挿入されるとともに先端部を集電体15の係着手
段151の例えば小孔中に押し込まれ同集電体15に一
体的に係着される。
It is inserted into the center of the container 11a through the notch 13b1 of the nonwoven fabric 13b, and its tip is pushed into, for example, a small hole in the attachment means 151 of the current collector 15, and is integrally attached to the current collector 15. be done.

しかして、このような構成によると、負極のリード端子
17の先端部を集電体15に係着させるだけで両者を一
体化することができるので実際に電池を組立てるにあた
っCは容器本体11a内に第1の正極12a、不織布1
3a、集電体15を有する負極14.不織布13bおよ
び第2の正極12bを順に積層し、最後にピン状リード
端子17を有する蓋体11bにて本体11aの開口部を
閉じるだけの工程となりその組立で工程を飛躍的に簡単
化でき。
According to such a configuration, the two can be integrated by simply attaching the tip of the negative electrode lead terminal 17 to the current collector 15, so that when actually assembling the battery, C is connected to the container body 11a. A first positive electrode 12a, a nonwoven fabric 1 inside
3a, a negative electrode 14 having a current collector 15; The assembly process can be dramatically simplified by simply laminating the nonwoven fabric 13b and the second positive electrode 12b in order, and finally closing the opening of the main body 11a with the lid 11b having the pin-shaped lead terminal 17.

量産化の著しい向上を図ることができる。また。Mass production can be significantly improved. Also.

蓋体1・1bを閉じる前に容器11a内の空隙つまり正
極12a、12b負極14と容器11a内壁間や負極リ
ード端子17周辺の空隙に充分電解液を満すことかで〜
き、しかも上述のように組立工程の簡単化により組立に
要する手数1時間を大巾に縮めることができるので、か
かる工程中の電解液の揮散をも抑制することができ、こ
れにより電池容器内空隙に充分の電解液を封入すること
ができ電池特性の向上をも図ることができる。ちなみに
本発明電池(A)と従来例電池CB)について15Ω連
続放電のもとて電極の放電利用率を比較したところ第3
図に示す結果が得られた。第3図によると、従来例電池
CB)では終止電圧2.5Vで約50%の利用率しか示
さなかったが、本発明電池で′は終止電圧2.5vで約
80チの高利用率を示し、電極の放電利用率を大巾に向
上させることができることが実証された。
Before closing the lids 1 and 1b, be sure to sufficiently fill the void in the container 11a, that is, the void between the positive electrodes 12a, 12b negative electrode 14 and the inner wall of the container 11a, and around the negative electrode lead terminal 17.
Moreover, as mentioned above, the simplification of the assembly process can greatly reduce the number of hours required for assembly, and the volatilization of the electrolyte during this process can also be suppressed. A sufficient amount of electrolyte can be filled in the void, and battery characteristics can also be improved. By the way, when we compared the discharge utilization rate of the electrode under 15Ω continuous discharge for the battery of the present invention (A) and the conventional battery CB), the third
The results shown in the figure were obtained. According to Fig. 3, the conventional battery CB) showed a utilization rate of only about 50% at a final voltage of 2.5V, but the battery of the present invention showed a high utilization rate of about 80% at a final voltage of 2.5V. It was demonstrated that the discharge utilization rate of the electrode could be greatly improved.

なお、この発明は上記実施例にのみ限定されず要旨を変
更しない範囲で適宜変形して実施できる。
It should be noted that the present invention is not limited to the above-mentioned embodiments, but can be implemented with appropriate modifications without changing the gist.

例えば上述では電池容器11を正極リード端子とし、ピ
ン状のリード端子17を負極リード端子としているが、
電池容器を負極リード端子とし、ピン状のリード端子を
正極リード端子とした電池にも適用できる。勿論正極、
負極ともにピン状IJ −ド端子にしたものにも適用で
きる。また集成体15とリード端子17の係着はリード
端子17の先端に鋭角状の突起を設けこれを集電体15
面にくい込ませるようにしてもよい。さら屹上述では偏
平形のものについて述べたが、筒状の電池にも適用する
こともできる。
For example, in the above description, the battery container 11 is used as the positive electrode lead terminal, and the pin-shaped lead terminal 17 is used as the negative electrode lead terminal.
It can also be applied to batteries in which the battery container is used as a negative lead terminal and the pin-shaped lead terminal is used as a positive lead terminal. Of course the positive electrode,
It can also be applied to a device in which both the negative electrode and the negative electrode are pin-shaped IJ-de terminals. Further, in order to connect the assembly 15 and the lead terminal 17, an acute-angled protrusion is provided at the tip of the lead terminal 17, and this is connected to the current collector 15.
It may be embedded into the surface. In the above, a flat type battery was described, but it can also be applied to a cylindrical battery.

以上述べたようにこの発明によればピン状IJ−ド端子
と集成体を係着させる構成さすることにより組立工・囚
を簡単化し得、壕産(生の向上を図ることができ、しか
も電池特性の向上をも図り得る非水溶媒電池を提供でき
る。
As described above, according to the present invention, by attaching the pin-shaped IJ-do terminal to the assembly, assembly workers and assemblies can be simplified, trench production (productivity) can be improved, and It is possible to provide a non-aqueous solvent battery that can also improve battery characteristics.

【図面の簡単な説明】[Brief explanation of drawings]

;g1図は従来の非水溶媒4池の一例を示す概略的構成
図、第2図はこの発明の一実施例を示す概略的信成図、
43図は同実施例を説明するための特性図Cある。 la、lb・・・電池容器    2a 、2b・・・
正極3a、3b・・・不織布     4・・・集′成
体5・・・負極        6・・・シール7・・
・リード端子    11・・・電池容器11a・・・
本体      11b・・・蓋体12a、 12b 
−・・正4&     13a、 13b −・不織布
12bi 、13bl・・・切欠部  14・・・負極
141・・・切欠部     15・・・集電体151
・・・係着手段    16・・・シール17・・・リ
ード端子 被筐 〉
;G1 is a schematic configuration diagram showing an example of a conventional four-cell non-aqueous solvent; FIG. 2 is a schematic diagram showing an embodiment of the present invention;
FIG. 43 is a characteristic diagram C for explaining the same embodiment. la, lb... battery container 2a, 2b...
Positive electrodes 3a, 3b...nonwoven fabric 4...aggregate 5...negative electrode 6...seal 7...
・Lead terminal 11...Battery container 11a...
Main body 11b...lid 12a, 12b
--Positive 4 & 13a, 13b --Nonwoven fabric 12bi, 13bl...Notch 14...Negative electrode 141...Notch 15...Current collector 151
... Attachment means 16 ... Seal 17 ... Lead terminal housing >

Claims (3)

【特許請求の範囲】[Claims] (1)  電池容器内に正極、負極を積層して収容し。 且つ正極、負極の少なくとも一方の電極のIJ−ド端子
として上記電池容器より突出されるピン状リード端子を
用いたものにおいて、上記少なくとも一方の電極の集電
体と上記リード端子の先端部を係着する手段を有するこ
とを特徴とする非水溶媒電池。
(1) A positive electrode and a negative electrode are stacked and housed in a battery container. Further, in the case where a pin-shaped lead terminal protruding from the battery container is used as an IJ terminal for at least one of the positive electrode and the negative electrode, the current collector of the at least one of the electrodes and the tip of the lead terminal are connected. A non-aqueous solvent battery characterized by having means for attaching the battery.
(2)上記係着手段は上記集電体に設けられた上記リー
ド端子の直径よりわずかlこ小さい小孔からなることを
特徴とする特許請求の範囲第1項又は第2項記載の非水
溶媒電池。
(2) A non-aqueous non-aqueous solution according to claim 1 or 2, characterized in that the anchoring means comprises a small hole slightly smaller than the diameter of the lead terminal provided in the current collector. Solvent battery.
(3)上記係着手段は上記鍵屯体に設けられた切り込み
からなることを特徴とする特許請求の範囲第1項又は第
2項記載の非水溶媒電池。
(3) The non-aqueous solvent battery according to claim 1 or 2, wherein the locking means comprises a notch provided in the key box.
JP57148893A 1982-08-26 1982-08-26 Nonaqueous solvent battery Pending JPS5937653A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57148893A JPS5937653A (en) 1982-08-26 1982-08-26 Nonaqueous solvent battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57148893A JPS5937653A (en) 1982-08-26 1982-08-26 Nonaqueous solvent battery

Publications (1)

Publication Number Publication Date
JPS5937653A true JPS5937653A (en) 1984-03-01

Family

ID=15463044

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57148893A Pending JPS5937653A (en) 1982-08-26 1982-08-26 Nonaqueous solvent battery

Country Status (1)

Country Link
JP (1) JPS5937653A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6219047U (en) * 1985-07-17 1987-02-04
JPS6353854A (en) * 1986-07-18 1988-03-08 エバ−レデイ バツテリ− カンパニ− インコ−ポレ−テツド Electrochemical battery
JPH02241335A (en) * 1989-03-14 1990-09-26 Takaoka Electric Mfg Co Ltd Commercial synchronous circuit

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6219047U (en) * 1985-07-17 1987-02-04
JPS6353854A (en) * 1986-07-18 1988-03-08 エバ−レデイ バツテリ− カンパニ− インコ−ポレ−テツド Electrochemical battery
JPH02241335A (en) * 1989-03-14 1990-09-26 Takaoka Electric Mfg Co Ltd Commercial synchronous circuit

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